The existing deep-sea sediment plume tests are mostly under small-scale static water and rarely under large-scale flowing water conditions.In this study,large-scale tank experiments of flowing water were designed and ...The existing deep-sea sediment plume tests are mostly under small-scale static water and rarely under large-scale flowing water conditions.In this study,large-scale tank experiments of flowing water were designed and conducted to investigate the morphological characteristics and concentration evolution of the sediment plumes under different discharge rates(Q)and initial sediment concentrations(c).Viscosity tests,resuspension tests and free settling tests of the sediment solution with different c values were performed to reveal the settling mechanism of the plume diffusion process.The results show that the plume diffusion morphology variation in flowing water has four stages and the plume concentration evolution has three stages.The larger the Q,the smaller the initial incidence angle at the discharge outlet,the larger the diffusion range,the poorer the stability and the more complicated the diffusion morphology.The larger the c,the larger the settling velocity,the faster the formation of high-concentration accumulation zone,the better the stability and the clearer the diffusion boundary.The research results could provide experimental data for assessing the impact of deep-sea mining on the ocean environment.展开更多
The recent upsurge in metro construction emphasizes the necessity of understanding the mechanical performance of metro shield tunnel subjected to the influence of ground fissures.In this study,a largescale experiment,...The recent upsurge in metro construction emphasizes the necessity of understanding the mechanical performance of metro shield tunnel subjected to the influence of ground fissures.In this study,a largescale experiment,in combination with numerical simulation,was conducted to investigate the influence of ground fissures on a metro shield tunnel.The results indicate that the lining contact pressure at the vault increases in the hanging wall while decreases in the footwall,resulting in a two-dimensional stress state of vertical shear and axial tension-compression,and simultaneous vertical dislocation and axial tilt for the segments around the ground fissure.In addition,the damage to curved bolts includes tensile yield,flexural yield,and shear twist,leading to obvious concrete lining damage,particularly at the vault,arch bottom,and hance,indicating that the joints in these positions are weak areas.The shield tunnel orthogonal to the ground fissure ultimately experiences shear failure,suggesting that the maximum actual dislocation of ground fissure that the structure can withstand is approximately 20 cm,and five segment rings in the hanging wall and six segment rings in the footwall also need to be reinforced.This study could provide a reference for metro design in ground fissure sites.展开更多
Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynam...Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynamic size and slower degradation.It is key to develop facile methods to large-scale synthesis of polymer rings with tunable compositions and microstructures.Recent progresses in large-scale synthesis of polymer rings against single-chain dynamic nanoparticles,and the example applications in synchronous enhancing toughness and strength of polymer nanocomposites are summarized.Once there is the breakthrough in rational design and effective large-scale synthesis of polymer rings and their functional derivatives,a family of cyclic functional hybrids would be available,thus providing a new paradigm in developing polymer science and engineering.展开更多
Transitioning from outcrossing to self-fertilization is a widespread reproductive strategy in plants,especially in environments where pollination is limited.Despite its prevalence,this transition has rarely been exami...Transitioning from outcrossing to self-fertilization is a widespread reproductive strategy in plants,especially in environments where pollination is limited.Despite its prevalence,this transition has rarely been examined using transplant experiments,and previous studies have overlooked the contribution of the male parent in elucidating mating diversity.In this study,six transplanted populations were generated to investigate the relationship of the pollination environment with plant mating patterns and fecundity in Primula oreodoxa,a species that exhibits both distyly(predominantly outcrossing)and homostyly(predominantly selfing),based on data from 3582 individuals and 11 SSR markers.Homostylous plants had fruit and seed sets comparable to those of distylous plants at lower elevations but exhibited a clear reproductive advantage at higher elevations,particularly compared with the S morph.As elevation increased,the populational selfing rates increased,and the genetic diversity among the progeny was reduced.Furthermore,the visitation frequency of long-tongued pollinators was negatively and positively correlated with the selfing rate and number of mates,respectively,in the L and S morphs.In contrast,short-tongued pollinator visitation showed opposite correlations with the selfing rate and number of mates in homostylous morphs.In most populations,individuals functioned consistently as both female and male,and mating occurred randomly,suggesting a breakdown of the distyly polymorphism.Overall,our results provide experimental validation of the reproductive advantages of homostyly at high elevations by revealing that pollinator visitation shapes the selfing rate and mating diversity within populations,potentially driving the divergence of mating systems along environmental gradients.展开更多
Rock-ice avalanches in cold high-mountain regions pose severe hazards due to their high mobility,yet the quantitative controls of particle-size ratio and ice content remain insufficiently constrained.This study invest...Rock-ice avalanches in cold high-mountain regions pose severe hazards due to their high mobility,yet the quantitative controls of particle-size ratio and ice content remain insufficiently constrained.This study investigates their coupled effects using inclinedflume experiments and Discrete Element Method(DEM)simulations,covering three gravel sizes(2-5 mm,5-7 mm,7-10 mm)and four ice-content levels(0%,20%,40%,60%).Run-out distance,velocity,energy components,flow regime(Savage number),and segregation indexαwere quantified.Increasing ice content significantly enhances mobility,but with diminishing marginal effectiveness.From 0%to 40%ice content,run-out distance increases by 41%-86%,whereas the additional increase from 40%to 60%contributes only 12%-23%.Particle-size ratio strongly governs segregation intensity.Fine-gravel groups reach segregation indices ofα=0.92-0.98,indicating nearly complete upward migration of ice,whereas medium-gravel and coarse-gravel groups exhibit much weaker segregation,stabilizing atα=0.68-0.74 and 0.60-0.69.Savage number analyses reveal marked flow-regime transitions.At 0%ice content,Savage numbers reach 1.0-1.5,indicating a collisional regime.Increasing ice content suppresses collisionality,with Savage numbers decreasing to 0.03-0.07 at 60%ice content,consistent with dense-regime flow.DEM energy analyses confirm this regime shift:for finegravel mixtures,collision energy decreases by 14%,while sliding-friction energy increases by 33%as ice content increases from 0%to 60%,reflecting enhanced overburden effects imposed by upward-segregated ice layers.Medium and coarse mixtures exhibit weaker or opposite energy-shift patterns,demonstrating strong size dependence.Mechanistically,large particle-size contrasts promote strong segregation and form dense basal rock layers that increase basal friction and reduce mobility.When particle sizes are similar or ice content is high,segregation remains limited,allowing ice to mix into the basal layer,thereby reducing basal friction and enhancing mobility.This research quantitatively demonstrates how composition controls particle spatial distribution,flow regime,and energy dissipation,offering new mechanistic insights into the propagation and deposition behaviors of rock-ice avalanches and improving hazard assessment in vulnerable high-mountain regions.展开更多
