As significant evidence of permafrost degradation,thermokarst lakes play an important role in the permafrost regions by regulating hydrology,ecology,and biogeochemistry.In the Sources Area of the Yellow River(SAYR),pe...As significant evidence of permafrost degradation,thermokarst lakes play an important role in the permafrost regions by regulating hydrology,ecology,and biogeochemistry.In the Sources Area of the Yellow River(SAYR),permafrost degradation has accelerated since the 1980s,and numerous thermokarst lakes have been discovered.In this paper,we use Sentinel-2 images to extract thermokarst lake boundaries and perform a regional-scale study on their geometry across the permafrost region in the SAYR.We also explored the spatiotemporal variations and potential drivers from the perspectives of the permafrost,climate,terrain and vegetation conditions.The results showed that there were 47,518 thermokarst lakes in 2021 with a total area of 190.22×106 m^(2),with an average size of 4,003.3 m^(2).The 44,928 ponds(≤10,000 m^(2))predominated the whole lake number(94.1%)but contributed to a small portion of the total lake area(28.8%).With 2,590 features(5.9%),small-sized(10,000 to 100,000 m^(2))and large-sized lakes(>100,000 m^(2))constituted up to 71.2%of the total lake area.Thermokarst lakes developed more significantly in warm permafrost regions than in cold permafrost areas;74.1%of lakes with a total area of 119.6×106 m^(2)(62.9%),were distributed in warm permafrost regions.Most thermokarst lakes were likely to develop within the elevation range of 4,500~4,800 m,on flat terrain(slope<10°),on SE and S aspects and in alpine meadow areas.The thermokarst lakes in the study region experienced significant shrinkage between 1990 and 2021,characterized by obvious lake drainage;the lake numbers decreased by 5418(56.1%),with a decreasing area of 58.63×106 m^(2)(49.0%).This shrinkage of the thermokarst lake area was attributable mainly to the intensified degradation of rich-ice permafrost thawing arising from continued climate warming,despite the wetting climatic trend.展开更多
Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan Distr...Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.展开更多
This study tracked the characteristics of atmospheric wet deposition of the toxic element arsenic(As)at both urban(Guangzhou(GZ))and forested(Dinghushan Natural Reserve(DHS))sites within the Pearl River Delta(PRD)regi...This study tracked the characteristics of atmospheric wet deposition of the toxic element arsenic(As)at both urban(Guangzhou(GZ))and forested(Dinghushan Natural Reserve(DHS))sites within the Pearl River Delta(PRD)region between 2016 and 2019,examining its correlation with rainfall patterns.Additionally,by employing backward trajectory analysis and the potential source contribution function(PSCF)in conjunction with pertinent emission inventories,we pinpointed the main pathways of atmospheric arsenic transport and evaluated the emission contributions from priority source areas.The study revealed that the atmospheric arsenic wet deposition fluxes at the GZ and DHS sites exhibited a trend of increase followed by a decrease over the four-year period.Wet season deposition fluxes were more than triple those of the dry season,with urban site showing a difference of over four times.Notably,wet season As deposition at both sites was predominantly affected by heavy rainfall from marine air masses,constituting 31%of the total deposition.The predominant trajectory directions contributing to arsenic deposition at GZ and DHS were northeast(55%)and south(53%),respectively.The primary source areas for both sites were largely outside the PRD region,with the GZ site having 80%to 95%of its source area in the non-PRD region,compared to 69%to 88%at the DHS site.Furthermore,non-PRD areas contributed approximately 65%to arsenic emissions for both sites,with the industrial sector being the dominant emission source,exceeding 97%of the total emissions.展开更多
The Gannan Yellow River source area(YRSA)is a typical ecological fragile region.Assessing the temporal and spatial patterns of resource and environmental carrying capacity(RECC)is crucial for both ecological security ...The Gannan Yellow River source area(YRSA)is a typical ecological fragile region.Assessing the temporal and spatial patterns of resource and environmental carrying capacity(RECC)is crucial for both ecological security and sustainable development of the Yellow River Basin and the YRSA.Based on RECC theory,this study developed a novel index system focused on human-livestock-grassland relationships to accurately capture resource and environmental carrying characteristics in pastoral regions.By establishing region-specific evaluation thresholds and using a comprehensive index approach,we analyzed spatial and temporal patterns of resource carrying capacity(RCC),environmental carrying capacity(ECC),and resource and environmental carrying capacity(RECC)in the Gannan region from 2005 to 2020.The results indicate that:1)The RECC followed an increasing–decreasing–increasing trajectory from 2005 to 2020,with values ranging from 0.30 to 0.69.The RECC in pastoral areas was not only higher but also exhibited greater variability compared to that in agricultural areas.2)The RCC remained at a low level,with values between 0.06 to 0.098.The index of water consumption per ten thousand Yuan of GDP increased significantly,suggesting that improvements in water use efficiency contributed to the enhancement of RCC.3)The ECC increased notably,shifting from the middle to a very high level,with values ranging from 0.233 to 0.611.ECC emerged as a key determinant of RECC,exhibiting a temporal trend closely aligned with that of RECC.Changes in ECC were primarily driven by factors such as overgrazing rates,the extent of grassland rodent control,and the area of grassland for reseeding and improvement.Based on these findings,future priorities should include the adoption of efficient water-saving irrigation technologies,the promotion of rotational grazing practices,and the optimization of land management strategies.展开更多
The mound-making behavior of plateau zokors is one of the most important factors in remodeling meadow microtopography and causing soil erosion in the Yellow River source area of western China,but little is known about...The mound-making behavior of plateau zokors is one of the most important factors in remodeling meadow microtopography and causing soil erosion in the Yellow River source area of western China,but little is known about the effects of microtopography on particle size characteristics(PSC)of eroded sediments from the bare slopes of zokor mounds during different rainfall events.In this study,we analyzed the relationship of microtopographic features derived from laser point cloud data and PSC of eroded sediments at six simulated rainfall intensities(all lasting 60 min).The effects of microtopography on PSC of eroded sediments were studied via partial least squares regression(PLSR)and structural equation modeling(SEM).The results showed that:(1)15-20 minutes from the beginning of rainfall was the sensitive period of soil loss from the slopes,and the function relationship between the rate of sediment and runoff and rainfall intensity can better predict the development trend of soil erosion;(2)Intense erosion occurred mainly in the upper half of the zokor mound,while deposition was mainly limited to its lower half.It is suggested that diminished plateau zokor activity intensity can effectively prevent and control soil erosion;(3)The PSC of eroded sediment is dominated by silt,followed by sand,with clay being the least abundant,and the eroded sediments with a particle size of 10-20μm were sensitive and highly susceptible to rainfall erosion.This finding facilitates the understanding of the formation process of surface geomorphology and the mechanism of soil erosion;(4)The PLSR model indicates that microtopography has an extensive influence on eroded sediments during hydraulic erosion,and the SEM analysis results further confirm that the fractal dimension was the best parameter to represent the PSC of eroded sediments,whereas surface cutting degree was the dominant factor controlling the PSC of eroded sediments.These findings are crucial for predicting soil erosion in the Yellow River source area and provide a new perspective for understanding soil erosion mechanisms in alpine meadow ecosystems.展开更多
Based on the decoupiing theory and method, an indicator system was built for the relation between economic development level and resource and environment carrying capacity. And the study was carried out on decoupling ...Based on the decoupiing theory and method, an indicator system was built for the relation between economic development level and resource and environment carrying capacity. And the study was carried out on decoupling degree and temporal changes of economic development level and resource and environment carrying ca- pacity in the central area of Yunnan Province. Results indicated that （i） the economic development level and resource and environment carrying capacity in the central area of Yunnan Province mainly experienced strong decoupling, weak decoupling, and ex- pansive negative coupling, and in general it was strong decoupling, and it took on re- verse ＂N＂ in temporal changes. （ii） Change rate of economic development level in the central area of Yunnan Province was greater than zero, but the amplitude of change was not large, while the change rate of resource and environment carrying capacity was negative in 2007-2008, and it was positive in the rest years; from 2007, it took on gradual expansion trend, and scissors difference gradually increased after experi- encing reverse ＂V＂ change. （iii） The strong decoupling was the main situation and it reached the peak value in T5 period and T6 pedod.展开更多
