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Distribution and exploration direction of medium-and large-sized marine carbonate gas fields in Sichuan Basin, SW China 被引量:20
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作者 MA Xinhua YANG Yu +1 位作者 WEN Long LUO Bing 《Petroleum Exploration and Development》 2019年第1期1-15,共15页
Based on the analysis of the basic characteristics of medium-and large-sized marine gas fields in Sichuan Basin, combined with the division of major reservoir forming geological units in the marine craton stage and th... Based on the analysis of the basic characteristics of medium-and large-sized marine gas fields in Sichuan Basin, combined with the division of major reservoir forming geological units in the marine craton stage and their control on key hydrocarbon accumulation factors, the distribution law of medium-and large-sized marine carbonate gas fields in the basin was examined and the exploration direction was pointed out. Through the analysis of the periodic stretching-uplifting background, it is concluded that five large scale paleo-rifts, three large scale paleo-uplifts, five large scale paleo erosion surfaces were formed in the marine craton stage of Sichuan Basin, and these geological units control the key reservoir forming factors of medium and large sized gas fields:(1) Large-scale paleo-rifts control the distribution of high-quality hydrocarbon generation centers.(2) The margin of large-scale paleo-rifts, high position of paleo-uplifts and paleo erosion surfaces control the distribution of high-quality reservoirs.(3) Large-scale paleo-rifts, paleo-uplifts, paleo erosion surfaces and present tectonic setting jointly control the formation of many types of large and medium-sized traps.(4) Natural gas accumulation is controlled by the inheritance evolution of traps in large geological units. Based on the comparative analysis of the distribution characteristics of medium-and large-sized gas fields and large geological units, it is proposed that the superimposition relationship between single or multiple geological units and the present structure controls the distribution of medium-and large-sized gas fields, and the "three paleo" superimposed area is the most advantageous. According to the above rules, the main exploration fields and directions of medium-and large-sized marine carbonate gas fields in Sichuan Basin include periphery of Deyang-Anyue paleo-rift, eastern margin of Longmenshan paleo-rift, margins of Kaijiang-Liangping oceanic trough and Chengkou-western Hubei oceanic trough, the high part of the subaqueous paleo-uplifts around Central Sichuan, paleo erosion surfaces of the top boundary of Maokou Formation in eastern and southern Sichuan Basin, paleo erosion surfaces of the top boundary of the Leikoupo Formation in central and western Sichuan Basin. 展开更多
关键词 Sichuan Basin marine CARBONATES medium-and large-sized gas fields GEOLOGIC unit reservoir forming factors paleo-rifts paleo-uplifts paleo erosion surfaces
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Rolling Fatigue Test of Large-Sized UHPC Member for Cable Stayed Bridge 被引量:3
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作者 Jeong-Rae Cho Young Jin Kim +2 位作者 Jong Sup Park Eun Suk Choi Won Jong Chin 《Engineering(科研)》 2012年第10期646-654,共9页
Recently, research strives to apply Ultra High Performance Concrete (UHPC) to large-sized structures owing to its remarkable mechanical performance and durability compared to normal concrete. The Korea Institute of Co... Recently, research strives to apply Ultra High Performance Concrete (UHPC) to large-sized structures owing to its remarkable mechanical performance and durability compared to normal concrete. The Korea Institute of Construction Technology proposed SuperBridge800, an edge girder type UHPC cable stayed bridge with central span of 800 m, through its detailed design. The bridge is designed to be erected through the connection of precast UHPC segments. The precast UHPC segment is monolithically composed of one ribbed deck slab and edge girders at each side. The connection between the precast segments is achieved by steel bars at the edge girders and by UHPC cast-in-place wet joint at the slab. Despite of the outstanding mechanical performance of UHPC, the fabrication of large-sized members is a difficult task since UHPC hardens faster than normal concrete and requires a special curing process. Therefore, the constructability of large-sized UHPC segment should be secured to achieve SuperBridge800. Besides, the performance of the connection between segments should also be guaranteed, especially in terms of the fatigue performance of the UHPC cast-in-place joint, which constitutes a weak point. To that goal, two half-scaled UHPC segments are manufactured and the constructability is examined by fabricating a large-sized UHPC member connected with respect to the design conditions. This study conducts rolling fatigue test on the so-fabricated large-sized UHPC member. Rolling fatigue test is carried out up to 2 million cycles considering actual vehicle load at each center and quarter points of the member. The test results confirm that the service limit state is satisfied. 展开更多
