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Seasonal emission patterns of airborne phytoncides in temperate forests from autumn to early spring:a case study of Xishui National Forest Park(Yichun,Northeast China)
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作者 Hongda Cai Yitong Wang +6 位作者 Xianwen Huang Sen Zhang Yankun Liu Jian Zhang Dongmei Zhao Peng Zhao Xiuhua Zhao 《Journal of Forestry Research》 2026年第1期256-271,共16页
Xishui National Forest Park in Heilongjiang Province hosts China's most pristine temperate forests and serves as a key site for ecotourism and forest therapy.However,the emission patterns of phytoncides(key bio ac... Xishui National Forest Park in Heilongjiang Province hosts China's most pristine temperate forests and serves as a key site for ecotourism and forest therapy.However,the emission patterns of phytoncides(key bio active compounds) remain poorly understood,limiting their therapeutic application.This study provides the first comprehensive characterization of spatiotemporal dynamics in airborne phytoncides and their synergistic interactions with environmental factors throughout the autumn-early spring seasonal transition in a temperate forest ecosystem.We analyzed the compositional dynamics of phytoncides and terpenoid content variations using thermal desorption-gas chromatography-mass spectrometry(TD-GC-MS) from September 2024 to March 2025.This period encompassed seasonal transitions from autumn to early spring,including diurnal variations in September and snowfall events in November.The method demonstrated detection limits(LODs) ranging from 1.35 to 5.33 ng m-3 and quantification limits(LOQs) from 4.09 to 16.15 ng m-3.Our results revealed pronounced seasonal fluctuations in phytoncide composition.In September,terpenoids,esters,alcohols,and alkanes displayed a diurnal "decrease-increase" trend,whereas aldehydes and ketones peaked at midday.Notably,esters and alcohols were undetectable in November and January.By January,terpenoids reached their lowest proportion(0.17±0.02%) at noon.Five terpenoids(α-pinene,myrcene,D-limonene,camphene,p-cymene) were detected in September,four(α-pinene,D-limonene,camphene,p-cymene) in November,two(D-limonene,p-cymene) in January,and only p-cymene in March.The total concentration and emission rate of the five terpenoids peaked in September afternoons at 1961.58±106.67 ng m^(-3) and653.86±35.56 ng m^(-3) h^(-1),respectively.Nocturnal emissions(32131.95±2522.21 ng m^(-3)) significantly surpassed daytime levels(14473.04±958.49 ng m^(-3)),with emission rates escalating from 1447.30±95.85 ng m^(-3) h^(-1)(day) to 5355.33±420.37 ng m^(-3) h^(-1)(night),marking a3.7-fold increase.Snowfall dramatically elevated terpenoid concentrations(pre-snowfall:158.58±14.12 ng m^(-3);post-snowfall:1080.57±57.76 ng m^(-3)) and emission rates(pre-snowfall:52.86±4.71 ng m^(-3) h^(-1);post-snowfall:360.19±19.25 ng m^(-3) h^(-1)),reflecting a 6.8-fold surge.This study underscores the profound influence of light intensity,seasonal shifts,and climatic conditions on airborne phytoncide levels,offering a scientific foundation for optimizing forest therapy and ecotourism strategies. 展开更多
关键词 Phytoncides Seasonal variation Diurnal-nocturnal patterns Snowfall impact Emission patterns
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Variation in vegetation characteristics and landscape patterns of urban forests:implications for ecosystem management under rapid urbanization
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作者 Jialin Zhong Jiamei Tu +5 位作者 Xin Li Yao Fu Wei Liu Foyi Zhang Shuyang Hu Qiong Wang 《Journal of Forestry Research》 2026年第2期224-238,共15页
Urban forests are essential components of green infrastructure,however,rapid urbanization-induced changes in landscape patterns may affect their ecosystem services through complex ecological processes.A total of 184 s... Urban forests are essential components of green infrastructure,however,rapid urbanization-induced changes in landscape patterns may affect their ecosystem services through complex ecological processes.A total of 184 sample plots in the built-up areas of Nanchang,China,were used as research sites.Urbanization intensities were categorized by the rate of impervious surface area,and forest types were classified into landscape and relaxation forest,attached forest(AF),road forest(RF),and ecological public welfare forest.This study aimed to explore the spatial variations in vegetation characteristics and landscape pattern indices of different forest types under