[Objective] The paper was to analyze the quality of flux observation data of rubber plantation.[Method]Based on the FSAM model,footprint and flux source area were analyzed according to the continuous flux measurement ...[Objective] The paper was to analyze the quality of flux observation data of rubber plantation.[Method]Based on the FSAM model,footprint and flux source area were analyzed according to the continuous flux measurement with the open-path eddy covariance system on the 50 m tower of Danzhou Key Field Station of Observation and Research for Tropical Agricultural Resources and Environments,Ministry of Agriculture from Jan 1 to Jun 30,2010.[Result] Under unstable stratification,source areas were smaller than those under stable conditions,and source areas in the dormant season were larger than those in the growing season at the same level.In the main wind direction 130°-270°,the upwind range of source areas was in the magnitude of 100-758 m and vertical upwind range was-251-251 m at 80% level under unstable stratification in the growing season,and they were some large than those under the unstable stratification in the dormant season.The source areas of the upwind and vertical upwind ranges were 173-1 858,-534-534 m especially under stable stratification in the growing season,and they were smaller than those under stable stratification in the dormant season.In the other wind directions of 0°-130° and 270°-360°,the ranges were similar to those of the growing season in the prevailing wind direction under the same atmospheric conditions.[Conclusion] The study would lay a foundation for the future flux calculation and analysis.展开更多
Climate change investigation at a watershed-scale plays a significant role in re- vealing the historical evolution and future trend of the runoff variation in watershed. This study examines the multisource hydrologica...Climate change investigation at a watershed-scale plays a significant role in re- vealing the historical evolution and future trend of the runoff variation in watershed. This study examines the multisource hydrological and meteorological variables over the source area of the Yellow River （SAYR） from 1961 to 2,012 and the future climate scenarios in the region during 2006-2100 based on the CMIP5 projection data. It recognizes the significant charac-teristics of the recent climate change in the SAYR and predicts the change trend of future flow in the region. It is found that （1） The climate in the SAYR has experienced a significant warm-wet change since the early 2000s, which is very different from the antecedent warm-dry trend since the late 1980s; （2） The warm-wet trend in the northwestern SAYR （the headwater area of the Yellow River （HAYR）, is more obvious than that in the whole SAYR; （3） With pre- cipitation increase, the runoff in the region also experienced an increasing process since 2006. The runoff variations in the region are sensitive to the changes of precipitation, PET and maximum air temperature, but not very sensitive to changes in mean and minimum air temperatures; （4） Based on the CMIP5 projection data, the warm-wet climate trend in SAYR are likely to continue until 2049 if considering three different （i.e. RCP2.6, RCP4.5 and RCP8.5） greenhouse gas emission scenarios, and the precipitation in SAYR will not be less than the current level before 2100; however, it is estimated that the recent flow increase in the SAYR is likely to be the decadal change and it will at most continue until the 2020s; （5） The inter-annual variations of the East Asian winter monsoon are found to be closely related to the variations of annual precipitation in the region. Meanwhile, the increased precipitation as well as the increase of potential evapotranspiration （PET） being far less than that of precipitation in the recent period are the main climate causes for the flow increase in the region.展开更多
With the analysis of the element geochemistry characteristics, the ancient lake infor- mation evolution history of the argillaceous source rocks in Lucaogou 0~/~＇~） Formation in San- gonghe area is reconstructed. A...With the analysis of the element geochemistry characteristics, the ancient lake infor- mation evolution history of the argillaceous source rocks in Lucaogou 0~/~＇~） Formation in San- gonghe area is reconstructed. According to the ancient lake information and total organic matter （TOC） characteristics of argillaceous source rocks, the study section is divided into 6 Subsec- tions. Subsection I mainly developed low-quality source rocks. This is because of the arid climate, high salinity, low lake productivity, unstable preservation conditions in this Subsection. Subsection II mainly developed high-quality source rocks. This is because of the humid climate, low salinity, high lake productivity, stable preservation conditions in this Subsection. Though the paleoclimate was humid and preservation conditions were stable. Lake productivity and the water salinity changed frequently. So Subsection III mainly developed medium-quality source rocks. Because of the humid climate, high lake productivity, medium sedimentary rate and stable preservation conditions, high-quality source rocks were developed in Subsection IV. The preservation conditions were stable, but other ancient lake information changed frequently. Therefore, the quality of the formed source rocks in Subsection V was different. Subsection VI mainly developed high-quality source rocks be- cause of the humid climate, medium sedimentary rate, high lake productivity, low salinity and good preservation conditions. In summary, the ancient lake information parameters and TOC characteris- tics of each Subsection are different from each other.展开更多
A study on designing the tax of nitrogen fertilizer can provide a new method for controlling nitrogen fertilizer non-point source pollution. The tax design of nitrogen fertilizer was discussed by utilizing the externa...A study on designing the tax of nitrogen fertilizer can provide a new method for controlling nitrogen fertilizer non-point source pollution. The tax design of nitrogen fertilizer was discussed by utilizing the external theory and the demand elasticity theory. The results indicated that the coefficient of price elasticity of nitrogen fertilizer demand is -0.21, which instructed that the market demand is in lack of elasticity in the short period and the impact of nitrogen fertilizer manufacturers is subtle. The 11 counties （cities and boroughs） in the Dongting Lake area in China, where the farmland nitrogen application surpassed the average ecological fertilization dosage, is listed to the taxation scope of nitrogen fertilizer tax. The environment loss will reduce 0.07 hundred million RMB yuan and the revenue will increase 0.89 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The loss, which was brought by the decreasing food supplies production, will be 0.58 hundred million RMB yuan and the net social benefit will be 0.38 hundred million RMB yuan following revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.49%. The variation scope of the income of farmers will range from -8.41 to 6.44%. The 5 areas, Yunxi Borough, Junshan Borough, Hanshou County, Jinshi City, and Ziyang Borough, had an increase in food supplies production after the revenue collection. The environment loss will reduce 0.01 hundred million RMB yuan and the revenue will increase 0.16 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The economic benefits, which was brought by the increasing cereals production, will be 0.67 hundred million RMB yuan and the net social benefit will be 0.84 hundred million RMB yuan after revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.06%. The variation scope of the increasing income of farmers will range from 0.69 to 6.44%. Considering the entire social welfare, taxation of nitrogen fertilizer will have more advantages than disadvantages in the Dongting Lake area.展开更多
