With the development of urban infrastructure,it is inevitable that shield tunnels will undercross intercity railways.However,the safe operation of intercity railways requires strict subgrade deformation.On the basis o...With the development of urban infrastructure,it is inevitable that shield tunnels will undercross intercity railways.However,the safe operation of intercity railways requires strict subgrade deformation.On the basis of the engineering background of the Lianghu Tunnel in Wuhan,the three-dimensional centrifuge test and numerical back analysis were used to study the development of subgrade surface settlement during shield tunneling.A three-dimensional numerical model with the same size as the prototype was subsequently established to further study the settlement development and torsion behavior of the subgrade during tunnel excavation.The results show that the maximum settlement point of the transverse settlement trough gradually moves to the tunnel axis during tunnel excavation and that the entire subgrade experiences torsional deformation.Moreover,the effect of the intersection angle between the axes of the tunnel and the subgrade on the surface settlement of the subgrade was further studied.The results show that the intersection angle has no effect on the maximum settlement,but the width of the settlement trough increases gradually with increasing angle.Finally,on the basis of the soil arching effect caused by tunnel excavation,the subgrade settlement during tunnel excavation is reduced by reinforcing the soil in different zones of soil arching.The results show that the settlement of the subgrade caused by the shield tunnel can be effectively controlled by adding reinforcement directly to the top of the tunnel,and the maximum settlement of the subgrade surface is reduced from 24.41 mm to 9.47 mm,a reduction of approximately 61.2%.展开更多
A new technique for the analysis of the three-dimensional collapse failure mechanism and the ground surface settlements for the large-diameter shield tunnels were presented.The technique is based on a velocity field m...A new technique for the analysis of the three-dimensional collapse failure mechanism and the ground surface settlements for the large-diameter shield tunnels were presented.The technique is based on a velocity field model using more different truncated solid conical blocks to clarify the multiblock failure mechanism.Furthermore,the shape of blocks between the failure surface and the tunnel face was considered as an entire circle,and the supporting pressure was assumed as non-uniform distribution on the tunnel face and increased with the tunnel embedded depth.The ground surface settlements and failure mechanism above large-diameter shield tunnels were also investigated under different supporting pressures by the finite difference method.展开更多
A case of Qinghuayuan tunnel excavation below the existing Beijing Subway Line 10 is presented.The new Qinghuayuan tunnel,part of the Beijing-Zhangjiakou High-speed Railway,was excavated by a shield machine with an ou...A case of Qinghuayuan tunnel excavation below the existing Beijing Subway Line 10 is presented.The new Qinghuayuan tunnel,part of the Beijing-Zhangjiakou High-speed Railway,was excavated by a shield machine with an outer diameter of 12.2 m.The existing subway was excavated by shallow tunnelling method.The project layout,geological conditions,reinforcement measures,operational parameters of shield machine and monitoring results of the project are introduced.During the Qinghuayuan tunnel excavation below the existing subway,total thrust,shield driving speed,cutterhead rotation speed and torque were manually controlled below the average values obtained from the previous monitoring of this project,which could effectively reduce the disturbance of the surrounding soil induced by shield excavation.The Gaussian fitting function can appropriately fit both the ground and the existing subway settlements.The trough width is influenced not only by the excavation overburden depth,but also by the forepoling reinforcement and tail void grouting measures.展开更多
When a fire occurs in an underground shield tunnel,it can result in substantial property damage and cause permanent harm to the tunnel lining structure.This is especially true for large-diameter shield tunnels that ha...When a fire occurs in an underground shield tunnel,it can result in substantial property damage and cause permanent harm to the tunnel lining structure.This is especially true for large-diameter shield tunnels that have numerous segments and joints,and are exposed to specific fire conditions in certain areas.This paper constructs a full-scale shield tunnel fire test platform and conducts a non-uniform fire test using the lining system of a three-ring large-diameter shield tunnel with an inner diameter of 10.5 m.Based on the tests,the tem-perature field distribution,high-temperature bursting,cracking phenomena,and deformation under fire conditions are observed.Fur-thermore,the post-fire damage forms of tunnel lining structures are obtained through the post-fire ultimate loading test,and the corresponding mechanism is explained.The test results illustrate that the radial and circumferential distribution of internal temperature within the tunnel lining,as well as the radial temperature gradient distribution on the inner surface of the lining,have non-uniform dis-tribution characteristics.As a result,the macroscopic phenomena of lining concrete bursting and crack development during the fire test mainly occur near the fire source,where the temperature rise gradient is the highest.In addition,the lining structure has a deformation characteristic of local outward expansion and cannot recover after the fire load is removed.The ultimate form of damage after the fire is dominated by crush damage from the inside out of the lining joints in the fire-exposed area.The above results serve as a foundation for future tunnel fire safety design and evaluation.展开更多