To improve the accuracy of rockburst risk evaluation in mining and tunnelling engineering,the influence of intermediate principal stress σ_(2) deserves further consideration,which has been neglected in general predic...To improve the accuracy of rockburst risk evaluation in mining and tunnelling engineering,the influence of intermediate principal stress σ_(2) deserves further consideration,which has been neglected in general prediction frameworks.This study employs an integrated approach that combines true-triaxial unloading experiments with three-dimensional grain-based discrete element modeling(PFC3D-GBM)to examine the effects of σ_(2) on strain systematically burst and elucidate the underlying mechanisms.Through this dual experimental–numerical methodology,the strainburst characteristics under varying σ_(2) are analyzed in detail regarding mechanical responses,failure evolution and patterns,microscope fracture mechanisms,and energy partitioning.The results indicate that elevated σ_(2) can enhance the bearing capacity of rock,thereby necessitating a higher stress condition required for strainburst.However,it also enlarges the potential strainburst intensity,manifesting as deeper rockburst pits and more violent ejection of rock fragments.An increasing σ_(2) facilitates the microscope transgranular fractures,inhibits intergranular tensile fractures,and raises the kinetic energy conversion ratio slightly.It affects the intensity of strainburst through the following mechanisms,including the increase of energy storage limit,the intensification of Poisson effect for lateral expansion,and the enhancement of the transgranular fracturing mechanism.In practical engineering,the depth and range of support needs to be ensured under high σ_(2) conditions,and it is recommended to use prestressing techniques to control the development of significant slabbing.展开更多
4-Bromo-3-methylphenol(BMP)is an important chemical intermediate with wide applications in the fields of medicine and pesticides.The synthesis of BMP from m-cresol via bromination is easy to carry out on an industrial...4-Bromo-3-methylphenol(BMP)is an important chemical intermediate with wide applications in the fields of medicine and pesticides.The synthesis of BMP from m-cresol via bromination is easy to carry out on an industrial scale.However,due to the formation of regioisomeric impurities during bromination and the low melting point of BMP,the separation process is prone to the formation of oily substances,resulting in low yield and purity.In this work,a new cocrystallization engineering approach was proposed to separate and purify BMP.Through design of experiments,the cocrystallization process of BMP and triethylenediamine(DABCO)was optimized using a minimum-run resolution IV screening design combined with response surface methodology.In addition,the obtained 2BMP-DABCO powder was characterized by thermal analysis,powder X-ray diffraction,infrared spectroscopy,and scanning electron microscopy.Single crystals of 2BMP-DABCO were grown from acetone by slow evaporation,and detailed structural information was obtained through single-crystal X-ray diffraction.The self-assembly mechanism was further clarified by density functional theory calculations.This study provides a simple,robust,and scalable method for the production of BMP and offers a reference for the separation and purification of phenolic substances.展开更多
Offshore wind power plays a crucial role in energy strategies.The results of traditional small-scale physical models may be unreliable when extrapolated to large field scales.This study addressed this limitation by co...Offshore wind power plays a crucial role in energy strategies.The results of traditional small-scale physical models may be unreliable when extrapolated to large field scales.This study addressed this limitation by conducting large-scale(1:13)experiments to investigate the scour hole pattern and equilibrium scour depth around both slender and large monopiles under irregular waves.The experiments adopted KeuleganeCarpenter number(NKC)values from 1.01 to 8.89 and diffraction parameter(D/L,where D is the diameter of the monopile,and L is the wave length)values from 0.016 to 0.056.The results showed that changes in the maximum scour location and scour hole shape around a slender monopile were associated with NKC,with differences observed between irregular and regular waves.Improving the calculation of NKC enhanced the accuracy of existing scour formulae under irregular waves.The maximum scour locations around a large monopile were consistently found on both sides,regardless of NKC and D/L,but the scour hole topography was influenced by both parameters.Notably,the scour range around a large monopile was at least as large as the monopile diameter.展开更多
This study examined the development of technician teams on large-scale instrument platforms in universities,using the State Key Laboratory of Natural and Biomimetic Drugs in the Peking University School of Pharmaceuti...This study examined the development of technician teams on large-scale instrument platforms in universities,using the State Key Laboratory of Natural and Biomimetic Drugs in the Peking University School of Pharmaceutical Sciences as a case study.Data were collected through questionnaire surveys and interviews conducted in 2017,followed by a questionnaire survey in 2023,offering both subjective and objective insights.The evolution of the platform’s technician team over the past 5 years was analyzed,highlighting key experiences and identifying ongoing challenges.Recommendations to enhance technician team development include recruiting skilled faculty,clearly defining job responsibilities,and refining the assessment and incentive systems.展开更多
1.Introduction Climate change mitigation pathways aimed at limiting global anthropogenic carbon dioxide(CO_(2))emissions while striving to constrain the global temperature increase to below 2℃—as outlined by the Int...1.Introduction Climate change mitigation pathways aimed at limiting global anthropogenic carbon dioxide(CO_(2))emissions while striving to constrain the global temperature increase to below 2℃—as outlined by the Intergovernmental Panel on Climate Change(IPCC)—consistently predict the widespread implementation of CO_(2)geological storage on a global scale.展开更多