Non-point source pollution is one of the primarily ecological issues affecting the Three Gorges Reservoir Area. In this paper, landscape resistance and motivation coefficient, which integrated various landscape elemen...Non-point source pollution is one of the primarily ecological issues affecting the Three Gorges Reservoir Area. In this paper, landscape resistance and motivation coefficient, which integrated various landscape elements, such as land use, soil, hydrology, topography, and vegetation, was established based on the effects of large-scale resistance and motivation on the formation of non-point source pollution. In addition, cost models of the landscape re- sistance and motivation coefficients were constructed based on the distances from the land- scape units to the sub-basin outlets in order to identify the ＂source＂ and ＂sink＂ patterns af- fecting the formation of non-point source pollution. The results indicated that the changes in the landscape resistance and motivation coefficients of the 16 sub-basins exhibited inverse relationships to their spatial distributions. The landscape resistance and motivation cost curves were more volatile than the landscape resistance and motivation coefficient curves. The landscape resistance and motivation cost trends of the 16 sub-basins became increas- ingly apparent along the flow of the Yangtze River. The landscape resistance and motivation cost models proposed in this paper could be used to identify large-scale non-point source pollution ＂source＂ and ＂sink＂ patterns. Moreover, the proposed model could be used to de- scribe the large-scale spatial characteristics of non-point source pollution formation based on ＂source＂ and ＂sink＂ landscape pattern indices, spatial localization, and landscape resistance and motivation coefficients.展开更多
In order to investigate the hydrocarbon generation process and gas potentials of source rocks in deepwater area of the Qiongdongnan Basin, kinetic parameters of gas generation （activation energy distribution and freq...In order to investigate the hydrocarbon generation process and gas potentials of source rocks in deepwater area of the Qiongdongnan Basin, kinetic parameters of gas generation （activation energy distribution and frequency factor） of the Yacheng Formation source rocks （coal and neritic mudstones） was determined by thermal simulation experiments in the closed system and the specific KINETICS Software. The results show that the activation energy （Ea） distribution of C1–C5 generation ranges from 50 to 74 kcal/mol with a frequency factor of 2.4×1015 s–1 for the neritic mudstone and the Ea distribution of C1–C5 generation ranges from 49 to 73 kcal/mol with a frequency factor of 8.92×1013 s–1 for the coal. On the basis of these kinetic parameters and combined with the data of sedimentary burial and paleothermal histories, the gas generation model of the Yacheng Formation source rocks closer to geological condition was worked out, indicating its main gas generation stage at Ro （vitrinite reflectance） of 1.25%–2.8%. Meanwhile, the gas generation process of the source rocks of different structural locations （central part, southern slope and south low uplift） in the Lingshui Sag was simulated. Among them, the gas generation of the Yacheng Formation source rocks in the central part and the southern slope of the sag entered the main gas window at 10 and 5 Ma respectively and the peak gas generation in the southern slope occurred at 3 Ma. The very late peak gas generation and the relatively large gas potential indices （GPI：20×10^8–60×10^8 m^3/km^2） would provide favorable conditions for the accumulation of large natural gas reserves in the deepwater area.展开更多
Understanding the connotation and principles of ecological compensation in water source reserve areas is the basis and guarantee for establishing and improving the ecological compensation mechanism of water source res...Understanding the connotation and principles of ecological compensation in water source reserve areas is the basis and guarantee for establishing and improving the ecological compensation mechanism of water source reserve areas.First,this paper reviews the three stages of ecological compensation research progress.Based on the review,using the theory of externality,the ecological environment system of water source reserve areas is then analyzed.This paper argues that the connotation of ecological compensation in water source reserve areas is a kind of institutional arrangement,which is designed to internalize externalities.Finally,based on the understanding of the connotation of ecological compensation in water source reserve areas,five principles for establishing and improving the ecological compensation mechanism are proposed,including the principle of fairness and justice,the principle of equivalence of equality and responsibility,the principle of flexibility and effectiveness,the principle of "earmark funds,and implementation by law," and the principle of government compensation supplemented with market compensation.展开更多
Non-point-source pollution has become a major threat to the water quality of the Three Gorges Reservoir(TGR);however,nutrient loadings from terrestrial sources are unclear due to a lack of in situ monitoring.A represe...Non-point-source pollution has become a major threat to the water quality of the Three Gorges Reservoir(TGR);however,nutrient loadings from terrestrial sources are unclear due to a lack of in situ monitoring.A representative small watershed in the central part of the TGR area was selected to monitor the loss of nitrogen(N) and phosphorous(P) continuously along with the runoff from 2007 through 2009 to understand the exact sources and loadings.Results show that the non-point-source nitrogen and phosphorus comes mainly from the storm runoff from residential areas,citrus orchards and sloping croplands,which contributes up to 76% of the loadings in this watershed.Thus,a crucial measure for controlling non-point-source pollution is to intercept storm runoff from the three sources.Paddy fields provide a sink for non-point-source N and P by intercepting the runoff and sediment along with their different forms of nitrogen and phosphorus.The N and P removal efficiency by paddy fields from residential areas is within the range of 56% to 98%.Paddy fields are an important land-use option for reducing the non-point-source loading of N and P in the TGR area.展开更多
To elucidate the air pollution characteristics of northern China, airborne PM_10（atmospheric dynamic equivalent diameter ≤ 10 μm） and PM_（2.5）（atmospheric dynamic equivalent diameter ≤ 2.5 μm） were sampled i...To elucidate the air pollution characteristics of northern China, airborne PM_10（atmospheric dynamic equivalent diameter ≤ 10 μm） and PM_（2.5）（atmospheric dynamic equivalent diameter ≤ 2.5 μm） were sampled in three different functional areas（Yuzhong County,Xigu District and Chengguan District） of Lanzhou, and their chemical composition（elements, ions, carbonaceous species） was analyzed. The results demonstrated that the highest seasonal mean concentrations of PM_10（369.48 μg/m^3） and PM_（2.5）（295.42 μg/m^3） were detected in Xigu District in the winter, the lowest concentration of PM_（2.5）（53.15 μg/m^3） was observed in Yuzhong District in the fall and PM_10（89.60 μg/m^3） in Xigu District in the fall.The overall average OC/EC（organic carbon/elemental carbon） value was close to the representative OC/EC ratio for coal consumption, implying that the pollution of Lanzhou could be attributed to the burning of coal. The content of SNA（the sum of sulfate, nitrate,ammonium, SNA） in PM_（2.5）in Yuzhong County was generally lower than that at other sites in all seasons. The content of SNA in PM_（2.5）and PM_10 in Yuzhong County was generally lower than that at other sites in all seasons（0.24–0.38）, indicating that the conversion ratios from precursors to secondary aerosols in the low concentration area was slower than in the area with high and intense pollutants. Six primary particulate matter sources were chosen based on positive matrix factorization（PMF） analysis, and emissions from dust, secondary aerosols, and coal burning were identified to be the primary sources responsible for the particle pollution in Lanzhou.展开更多
Long-term changes of composition, sources and burial fluxes of TOC （total organic carbon） in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper. Firstly, si...Long-term changes of composition, sources and burial fluxes of TOC （total organic carbon） in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper. Firstly, similarity analysis is employed to confirm that the carbon burial features resulted from two collected cores are typical in the central Yellow Sea mud area where YSWC （Yellow Sea Warm Current） is prevalent. On this basis, the burial flux of TOC here was considered to be 235.5-488.4 pmol/（cm^2.a） since the first industrial revolution, accounting for about 70%-90% among burial fluxes of TC （total carbon） in the sediments. Compared TOC/TC ratio in the two cores with that in other marine sediments worldwide, we suggest that the growth of calcareous/non-calcareous organisms and dissolution of IC （inorganic carbon） are important factors controlling the TOC/TC ratio in sediment. Results of two-end mixed model based on fi13C data indicate that marine-derived organic carbon （OCa） is the main part among total burial organic carbon which accounts for a ratio over 85%. Due to the high TOC/TC ratio in the two cores, TC in the sediments also mainly exists as OCa, and the proportion of OCa is about 60%-80%. Away from the shore and relatively high primary production in upper waters are the main reasons that OCa is predominant among all burial OC in sediments of the central Yellow Sea mud area. Burial of OC in this mud area is probably mainly influenced by the human activities. Although the economic development during the late 19th century caused by the first industrial revolution in China did not obviously increase the TOC burial fluxes in the sediments, the rise of industry and agriculture after the founding of new China has clearly increased the TOC burial flux since 1950s. Otherwise, we also realize that among TC burial fluxes, TIC account for about 10%-30% in sediments of the central Yellow Sea mud area, so its burial could not be simply ignored here. Distinct from TOC burial, long-term TIC burial fluxes variations relate with climate changes more closely： the East Asian summer monsoon may influence the strength of the Huanghe River （Yellow River） flood, which could further affect the transport of terrestrial IC from land to the central Yellow Sea as well as the burial of these IC in the sediments.展开更多