关键词 UHPC CABLE Stayed BRIDGE ROLLING FATIGUE Test large-sized UHPC MEMBER
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Autonomous Formation Flight Control of Large-Sized Flapping-Wing Flying Robots Based on Leader–Follower Strategy 被引量:1
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作者 Hui Xu Yuanpeng Wang +2 位作者 Erzhen Pan Wenfu Xu Dong Xue 《Journal of Bionic Engineering》 SCIE EI CSCD 2023年第6期2542-2558,共17页
Birds in nature exhibit excellent long-distance flight capabilities through formation flight,which could reduce energy consumption and improve flight efficiency.Inspired by the biological habits of birds,this paper pr... Birds in nature exhibit excellent long-distance flight capabilities through formation flight,which could reduce energy consumption and improve flight efficiency.Inspired by the biological habits of birds,this paper proposes an autonomous formation flight control method for Large-sized Flapping-Wing Flying Robots(LFWFRs),which can enhance their search range and flight efficiency.First,the kinematics model for LFWFRs is established.Then,an autonomous flight controller based on this model is designed,which has multiple flight control modes,including attitude stabilization,course keeping,hovering,and so on.Second,a formation flight control method is proposed based on the leader–follower strategy and periodic characteristics of flapping-wing flight.The up and down fluctuation of the fuselage of each LFWFR during wing flapping is considered in the control algorithm to keep the relative distance,which overcomes the trajectory divergence caused by sensor delay and fuselage fluctuation.Third,typical formation flight modes are realized,including straight formation,circular formation,and switching formation.Finally,the outdoor formation flight experiment is carried out,and the proposed autonomous formation flight control method is verified in real environment. 展开更多
关键词 BIONIC large-sized flapping-wing flying robot HIT-Phoenix Periodic flight characteristics Formation flight Leader follower strategy
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Modeling and simulation of 3D thermal stresses of large-sized castings in solidification processes 被引量:2
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作者 J.Q.Wang D.W.Yu +2 位作者 X.Sun S.F.Su B.Z.Li 《China Foundry》 SCIE CAS 2004年第S1期20-24,共5页
When heavy machines and large scaled receiver system of communication equipment are manufactured, it always needs to produce large-sized steel castings, aluminum castings and etc. Some defects of hot cracking by therm... When heavy machines and large scaled receiver system of communication equipment are manufactured, it always needs to produce large-sized steel castings, aluminum castings and etc. Some defects of hot cracking by thermal stress often appear during solidification process as these castings are produced, which results in failure of castings. Therefore predicting the effects of technological parameters for production of castings on the thermal stress during solidification process becomes an important means. In this paper, the mathematical models have been established and numerical calculation of temperature fields by using finite difference method (FDM) and then thermal stress fields by using finite element method (FEM) during solidification process of castings have been carried out. The technological parameters of production have been optimized by the results of calculation and the defects of hot cracking have been eliminated. Modeling and simulation of 3D thermal stress during solidification processes of large-sized castings provided a scientific basis, which promoted further development of advanced manufacturing technique. 展开更多
关键词 large-sized castings simulation of 3D temperature fields simulation of 3D thermal stress fields defect of hot cracking solidification process
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Experimental investigation and numerical simulation of large-sized aluminum tube extrusion forming
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作者 吕亚臣 骆俊廷 +1 位作者 马春荣 徐岩 《Journal of Central South University》 SCIE EI CAS 2008年第S2期293-295,共3页