Accurate acquisition of the lithological composition of a tunnel face is crucial for efficient tunneling and hazard prevention in large-diameter slurry shield tunnels.While widely applied,current data-driven methods o...Accurate acquisition of the lithological composition of a tunnel face is crucial for efficient tunneling and hazard prevention in large-diameter slurry shield tunnels.While widely applied,current data-driven methods often face challenges such as indirect prediction,data sparsity,and data drift,which limit their accuracy and generalizability.This study develops an integrated method that combines a knowledge-driven method to directly compute distribution patterns of lithological components,which are used as a priori knowledge to guide the development of a data-driven method.Coupled Markov chain(CMC)and deep neural networks(DNNs)serve as the knowledge-driven and data-driven components,respectively.Additionally,a dynamic prediction strategy is proposed,where the model is continuously optimized as construction progresses and training samples accumulate,rather than being statically trained on post-construction data,as is common in data-driven methods.Finally,the proposed method is evaluated using a real-world project.The evaluation results show that the integrated method outperforms both individual data-and knowledge-driven methods,demonstrating higher predictive performance,greater stability,and greater robustness to data scarcity and data drift.Furthermore,the dynamic prediction strategy better captures the effects of gradual data accumulation and lithological spatial variability on prediction performance during construction,providing new insights for real-time prediction in practical tunneling applications.展开更多
Due to the shield tunneling underneath,long-term settlements may develop in the existing metro tunnels.The compensation grouting is applied worldwide to stabilize the settlement of ground and existing structures.Few f...Due to the shield tunneling underneath,long-term settlements may develop in the existing metro tunnels.The compensation grouting is applied worldwide to stabilize the settlement of ground and existing structures.Few field studies concerning large-diameter shield pass-ing tunnel from below have analyzed the interaction between the compensation grouting and the existing tunnel.This paper presents a case study on the response of the operating metro tunnels to the compensation grouting of an underlying large-diameter tunnel in muddy clay stratum.The tunnel deformations before,during,and after the compensation grouting were monitored and analyzed.The long-term tunnel settlements were mitigated and stabilized by the timely compensation grouting.Smaller settlement rates were observed during the grouting treatment,and the settlement was gradually stabilized three months after the grouting.The grouting holes at the tunnel invert were used initially for better grouting efficiency.The horizontal displacement and convergence developed during the grouting construc-tion and remained stable after the grouting process.Moreover,some limitations of the grouting treatment were discussed.The tunnel settlement in the section close to the center-line of the south-line tunnel cannot be prevented effectively.The differential displacement cannot be reduced by this grouting program.展开更多
In large-diameter shield tunnels,applying the double-layer lining structure can improve the load-bearing properties and maintain the stability of segmental lining.The secondary lining thickness is a key parameter in t...In large-diameter shield tunnels,applying the double-layer lining structure can improve the load-bearing properties and maintain the stability of segmental lining.The secondary lining thickness is a key parameter in the design of a double lining structure,which is worth being explored.Based on an actual large-diameter shield tunnel,loading model tests are carried out to investigate the effect of the secondary lining thickness on the mechanical behaviours of the double lining structure.The test results show that within the range of secondary lining thicknesses discussed,the load-bearing limit of the double-layer lining increases with growing secondary lining thickness.As a passive support,the secondary lining acts as an auxiliary load-bearing structure by contacting the segment.And changes in secondary lining thickness have a significant effect on the contact state between the segment and secondary lining,with both the contact pressure level and the contact area between the two varying.For double-layer lining structures in large-diameter shield tunnels,it is proposed that the stiffness of the secondary lining needs to be matched to the stiffness of the segment,as this allows them to have a coordinated deformation and a good joint load-bearing effect.展开更多
The employment of large-diameter shield machines has increased the likelihood of encountering composite formations,posing engineering challenges associated with excessive surface settlement.To tackle this issue,this s...The employment of large-diameter shield machines has increased the likelihood of encountering composite formations,posing engineering challenges associated with excessive surface settlement.To tackle this issue,this study introduces a hybrid model which integrates the extreme learning machine(ELM)with the sparrow search algorithm(SSA)to predict longitudinal surface settlement.Based on on-site measurements.this study analyzed longitudinal surface settlement patterns across both homogeneous and composite formations.Tunneling parameters,geological parameters,and geometrical parameters were considered as input parameters.Furthermore,this study conducted a comparative analysis of the predictive performance among SSA-ELM,ELM,and SSA-back propagation(BP),with respect to coefficient of determination(R^(2)),mean absolute error(MAE),root mean square error(RMSE),and training time.Last,in anticipation of potential risks,a feasible optimization approach is provided.SSA-ELM outperforms both ELM and SSA-BP in terms of R^(2),MAE,and RMSE,with values of 0.8822,0.3357,and 0.4072,respectively.Regarding training time,SSA-ELM requires 0.2346 s,prior to SSA-BP with a value of 1.8427.Although it is not as fast as ELM,the discrepancy between SSA-ELM and ELM is only 0.1187 s.Overall,SSA-ELM demonstrates higher performance and serves as an effective tool to guide the construction process.展开更多