Many observations in and model simulations for northern basins have confirmed an increased streamflow from degrading permafrost,while the streamflow has declined in the source area of the Yellow River(SAYR,above the T...Many observations in and model simulations for northern basins have confirmed an increased streamflow from degrading permafrost,while the streamflow has declined in the source area of the Yellow River(SAYR,above the Tanag hydrological station)on the northeastern Qinghai-Tibet Plateau,West China.How and to what extent does the degrading permafrost change the flow in the SAYR?According to seasonal regimes of hydrological processes,the SAYR is divided intofour sub-basins with varied permafrost extents to detect impacts of permafrost degradation on the Yellow River streamflow.Results show that permafrost degradation may have released appreciable meltwater for recharging groundwater.The potential release rate of ground-ice melt-water in the Sub-basin 1(the headwater area of the Yellow River(HAYR),above the Huangheyan hydrological station)is the highest(5.6 mm per year),contributing to 14.4%of the annual Yellow River streamflow at Huangheyan.Seasonal/intra-and annual shifts of streamflow,a possible signal for the marked alteration of hydrological processes by permafrost degradation,is observed in the HAYR,but the shifts are minor in other sub-basins in the SAYR.Improved hydraulic connectivity is expected to occur during and after certain degrees of permafrost degradation.Direct impacts of permafrost degradation on the annual Yellow River streamflow in the SAYR at Tanag,i.e.,from the meltwater of ground-ice,is estimated at 4.9%that of the annual Yellow River discharge at Tanag,yet with a high uncertainty,due to neglecting of the improved hydraulic connections from permafrost degradation and the flow generation conditions for the ground-ice meltwater.Enhanced evapotranspiration,substantial weakening of the Southwest China Autumn Rain,and anthropogenic disturbances may largely account for the declined streamflow in the SAYR.展开更多
Acoustic emission(AE)localization plays an important role in the prediction and control of potential hazardous sources in complex structures.However,existing location methods have less discussion on the presence of un...Acoustic emission(AE)localization plays an important role in the prediction and control of potential hazardous sources in complex structures.However,existing location methods have less discussion on the presence of unknown empty areas.This paper proposes an AE source location method for structures containing unknown empty areas(SUEA).Firstly,this method identifies the shape,size,and location of empty areas in the unknown region by exciting the active AE sources and using the collected AE arrivals.Then,the unknown AE source can be located considering the identified empty areas.The lead break experiments were performed to verify the effectiveness and accuracy of the proposed method.Five specimens were selected containing empty areas with different positions,shapes,and sizes.Results show the average location accuracy of the SUEA increased by 78%compared to the results of the existing method.It can provide a more accurate solution for locating AE sources in complex structures containing unknown empty areas such as tunnels,bridges,railroads,and caves in practical engineering.展开更多
Based on stable isotope analysis, we characterized the dietary regime of the Manila clam Ruditapesphilippinarum inhabiting intertidal areas along the Liaodong Peninsula, Northern China. Samples, including particulate ...Based on stable isotope analysis, we characterized the dietary regime of the Manila clam Ruditapesphilippinarum inhabiting intertidal areas along the Liaodong Peninsula, Northern China. Samples, including particulate organic matter （POM; n=30）, benthic microalgae （BMI; n=30） and R. philippinarum （n=60）, were collected from six sampling sites displaying the same ecological conditions. Of the two primary food sources, POM was more depleted in δ13C （-20.61‰ to -22.89%0） than BMI was （-13.90‰ to -16.66‰）. With respect to 15N, BMI was more enriched （2.90%0 to 4.07%0） than POM was （4.13‰ to 5.12‰）. The δ13C values of R. philippinarum ranged from -18.78‰ to -19.35‰ and the δ15N values from 7.96%0 to 8.63‰, which were intermediate between the POM and BMI values. In a two-source isotope mixing model, we estimated the relative contributions of POM and BMI to the diet ofR. philippinarum to be 74.2% and 25.8%, respectively. We conclude that R. philippinarum feeds mainly on POM, and BMI is also an important supplemental food source in intertidal areas.展开更多
Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some d...Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some drilling wells of deep water area close to the central depression belt, Miocene marine source rocks with better organic matter abundance and hydrocarbon generation have been found, which have achieved better source rock standard based on the analysis of geochemical charac- teristics. Although there are no exploratory wells in deep water area of the research region, through the comparative analysis of geochemical data of several typical exploratory wells respectively from shallow water area in the basin, central depression belt margin in deep-water area of the basin and Site 1148 of deep sea drilling in the South China Sea Basin, it reveals that the tendency of the quality of source rocks becomes positive gradually from delta to bathyal environment, which then becomes negative as in deep oceanic environment. Owing to the lack of terrestrial organic matter input, the important controlling factors of Miocene marine source rocks in the Qiongdongnan Basin are ocean productivity and preservation conditions of organic matter. The element geochemistry data indicate that the tendency of the paleoproductivity and the preservation conditions of organic matter become positive as water depth increase from shallow area to bathyal area close to central depression belt. So it is speculated that there must exist high quality source rocks in the central depression area where the preservation conditions of organic matter are much better. Besides, in theory, in oxygen-poor zone of oceanic environment at the water depth 400–1 000 m, the preservation conditions of organic matter are well thus forming high-quality marine source rocks. The result- ing speculation, it is reasonable to consider that there are high hydrocarbon generation potential source rocks in bathyal environment of the Qiongdongnan Basin, especially at the water depth 400– 1 000 m.展开更多
基金supported by the Natural Science Foundation of Qinghai Province,China(No.2021-ZJ940Q)the Open Project of State Key Laboratory of Plateau Ecology and Agriculture,Qinghai University(No.2022-ZZ-02)。
文摘As significant evidence of permafrost degradation,thermokarst lakes play an important role in the permafrost regions by regulating hydrology,ecology,and biogeochemistry.In the Sources Area of the Yellow River(SAYR),permafrost degradation has accelerated since the 1980s,and numerous thermokarst lakes have been discovered.In this paper,we use Sentinel-2 images to extract thermokarst lake boundaries and perform a regional-scale study on their geometry across the permafrost region in the SAYR.We also explored the spatiotemporal variations and potential drivers from the perspectives of the permafrost,climate,terrain and vegetation conditions.The results showed that there were 47,518 thermokarst lakes in 2021 with a total area of 190.22×106 m^(2),with an average size of 4,003.3 m^(2).The 44,928 ponds(≤10,000 m^(2))predominated the whole lake number(94.1%)but contributed to a small portion of the total lake area(28.8%).With 2,590 features(5.9%),small-sized(10,000 to 100,000 m^(2))and large-sized lakes(>100,000 m^(2))constituted up to 71.2%of the total lake area.Thermokarst lakes developed more significantly in warm permafrost regions than in cold permafrost areas;74.1%of lakes with a total area of 119.6×106 m^(2)(62.9%),were distributed in warm permafrost regions.Most thermokarst lakes were likely to develop within the elevation range of 4,500~4,800 m,on flat terrain(slope<10°),on SE and S aspects and in alpine meadow areas.The thermokarst lakes in the study region experienced significant shrinkage between 1990 and 2021,characterized by obvious lake drainage;the lake numbers decreased by 5418(56.1%),with a decreasing area of 58.63×106 m^(2)(49.0%).This shrinkage of the thermokarst lake area was attributable mainly to the intensified degradation of rich-ice permafrost thawing arising from continued climate warming,despite the wetting climatic trend.