sing the natural limestone samples taken from the field with dimension of 500 mm×500 mm×1 000 mm, the D-D (dilatancy-diffusion) seismogeny pattern was modeled under the condition of water injection, which ob...sing the natural limestone samples taken from the field with dimension of 500 mm×500 mm×1 000 mm, the D-D (dilatancy-diffusion) seismogeny pattern was modeled under the condition of water injection, which observes the time-space evolutionary features about the relative physics fields of the loaded samples from deformation, formation of microcracks to the occurrence of main rupture. The results of observed apparent resistivity show: ① The process of the deformation from microcrack to main rupture on the loaded rock sample could be characterized by the precursory spatial-temporal changes in the observation of apparent resistivity; ② The precursory temporal changes of observation in apparent resistivity could be divided into several stages, and its spatial distribution shows the difference in different parts of the rock sample; ③ Before the main rupture of the rock sample the obvious ″tendency anomaly′ and ′short-term anomaly″ were observed, and some of them could be likely considered as the ″impending earthquake ″anomaly precursor of apparent resistivity. The changes and distribution features of apparent resistivity show that they are intrinsically related to the dilatancy phenomenon of the loaded rock sample. Finally, this paper discusses the mechanism of resistivity change of loaded rock sample theoretically.展开更多
Based on an analysis of the relationship between the tropical cyclone genesis frequency and large-scale circulation anomaly in NCEP reanalysis, large-scale atmosphere circulation information forecast by the JAMSTEC SI...Based on an analysis of the relationship between the tropical cyclone genesis frequency and large-scale circulation anomaly in NCEP reanalysis, large-scale atmosphere circulation information forecast by the JAMSTEC SINTEX-F coupled model is used to build a statistical model to predict the cyclogenesis frequency over the South China Sea and the western North Pacific. The SINTEX-F coupled model has relatively good prediction skill for some circulation features associated with the cyclogenesis frequency including sea level pressure, wind vertical shear, Intertropical Convergence Zone and cross-equatorial air flows. Predictors derived from these large-scale circulations have good relationships with the cyclogenesis frequency over the South China Sea and the western North Pacific. A multivariate linear regression(MLR) model is further designed using these predictors. This model shows good prediction skill with the anomaly correlation coefficient reaching, based on the cross validation, 0.71 between the observed and predicted cyclogenesis frequency. However, it also shows relatively large prediction errors in extreme tropical cyclone years(1994 and 1998, for example).展开更多
The Keulegan-Carpenter(KC)number is the main dimensionless parameter that affects the local scour of offshore wind power monopile foundations.This study conducted large-scale(1:13)physical model tests to study the loc...The Keulegan-Carpenter(KC)number is the main dimensionless parameter that affects the local scour of offshore wind power monopile foundations.This study conducted large-scale(1:13)physical model tests to study the local scour shape,equilibrium scour depth,and local scour volume of offshore wind power monopiles under the action of irregular waves with different KC numbers.Systematic experiments were carried out with the KC number ranging from 1.0 to 13.0.With a small KC number(KC<6),and especially when the KC number was less than 4,the scour mainly occurred on both cross-flow sides of the monopile with a low scour depth.When the KC number exceeded 4,the shape of the scour hole changed from a fan to an ellipse,and the maximum scour depth increased significantly with KC.With a large KC number(KC>6),the proposed method better predicted the equilibrium scour depth when the wave broke.In addition,according to the results of three-dimensional terrain scanning,the relationship between the local equilibrium scour volume of a single offshore wind power monopile and the KC number was derived.This provided a rational method for estimation of the riprap redundancy for monopile protection against scour.展开更多
Wind energy has been rapidly developed in China during the past decades and the installed capacity has been the largest in the world. In the future, utilization of wind power is still expected to carry out in China ma...Wind energy has been rapidly developed in China during the past decades and the installed capacity has been the largest in the world. In the future, utilization of wind power is still expected to carry out in China mainly with a large-scale centralized layout. Here, we examine the potential climatic impacts of large-scale windfarms associated with deployment scale in China using numerical experiments, in which four deployment scenarios were designed. These four scenarios represented relatively small- (484 GW), medium- (2165 GW) and large-scale (3490 GW and 5412 GW) installed wind power capacities, respectively. Results showed that turbulent kinetic energy, wind velocity, and air temperature varied consistently within those windfarms with the largest changes in turbine hub heights. Moreover, the above relatively large- scale windfarms could induce regional wanning with a maximum of above 0.8 °C in North China. This regional warming may be linked to an anomalous circulation pattern with a negative pressure anomaly center in Northeast China and a positive pressure anomaly center in the middle and lower reaches of the Yangtze-Huaihe River Basin.展开更多
Based on the analysis of typical lacustrine shale oil zones in China and their geological characteristics,this study elucidates the fundamental differences between the enrichment patterns of shale oil sweet spots and ...Based on the analysis of typical lacustrine shale oil zones in China and their geological characteristics,this study elucidates the fundamental differences between the enrichment patterns of shale oil sweet spots and conventional oil and gas.The key parameters and evaluation methods for assessing the large-scale production potential of lacustrine shale oil are proposed.The results show that shale oil is a petroleum resource that exists in organic-rich shale formations,in other words,it is preserved in its source bed,following a different process of generation-accumulation-enrichment from conventional oil and gas.Thus,the concept of“reservoir”seems to be inapplicable to shale oil.In China,lacustrine shale oil is distributed widely,but the geological characteristics and sweet spots enrichment patterns of shale oil vary significantly in lacustrine basins where the water environment and the tectonic evolution and diagenetic transformation frameworks are distinct.The core of the evaluation of lacustrine shale oil is“sweet spot volume”.The key factors for evaluating the large-scale production of continental shale oil are the oil storage capacity,oil-bearing capacity and oil producing capacity.The key parameters for evaluating these capacities are total porosity,oil content,and free oil content,respectively.It is recommended to determine the total porosity of shale by combining helium porosity measurement with nuclear magnetic resonance(NMR)method,the oil content of key layers by using organic solvent extraction,NMR method and high pressure mercury intrusion methods,and the free oil content by using NMR fluid distribution secondary spectral stripping decomposition and logging.The research results contribute supplemental insights on continental shale oil deliverability in China,and provide a scientific basis for the rapid exploration and large-scale production of lacustrine shale oil.展开更多