Large-sized aluminum tube has big section effect, aspect ratio and thin thickness, so that the extrusion technology is complex and the large specific pressure is generated in extrusion cavity. The temperature variatio... Large-sized aluminum tube has big section effect, aspect ratio and thin thickness, so that the extrusion technology is complex and the large specific pressure is generated in extrusion cavity. The temperature variation and velocity effect is difficult to control. The extrusion forming of large-sized aluminum tube was researched and simulated. Three-dimensional thermo-mechanical coupled finite element model was constructed and appropriate boundary conditions were given out. The results show that large-sized aluminum tube can be formed by isothermal extrusion through controlling the extrusion velocity and founding the relationship between extrusion velocity and extrusion temperature. 展开更多
关键词 large-sized ALUMINUM TUBE EXTRUSION NUMERICAL simulation
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A method of manufacturing process modeling based on activity network for large-sized and complex products
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作者 吕民 佟振博 王刚 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2008年第6期777-780,共4页
Simulation technique is an efficient approach to realize the planning and scheduling of manufacturing process of products. An appropriate and efficient manufacturing process model is the basis and key of manufacturing... Simulation technique is an efficient approach to realize the planning and scheduling of manufacturing process of products. An appropriate and efficient manufacturing process model is the basis and key of manufacturing process simulation. By analyzing the features of large-sized and complex products, a method of manufacturing process modeling based on activity network is presented and a mapping algorithm of translating BOM/BOP into the manufacturing process model is designed in detail. 展开更多
关键词 manufacturing process modeling large-sized and complex products workflow modeling
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应用染色放大内镜进行JNET分型与Pit pattern分型在结直肠侧向发育型肿瘤中的诊断价值分析
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作者 黄波 赵丽然 +4 位作者 张晓旭 张玲 涂征艳 王春晖 高天霞 《中国实用医药》 2025年第7期19-23,共5页
目的应用染色放大内镜对结直肠侧向发育型肿瘤(LST)患者进行日本内镜窄带光成像(NBI)技术专家小组(JNET)分型、Pit pattern分型,探究其诊断价值和临床意义。方法108例疑似结直肠LST并接受内镜黏膜下剥离术(ESD)患者,通过术前应用染色放... 目的应用染色放大内镜对结直肠侧向发育型肿瘤(LST)患者进行日本内镜窄带光成像(NBI)技术专家小组(JNET)分型、Pit pattern分型,探究其诊断价值和临床意义。方法108例疑似结直肠LST并接受内镜黏膜下剥离术(ESD)患者,通过术前应用染色放大内镜进行JNET、Pit pattern分型,并与ESD术后病理结果进行一致性分析,对比JNET分型及Pit pattern分型对结直肠LST的诊断效能。结果108例患者最终术后病理分型为非肿瘤性病变25例,肿瘤性病变83例。Pitpattern分型诊断结果与病理诊断结果有一定的一致性,差异具有显著统计学意义(Kappa值=0.519,P<0.001)。JNET分型诊断结果与病理诊断结果有一定的一致性,差异具有显著统计学意义(Kappa值=0.452,P<0.001)。JNET分型及Pit pattern分型诊断结直肠LST的特异度、阳性预测值、阴性预测值对比无显著差异(P>0.05)。JNET分型诊断结直肠LST的敏感度98.8%、准确率88.9%明显高于Pit pattern分型的91.6%、78.7%,差异具有统计学意义(P<0.05)。结论应用染色放大内镜进行JNET分型与Pit pattern分型对结直肠LST诊断具有良好价值,JNET分型优于Pitpattern分型。 展开更多
关键词 染色放大内镜 侧向发育型肿瘤 日本内镜窄带光成像技术专家小组分型 pit pattern分型 诊断价值
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Preparation and Performance of Large-Size Seamless Zirconium-Titanium-Steel Composite Plate 被引量:1
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作者 Wu Jiangtao Wang Ding +7 位作者 Huang Xingli Zou Juntao Zhang Penghui Gao Ruibo Yang Huan Zhang Tao Ren Qianyu Wei Yong 《稀有金属材料与工程》 北大核心 2025年第2期319-326,共8页
Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,p... Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,phased array waveform shape,interface structure shape,electronic scanning,and mechanical property testing.Results show that the rolling temperature of zirconiumtitanium complex should be controlled at 760°C,and the rolling reduction of each pass should be controlled at 10%–25%.The explosive velocity to prepare zirconium-titanium-steel composite plates should be controlled at 2450–2500 m/s,the density should be 0.78 g/cm3,the stand-off height should be 12 mm,and the explosive height of Zone A and Zone B should be 45–50 mm.Explosive welding combined with rolling method reduces the impact of explosive welding and multiple heat treatment on material properties.Meanwhile,the problems of surface wrinkling and cracking,which occur during the preparation process of large-sized zirconiumtitanium-steel composite plate,can be solved. 展开更多
关键词 large-size seamless zirconium-titanium-steel composite plate explosive welding+rolling phased array interface structure
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Major Companies Producing Large-Sized Castings and Their Capacity in Consecutive Three Years
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《China Foundry》 SCIE CAS 2008年第4期308-308,共1页
关键词 Co Major Companies Producing large-sized Castings and Their Capacity in Consecutive Three Years
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The Importance of Stakeholder Engagement in Progressive Rehabilitation of Large-Scale Open Pit Mines—A Case Study of Lumwana Mine
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作者 Mususu Kosta Mpongo Kaonda Baxter Nsontaulwa 《Journal of Environmental Protection》 2024年第10期963-974,共12页