基金supported by Inner Mongolia Autonomous Region Department of Education Science and Technology Talent Project(No.NJYT22040)Inner Mongolia Agricultural University Young Teachers'Scientific Research Ability Promotion Project(No.BR220102)+4 种基金the National Natural Science Foundation of China(No.52260029)the National Key R&D Program(No.2019YFC0409204)Inner Mongolia Natural Science Foundation(No.2021MS04013)the Science and Technology Project of Inner Mongolia Autonomous Region(No.2023YFHH0060)Inner Mongolia AutonomousRegion Science and Technology Leading TalentTeam(No.2022LJRC0007).
文摘Analyzing the sources of nitrogen and phosphorus pollution in atmospheric deposition is crucial for protecting the surfacewater environment in vulnerable areas.This study focused on the Dahekou Reservoir,Shayuan District,Xilin Gol League,Inner Mongolia,China.It established 12 monitoring sites,conducted one-year monitoring,and collected 144 samples.The concentrations of nitrogen,phosphorus,and water-soluble ions in atmospheric wet sedimentation were measured.This study identified atmospheric precipitation types,revealed seasonal variations in nitrogen and phosphorus concentrations,assessed the contribution of atmosphericwet sedimentation to reservoirwater quality.Utilizing the airmass backward trajectory(HYSPLIT)model and PMF model,themain pollution sources were analyzed.The results were as follows.1)During the observation period,the atmospheric precipitation types were nitric acid rain in spring,sulfuric acid rain in winter,and mixed acid rain in summer and autumn.2)The monthly concentrations of nitrogen and phosphorus of various forms varied significantly,with NH_(4)^(+)-N peaking in spring,NO_(3)^(-)-N and DOP in autumn,and DIP and DON in summer.Annual pollution loads of atmospheric nitrogen and phosphorus precipitation into the reservoir were 35.77 and 4.17 t/a,respectively,severely impacting reservoir water quality.3)Precipitation was negatively correlated with TN concentration,particularly with the NO_(3)^(-)-N/TN ratio,and positively correlated with TP and DIP concen-trations.4)The analysis of pollution sources indicated that the sources of atmospheric nitrogen and phosphorus wet deposition pollution in the study area included agricultural,anthropogenic,dust,and coal sources,with contribution rates of 32.4%,25.6%,21.0%,and 21.0%,respectively.
基金supported by the National Natural Science Foundation of China(Nos.42121004,42275107,and 42077205)the National Key Research and Development Plan(No.2023YFC3706202)+1 种基金the Foundational and Applied Basic Research in Guangzhou in 2023(No.2023A04J0251)the Special Fund Project for Science and Technology Innovation Strategy of Guangdong Province(No.2019B121205004)。
文摘This study tracked the characteristics of atmospheric wet deposition of the toxic element arsenic(As)at both urban(Guangzhou(GZ))and forested(Dinghushan Natural Reserve(DHS))sites within the Pearl River Delta(PRD)region between 2016 and 2019,examining its correlation with rainfall patterns.Additionally,by employing backward trajectory analysis and the potential source contribution function(PSCF)in conjunction with pertinent emission inventories,we pinpointed the main pathways of atmospheric arsenic transport and evaluated the emission contributions from priority source areas.The study revealed that the atmospheric arsenic wet deposition fluxes at the GZ and DHS sites exhibited a trend of increase followed by a decrease over the four-year period.Wet season deposition fluxes were more than triple those of the dry season,with urban site showing a difference of over four times.Notably,wet season As deposition at both sites was predominantly affected by heavy rainfall from marine air masses,constituting 31%of the total deposition.The predominant trajectory directions contributing to arsenic deposition at GZ and DHS were northeast(55%)and south(53%),respectively.The primary source areas for both sites were largely outside the PRD region,with the GZ site having 80%to 95%of its source area in the non-PRD region,compared to 69%to 88%at the DHS site.Furthermore,non-PRD areas contributed approximately 65%to arsenic emissions for both sites,with the industrial sector being the dominant emission source,exceeding 97%of the total emissions.
基金funded by the Gansu Provincial Science and Technology Program in China(Grant No.22ZD6FA005)。
文摘The Gannan Yellow River source area(YRSA)is a typical ecological fragile region.Assessing the temporal and spatial patterns of resource and environmental carrying capacity(RECC)is crucial for both ecological security and sustainable development of the Yellow River Basin and the YRSA.Based on RECC theory,this study developed a novel index system focused on human-livestock-grassland relationships to accurately capture resource and environmental carrying characteristics in pastoral regions.By establishing region-specific evaluation thresholds and using a comprehensive index approach,we analyzed spatial and temporal patterns of resource carrying capacity(RCC),environmental carrying capacity(ECC),and resource and environmental carrying capacity(RECC)in the Gannan region from 2005 to 2020.The results indicate that:1)The RECC followed an increasing–decreasing–increasing trajectory from 2005 to 2020,with values ranging from 0.30 to 0.69.The RECC in pastoral areas was not only higher but also exhibited greater variability compared to that in agricultural areas.2)The RCC remained at a low level,with values between 0.06 to 0.098.The index of water consumption per ten thousand Yuan of GDP increased significantly,suggesting that improvements in water use efficiency contributed to the enhancement of RCC.3)The ECC increased notably,shifting from the middle to a very high level,with values ranging from 0.233 to 0.611.ECC emerged as a key determinant of RECC,exhibiting a temporal trend closely aligned with that of RECC.Changes in ECC were primarily driven by factors such as overgrazing rates,the extent of grassland rodent control,and the area of grassland for reseeding and improvement.Based on these findings,future priorities should include the adoption of efficient water-saving irrigation technologies,the promotion of rotational grazing practices,and the optimization of land management strategies.
基金financially supported by the Qinghai University Graduate Student Research and Practice Innovation Project(2025-GPKY-12)Basic Research Project of Qinghai Provincial Science and Technology Department(2021-ZJ-701)+1 种基金National Natural Science Foundation of China(U23A20159,42161068)the 111 Project of China(D18013)。
文摘The mound-making behavior of plateau zokors is one of the most important factors in remodeling meadow microtopography and causing soil erosion in the Yellow River source area of western China,but little is known about the effects of microtopography on particle size characteristics(PSC)of eroded sediments from the bare slopes of zokor mounds during different rainfall events.In this study,we analyzed the relationship of microtopographic features derived from laser point cloud data and PSC of eroded sediments at six simulated rainfall intensities(all lasting 60 min).The effects of microtopography on PSC of eroded sediments were studied via partial least squares regression(PLSR)and structural equation modeling(SEM).The results showed that:(1)15-20 minutes from the beginning of rainfall was the sensitive period of soil loss from the slopes,and the function relationship between the rate of sediment and runoff and rainfall intensity can better predict the development trend of soil erosion;(2)Intense erosion occurred mainly in the upper half of the zokor mound,while deposition was mainly limited to its lower half.It is suggested that diminished plateau zokor activity intensity can effectively prevent and control soil erosion;(3)The PSC of eroded sediment is dominated by silt,followed by sand,with clay being the least abundant,and the eroded sediments with a particle size of 10-20μm were sensitive and highly susceptible to rainfall erosion.This finding facilitates the understanding of the formation process of surface geomorphology and the mechanism of soil erosion;(4)The PLSR model indicates that microtopography has an extensive influence on eroded sediments during hydraulic erosion,and the SEM analysis results further confirm that the fractal dimension was the best parameter to represent the PSC of eroded sediments,whereas surface cutting degree was the dominant factor controlling the PSC of eroded sediments.These findings are crucial for predicting soil erosion in the Yellow River source area and provide a new perspective for understanding soil erosion mechanisms in alpine meadow ecosystems.