As an advanced combat weapon,Unmanned Aerial Vehicles(UAVs)have been widely used in military wars.In this paper,we formulated the Autonomous Navigation Control(ANC)problem of UAVs as a Markov Decision Process(MDP)and ...As an advanced combat weapon,Unmanned Aerial Vehicles(UAVs)have been widely used in military wars.In this paper,we formulated the Autonomous Navigation Control(ANC)problem of UAVs as a Markov Decision Process(MDP)and proposed a novel Deep Reinforcement Learning(DRL)method to allow UAVs to perform dynamic target tracking tasks in large-scale unknown environments.To solve the problem of limited training experience,the proposed Imaginary Filtered Hindsight Experience Replay(IFHER)generates successful episodes by reasonably imagining the target trajectory in the failed episode to augment the experiences.The welldesigned goal,episode,and quality filtering strategies ensure that only high-quality augmented experiences can be stored,while the sampling filtering strategy of IFHER ensures that these stored augmented experiences can be fully learned according to their high priorities.By training in a complex environment constructed based on the parameters of a real UAV,the proposed IFHER algorithm improves the convergence speed by 28.99%and the convergence result by 11.57%compared to the state-of-the-art Twin Delayed Deep Deterministic Policy Gradient(TD3)algorithm.The testing experiments carried out in environments with different complexities demonstrate the strong robustness and generalization ability of the IFHER agent.Moreover,the flight trajectory of the IFHER agent shows the superiority of the learned policy and the practical application value of the algorithm.展开更多
The titanium alloy strut serves as a key load-bearing component of aircraft landing gear,typically manufactured via forging.The friction condition has important influence on material flow and cavity filling during the...The titanium alloy strut serves as a key load-bearing component of aircraft landing gear,typically manufactured via forging.The friction condition has important influence on material flow and cavity filling during the forging process.Using the previously optimized shape and initial position of preform,the influence of the friction condition(friction factor m=0.1–0.3)on material flow and cavity filling was studied by numerical method with a shear friction model.A novel filling index was defined to reflect material flow into left and right flashes and zoom in on friction-induced results.The results indicate that the workpiece moves rigidly to the right direction,with the displacement decreasing as m increases.When m<0.18,the underfilling defect will occur in the left side of strut forging,while overflow occurs in the right forging die cavity.By combining the filling index and analyses of material flow and filling status,a reasonable friction factor interval of m=0.21–0.24 can be determined.Within this interval,the cavity filling behavior demonstrates robustness,with friction fluctuations exerting minimal influence.展开更多
A spice formulation study in Burkina Faso was carried out using local ingredients for the benefit of households. The objective of this study was to propose some spice formulations based on local ingredients in order t...A spice formulation study in Burkina Faso was carried out using local ingredients for the benefit of households. The objective of this study was to propose some spice formulations based on local ingredients in order to reduce the use of chemical spices in the preparation of different dishes. The Design of Experiments (DOE) methodology was used for the formulation of the spices and their physicochemical, nutritional and sensory characteristics were evaluated by standardized and standard methods. The results obtained showed lipid contents (g/100 g DM) ranging from 10.41 ± 0.26 to 15.64 ± 0.68, total sugars from 4.39 ± 0.32 to 5.46 ± 0.31, protein from 3.65 ± 0.17 to 12.04 ± 0.35 and ash from 5.83 ± 0.01 to 7.02 ± 0.01. The polyphenol content ranged from 9.09 ± 1.60 to 11.33 ± 0.90, and the flavonoid content ranged from 0.65 ± 0.03 to 1.08 ± 0.13. The sensory analysis carried out showed that the spices have generally satisfactory organoleptic characteristics. These results constitute new information in the diet of populations and are an alternative to the chemical spices used in their cooking.展开更多
The effects of topography on baroclinic wave flows are studied experimentally in a thermally driven rotating annulus of fluid.Fourier analysis and complex principal component (CPC) analysis of the experimental data sh...The effects of topography on baroclinic wave flows are studied experimentally in a thermally driven rotating annulus of fluid.Fourier analysis and complex principal component (CPC) analysis of the experimental data show that, due to topographic forcing, the flow is bimodal rather than a single mode. Under suitable imposed experimental parameters, near thermal Rossby number ROT = 0.1 and Taylor number Ta = 2.2 × 107, the large-scale topography produces low-frequency oscillation in the flow and rather long-lived flow pattern resembling blocking in the atmospheric circulation. The 'blocking' phenomenon is caused by the resonance of travelling waves and the quasi-stationary waves forced by topography.The large-scale topography transforms wavenumber-homogeneous flows into wavenumber-dispersed flows, and the dispersed flows possess lower wavenumbers.展开更多
Based on questionnaire surveys and field interviews conducted with various types of agricultural production organizations across five districts and four counties in Daqing City,this study combines relevant theoretical...Based on questionnaire surveys and field interviews conducted with various types of agricultural production organizations across five districts and four counties in Daqing City,this study combines relevant theoretical frameworks to systematically examine the evolution,performance,and influencing factors of governance mechanisms within these organizations.Using both quantitative and inductive analytical methods,the paper proposes innovative designs and supporting measures for improving governance mechanisms.The findings reveal that,amid large-scale farmland circulation,the governance mechanisms of agricultural production organizations in Daqing City are evolving from traditional to modern structures.However,challenges remain in areas such as decision-making efficiency,benefit distribution,and supervision mechanisms.In response,this study proposes innovative governance designs focusing on decision-making processes,profit-sharing mechanisms,and risk prevention.Corresponding policy recommendations are also provided to support the sustainable development of agricultural modernization in China.展开更多
基金supported by the Major Project of Hunan Natural Science Foundation,China(No.2021JC0010)the National Natural Science Foundation of China(No.51274251)。
文摘The existing deep-sea sediment plume tests are mostly under small-scale static water and rarely under large-scale flowing water conditions.In this study,large-scale tank experiments of flowing water were designed and conducted to investigate the morphological characteristics and concentration evolution of the sediment plumes under different discharge rates(Q)and initial sediment concentrations(c).Viscosity tests,resuspension tests and free settling tests of the sediment solution with different c values were performed to reveal the settling mechanism of the plume diffusion process.The results show that the plume diffusion morphology variation in flowing water has four stages and the plume concentration evolution has three stages.The larger the Q,the smaller the initial incidence angle at the discharge outlet,the larger the diffusion range,the poorer the stability and the more complicated the diffusion morphology.The larger the c,the larger the settling velocity,the faster the formation of high-concentration accumulation zone,the better the stability and the clearer the diffusion boundary.The research results could provide experimental data for assessing the impact of deep-sea mining on the ocean environment.