rapid urbanization.The results indicated that the largest patch index(LPI),aggregation index(AI),and percentage of landscape(PLAND)in RF and AF were lower than those in the other forest types(p<0.05).With increasing urbanization intensity,the mean perimeter-area ratio increased by 130.84%,whereas the PLAND,LPI,and AI decreased by 22−86%(p<0.05).Redundancy analysis and variation partitioning suggested that the interpretation rate of landscape pattern indices for variations in vegetation characteristics increased from low to heavy urbanization areas.Especially,the landscape shape index,patch connection index,PLAND,and mean patch size were significantly correlated with vegetation characteristics(e.g.,tree richness,herb coverage,and tree height).In the future,appropriate landscape layout superiority cases should be considered in different urbanization areas and forest types;for instance,increasing the patch connection index will beneficially improve the diversity of trees and herbs in heavy urbanization areas and the RF.This study serves as a reference for maximizing the ecosystem services of urban forests. 展开更多
关键词 Forest type VEGETATION URBANIZATION Landscape pattern
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Improving Online Restore Performance of Backup Storage via Historical File Access Pattern
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作者 Ruidong Chen Guopeng Wang +5 位作者 Jingyuan Yang Ziyu Wang Fang Zou Jia Sun Xingpeng Tang Ting Chen 《Computers, Materials & Continua》 2026年第3期1536-1558,共23页
The performance of data restore is one of the key indicators of user experience for backup storage systems.Compared to the traditional offline restore process,online restore reduces downtime during backup restoration,... The performance of data restore is one of the key indicators of user experience for backup storage systems.Compared to the traditional offline restore process,online restore reduces downtime during backup restoration,allowing users to operate on already restored files while other files are still being restored.This approach improves availability during restoration tasks but suffers from a critical limitation:inconsistencies between the access sequence and the restore sequence.In many cases,the file a user needs to access at a given moment may not yet be restored,resulting in significant delays and poor user experience.To this end,we present Histore,which builds on the user’s historical access sequence to schedule the restore sequence,in order to reduce users’access delayed time.Histore includes three restore approaches:(i)the frequency-based approach,which restores files based on historical file access frequencies and prioritizes ensuring the availability of frequently accessed files;(ii)the graph-based approach,which preferentially restores the frequently accessed files as well as their correlated files based on historical access patterns,and(iii)the trie-based approach,which restores particular files based on both users’real-time and historical access patterns to deduce and restore the files to be accessed in the near future.We implement a prototype of Histore and evaluate its performance from multiple perspectives.Trace-driven experiments on two datasets show that Histore significantly reduces users’delay time by 4-700×with only 1.0%-14.5%additional performance overhead. 展开更多
关键词 Online restore access pattern correlation graph TRIE
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Vascular plant diversity and distribution pattern in Tajikistan:A global hotspot of diversity
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作者 ZHOU Yixin MA Suliya +7 位作者 LI Wenjun Parvina KURBONOVA Mariyo BOBOEV LI Yufan Hikmat HISORIEV MA Keping YANG Weikang ZHANG Yuanming 《Regional Sustainability》 2026年第1期37-53,共17页
Tajikistan represents a core region of the biodiversity hotspot in Central Asian mountains and has exceptional vascular plant diversity.However,the species diversity of the country faces urgent conservation challenges... Tajikistan represents a core region of the biodiversity hotspot in Central Asian mountains and has exceptional vascular plant diversity.However,the species diversity of the country faces urgent conservation challenges.There has been a lack of a comprehensive and multidimensional assessment to inform strategic conservation planning.Therefore,this study integrated 4 key biodiversity indices including species richness(SR),phylogenetic diversity(PD),threatened species richness(TSR),and endemic species richness(ESR)to map species