基金Supported by Scientific Research Foundation of Yunnan Provincial Department of Education(2015J088)~~
文摘Based on the decoupiing theory and method, an indicator system was built for the relation between economic development level and resource and environment carrying capacity. And the study was carried out on decoupling degree and temporal changes of economic development level and resource and environment carrying ca- pacity in the central area of Yunnan Province. Results indicated that （i） the economic development level and resource and environment carrying capacity in the central area of Yunnan Province mainly experienced strong decoupling, weak decoupling, and ex- pansive negative coupling, and in general it was strong decoupling, and it took on re- verse ＂N＂ in temporal changes. （ii） Change rate of economic development level in the central area of Yunnan Province was greater than zero, but the amplitude of change was not large, while the change rate of resource and environment carrying capacity was negative in 2007-2008, and it was positive in the rest years; from 2007, it took on gradual expansion trend, and scissors difference gradually increased after experi- encing reverse ＂V＂ change. （iii） The strong decoupling was the main situation and it reached the peak value in T5 period and T6 pedod.
基金Supported by the Fundamental Research Funds for Rubber Research Institute,CATAS (1630022011013 )Hainan Natural Science Foundation (807045)Running Costs of Danzhou Key Field Station of Observation and Research for Tropical Agricultural Resources and Environments,Ministry of Agriculture~~
文摘[Objective] The paper was to analyze the quality of flux observation data of rubber plantation.[Method]Based on the FSAM model,footprint and flux source area were analyzed according to the continuous flux measurement with the open-path eddy covariance system on the 50 m tower of Danzhou Key Field Station of Observation and Research for Tropical Agricultural Resources and Environments,Ministry of Agriculture from Jan 1 to Jun 30,2010.[Result] Under unstable stratification,source areas were smaller than those under stable conditions,and source areas in the dormant season were larger than those in the growing season at the same level.In the main wind direction 130°-270°,the upwind range of source areas was in the magnitude of 100-758 m and vertical upwind range was-251-251 m at 80% level under unstable stratification in the growing season,and they were some large than those under the unstable stratification in the dormant season.The source areas of the upwind and vertical upwind ranges were 173-1 858,-534-534 m especially under stable stratification in the growing season,and they were smaller than those under stable stratification in the dormant season.In the other wind directions of 0°-130° and 270°-360°,the ranges were similar to those of the growing season in the prevailing wind direction under the same atmospheric conditions.[Conclusion] The study would lay a foundation for the future flux calculation and analysis.
基金The Key Deployment Project of the Chinese Academy of Sciences, No.Y322G73001 National Natural Science Foundation of China, No.91225302, No.91437217, No.41375022, No.41175027 Acknowledgments The TRMM data are provided by the NASA/Goddard Space Flight Center＇s Mesoscale Atmospheric Processes Laboratory and PPS, which develop and compute the TMPA as a contribution to TRMM. We acknowledge computing resources and time on the Supercomputing Center of Cold and Arid Region Environment and Engineering Research Institute of Chinese Academy of Sciences. We also acknowledge National Climate Center of China for collecting, analyzing and providing the data of the World Climate Research Programme＇s （WCRP＇s） the Fifth Phase of the Coupled Model Intercomparison Project （CMIP5）.
文摘Climate change investigation at a watershed-scale plays a significant role in re- vealing the historical evolution and future trend of the runoff variation in watershed. This study examines the multisource hydrological and meteorological variables over the source area of the Yellow River （SAYR） from 1961 to 2,012 and the future climate scenarios in the region during 2006-2100 based on the CMIP5 projection data. It recognizes the significant charac-teristics of the recent climate change in the SAYR and predicts the change trend of future flow in the region. It is found that （1） The climate in the SAYR has experienced a significant warm-wet change since the early 2000s, which is very different from the antecedent warm-dry trend since the late 1980s; （2） The warm-wet trend in the northwestern SAYR （the headwater area of the Yellow River （HAYR）, is more obvious than that in the whole SAYR; （3） With pre- cipitation increase, the runoff in the region also experienced an increasing process since 2006. The runoff variations in the region are sensitive to the changes of precipitation, PET and maximum air temperature, but not very sensitive to changes in mean and minimum air temperatures; （4） Based on the CMIP5 projection data, the warm-wet climate trend in SAYR are likely to continue until 2049 if considering three different （i.e. RCP2.6, RCP4.5 and RCP8.5） greenhouse gas emission scenarios, and the precipitation in SAYR will not be less than the current level before 2100; however, it is estimated that the recent flow increase in the SAYR is likely to be the decadal change and it will at most continue until the 2020s; （5） The inter-annual variations of the East Asian winter monsoon are found to be closely related to the variations of annual precipitation in the region. Meanwhile, the increased precipitation as well as the increase of potential evapotranspiration （PET） being far less than that of precipitation in the recent period are the main climate causes for the flow increase in the region.
基金supported by the National Natural Science Foundation of China(Nos.40972076 and 41302075)National Technical Key Special Project of China(No.2008ZX05018-001-004)
文摘With the analysis of the element geochemistry characteristics, the ancient lake infor- mation evolution history of the argillaceous source rocks in Lucaogou 0~/~＇~） Formation in San- gonghe area is reconstructed. According to the ancient lake information and total organic matter （TOC） characteristics of argillaceous source rocks, the study section is divided into 6 Subsec- tions. Subsection I mainly developed low-quality source rocks. This is because of the arid climate, high salinity, low lake productivity, unstable preservation conditions in this Subsection. Subsection II mainly developed high-quality source rocks. This is because of the humid climate, low salinity, high lake productivity, stable preservation conditions in this Subsection. Though the paleoclimate was humid and preservation conditions were stable. Lake productivity and the water salinity changed frequently. So Subsection III mainly developed medium-quality source rocks. Because of the humid climate, high lake productivity, medium sedimentary rate and stable preservation conditions, high-quality source rocks were developed in Subsection IV. The preservation conditions were stable, but other ancient lake information changed frequently. Therefore, the quality of the formed source rocks in Subsection V was different. Subsection VI mainly developed high-quality source rocks be- cause of the humid climate, medium sedimentary rate, high lake productivity, low salinity and good preservation conditions. In summary, the ancient lake information parameters and TOC characteris- tics of each Subsection are different from each other.
文摘A study on designing the tax of nitrogen fertilizer can provide a new method for controlling nitrogen fertilizer non-point source pollution. The tax design of nitrogen fertilizer was discussed by utilizing the external theory and the demand elasticity theory. The results indicated that the coefficient of price elasticity of nitrogen fertilizer demand is -0.21, which instructed that the market demand is in lack of elasticity in the short period and the impact of nitrogen fertilizer manufacturers is subtle. The 11 counties （cities and boroughs） in the Dongting Lake area in China, where the farmland nitrogen application surpassed the average ecological fertilization dosage, is listed to the taxation scope of nitrogen fertilizer tax. The environment loss will reduce 0.07 hundred million RMB yuan and the revenue will increase 0.89 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The loss, which was brought by the decreasing food supplies production, will be 0.58 hundred million RMB yuan and the net social benefit will be 0.38 hundred million RMB yuan following revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.49%. The variation scope of the income of farmers will range from -8.41 to 6.44%. The 5 areas, Yunxi Borough, Junshan Borough, Hanshou County, Jinshi City, and Ziyang Borough, had an increase in food supplies production after the revenue collection. The environment loss will reduce 0.01 hundred million RMB yuan and the revenue will increase 0.16 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The economic benefits, which was brought by the increasing cereals production, will be 0.67 hundred million RMB yuan and the net social benefit will be 0.84 hundred million RMB yuan after revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.06%. The variation scope of the increasing income of farmers will range from 0.69 to 6.44%. Considering the entire social welfare, taxation of nitrogen fertilizer will have more advantages than disadvantages in the Dongting Lake area.