The synchronous construction of the secondary lining during the boring of large-diameter shield faces challenges such as the design of the lining jumbo,the high requirements on the performance for the lining jumbo,the...The synchronous construction of the secondary lining during the boring of large-diameter shield faces challenges such as the design of the lining jumbo,the high requirements on the performance for the lining jumbo,the organization of the construction activities in the small and confined area,the horizontal transportation for shield boring and high safety management requirements.A super-long invert lining construction jumbo,as well as the matching California switch,is developed,which provides solution for the confliction between the invert lining construction and the horizontal transportation.The procedure and method for the synchronous operation of the shield boring and the secondary lining are developed by referring to the synchronous construction of the secondary lining during the boring of the TBMs in hard rocks.Due to the adoption of the synchronous operation of the shield boring and the secondary lining,the construction period is shortened and the construction cost is reduced.The paper can provide reference for the synchronous construction of the secondary lining in similar projects in the future.展开更多
Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway s...Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway stability and relief effectiveness.In this study,a mechanical model for optimal matching between the large-diameter drilling hole and anchoring hole was established following the principle of synergistic control.The influence of large-diameter drilling hole diameter on the optimal spacing under the synergistic relief effect was investigated by integrating theoretical analysis,numerical simulation,and field practice.The results suggest that the hole spacing achieved a synergistic effect in a certain range when the optimal hole spacing increased linearly with the hole diameter.For instance,when the anchoring hole diameter was 20 mm,an increase in the aperture ratio from 5 to 10 brought about an increase in the optimal spacing from 0.25 m to 0.45 m.Additionally,the vertical stress between the large-diameter drilling hole and anchor hole increased nonlinearly under the condition of constant pore ratio but varying hole spacing.Both excessively small and excessively large hole spacings were detrimental to the pressure relief effect.In the engineering practice,optimizing the hole spacing from 0.55 m to 0.45 m in the 1208 working face contributed to reducing coal body drilling cuttings and the roadway moving quantity by 33%and 19.2%,respectively.This demonstrates that the pressure relief-support reinforcement synergistic effect should be fully considered in optimization design.展开更多
The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D i...The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.展开更多
The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combi...The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combines numerical simulation with machine learning techniques to explore this issue.It presents a summary of special-shaped tunnel geometries and introduces a shape coefficient.Through the finite element software,Plaxis3D,the study simulates six key parameters—shape coefficient,burial depth ratio,tunnel’s longest horizontal length,internal friction angle,cohesion,and soil submerged bulk density—that impact uplift resistance across different conditions.Employing XGBoost and ANN methods,the feature importance of each parameter was analyzed based on the numerical simulation results.The findings demonstrate that a tunnel shape more closely resembling a circle leads to reduced uplift resistance in the overlying soil,whereas other parameters exhibit the contrary effects.Furthermore,the study reveals a diminishing trend in the feature importance of buried depth ratio,internal friction angle,tunnel longest horizontal length,cohesion,soil submerged bulk density,and shape coefficient in influencing uplift resistance.展开更多
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption ar...With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.展开更多
In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of co...In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors.展开更多
Although machine learning models have achieved high enough accuracy in predicting shield position deviations,their“black box”nature makes the prediction mechanisms and decision-making processes opaque,leading to wea...Although machine learning models have achieved high enough accuracy in predicting shield position deviations,their“black box”nature makes the prediction mechanisms and decision-making processes opaque,leading to weaker explanations and practicability.This study introduces a novel explainable deep learning framework comprising the Informer model with enhanced attention mechanisms(EAMInfor)and deep learning important features(DeepLIFT),aimed at improving the prediction accuracy of shield position deviations and providing interpretability for predictive results.The EAMInfor model attempts to integrate channel attention,spatial attention,and simple attention modules to improve the Informer model's performance.The framework is tested with the four different geological conditions datasets generated from the Xiamen metro line 3,China.Results show that the EAMInfor model outperforms the traditional Informer and comparison models.The analysis with the DeepLIFT method indicates that the push thrust of push cylinder and the earth chamber pressure are the most significant features,while the stroke length of the push cylinder demonstrated lower importance.Furthermore,the variation trends in the significance of data points within input sequences exhibit substantial differences between single and composite strata.This framework not only improves predictive accuracy but also strengthens the credibility and reliability of the results.展开更多