Mining globally contributes to the growth of many economies of the world. Since its inception, the Zambian mining industry has contributed largely to the country’s economy. The various developments both in technology... Mining globally contributes to the growth of many economies of the world. Since its inception, the Zambian mining industry has contributed largely to the country’s economy. The various developments both in technology and knowledge have contributed to the scale at which mining is being done. Challenges in such a setting arise due to the socio-economic and environmental impacts of mining, which create multidimensional problems. The study investigated the importance of engaging stakeholders in progressive rehabilitation programs for large-scale open pit mines, using a case study of the Lumwana Mine and its host community, Manyama. A qualitative approach was used, and data was collected through one-on-one interviews. A combination of convenient and quota sampling was used to engage with host community leaders, professionals and academicians from various fields and institutions. Results showed that most participants had agreed that stakeholder engagement is important for progressive rehabilitation, but the challenge was that the host community and municipal council representatives were not aware of any progressive rehabilitation efforts at Lumwana Mine. This was attributed to a lack of stakeholder engagement and communication of mitigation progress activities by the Lumwana Mine. Results also revealed that the lack of environmental impact assessment regulations to compel companies to involve stakeholders throughout the entire life of the mine other than just at the pre-mining stage led to a lack of compliance and accountability in rehabilitation. 展开更多
关键词 Progressive Rehabilitation Stakeholder Engagement Open pit Environmental Impact
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A thermal stress loading technique for large-sized hot dry rock mechanical tests
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作者 Huiling Ci Bing Bai +2 位作者 Hongwu Lei Yan Zou Jianfeng Liu 《Deep Underground Science and Engineering》 2024年第3期326-337,共12页
Testing of large-sized specimens is becoming increasingly important in deep underground rock mechanics and engineering.In traditional mechanical loading,stresses on large-sized specimens are achieved by large host fra... Testing of large-sized specimens is becoming increasingly important in deep underground rock mechanics and engineering.In traditional mechanical loading,stresses on large-sized specimens are achieved by large host frames and hydraulic pumps,which could lead to great investment.Low-cost testing machines clearly always have great appeal.In this study,a new approach is proposed using thermal expansion stress to load rock specimens,which may be particularly suitable for tests of deep hot dry rock with high temperatures.This is a different technical route from traditional mechanical loading through hydraulic pressure.For the rock mechanics test system of hot dry rock that already has an investment in heating systems,this technology may reduce the cost of the loading subsystem by fully utilizing the temperature changes.This paper presents the basic principle and a typical design of this technical solution.Preliminary feasibility analysis is then conducted based on numerical simulations.Although some technical details still need to be resolved,the feasibility of this loading approach has been preliminarily confirmed. 展开更多
关键词 deep rock engineering high-temperature and high-stress conditions hot dry rock large-sized model test thermal stress loading
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Optimization of Operation Mode of Large-sized and Medium-sized Hydropower Stations
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作者 PENG Liantong 《外文科技期刊数据库(文摘版)工程技术》 2021年第1期307-311,共5页
Large and medium-sized hydropower stations generally include multiple units, so the operation control is more complex. If the operation mode is not reasonable, it will not only fail to play the functions of large and ... Large and medium-sized hydropower stations generally include multiple units, so the operation control is more complex. If the operation mode is not reasonable, it will not only fail to play the functions of large and medium-sized hydropower stations, but also affect various regional regulation and control work. Therefore, it is necessary to find the most scientific operation mode to ensure the operation effect of hydropower stations. This paper summarizes the optimization methods commonly used in the operation of hydropower stations, then analyzes the common problems in the operation of hydropower stations, and finally discusses the specific methods to optimize the operation of hydropower stations. Through the research to help improve the operation of hydropower stations, to enhance the scientific operation of large and medium-sized hydropower stations. 展开更多