diversity distribution patterns,identify conservation gaps,and elucidate their effects of climatic factors.This study revealed that species diversity shows a clear trend of decreasing from the western region to the eastern region of Tajikistan.The central–western mountains(specifically the Gissar-Darvasian and Zeravshanian regions)emerge as irreplaceable biodiversity hotspots.However,we found a severe spatial mismatch between these priority areas and the existing protected areas(PAs).Protection coverage for all hotspots was alarmingly low,ranging from 31.00%to 38.00%.Consequently,a critical 64.80%of integrated priority areas fall outside of the current PAs,representing a major conservation gap.This study identified precipitation seasonality and isothermality as the principal drivers,collectively explaining over 50.00%of the diversity variation and suggesting high vulnerability to hydrological shifts.Furthermore,we detected significant geographic sampling bias in the public biodiversity databases,with the most critical hotspot being systematically under-sampled.This study provides a robust scientific basis for conservation action,highlighting the urgent need to strategically expand PAs in the under-protected southwestern region and to mitigate critical sampling gaps through targeted data digitization and field surveys.These measures are indispensable for securing Tajikistan’s unique biodiversity and achieving the Kunming-Montreal Global Biodiversity Framework Target 3(“30×30 Protection”). 展开更多
关键词 Vascular plant Species diversity Distribution pattern Conservation gaps TAJIKISTAN
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Patterned line-illumination mesoscopy with a moving slit for enhancing background suppression in cortex-wide mouse brain imaging
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作者 Chaowei Zhuang Yi Yang Hao Xie 《Chinese Physics B》 2026年第2期679-684,共6页
Wide-field mesoscopy provides the capabilities of cortex-wide field of view(FOV),cellular resolution and high frame rate for neuronal imaging in the mouse brain.However,inherent background fluorescence degrades the im... Wide-field mesoscopy provides the capabilities of cortex-wide field of view(FOV),cellular resolution and high frame rate for neuronal imaging in the mouse brain.However,inherent background fluorescence degrades the image quality and hinders neuronal signal extraction.To address this problem,we first introduce a cortex-wide,high-resolution lineillumination mesoscope with a moving slit designed for in vivo mouse brain imaging.This system achieves a 6.6×6.6 mm FOV,microscale cellular resolution,a high frame rate of 10 Hz,as well as the background rejection ability.Furthermore,we integrated patterned illumination into the system to enhance the background suppression.Experimental results show that the proposed system successfully captures neurodynamics in the living mouse brain.Compared with conventional wide-field mesoscopes,the cortex-wide patterned line-illumination mesoscope(PLIM)achieves a threefold increase in the signal-to-background ratio(SBR).With patterned illumination integrated,the SBR enhancement further reaches four-anda-half-fold. 展开更多
关键词 wide-field fluorescence imaging optical sectioning patterned illumination
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Patterns of utilization of antipsychotic drugs and direct medical costs among patients with schizophrenia in a tertiary care hospital
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作者 Aqeel Haider Lekha Saha Debashish Basu 《World Journal of Psychiatry》 2026年第1期125-135,共11页
BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Resear... BACKGROUND Drug utilization research has an important role in assisting the healthcare administration to know,compute,and refine the prescription whose principal objective is to enable the rational use of drugs.Research in developing nations relating to the cost of treatment is scarce when compared with developed countries.Thus,the drug utilization research studies from developing nations are most needed,and their number has been growing.AIM To evaluate patterns of utilization of antipsychotic drugs and direct medical cost analysis in patients newly diagnosed with schizophrenia.METHODS The present study was observational in type and based on a retrospective cohort to evaluate patterns of utilization of antipsychotic drugs using World Health Organization(WHO)core prescribing indicators and anatomical therapeutic chemical/defined daily dose indicators.We also calculated