Shield tunneling in saturated ground poses challenges due to the potential risk of ground collapse resulting from seepage force and inadequate support pressure.This study employed a laboratory model test and a theoret...Shield tunneling in saturated ground poses challenges due to the potential risk of ground collapse resulting from seepage force and inadequate support pressure.This study employed a laboratory model test and a theoretical validation to elucidate the mechanisms of face failure and subsequent ground collapse in saturated ground during slurry pressure-balanced shield(SPBS)tunneling operations.A slurry circulation system was developed to ensure steady shield tunneling and to replicate the phenomena of ground collapse.Investigations into shield tunneling parameters and ground responses,including soil pressure,pore water pressure,and surface subsidence,were conducted to understand the mechanisms of face failure and subsequent ground collapse.The theoretical solution for the critical collapse pressure of the tunnel face,based on the rotational failure mechanism,was validated through the comparison with the experimentally determined critical collapse pressure.The results indicate that:(1)appropriate adjustments of tunneling parameters are crucial for promoting filtercake formation,maintaining chamber pressure,and minimizing ground subsidence;(2)chamber pressure,soil pressure,pore water pressure,and ground subsidence are closely correlated with shield tunneling parameters and the formation of filter cake;(3)ground collapse follows a continuous failure mode due to the destruction of filtercake and the decrease in chamber pressure;(4)the soil pressure at the cutterhead is more sensitive to disturbances from shield tunneling than chamber pressure;and(5)experimentally determined critical collapse pressures is consistent with the theoretical solution of limit analysis.展开更多
Estimating the properties of foam-conditioned clay soils is important for both conditioning and recycling goals in earth pressure balance(EPB)shield tunneling.In this study,the vacuum dewatering behaviors of foam-cond...Estimating the properties of foam-conditioned clay soils is important for both conditioning and recycling goals in earth pressure balance(EPB)shield tunneling.In this study,the vacuum dewatering behaviors of foam-conditioned clay soils were investigated,with their potential use as an alternative means to assess foam optimization being examined.A series of laboratory and fieldtests was conducted,including vacuum dewatering tests that considered the effects of filtrationtime and pressure,vane shear tests,and improved cone pullout tests under different gravimetric water content(w)and foam injection ratio(FIR)conditions.It was found that the filtrate loss(FL),which characterizes dewaterability,was increased by extended vacuum filtrationtime and elevated pressure.While increases in w and FIR enhanced FL,reductions were observed in the undrained shear strength(cu),tangential adhesion stress(Fs),and normal adhesion stress(Fn).Furthermore,a linear decrease in FL with increasing mechanical indices(cu,Fs,and Fn)was demonstrated by both laboratory and fielddata fittingresults,regardless of w,FIR,and dewatering conditions.This study provides novel insights into the understanding of vacuum dewatering mechanisms in foam-conditioned clay soils,while a simple approach is proposed for evaluating foam conditioning effectiveness in EPB shield tunneling applications.展开更多
Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardan...Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.展开更多
Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work de...Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work develops a layer-structured composite system based on carbon nanotube(CNT)film comprising ionic liquid(IL)interlayer for infrared(IR)modulation and surface-engineered Cu_(2)O nanoparticles for visible camouflage.The CNT/IL/CNT architecture enables reversible IR emissivity switching(Δε≈0.55)through electrically driven ion intercalation/deintercalation within 2 s,while spray-coated Cu_(2)O nanoparticles(100~400 nm diameter)on the top CNT film layer generate rich structure colors with 90%IR transmittance.This spectral-decoupling design overcomes the traditional trade-off between color visibility and IR transmittance observed in pigment-based systems.Remarkably,due to physical interface coupling,the Cu_(2)O-coated layer-structured system maintains exceptional electrical conductivity,enabling simultaneous electromagnetic interference shielding and electrothermal energy conversion.The integrated system demonstrates long-term operational stability.By unifying visible-IR camouflage,electromagnetic protection,and energy management in a lightweight platform,this work provides an important paradigm for cross-band camouflage technologies.展开更多
基金funding support from the National Natural Science Foundation of China(Grant Nos.52208355and 52378308)Shenzhen University's 2035 Program for Excellent Research(Grant No.00000219).