基金supported by the National Key Research&Development Program of China(Grant No.2023YFC3008404)the Key Laboratory of Earth Fissures Geological Disaster,Ministry of Natural Resources,China(Grant Nos.EFGD20240609 and EFGD20240610).
文摘The recent upsurge in metro construction emphasizes the necessity of understanding the mechanical performance of metro shield tunnel subjected to the influence of ground fissures.In this study,a largescale experiment,in combination with numerical simulation,was conducted to investigate the influence of ground fissures on a metro shield tunnel.The results indicate that the lining contact pressure at the vault increases in the hanging wall while decreases in the footwall,resulting in a two-dimensional stress state of vertical shear and axial tension-compression,and simultaneous vertical dislocation and axial tilt for the segments around the ground fissure.In addition,the damage to curved bolts includes tensile yield,flexural yield,and shear twist,leading to obvious concrete lining damage,particularly at the vault,arch bottom,and hance,indicating that the joints in these positions are weak areas.The shield tunnel orthogonal to the ground fissure ultimately experiences shear failure,suggesting that the maximum actual dislocation of ground fissure that the structure can withstand is approximately 20 cm,and five segment rings in the hanging wall and six segment rings in the footwall also need to be reinforced.This study could provide a reference for metro design in ground fissure sites.
基金Supported by the National Natural Science Foundation of China(Nos.52293472,22473096 and 22471164)。
文摘Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynamic size and slower degradation.It is key to develop facile methods to large-scale synthesis of polymer rings with tunable compositions and microstructures.Recent progresses in large-scale synthesis of polymer rings against single-chain dynamic nanoparticles,and the example applications in synchronous enhancing toughness and strength of polymer nanocomposites are summarized.Once there is the breakthrough in rational design and effective large-scale synthesis of polymer rings and their functional derivatives,a family of cyclic functional hybrids would be available,thus providing a new paradigm in developing polymer science and engineering.
基金funded by grants from the National Natural Science Foundation of China(31800314,32370239,U160323)the foundation of South China Botanical Garden,Chinese Academy of Sciences(QNXM-06)to SY and the Doctoral Research Foundation of China West Normal University(412994).
文摘Transitioning from outcrossing to self-fertilization is a widespread reproductive strategy in plants,especially in environments where pollination is limited.Despite its prevalence,this transition has rarely been examined using transplant experiments,and previous studies have overlooked the contribution of the male parent in elucidating mating diversity.In this study,six transplanted populations were generated to investigate the relationship of the pollination environment with plant mating patterns and fecundity in Primula oreodoxa,a species that exhibits both distyly(predominantly outcrossing)and homostyly(predominantly selfing),based on data from 3582 individuals and 11 SSR markers.Homostylous plants had fruit and seed sets comparable to those of distylous plants at lower elevations but exhibited a clear reproductive advantage at higher elevations,particularly compared with the S morph.As elevation increased,the populational selfing rates increased,and the genetic diversity among the progeny was reduced.Furthermore,the visitation frequency of long-tongued pollinators was negatively and positively correlated with the selfing rate and number of mates,respectively,in the L and S morphs.In contrast,short-tongued pollinator visitation showed opposite correlations with the selfing rate and number of mates in homostylous morphs.In most populations,individuals functioned consistently as both female and male,and mating occurred randomly,suggesting a breakdown of the distyly polymorphism.Overall,our results provide experimental validation of the reproductive advantages of homostyly at high elevations by revealing that pollinator visitation shapes the selfing rate and mating diversity within populations,potentially driving the divergence of mating systems along environmental gradients.
基金funded by the Natural Science Foundation of China(Grants No 42277127)。
文摘Rock-ice avalanches in cold high-mountain regions pose severe hazards due to their high mobility,yet the quantitative controls of particle-size ratio and ice content remain insufficiently constrained.This study investigates their coupled effects using inclinedflume experiments and Discrete Element Method(DEM)simulations,covering three gravel sizes(2-5 mm,5-7 mm,7-10 mm)and four ice-content levels(0%,20%,40%,60%).Run-out distance,velocity,energy components,flow regime(Savage number),and segregation indexαwere quantified.Increasing ice content significantly enhances mobility,but with diminishing marginal effectiveness.From 0%to 40%ice content,run-out distance increases by 41%-86%,whereas the additional increase from 40%to 60%contributes only 12%-23%.Particle-size ratio strongly governs segregation intensity.Fine-gravel groups reach segregation indices ofα=0.92-0.98,indicating nearly complete upward migration of ice,whereas medium-gravel and coarse-gravel groups exhibit much weaker segregation,stabilizing atα=0.68-0.74 and 0.60-0.69.Savage number analyses reveal marked flow-regime transitions.At 0%ice content,Savage numbers reach 1.0-1.5,indicating a collisional regime.Increasing ice content suppresses collisionality,with Savage numbers decreasing to 0.03-0.07 at 60%ice content,consistent with dense-regime flow.DEM energy analyses confirm this regime shift:for finegravel mixtures,collision energy decreases by 14%,while sliding-friction energy increases by 33%as ice content increases from 0%to 60%,reflecting enhanced overburden effects imposed by upward-segregated ice layers.Medium and coarse mixtures exhibit weaker or opposite energy-shift patterns,demonstrating strong size dependence.Mechanistically,large particle-size contrasts promote strong segregation and form dense basal rock layers that increase basal friction and reduce mobility.When particle sizes are similar or ice content is high,segregation remains limited,allowing ice to mix into the basal layer,thereby reducing basal friction and enhancing mobility.This research quantitatively demonstrates how composition controls particle spatial distribution,flow regime,and energy dissipation,offering new mechanistic insights into the propagation and deposition behaviors of rock-ice avalanches and improving hazard assessment in vulnerable high-mountain regions.