关键词 large-sized and medium-sized hydropower stations operation mode OPTIMIZATION
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The first domesticated large-sized nuclear power plant was built up
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《Electricity》 2001年第4期52-52,共1页
关键词 The first domesticated large-sized nuclear power plant was built up
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Numerical Simulation of the Pitting Corrosion Behavior of Stainless Steel Bellows Influenced by Varying Liquid Film Thicknesses
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作者 Lu-Jun Ren Guo-Min Li +2 位作者 Zhen-Xiao Zhu Hai-Yan Xiong Bing Li 《电化学(中英文)》 北大核心 2025年第7期37-51,共15页
To advance the understanding of the corrosion behavior of stainless steel bellows in marine atmospheric environments and enhance the precision of service life predictions,this study employs finite element simulations ... To advance the understanding of the corrosion behavior of stainless steel bellows in marine atmospheric environments and enhance the precision of service life predictions,this study employs finite element simulations to investigate the pitting corrosion rates and pit morphologies of bellows peaks and troughs under varying electrolyte film thicknesses.The model incorporates localized electrochemical reactions,oxygen concentration,and homogeneous solution reactions.For improved computational accuracy,the fitted polarization curve data were directly applied as nonlinear boundary conditions on the electrode surface via interpolation functions.Simulation results reveal that the peak regions exhibit faster corrosion rates than the trough regions.With increasing electrolyte film thickness(from 10μm to 500μm),corrosion rates at both peaks and troughs decrease progressively,and after 120 hours of simulation,the maximum corrosion rate at the peaks declines from 0.720 mm/a to 0.130 mm/a,and at the troughs from 0.520 mm/a to 0.120 mm/a,with the disparity in corrosion rates diminishing over time.Furthermore,as corrosion progresses,pits propagate deeper into the substrate,exhibiting both vertical penetration and lateral expansion along the passive film interface,ultimately breaching the substrate.This research offers valuable insights into designing corrosion mitigation strategies for stainless steel bellows in marine environments. 展开更多
关键词 Finite element method pitting corrosion Stainless steel bellows Electrolyte film thickness
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Correlation between metastable pitting and structural heterogeneity in Co-based metallic glasses
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作者 Haoran Ma Dongxue Han +7 位作者 Chunyang Mu Feixiong Mao Aina He Yaqiang Dong Deren Li Qikui Man Baogen Shen Jiawei Li 《Journal of Materials Science & Technology》 2025年第25期125-136,共12页
By employing micrometer-diameter microelectrodes, the metastable pitting corrosion behavior of Co_(68.15)Fe_(4.35)Si_(12.5)B_(12)Cr_(3) metallic glasses (MGs) exposed to 0.6 mol/L NaCl solution was investigated to cla... By employing micrometer-diameter microelectrodes, the metastable pitting corrosion behavior of Co_(68.15)Fe_(4.35)Si_(12.5)B_(12)Cr_(3) metallic glasses (MGs) exposed to 0.6 mol/L NaCl solution was investigated to clarify the correlation between metastable pitting and structural heterogeneity in MGs. Thermally induced degeneration of structural heterogeneity inhibits the initiation, decelerates the growth kinetics, and accelerates the repassivation kinetics of metastable pits while also decreasing the probability of transition from metastability to stability. This enhanced resistance to pitting corrosion is attributed to a reduction in active pitting precursor sites and a decrease in electrochemical activity caused by the structural homogenization of MGs. 展开更多
关键词 Metallic glasses Structural heterogeneity Metastable pitting pitting kinetics
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Numerical Simulation of M-Shaped Multi-Row Pile-Supported Foundation Pit Excavation Based on ABAQUS
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作者 Meng Chen Chuanteng Huang +3 位作者 Shuang Pu Jilun Cai Zuocai Li Yufu Huang 《Journal of World Architecture》 2025年第3期55-63,共9页