文摘With the development of urban infrastructure,it is inevitable that shield tunnels will undercross intercity railways.However,the safe operation of intercity railways requires strict subgrade deformation.On the basis of the engineering background of the Lianghu Tunnel in Wuhan,the three-dimensional centrifuge test and numerical back analysis were used to study the development of subgrade surface settlement during shield tunneling.A three-dimensional numerical model with the same size as the prototype was subsequently established to further study the settlement development and torsion behavior of the subgrade during tunnel excavation.The results show that the maximum settlement point of the transverse settlement trough gradually moves to the tunnel axis during tunnel excavation and that the entire subgrade experiences torsional deformation.Moreover,the effect of the intersection angle between the axes of the tunnel and the subgrade on the surface settlement of the subgrade was further studied.The results show that the intersection angle has no effect on the maximum settlement,but the width of the settlement trough increases gradually with increasing angle.Finally,on the basis of the soil arching effect caused by tunnel excavation,the subgrade settlement during tunnel excavation is reduced by reinforcing the soil in different zones of soil arching.The results show that the settlement of the subgrade caused by the shield tunnel can be effectively controlled by adding reinforcement directly to the top of the tunnel,and the maximum settlement of the subgrade surface is reduced from 24.41 mm to 9.47 mm,a reduction of approximately 61.2%.
基金Project(41202220) supported by the National Natural Science Foundation of ChinaProject(2011YYL034) supported by the Fundamental Research Funds for the Central Universities,China
文摘A new technique for the analysis of the three-dimensional collapse failure mechanism and the ground surface settlements for the large-diameter shield tunnels were presented.The technique is based on a velocity field model using more different truncated solid conical blocks to clarify the multiblock failure mechanism.Furthermore,the shape of blocks between the failure surface and the tunnel face was considered as an entire circle,and the supporting pressure was assumed as non-uniform distribution on the tunnel face and increased with the tunnel embedded depth.The ground surface settlements and failure mechanism above large-diameter shield tunnels were also investigated under different supporting pressures by the finite difference method.
基金Project(U1934210)supported by the Key Project of High-speed Rail Joint Fund of National Natural Science Foundation of ChinaProject(8202037)supported by the Natural Science Foundation of Beijing,China。
文摘A case of Qinghuayuan tunnel excavation below the existing Beijing Subway Line 10 is presented.The new Qinghuayuan tunnel,part of the Beijing-Zhangjiakou High-speed Railway,was excavated by a shield machine with an outer diameter of 12.2 m.The existing subway was excavated by shallow tunnelling method.The project layout,geological conditions,reinforcement measures,operational parameters of shield machine and monitoring results of the project are introduced.During the Qinghuayuan tunnel excavation below the existing subway,total thrust,shield driving speed,cutterhead rotation speed and torque were manually controlled below the average values obtained from the previous monitoring of this project,which could effectively reduce the disturbance of the surrounding soil induced by shield excavation.The Gaussian fitting function can appropriately fit both the ground and the existing subway settlements.The trough width is influenced not only by the excavation overburden depth,but also by the forepoling reinforcement and tail void grouting measures.
基金the financial support from the National Natural Science Foundation of China-Joint Fund Project(Grant No.U1834208).
文摘When a fire occurs in an underground shield tunnel,it can result in substantial property damage and cause permanent harm to the tunnel lining structure.This is especially true for large-diameter shield tunnels that have numerous segments and joints,and are exposed to specific fire conditions in certain areas.This paper constructs a full-scale shield tunnel fire test platform and conducts a non-uniform fire test using the lining system of a three-ring large-diameter shield tunnel with an inner diameter of 10.5 m.Based on the tests,the tem-perature field distribution,high-temperature bursting,cracking phenomena,and deformation under fire conditions are observed.Fur-thermore,the post-fire damage forms of tunnel lining structures are obtained through the post-fire ultimate loading test,and the corresponding mechanism is explained.The test results illustrate that the radial and circumferential distribution of internal temperature within the tunnel lining,as well as the radial temperature gradient distribution on the inner surface of the lining,have non-uniform dis-tribution characteristics.As a result,the macroscopic phenomena of lining concrete bursting and crack development during the fire test mainly occur near the fire source,where the temperature rise gradient is the highest.In addition,the lining structure has a deformation characteristic of local outward expansion and cannot recover after the fire load is removed.The ultimate form of damage after the fire is dominated by crush damage from the inside out of the lining joints in the fire-exposed area.The above results serve as a foundation for future tunnel fire safety design and evaluation.
基金supported by the Beijing Natural Science Foundation(Grant No.8252012)the National Natural Science Foundation of China(Grant No.52378475).