基金supported by the National Natural Science Foundation of China(No.42507210)the Fundamental Research Funds for the Central Universities(No.2025XJSB01)+1 种基金the State Key Laboratory for Tunnel Engineering(No.SKLTEK202421)the Foundation of Key Laboratory of Deep Coal Resource Mining(China University of Mining and Technology),Ministry of Education(No.KLDCRMMOE24KF11).
文摘To improve the accuracy of rockburst risk evaluation in mining and tunnelling engineering,the influence of intermediate principal stress σ_(2) deserves further consideration,which has been neglected in general prediction frameworks.This study employs an integrated approach that combines true-triaxial unloading experiments with three-dimensional grain-based discrete element modeling(PFC3D-GBM)to examine the effects of σ_(2) on strain systematically burst and elucidate the underlying mechanisms.Through this dual experimental–numerical methodology,the strainburst characteristics under varying σ_(2) are analyzed in detail regarding mechanical responses,failure evolution and patterns,microscope fracture mechanisms,and energy partitioning.The results indicate that elevated σ_(2) can enhance the bearing capacity of rock,thereby necessitating a higher stress condition required for strainburst.However,it also enlarges the potential strainburst intensity,manifesting as deeper rockburst pits and more violent ejection of rock fragments.An increasing σ_(2) facilitates the microscope transgranular fractures,inhibits intergranular tensile fractures,and raises the kinetic energy conversion ratio slightly.It affects the intensity of strainburst through the following mechanisms,including the increase of energy storage limit,the intensification of Poisson effect for lateral expansion,and the enhancement of the transgranular fracturing mechanism.In practical engineering,the depth and range of support needs to be ensured under high σ_(2) conditions,and it is recommended to use prestressing techniques to control the development of significant slabbing.
基金supported by the National Natural Science Foundation of China(22177011(R.Z.Qiao),21977012(R.Z.Qiao),and 21572018(C.Li))the National High-Level Hospital Clinical Research Funding(2023-NHLHCRF-YXHZ-ZRMS-02)the Joint Project of BRCBC(Biomedical Translational Engineering Research Center of BUCT-CJFH)(XK2020-06).
文摘4-Bromo-3-methylphenol(BMP)is an important chemical intermediate with wide applications in the fields of medicine and pesticides.The synthesis of BMP from m-cresol via bromination is easy to carry out on an industrial scale.However,due to the formation of regioisomeric impurities during bromination and the low melting point of BMP,the separation process is prone to the formation of oily substances,resulting in low yield and purity.In this work,a new cocrystallization engineering approach was proposed to separate and purify BMP.Through design of experiments,the cocrystallization process of BMP and triethylenediamine(DABCO)was optimized using a minimum-run resolution IV screening design combined with response surface methodology.In addition,the obtained 2BMP-DABCO powder was characterized by thermal analysis,powder X-ray diffraction,infrared spectroscopy,and scanning electron microscopy.Single crystals of 2BMP-DABCO were grown from acetone by slow evaporation,and detailed structural information was obtained through single-crystal X-ray diffraction.The self-assembly mechanism was further clarified by density functional theory calculations.This study provides a simple,robust,and scalable method for the production of BMP and offers a reference for the separation and purification of phenolic substances.
基金supported by the National Nature Science Foundation of China National Outstanding Youth Science Fund Project(Grant No.52122109)the National Natural Science Foundation of China(Grants No.51861165102 and 52039005).
文摘Offshore wind power plays a crucial role in energy strategies.The results of traditional small-scale physical models may be unreliable when extrapolated to large field scales.This study addressed this limitation by conducting large-scale(1:13)experiments to investigate the scour hole pattern and equilibrium scour depth around both slender and large monopiles under irregular waves.The experiments adopted KeuleganeCarpenter number(NKC)values from 1.01 to 8.89 and diffraction parameter(D/L,where D is the diameter of the monopile,and L is the wave length)values from 0.016 to 0.056.The results showed that changes in the maximum scour location and scour hole shape around a slender monopile were associated with NKC,with differences observed between irregular and regular waves.Improving the calculation of NKC enhanced the accuracy of existing scour formulae under irregular waves.The maximum scour locations around a large monopile were consistently found on both sides,regardless of NKC and D/L,but the scour hole topography was influenced by both parameters.Notably,the scour range around a large monopile was at least as large as the monopile diameter.
文摘This study examined the development of technician teams on large-scale instrument platforms in universities,using the State Key Laboratory of Natural and Biomimetic Drugs in the Peking University School of Pharmaceutical Sciences as a case study.Data were collected through questionnaire surveys and interviews conducted in 2017,followed by a questionnaire survey in 2023,offering both subjective and objective insights.The evolution of the platform’s technician team over the past 5 years was analyzed,highlighting key experiences and identifying ongoing challenges.Recommendations to enhance technician team development include recruiting skilled faculty,clearly defining job responsibilities,and refining the assessment and incentive systems.
基金supported by the National Key Research and Development Program of China(2022YFE0206700)。
文摘1.Introduction Climate change mitigation pathways aimed at limiting global anthropogenic carbon dioxide(CO_(2))emissions while striving to constrain the global temperature increase to below 2℃—as outlined by the Intergovernmental Panel on Climate Change(IPCC)—consistently predict the widespread implementation of CO_(2)geological storage on a global scale.