文摘Non-point source pollution is one of the primarily ecological issues affecting the Three Gorges Reservoir Area. In this paper, landscape resistance and motivation coefficient, which integrated various landscape elements, such as land use, soil, hydrology, topography, and vegetation, was established based on the effects of large-scale resistance and motivation on the formation of non-point source pollution. In addition, cost models of the landscape re- sistance and motivation coefficients were constructed based on the distances from the land- scape units to the sub-basin outlets in order to identify the ＂source＂ and ＂sink＂ patterns af- fecting the formation of non-point source pollution. The results indicated that the changes in the landscape resistance and motivation coefficients of the 16 sub-basins exhibited inverse relationships to their spatial distributions. The landscape resistance and motivation cost curves were more volatile than the landscape resistance and motivation coefficient curves. The landscape resistance and motivation cost trends of the 16 sub-basins became increas- ingly apparent along the flow of the Yangtze River. The landscape resistance and motivation cost models proposed in this paper could be used to identify large-scale non-point source pollution ＂source＂ and ＂sink＂ patterns. Moreover, the proposed model could be used to de- scribe the large-scale spatial characteristics of non-point source pollution formation based on ＂source＂ and ＂sink＂ landscape pattern indices, spatial localization, and landscape resistance and motivation coefficients.
基金The National Science and Technology Major Project of China under contract No.2011ZX05025-002
文摘In order to investigate the hydrocarbon generation process and gas potentials of source rocks in deepwater area of the Qiongdongnan Basin, kinetic parameters of gas generation （activation energy distribution and frequency factor） of the Yacheng Formation source rocks （coal and neritic mudstones） was determined by thermal simulation experiments in the closed system and the specific KINETICS Software. The results show that the activation energy （Ea） distribution of C1–C5 generation ranges from 50 to 74 kcal/mol with a frequency factor of 2.4×1015 s–1 for the neritic mudstone and the Ea distribution of C1–C5 generation ranges from 49 to 73 kcal/mol with a frequency factor of 8.92×1013 s–1 for the coal. On the basis of these kinetic parameters and combined with the data of sedimentary burial and paleothermal histories, the gas generation model of the Yacheng Formation source rocks closer to geological condition was worked out, indicating its main gas generation stage at Ro （vitrinite reflectance） of 1.25%–2.8%. Meanwhile, the gas generation process of the source rocks of different structural locations （central part, southern slope and south low uplift） in the Lingshui Sag was simulated. Among them, the gas generation of the Yacheng Formation source rocks in the central part and the southern slope of the sag entered the main gas window at 10 and 5 Ma respectively and the peak gas generation in the southern slope occurred at 3 Ma. The very late peak gas generation and the relatively large gas potential indices （GPI：20×10^8–60×10^8 m^3/km^2） would provide favorable conditions for the accumulation of large natural gas reserves in the deepwater area.
基金supported by National Social Science Fund "Study on the construction of ecological compensation system and the related policies of the water source protection zone"[Grant Number 14BJY027]Project of Humanities and Social Science Fund of Ministry of Education "Calculation and compensation method of ecological compensation in River Basin"[Grant Number 13YJA790025]
文摘Understanding the connotation and principles of ecological compensation in water source reserve areas is the basis and guarantee for establishing and improving the ecological compensation mechanism of water source reserve areas.First,this paper reviews the three stages of ecological compensation research progress.Based on the review,using the theory of externality,the ecological environment system of water source reserve areas is then analyzed.This paper argues that the connotation of ecological compensation in water source reserve areas is a kind of institutional arrangement,which is designed to internalize externalities.Finally,based on the understanding of the connotation of ecological compensation in water source reserve areas,five principles for establishing and improving the ecological compensation mechanism are proposed,including the principle of fairness and justice,the principle of equivalence of equality and responsibility,the principle of flexibility and effectiveness,the principle of "earmark funds,and implementation by law," and the principle of government compensation supplemented with market compensation.
基金supported by the National Science & Technology Pillar Program(Grant No. 2011BAD31B03)the Special Project on Water Pollution Control by the National Science & Technology Pillar Program(Grant No. 2009ZX07104-002)
文摘Non-point-source pollution has become a major threat to the water quality of the Three Gorges Reservoir(TGR);however,nutrient loadings from terrestrial sources are unclear due to a lack of in situ monitoring.A representative small watershed in the central part of the TGR area was selected to monitor the loss of nitrogen(N) and phosphorous(P) continuously along with the runoff from 2007 through 2009 to understand the exact sources and loadings.Results show that the non-point-source nitrogen and phosphorus comes mainly from the storm runoff from residential areas,citrus orchards and sloping croplands,which contributes up to 76% of the loadings in this watershed.Thus,a crucial measure for controlling non-point-source pollution is to intercept storm runoff from the three sources.Paddy fields provide a sink for non-point-source N and P by intercepting the runoff and sediment along with their different forms of nitrogen and phosphorus.The N and P removal efficiency by paddy fields from residential areas is within the range of 56% to 98%.Paddy fields are an important land-use option for reducing the non-point-source loading of N and P in the TGR area.
基金supported by the Special Scientific Research Funds for Environment Protection Commonweal Section (Nos.201409003,201309011)the National Natural Science Foundation of China (No.41375132)+2 种基金the CAS Strategic Priority Research Program (No.XDB05030400)the National Basic Research Program of China (No.2014CB441203)the Beijing Municipal Science and Technology Plan (No.Z131100006113013)
文摘To elucidate the air pollution characteristics of northern China, airborne PM_10（atmospheric dynamic equivalent diameter ≤ 10 μm） and PM_（2.5）（atmospheric dynamic equivalent diameter ≤ 2.5 μm） were sampled in three different functional areas（Yuzhong County,Xigu District and Chengguan District） of Lanzhou, and their chemical composition（elements, ions, carbonaceous species） was analyzed. The results demonstrated that the highest seasonal mean concentrations of PM_10（369.48 μg/m^3） and PM_（2.5）（295.42 μg/m^3） were detected in Xigu District in the winter, the lowest concentration of PM_（2.5）（53.15 μg/m^3） was observed in Yuzhong District in the fall and PM_10（89.60 μg/m^3） in Xigu District in the fall.The overall average OC/EC（organic carbon/elemental carbon） value was close to the representative OC/EC ratio for coal consumption, implying that the pollution of Lanzhou could be attributed to the burning of coal. The content of SNA（the sum of sulfate, nitrate,ammonium, SNA） in PM_（2.5）in Yuzhong County was generally lower than that at other sites in all seasons. The content of SNA in PM_（2.5）and PM_10 in Yuzhong County was generally lower than that at other sites in all seasons（0.24–0.38）, indicating that the conversion ratios from precursors to secondary aerosols in the low concentration area was slower than in the area with high and intense pollutants. Six primary particulate matter sources were chosen based on positive matrix factorization（PMF） analysis, and emissions from dust, secondary aerosols, and coal burning were identified to be the primary sources responsible for the particle pollution in Lanzhou.