文摘Accurate acquisition of the lithological composition of a tunnel face is crucial for efficient tunneling and hazard prevention in large-diameter slurry shield tunnels.While widely applied,current data-driven methods often face challenges such as indirect prediction,data sparsity,and data drift,which limit their accuracy and generalizability.This study develops an integrated method that combines a knowledge-driven method to directly compute distribution patterns of lithological components,which are used as a priori knowledge to guide the development of a data-driven method.Coupled Markov chain(CMC)and deep neural networks(DNNs)serve as the knowledge-driven and data-driven components,respectively.Additionally,a dynamic prediction strategy is proposed,where the model is continuously optimized as construction progresses and training samples accumulate,rather than being statically trained on post-construction data,as is common in data-driven methods.Finally,the proposed method is evaluated using a real-world project.The evaluation results show that the integrated method outperforms both individual data-and knowledge-driven methods,demonstrating higher predictive performance,greater stability,and greater robustness to data scarcity and data drift.Furthermore,the dynamic prediction strategy better captures the effects of gradual data accumulation and lithological spatial variability on prediction performance during construction,providing new insights for real-time prediction in practical tunneling applications.
基金support from the National Natural Science Foundation of China(Grant Nos.51778575)the Zhejiang Provincial Science and Technology Department(Grant Nos.2019C03103)the Science and Technology Committee of Shanghai Municipality(Grant Nos.16QB1403400).
文摘Due to the shield tunneling underneath,long-term settlements may develop in the existing metro tunnels.The compensation grouting is applied worldwide to stabilize the settlement of ground and existing structures.Few field studies concerning large-diameter shield pass-ing tunnel from below have analyzed the interaction between the compensation grouting and the existing tunnel.This paper presents a case study on the response of the operating metro tunnels to the compensation grouting of an underlying large-diameter tunnel in muddy clay stratum.The tunnel deformations before,during,and after the compensation grouting were monitored and analyzed.The long-term tunnel settlements were mitigated and stabilized by the timely compensation grouting.Smaller settlement rates were observed during the grouting treatment,and the settlement was gradually stabilized three months after the grouting.The grouting holes at the tunnel invert were used initially for better grouting efficiency.The horizontal displacement and convergence developed during the grouting construc-tion and remained stable after the grouting process.Moreover,some limitations of the grouting treatment were discussed.The tunnel settlement in the section close to the center-line of the south-line tunnel cannot be prevented effectively.The differential displacement cannot be reduced by this grouting program.
基金supported by the National Natural Science Foundation of China(Grant Nos.52178398,51991394,and 51278424).
文摘In large-diameter shield tunnels,applying the double-layer lining structure can improve the load-bearing properties and maintain the stability of segmental lining.The secondary lining thickness is a key parameter in the design of a double lining structure,which is worth being explored.Based on an actual large-diameter shield tunnel,loading model tests are carried out to investigate the effect of the secondary lining thickness on the mechanical behaviours of the double lining structure.The test results show that within the range of secondary lining thicknesses discussed,the load-bearing limit of the double-layer lining increases with growing secondary lining thickness.As a passive support,the secondary lining acts as an auxiliary load-bearing structure by contacting the segment.And changes in secondary lining thickness have a significant effect on the contact state between the segment and secondary lining,with both the contact pressure level and the contact area between the two varying.For double-layer lining structures in large-diameter shield tunnels,it is proposed that the stiffness of the secondary lining needs to be matched to the stiffness of the segment,as this allows them to have a coordinated deformation and a good joint load-bearing effect.
基金sponsored by the National Natural Science Foundation of China(Grant Nos.52178386 and 52378336)。
文摘The employment of large-diameter shield machines has increased the likelihood of encountering composite formations,posing engineering challenges associated with excessive surface settlement.To tackle this issue,this study introduces a hybrid model which integrates the extreme learning machine(ELM)with the sparrow search algorithm(SSA)to predict longitudinal surface settlement.Based on on-site measurements.this study analyzed longitudinal surface settlement patterns across both homogeneous and composite formations.Tunneling parameters,geological parameters,and geometrical parameters were considered as input parameters.Furthermore,this study conducted a comparative analysis of the predictive performance among SSA-ELM,ELM,and SSA-back propagation(BP),with respect to coefficient of determination(R^(2)),mean absolute error(MAE),root mean square error(RMSE),and training time.Last,in anticipation of potential risks,a feasible optimization approach is provided.SSA-ELM outperforms both ELM and SSA-BP in terms of R^(2),MAE,and RMSE,with values of 0.8822,0.3357,and 0.4072,respectively.Regarding training time,SSA-ELM requires 0.2346 s,prior to SSA-BP with a value of 1.8427.Although it is not as fast as ELM,the discrepancy between SSA-ELM and ELM is only 0.1187 s.Overall,SSA-ELM demonstrates higher performance and serves as an effective tool to guide the construction process.