文摘sing the natural limestone samples taken from the field with dimension of 500 mm×500 mm×1 000 mm, the D-D (dilatancy-diffusion) seismogeny pattern was modeled under the condition of water injection, which observes the time-space evolutionary features about the relative physics fields of the loaded samples from deformation, formation of microcracks to the occurrence of main rupture. The results of observed apparent resistivity show: ① The process of the deformation from microcrack to main rupture on the loaded rock sample could be characterized by the precursory spatial-temporal changes in the observation of apparent resistivity; ② The precursory temporal changes of observation in apparent resistivity could be divided into several stages, and its spatial distribution shows the difference in different parts of the rock sample; ③ Before the main rupture of the rock sample the obvious ″tendency anomaly′ and ′short-term anomaly″ were observed, and some of them could be likely considered as the ″impending earthquake ″anomaly precursor of apparent resistivity. The changes and distribution features of apparent resistivity show that they are intrinsically related to the dilatancy phenomenon of the loaded rock sample. Finally, this paper discusses the mechanism of resistivity change of loaded rock sample theoretically.
基金Specialized Science and Technology Project for Public Welfare Industry(GYHY200906015)National Basic Research Program of China(973 Program,2010CB428606)Key Technologies R&D Program of China(2009BAC51B05)
文摘Based on an analysis of the relationship between the tropical cyclone genesis frequency and large-scale circulation anomaly in NCEP reanalysis, large-scale atmosphere circulation information forecast by the JAMSTEC SINTEX-F coupled model is used to build a statistical model to predict the cyclogenesis frequency over the South China Sea and the western North Pacific. The SINTEX-F coupled model has relatively good prediction skill for some circulation features associated with the cyclogenesis frequency including sea level pressure, wind vertical shear, Intertropical Convergence Zone and cross-equatorial air flows. Predictors derived from these large-scale circulations have good relationships with the cyclogenesis frequency over the South China Sea and the western North Pacific. A multivariate linear regression(MLR) model is further designed using these predictors. This model shows good prediction skill with the anomaly correlation coefficient reaching, based on the cross validation, 0.71 between the observed and predicted cyclogenesis frequency. However, it also shows relatively large prediction errors in extreme tropical cyclone years(1994 and 1998, for example).
基金supported by the National Natural Science Foundation of China(Grants No.52001149,52039005,and 51861165102)the Research Funds for the Central Universities(Grants No.TKS20210102,TKS20210110,and TKS20210303)the Tianjin Science and Technology Planning Project(Grant No.17PTYPHZ00080).
文摘The Keulegan-Carpenter(KC)number is the main dimensionless parameter that affects the local scour of offshore wind power monopile foundations.This study conducted large-scale(1:13)physical model tests to study the local scour shape,equilibrium scour depth,and local scour volume of offshore wind power monopiles under the action of irregular waves with different KC numbers.Systematic experiments were carried out with the KC number ranging from 1.0 to 13.0.With a small KC number(KC<6),and especially when the KC number was less than 4,the scour mainly occurred on both cross-flow sides of the monopile with a low scour depth.When the KC number exceeded 4,the shape of the scour hole changed from a fan to an ellipse,and the maximum scour depth increased significantly with KC.With a large KC number(KC>6),the proposed method better predicted the equilibrium scour depth when the wave broke.In addition,according to the results of three-dimensional terrain scanning,the relationship between the local equilibrium scour volume of a single offshore wind power monopile and the KC number was derived.This provided a rational method for estimation of the riprap redundancy for monopile protection against scour.
基金s We acknowledged the financial support of the National Key Research and Development Program of China (2018YFB1502803), the National Natural Science Foundation of China (41475066), and Tsinghua University Initiative Sci entific Research Program (20131089357, 20131089356).
文摘Wind energy has been rapidly developed in China during the past decades and the installed capacity has been the largest in the world. In the future, utilization of wind power is still expected to carry out in China mainly with a large-scale centralized layout. Here, we examine the potential climatic impacts of large-scale windfarms associated with deployment scale in China using numerical experiments, in which four deployment scenarios were designed. These four scenarios represented relatively small- (484 GW), medium- (2165 GW) and large-scale (3490 GW and 5412 GW) installed wind power capacities, respectively. Results showed that turbulent kinetic energy, wind velocity, and air temperature varied consistently within those windfarms with the largest changes in turbine hub heights. Moreover, the above relatively large- scale windfarms could induce regional wanning with a maximum of above 0.8 °C in North China. This regional warming may be linked to an anomalous circulation pattern with a negative pressure anomaly center in Northeast China and a positive pressure anomaly center in the middle and lower reaches of the Yangtze-Huaihe River Basin.
基金Supported by the National Key R&D Program of China(2024YFE0114000)Science and Technology Project of China National Petroleum Corporation(2024DJ8702).
文摘Based on the analysis of typical lacustrine shale oil zones in China and their geological characteristics,this study elucidates the fundamental differences between the enrichment patterns of shale oil sweet spots and conventional oil and gas.The key parameters and evaluation methods for assessing the large-scale production potential of lacustrine shale oil are proposed.The results show that shale oil is a petroleum resource that exists in organic-rich shale formations,in other words,it is preserved in its source bed,following a different process of generation-accumulation-enrichment from conventional oil and gas.Thus,the concept of“reservoir”seems to be inapplicable to shale oil.In China,lacustrine shale oil is distributed widely,but the geological characteristics and sweet spots enrichment patterns of shale oil vary significantly in lacustrine basins where the water environment and the tectonic evolution and diagenetic transformation frameworks are distinct.The core of the evaluation of lacustrine shale oil is“sweet spot volume”.The key factors for evaluating the large-scale production of continental shale oil are the oil storage capacity,oil-bearing capacity and oil producing capacity.The key parameters for evaluating these capacities are total porosity,oil content,and free oil content,respectively.It is recommended to determine the total porosity of shale by combining helium porosity measurement with nuclear magnetic resonance(NMR)method,the oil content of key layers by using organic solvent extraction,NMR method and high pressure mercury intrusion methods,and the free oil content by using NMR fluid distribution secondary spectral stripping decomposition and logging.The research results contribute supplemental insights on continental shale oil deliverability in China,and provide a scientific basis for the rapid exploration and large-scale production of lacustrine shale oil.