The M-shaped multi-row pile foundation retaining structure represents an enhanced version of conventional multi-row anti-sliding support systems.To date,the implementation of M-shaped pile configurations in foundation... The M-shaped multi-row pile foundation retaining structure represents an enhanced version of conventional multi-row anti-sliding support systems.To date,the implementation of M-shaped pile configurations in foundation pit excavations has not been extensively investigated,with particularly scant research focusing on their load-bearing mechanisms and stress redistribution characteristics.Furthermore,numerical modeling methodologies for such geometrically optimized pile networks remain underdeveloped compared to practical engineering applications,creating a notable research-practice gap in geotechnical engineering.A comparative finite element analysis was systematically conducted using ABAQUS software to establish three distinct excavation support configurations:single-row cantilever retaining structures,three-row cantilever configurations,and M-shaped multi-row pile foundation systems.Subsequent numerical simulations enabled quantitative comparisons of critical performance indicators,including pile stress distribution patterns,lateral displacement profiles,and bending moment diagrams across different structural typologies.The parametric investigation revealed characteristic mechanical responses associated with each configuration,establishing corresponding mechanical principles governing the interaction between pile topology and soil-structure behavior towers.The findings of this study provide critical references for the design optimization of M-shaped multi-row pile foundation retaining systems. 展开更多
关键词 M-shaped multi-row piles Foundation pit excavation Numerical simulation ABAQUS
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Integrating models of real aboveground scene and underground geological structures at an open pit mine
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作者 Biao DONG Wenjun TAN +4 位作者 Weichao CHANG Baoting LI Yanliang GUO Quanxing HU Guangwei LIU 《虚拟现实与智能硬件(中英文)》 2025年第4期406-420,共15页
Background As information technology has advanced and been popularized,open pit mining has rapidly developed toward integration and digitization.The three-dimensional reconstruction technology has been successfully ap... Background As information technology has advanced and been popularized,open pit mining has rapidly developed toward integration and digitization.The three-dimensional reconstruction technology has been successfully applied to geological reconstruction and modeling of surface scenes in open pit mines.However,an integrated modeling method for surface and underground mine sites has not been reported.Methods In this study,we propose an integrated modeling method for open pit mines that fuses a real scene on the surface with an underground geological model.Based on oblique photography,a real-scene model was established on the surface.Based on the surface-stitching method proposed,the upper and lower surfaces and sides of the model were constructed in stages to construct a complete underground three-dimensional geological model,and the aboveground and underground models were registered together to build an integrated open pit mine model.Results The oblique photography method used reconstructed a surface model of an open pit mine using a real scene.The surface-stitching algorithm proposed was compared with the ball-pivoting and Poisson algorithms,and the integrity of the reconstructed model was markedly superior to that of the other two reconstruction methods.In addition,the surface-stitching algorithm was applied to the reconstruction of different formation models and showed good stability and reconstruction efficiency.Finally,the aboveground and underground models were accurately fitted after registration to form an integrated model.Conclusions The proposed method can efficiently establish an integrated open pit model.Based on the integrated model,an open pit auxiliary planning system was designed and realized.It supports the functions of mining planning and output calculation,assists users in mining planning and operation management,and improves production efficiency and management levels. 展开更多
关键词 Three-dimensional reconstruction Computer graphics VISUALIZATION Integrated model Open pit mine
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Enhanced pitting resistance for high-entropy alloys by precipitating nano-size d L12-strengthene d phase
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作者 Tianrun Li Debin Wang +3 位作者 Jingping Cui Qi Wang Suode Zhang Jianqiang Wang 《Journal of Materials Science & Technology》 2025年第5期53-66,共14页