文摘The synchronous construction of the secondary lining during the boring of large-diameter shield faces challenges such as the design of the lining jumbo,the high requirements on the performance for the lining jumbo,the organization of the construction activities in the small and confined area,the horizontal transportation for shield boring and high safety management requirements.A super-long invert lining construction jumbo,as well as the matching California switch,is developed,which provides solution for the confliction between the invert lining construction and the horizontal transportation.The procedure and method for the synchronous operation of the shield boring and the secondary lining are developed by referring to the synchronous construction of the secondary lining during the boring of the TBMs in hard rocks.Due to the adoption of the synchronous operation of the shield boring and the secondary lining,the construction period is shortened and the construction cost is reduced.The paper can provide reference for the synchronous construction of the secondary lining in similar projects in the future.
基金Project(52274086)supported by the National Natural Science Foundation of ChinaProject(2024KJH069)supported by the Shandong Provincial Youth Innovation and Technology Support Program,ChinaProject(tstp20221126)supported by the Project of Taishan Scholar in Shandong Province,China。
文摘Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway stability and relief effectiveness.In this study,a mechanical model for optimal matching between the large-diameter drilling hole and anchoring hole was established following the principle of synergistic control.The influence of large-diameter drilling hole diameter on the optimal spacing under the synergistic relief effect was investigated by integrating theoretical analysis,numerical simulation,and field practice.The results suggest that the hole spacing achieved a synergistic effect in a certain range when the optimal hole spacing increased linearly with the hole diameter.For instance,when the anchoring hole diameter was 20 mm,an increase in the aperture ratio from 5 to 10 brought about an increase in the optimal spacing from 0.25 m to 0.45 m.Additionally,the vertical stress between the large-diameter drilling hole and anchor hole increased nonlinearly under the condition of constant pore ratio but varying hole spacing.Both excessively small and excessively large hole spacings were detrimental to the pressure relief effect.In the engineering practice,optimizing the hole spacing from 0.55 m to 0.45 m in the 1208 working face contributed to reducing coal body drilling cuttings and the roadway moving quantity by 33%and 19.2%,respectively.This demonstrates that the pressure relief-support reinforcement synergistic effect should be fully considered in optimization design.
基金Supported by the National Natural Science Foundation of China(22378181).
文摘The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.
基金Guangzhou Metro Scientific Research Project(No.JT204-100111-23001)Chongqing Municipal Special Project for Technological Innovation and Application Development(No.CSTB2022TIAD-KPX0101)Science and Technology Research and Development Program of China State Railway Group Co.,Ltd.(No.N2023G045)。
文摘The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combines numerical simulation with machine learning techniques to explore this issue.It presents a summary of special-shaped tunnel geometries and introduces a shape coefficient.Through the finite element software,Plaxis3D,the study simulates six key parameters—shape coefficient,burial depth ratio,tunnel’s longest horizontal length,internal friction angle,cohesion,and soil submerged bulk density—that impact uplift resistance across different conditions.Employing XGBoost and ANN methods,the feature importance of each parameter was analyzed based on the numerical simulation results.The findings demonstrate that a tunnel shape more closely resembling a circle leads to reduced uplift resistance in the overlying soil,whereas other parameters exhibit the contrary effects.Furthermore,the study reveals a diminishing trend in the feature importance of buried depth ratio,internal friction angle,tunnel longest horizontal length,cohesion,soil submerged bulk density,and shape coefficient in influencing uplift resistance.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金financially supported by the Natural Science Foundation of Shandong Province(No.ZR2024QE446)。
文摘With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.
基金supported by the Guangdong Basic and Applied Basic Research Foundation,China(No.2021B1515140007).
文摘In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors.
基金supported by the National Natural Science Foundation of China(Grant Nos.52378392,52408356)the Foal Eagle Program Youth Top-notch Talent Project of Fujian Province,China(Grant No.00387088).
文摘Although machine learning models have achieved high enough accuracy in predicting shield position deviations,their“black box”nature makes the prediction mechanisms and decision-making processes opaque,leading to weaker explanations and practicability.This study introduces a novel explainable deep learning framework comprising the Informer model with enhanced attention mechanisms(EAMInfor)and deep learning important features(DeepLIFT),aimed at improving the prediction accuracy of shield position deviations and providing interpretability for predictive results.The EAMInfor model attempts to integrate channel attention,spatial attention,and simple attention modules to improve the Informer model's performance.The framework is tested with the four different geological conditions datasets generated from the Xiamen metro line 3,China.Results show that the EAMInfor model outperforms the traditional Informer and comparison models.The analysis with the DeepLIFT method indicates that the push thrust of push cylinder and the earth chamber pressure are the most significant features,while the stroke length of the push cylinder demonstrated lower importance.Furthermore,the variation trends in the significance of data points within input sequences exhibit substantial differences between single and composite strata.This framework not only improves predictive accuracy but also strengthens the credibility and reliability of the results.