基金co-supported by the National Natural Science Foundation of China(Nos.62003267 and 61573285)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2020JQ-220)+1 种基金the Open Project of Science and Technology on Electronic Information Control Laboratory,China(No.JS20201100339)the Open Project of Science and Technology on Electromagnetic Space Operations and Applications Laboratory,China(No.JS20210586512).
文摘As an advanced combat weapon,Unmanned Aerial Vehicles(UAVs)have been widely used in military wars.In this paper,we formulated the Autonomous Navigation Control(ANC)problem of UAVs as a Markov Decision Process(MDP)and proposed a novel Deep Reinforcement Learning(DRL)method to allow UAVs to perform dynamic target tracking tasks in large-scale unknown environments.To solve the problem of limited training experience,the proposed Imaginary Filtered Hindsight Experience Replay(IFHER)generates successful episodes by reasonably imagining the target trajectory in the failed episode to augment the experiences.The welldesigned goal,episode,and quality filtering strategies ensure that only high-quality augmented experiences can be stored,while the sampling filtering strategy of IFHER ensures that these stored augmented experiences can be fully learned according to their high priorities.By training in a complex environment constructed based on the parameters of a real UAV,the proposed IFHER algorithm improves the convergence speed by 28.99%and the convergence result by 11.57%compared to the state-of-the-art Twin Delayed Deep Deterministic Policy Gradient(TD3)algorithm.The testing experiments carried out in environments with different complexities demonstrate the strong robustness and generalization ability of the IFHER agent.Moreover,the flight trajectory of the IFHER agent shows the superiority of the learned policy and the practical application value of the algorithm.
基金National Natural Science Foundation of China(52375378)National Key Laboratory of Metal Forming Technology and Heavy Equipment(S2308100.W12)Huxiang High-Level Talent Gathering Project of Hunan Province(2021RC5001)。
文摘The titanium alloy strut serves as a key load-bearing component of aircraft landing gear,typically manufactured via forging.The friction condition has important influence on material flow and cavity filling during the forging process.Using the previously optimized shape and initial position of preform,the influence of the friction condition(friction factor m=0.1–0.3)on material flow and cavity filling was studied by numerical method with a shear friction model.A novel filling index was defined to reflect material flow into left and right flashes and zoom in on friction-induced results.The results indicate that the workpiece moves rigidly to the right direction,with the displacement decreasing as m increases.When m<0.18,the underfilling defect will occur in the left side of strut forging,while overflow occurs in the right forging die cavity.By combining the filling index and analyses of material flow and filling status,a reasonable friction factor interval of m=0.21–0.24 can be determined.Within this interval,the cavity filling behavior demonstrates robustness,with friction fluctuations exerting minimal influence.
文摘A spice formulation study in Burkina Faso was carried out using local ingredients for the benefit of households. The objective of this study was to propose some spice formulations based on local ingredients in order to reduce the use of chemical spices in the preparation of different dishes. The Design of Experiments (DOE) methodology was used for the formulation of the spices and their physicochemical, nutritional and sensory characteristics were evaluated by standardized and standard methods. The results obtained showed lipid contents (g/100 g DM) ranging from 10.41 ± 0.26 to 15.64 ± 0.68, total sugars from 4.39 ± 0.32 to 5.46 ± 0.31, protein from 3.65 ± 0.17 to 12.04 ± 0.35 and ash from 5.83 ± 0.01 to 7.02 ± 0.01. The polyphenol content ranged from 9.09 ± 1.60 to 11.33 ± 0.90, and the flavonoid content ranged from 0.65 ± 0.03 to 1.08 ± 0.13. The sensory analysis carried out showed that the spices have generally satisfactory organoleptic characteristics. These results constitute new information in the diet of populations and are an alternative to the chemical spices used in their cooking.
基金This research was supported by the U.S. National Science Foundation Grants ATM-8709410 and ATM-8714674.
文摘The effects of topography on baroclinic wave flows are studied experimentally in a thermally driven rotating annulus of fluid.Fourier analysis and complex principal component (CPC) analysis of the experimental data show that, due to topographic forcing, the flow is bimodal rather than a single mode. Under suitable imposed experimental parameters, near thermal Rossby number ROT = 0.1 and Taylor number Ta = 2.2 × 107, the large-scale topography produces low-frequency oscillation in the flow and rather long-lived flow pattern resembling blocking in the atmospheric circulation. The 'blocking' phenomenon is caused by the resonance of travelling waves and the quasi-stationary waves forced by topography.The large-scale topography transforms wavenumber-homogeneous flows into wavenumber-dispersed flows, and the dispersed flows possess lower wavenumbers.
基金Supported by Daqing City Philosophy and Social Sciences Planning Research Project(DSGB 2025011)the Heilongjiang Province Education Science Planning Key Project(GJB1320229).
文摘Based on questionnaire surveys and field interviews conducted with various types of agricultural production organizations across five districts and four counties in Daqing City,this study combines relevant theoretical frameworks to systematically examine the evolution,performance,and influencing factors of governance mechanisms within these organizations.Using both quantitative and inductive analytical methods,the paper proposes innovative designs and supporting measures for improving governance mechanisms.The findings reveal that,amid large-scale farmland circulation,the governance mechanisms of agricultural production organizations in Daqing City are evolving from traditional to modern structures.However,challenges remain in areas such as decision-making efficiency,benefit distribution,and supervision mechanisms.In response,this study proposes innovative governance designs focusing on decision-making processes,profit-sharing mechanisms,and risk prevention.Corresponding policy recommendations are also provided to support the sustainable development of agricultural modernization in China.