基金The National Key Basic Research Program of China under contract No.2010CB428902the United Program of National Natural Science Foundation of China and Shandong Province under contract No.U1406403the Special Fund for Basic Scientific Research Business of Central Public Research Institutes under contrast No.20603022013003
文摘Long-term changes of composition, sources and burial fluxes of TOC （total organic carbon） in sediments of the central Yellow Sea mud area and their possible affecting factors are discussed in this paper. Firstly, similarity analysis is employed to confirm that the carbon burial features resulted from two collected cores are typical in the central Yellow Sea mud area where YSWC （Yellow Sea Warm Current） is prevalent. On this basis, the burial flux of TOC here was considered to be 235.5-488.4 pmol/（cm^2.a） since the first industrial revolution, accounting for about 70%-90% among burial fluxes of TC （total carbon） in the sediments. Compared TOC/TC ratio in the two cores with that in other marine sediments worldwide, we suggest that the growth of calcareous/non-calcareous organisms and dissolution of IC （inorganic carbon） are important factors controlling the TOC/TC ratio in sediment. Results of two-end mixed model based on fi13C data indicate that marine-derived organic carbon （OCa） is the main part among total burial organic carbon which accounts for a ratio over 85%. Due to the high TOC/TC ratio in the two cores, TC in the sediments also mainly exists as OCa, and the proportion of OCa is about 60%-80%. Away from the shore and relatively high primary production in upper waters are the main reasons that OCa is predominant among all burial OC in sediments of the central Yellow Sea mud area. Burial of OC in this mud area is probably mainly influenced by the human activities. Although the economic development during the late 19th century caused by the first industrial revolution in China did not obviously increase the TOC burial fluxes in the sediments, the rise of industry and agriculture after the founding of new China has clearly increased the TOC burial flux since 1950s. Otherwise, we also realize that among TC burial fluxes, TIC account for about 10%-30% in sediments of the central Yellow Sea mud area, so its burial could not be simply ignored here. Distinct from TOC burial, long-term TIC burial fluxes variations relate with climate changes more closely： the East Asian summer monsoon may influence the strength of the Huanghe River （Yellow River） flood, which could further affect the transport of terrestrial IC from land to the central Yellow Sea as well as the burial of these IC in the sediments.
基金the Chinese Academy of Sciences Strategic Priority Research Program(XDA20100103)Ministry of Science and Technology of China Key R&D Program(2017YFC0405704)CAS Overseas Professorships of Victor F Bense and Sergey S Marchenko at the former Cold and Arid Regions Environmental and Engineering Research Institute(now renamed to Northwest Institute of Eco-Environment and Resources),CAS during 2013-2016.
文摘Many observations in and model simulations for northern basins have confirmed an increased streamflow from degrading permafrost,while the streamflow has declined in the source area of the Yellow River(SAYR,above the Tanag hydrological station)on the northeastern Qinghai-Tibet Plateau,West China.How and to what extent does the degrading permafrost change the flow in the SAYR?According to seasonal regimes of hydrological processes,the SAYR is divided intofour sub-basins with varied permafrost extents to detect impacts of permafrost degradation on the Yellow River streamflow.Results show that permafrost degradation may have released appreciable meltwater for recharging groundwater.The potential release rate of ground-ice melt-water in the Sub-basin 1(the headwater area of the Yellow River(HAYR),above the Huangheyan hydrological station)is the highest(5.6 mm per year),contributing to 14.4%of the annual Yellow River streamflow at Huangheyan.Seasonal/intra-and annual shifts of streamflow,a possible signal for the marked alteration of hydrological processes by permafrost degradation,is observed in the HAYR,but the shifts are minor in other sub-basins in the SAYR.Improved hydraulic connectivity is expected to occur during and after certain degrees of permafrost degradation.Direct impacts of permafrost degradation on the annual Yellow River streamflow in the SAYR at Tanag,i.e.,from the meltwater of ground-ice,is estimated at 4.9%that of the annual Yellow River discharge at Tanag,yet with a high uncertainty,due to neglecting of the improved hydraulic connections from permafrost degradation and the flow generation conditions for the ground-ice meltwater.Enhanced evapotranspiration,substantial weakening of the Southwest China Autumn Rain,and anthropogenic disturbances may largely account for the declined streamflow in the SAYR.
基金We are grateful for the financial support from the National Science Foundation for Excellent Young Scholars of China(51822407)the Natural Science Foundation of China(51774327)+1 种基金the Special Fund for Basic Scientific Research Operations in Universities(2282020cxqd055)the Fundamental Research Funds for the Central Universities of Central South University(2021zzts0875).
文摘Acoustic emission(AE)localization plays an important role in the prediction and control of potential hazardous sources in complex structures.However,existing location methods have less discussion on the presence of unknown empty areas.This paper proposes an AE source location method for structures containing unknown empty areas(SUEA).Firstly,this method identifies the shape,size,and location of empty areas in the unknown region by exciting the active AE sources and using the collected AE arrivals.Then,the unknown AE source can be located considering the identified empty areas.The lead break experiments were performed to verify the effectiveness and accuracy of the proposed method.Five specimens were selected containing empty areas with different positions,shapes,and sizes.Results show the average location accuracy of the SUEA increased by 78%compared to the results of the existing method.It can provide a more accurate solution for locating AE sources in complex structures containing unknown empty areas such as tunnels,bridges,railroads,and caves in practical engineering.
基金Supported by the Modern Agro-industry Technology Research System (No.CARS-48)the State Oceanic Administration of China (No.200905020)
文摘Based on stable isotope analysis, we characterized the dietary regime of the Manila clam Ruditapesphilippinarum inhabiting intertidal areas along the Liaodong Peninsula, Northern China. Samples, including particulate organic matter （POM; n=30）, benthic microalgae （BMI; n=30） and R. philippinarum （n=60）, were collected from six sampling sites displaying the same ecological conditions. Of the two primary food sources, POM was more depleted in δ13C （-20.61‰ to -22.89%0） than BMI was （-13.90‰ to -16.66‰）. With respect to 15N, BMI was more enriched （2.90%0 to 4.07%0） than POM was （4.13‰ to 5.12‰）. The δ13C values of R. philippinarum ranged from -18.78‰ to -19.35‰ and the δ15N values from 7.96%0 to 8.63‰, which were intermediate between the POM and BMI values. In a two-source isotope mixing model, we estimated the relative contributions of POM and BMI to the diet ofR. philippinarum to be 74.2% and 25.8%, respectively. We conclude that R. philippinarum feeds mainly on POM, and BMI is also an important supplemental food source in intertidal areas.
基金The Major State Basic Research Development Program (973 Program) under contract No. 2009CB219402
文摘Drilling wells reveal that the organic matter abundance of Miocene marine source rocks in shallow water area of the Qiongdongnan Basin is relatively low with poor hydrocarbon generation poten- tial. However, in some drilling wells of deep water area close to the central depression belt, Miocene marine source rocks with better organic matter abundance and hydrocarbon generation have been found, which have achieved better source rock standard based on the analysis of geochemical charac- teristics. Although there are no exploratory wells in deep water area of the research region, through the comparative analysis of geochemical data of several typical exploratory wells respectively from shallow water area in the basin, central depression belt margin in deep-water area of the basin and Site 1148 of deep sea drilling in the South China Sea Basin, it reveals that the tendency of the quality of source rocks becomes positive gradually from delta to bathyal environment, which then becomes negative as in deep oceanic environment. Owing to the lack of terrestrial organic matter input, the important controlling factors of Miocene marine source rocks in the Qiongdongnan Basin are ocean productivity and preservation conditions of organic matter. The element geochemistry data indicate that the tendency of the paleoproductivity and the preservation conditions of organic matter become positive as water depth increase from shallow area to bathyal area close to central depression belt. So it is speculated that there must exist high quality source rocks in the central depression area where the preservation conditions of organic matter are much better. Besides, in theory, in oxygen-poor zone of oceanic environment at the water depth 400–1 000 m, the preservation conditions of organic matter are well thus forming high-quality marine source rocks. The result- ing speculation, it is reasonable to consider that there are high hydrocarbon generation potential source rocks in bathyal environment of the Qiongdongnan Basin, especially at the water depth 400– 1 000 m.