基金support of the National Natural Science Foundation of China(Grant Nos.52179116 and 51991392)the support of Key Deployment Projects of Chinese Academy of Sciences(Grant No.ZDRW-ZS-2021-3).
文摘Shield tunneling in saturated ground poses challenges due to the potential risk of ground collapse resulting from seepage force and inadequate support pressure.This study employed a laboratory model test and a theoretical validation to elucidate the mechanisms of face failure and subsequent ground collapse in saturated ground during slurry pressure-balanced shield(SPBS)tunneling operations.A slurry circulation system was developed to ensure steady shield tunneling and to replicate the phenomena of ground collapse.Investigations into shield tunneling parameters and ground responses,including soil pressure,pore water pressure,and surface subsidence,were conducted to understand the mechanisms of face failure and subsequent ground collapse.The theoretical solution for the critical collapse pressure of the tunnel face,based on the rotational failure mechanism,was validated through the comparison with the experimentally determined critical collapse pressure.The results indicate that:(1)appropriate adjustments of tunneling parameters are crucial for promoting filtercake formation,maintaining chamber pressure,and minimizing ground subsidence;(2)chamber pressure,soil pressure,pore water pressure,and ground subsidence are closely correlated with shield tunneling parameters and the formation of filter cake;(3)ground collapse follows a continuous failure mode due to the destruction of filtercake and the decrease in chamber pressure;(4)the soil pressure at the cutterhead is more sensitive to disturbances from shield tunneling than chamber pressure;and(5)experimentally determined critical collapse pressures is consistent with the theoretical solution of limit analysis.
基金supported by the National Youth Top-notch Talent Support Program of China(Grant No.00389335)the National Natural Science Foundation of China(Grant No.52378392)the“Foal Eagle Program”Youth Top-notch Talent Project of Fujian Province(Grant No.00387088).
文摘Estimating the properties of foam-conditioned clay soils is important for both conditioning and recycling goals in earth pressure balance(EPB)shield tunneling.In this study,the vacuum dewatering behaviors of foam-conditioned clay soils were investigated,with their potential use as an alternative means to assess foam optimization being examined.A series of laboratory and fieldtests was conducted,including vacuum dewatering tests that considered the effects of filtrationtime and pressure,vane shear tests,and improved cone pullout tests under different gravimetric water content(w)and foam injection ratio(FIR)conditions.It was found that the filtrate loss(FL),which characterizes dewaterability,was increased by extended vacuum filtrationtime and elevated pressure.While increases in w and FIR enhanced FL,reductions were observed in the undrained shear strength(cu),tangential adhesion stress(Fs),and normal adhesion stress(Fn).Furthermore,a linear decrease in FL with increasing mechanical indices(cu,Fs,and Fn)was demonstrated by both laboratory and fielddata fittingresults,regardless of w,FIR,and dewatering conditions.This study provides novel insights into the understanding of vacuum dewatering mechanisms in foam-conditioned clay soils,while a simple approach is proposed for evaluating foam conditioning effectiveness in EPB shield tunneling applications.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3700300)the National Natural Science Foundation of China(Nos.52573017 and U21B2093)+1 种基金Key Research and Development Program of Ningbo(No.2022Z200)the Zhejiang Provincial Natural Science Foundation(No.LY23E030005)。
文摘Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.
基金Financial support from the National Nature Science Foundation of China(No.:52373244)the Foundation of National Science and Technology Key Laboratory(No.:KZ571801)。
文摘Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work develops a layer-structured composite system based on carbon nanotube(CNT)film comprising ionic liquid(IL)interlayer for infrared(IR)modulation and surface-engineered Cu_(2)O nanoparticles for visible camouflage.The CNT/IL/CNT architecture enables reversible IR emissivity switching(Δε≈0.55)through electrically driven ion intercalation/deintercalation within 2 s,while spray-coated Cu_(2)O nanoparticles(100~400 nm diameter)on the top CNT film layer generate rich structure colors with 90%IR transmittance.This spectral-decoupling design overcomes the traditional trade-off between color visibility and IR transmittance observed in pigment-based systems.Remarkably,due to physical interface coupling,the Cu_(2)O-coated layer-structured system maintains exceptional electrical conductivity,enabling simultaneous electromagnetic interference shielding and electrothermal energy conversion.The integrated system demonstrates long-term operational stability.By unifying visible-IR camouflage,electromagnetic protection,and energy management in a lightweight platform,this work provides an important paradigm for cross-band camouflage technologies.