direct medical costs for a period of 6 months.RESULTS This study has found that atypical antipsychotics are the mainstay of treatment for schizophrenia in every age group and subcategories of schizophrenia.The evaluation based on WHO prescribing indicators showed a low average number of drugs per prescription and low prescribing frequency of antipsychotics from the National List of Essential Medicines 2015 and the WHO Essential Medicines List 2019.The total mean drug cost of our study was 1396 Indian rupees.The total mean cost due to the investigation in our study was 1017.34 Indian rupees.Therefore,the total mean direct medical cost incurred on patients in our study was 4337.28 Indian rupees.CONCLUSION The information from the present study can be used for reviewing and updating treatment policy at the institutional level. 展开更多
关键词 patterns of utilization Antipsychotic drugs Direct medical cost SCHIZOPHRENIA DRUGS
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Unravelling tree diversity patterns and responses to environmental gradients in a tropical forest landscape of the Western Ghats
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作者 Naveen Babu Kanda Ashaq Ahmad Dar +2 位作者 Kurian Ayushi Ayyappan Narayanan Narayanaswamy Parthasarathy 《Plant Diversity》 2026年第1期92-106,共15页
Understanding spatial patterns of plant species diversity and the factors(e.g.,climate and human)that drive these patterns is essential for biodiversity conservation.We used data from 1700.1-ha forest plots in the She... Understanding spatial patterns of plant species diversity and the factors(e.g.,climate and human)that drive these patterns is essential for biodiversity conservation.We used data from 1700.1-ha forest plots in the Shettihalli tropical forest landscape of the Western Ghats biodiversity hotspot,India,to analyse tree community composition and the drivers ofα-diversity(Shannon)andβ-diversity(LCBD).Compositional patterns were visualized using Non-Metric Multidimensional Scaling(NMDS),and hybrid feature selection with structural equation modeling(SEM)was employed to evaluate the direct and indirect effects of environmental variables on diversity.NMDS identified four distinct forest types in the Shettihalli landscape:semi-evergreen,dry deciduous,moist deciduous,and plantation forests,each with distinct plant composition.Shannon diversity and ecological uniqueness was significantly higher in semi-evergreen forest than in deciduous forest plots.The SEMs explained about 79%and 39–45%of the variation inα-diversity andβ-diversity.Our analysis indicated that current diversity patterns result from multiple processes,with structure,disturbance,and edaphic parameters exerting the strongest direct and indirect effects onα-diversity.β-diversity,in contrast,was largely influenced by climate,topography,stand structure,and edaphic factors.Overall,our findings indicate that various factors(e.g.,climate,topography,and human disturbance)interact to shape tree diversity patterns in tropical forests.These findings will help develop unique conservation and management strategies for distinct forest types in tropical forest ecosystems. 展开更多
关键词 Alpha diversity Beta diversity Machine learning Structural equation modeling Vegetation patterns Western Ghats
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Mineral resources of Asia continent:Resource endowment,mining industry pattern,and contributions to the world economy
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作者 Xi-feng Chen Gang Wang +2 位作者 Yan-xiong Mei Hai-jie Zhao Yan-yun Ma 《China Geology》 2026年第1期1-24,共24页
Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of mineral... Mineral resources in Asia continent and its mining industry play a significant role in the economic growth and industrialization of both Asia and the world.Asia continent boasts the most comprehensive kinds of minerals,with reserves of at least 38 of over 80 widely used minerals worldwide accounting for more than30%of the global total reserves.Asia continent experienced three main tectonic evolution and mineralization stages:The Precambrian,the Paleozoic,and the Mesozoic to Cenozoic.The abundant mineral resources in this continent can be divided into seven first-order metallogenic belts(metallogenic domains),18 second-order metallogenic belts(metallogenic provinces),61 third-order metallogenic belts(metallogenic zones),and nine main minerogenetic series.Asia continent exhibits the most significant metallogenic specialization among all continents.Specifically,granite