Precipitation-strengthened HEAs exhibit outstanding integration of strength and toughness at ambient temperature.Nevertheless,precipitates generally reduce the localized corrosion resistance in aggressive solution env... Precipitation-strengthened HEAs exhibit outstanding integration of strength and toughness at ambient temperature.Nevertheless,precipitates generally reduce the localized corrosion resistance in aggressive solution environments.To solve this problem,a strategy of introducing nano-sized L12 precipitates in CoCrFeNiAlTi HEAs has been proposed in this work.Results demonstrate the pitting corrosion potential can be elevated from 258 mVSCE to 603 mVSCE by increasing the precipitate content to 38 wt.%.Such an improvement in localized corrosion resistance can be attributed to two aspects.Firstly,L12 precipitates tend to be dissolved during the corrosion process,which promotes the heterogeneous nucleation of protective Cr2 O3 due to the rapid deposition of oxides/hydroxides of Al/Ti,and improves the passive film stability due to the Crrich FCC matrix.Secondly,the dissolution kinetic inside the pits can be suppressed on account of the enrichment of Cr element in the FCC matrix,thus inhibiting the pitting growth.In summary,the current work not only reveals the mechanisms of the nano-sized L12 precipitates upon the corrosion behavior,but also provides a strategy for designing corrosion-resistant HEA. 展开更多
关键词 High entropy alloys PRECIpitATION Passive films pitting corrosion
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Synergistic regulation of mechanical properties and pitting corrosion resistance of high-nitrogen austenitic stainless steel via vanadium microalloying
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作者 Cun-shuai Zhang Qian Hu +3 位作者 Shi-qi Zhang Zhi-xian Peng Ming-yang Li Jing Liu 《Journal of Iron and Steel Research International》 2025年第11期4013-4025,共13页
The addition of vanadium substantially enhances the strength of the high-nitrogen austenitic stainless steel(HNASS),while maintaining excellent ductility and pitting corrosion resistance.The effects of vanadium microa... The addition of vanadium substantially enhances the strength of the high-nitrogen austenitic stainless steel(HNASS),while maintaining excellent ductility and pitting corrosion resistance.The effects of vanadium microalloying on the microstructure,mechanical properties,and pitting resistance of HNASS were systematically analyzed with a focus on the role of VN during the pitting process.The results suggest that vanadium promoted the precipitation of VN,contributing to grain boundary pinning and grain refinement.As vanadium content increased,the number of precipitates rose,and the average grain size decreased.At lower vanadium content(0-0.2 wt.%),the strength of the material was significantly reinforced with increasing vanadium content,while maintaining excellent ductility and pitting resistance.However,when the vanadium content reached 0.3-0.4 wt.%,precipitates demonstrated a substantially increased number and coarsened,accompanied by the formation of numerous dislocations around the precipitates.This brought about further strength reinforcement but a marked decline in ductility and pitting resistance.Additionally,pitting corrosion was initiated at the matrix-VN interface.Compared to the matrix,VN exhibited higher reactivity and preferentially reacted with Cl−ions,provoking dissolution.However,NH4+generated during the dissolution of VN facilitated repassivation of the material,suppressing further pitting propagation. 展开更多
关键词 High-nitrogen austenitic stainless steel Vanadium microalloying PRECIpitATE pitting corrosion Mechanical property
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Effect of HAGBs for ultra-high strength stainless steel on pitting/microcrack initiation with synergy between strain and corrosion environment
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作者 Zhenjiang Zhao Mei Yu +5 位作者 Chao Han Zhong Yang Peng Teng Jinyan Zhong Songmei Li Jianhua Liu 《Journal of Materials Science & Technology》 2025年第29期74-88,共15页
In this work,the effect of high angle grain boundaries(HAGBs),including prior austenite grain boundaries(PAGB),packet grain boundaries(PGB)and block grain boundaries(BGB),on the priority of pitting and microcrack init... In this work,the effect of high angle grain boundaries(HAGBs),including prior austenite grain boundaries(PAGB),packet grain boundaries(PGB)and block grain boundaries(BGB),on the priority of pitting and microcrack initiation for 10Cr13Co13Mo5Ni3W1VE ultra-high strength stainless steel(UHSS)has been clarified.PAGB had the highest carbide distribution coefficient and was the main location where pitting preferentially initiated for the UHSS in 3.5 wt.%NaCl solution without strain.It was shown that nanocarbides were the key factor of pitting initiation for the UHSS without strain.However,BGB was the key factor of pitting/microcrack initiation for the UHSS with strain,which was attributed to the high-density dislocations accumulated at BGB and then enhanced the local electrochemical activity of the UHSS surface.The change of the key factor for the pitting initiation in the UHSS was the result of the synergy between strain and corrosion environment.This study provides guidance for designing advanced UHSS with high service stability and safety. 展开更多
关键词 HAGBs in the UHSS STRAIN Corrosion environment pitTING Microcrack initiation
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