belts of Asia continent manifest pronounced metallogenic specialization of tin,rare metals,and porphyry Cu-Au-Mo deposits.Its maficultramafic rock belts and ophiolite belts display notable metallogenic specialization of lateritic nickel deposits and magmatic type chromite deposits,while its Mesozoic to Cenozoic basalt belts show remarkable metallogenic specialization of lateritic bauxite deposits.Consequently,many giant metallogenic belts were formed,including the Southeast Asian tin belt,the Qinghai-Xizang Plateau rare metal metallogenic belt,the Tethyan porphyry Cu-Au-Mo metallogenic belt,the circum-Pacific porphyry Cu-Au-Mo metallogenic belt,the Southeast Asian lateritic bauxite metallogenic belt,the Deccan Plateau lateritic bauxite metallogenic belt in India,the Southeast Asian lateritic nickel metallogenic belt,and the Tethyan magmatic type chromite metallogenic belt—all of which are significant metallogenic belts in Asia continent.Future mineral exploration in Asia should focus primarily on the Precambrian mineralization of ancient cratons,the Paleozoic mineralization of the Central Asian-Mongolian orogenic belt,and the Mesozoic to Cenozoic mineralization of the Tethyan and circum-Pacific mobile belts.Asia's mining industry not only underpins its own economic growth but also propels global economic development and industrialization,contributing significantly to the world economy.Asia boasts the highest production value of minerals,the largest annual production of minerals,and the greatest trade value of mineral products among all the continents,having emerged as the trade center of global mineral products and the center of the mining industry economy.China is identified as one of the few countries that possess the most comprehensive kinds of minerals,and its mining industry has supported and driven the economic development and industrialization of Asia and even the world.Standing as the largest mineral producer worldwide,China ranked first in the production of 28 mineral commodities in the world in 2022.Besides,China exhibits the highest annual production value of minerals and the largest trade value of mineral products among all countries.Therefore,China's demand for global mineral products influences the global supply and demand patterns of minerals and the world economic situation. 展开更多
关键词 Mineral resource endowment Minerogenetic series Metallogenic specialization Carbonate-type REE deposits Weathering-type REE deposits Hard rock-type lithium deposits Laterite nickel deposits Crystalline graphite deposits Magmatic nickel deposits Significant metallogenic belt Mining industry development pattern Mineral exploration and exploitation World economy Contribution Asia continent
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降解检材STR分型Ladder-Like条带形成原因的探讨 被引量:1
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作者 楼迪栋 余纯应 +3 位作者 黄代新 赵贵森 任文 杨庆恩 《中国法医学杂志》 CSCD 2005年第6期332-334,共3页
目的探讨降解DNA短串联重复序列PCR扩增产物在PAGE中Ladder-L ike条带的形成原因。方法用一组人工合成的不同长度的D8S1179DNA单链,模拟降解检材中的断裂DNA;利用John M设计的D8S1179引物对模拟模板的DNA单链进行PCR扩增,PAGE分离。结... 目的探讨降解DNA短串联重复序列PCR扩增产物在PAGE中Ladder-L ike条带的形成原因。方法用一组人工合成的不同长度的D8S1179DNA单链,模拟降解检材中的断裂DNA;利用John M设计的D8S1179引物对模拟模板的DNA单链进行PCR扩增,PAGE分离。结果不同模拟模板的DNA单链的组合可以扩增出不同的Lad-der-L ike条带。结论短串联重复序列Ladder-like条带是PCR过程中降解DNA多态区互补扩增的产物。 展开更多
关键词 法医物证学 短串联重复序 ladder-like条带 PCR—STR分型降解检材 降解检材
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Synthesis of Ladder-like Polyphenylsilsesquioxanes with Fairly High Regularity Using 1,2-Ethylenediamine as Endo-template 被引量:2
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作者 杨雄发 Cheng Cao +3 位作者 Zhong-hong Chen Jia Liu Meng-xian Luo 来国桥 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2015年第9期1305-1312,共8页
Ladder-like polyphenylsilsesquioxanes with fairly high regularity were synthesized using an endo-template 1,2-ethylenediamine at mild temperature via direct co-hydrolysis and condensation reactions in the presence of ... Ladder-like polyphenylsilsesquioxanes with fairly high regularity were synthesized using an endo-template 1,2-ethylenediamine at mild temperature via direct co-hydrolysis and condensation reactions in the presence of acid catalysts in the mixture of 1,4-dioxane/H20. The features for synthesis of ladder-like polyphenylsilsesquioxanes were investigated in detail. The products obtained were characterized by FTIR, SEC, XRD and NMR. 展开更多
关键词 ladder-like Poly(phenyl silsesquioxanes) Endo-template.
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SYNTHESIS AND CHARACTERIZATION OF A NOVEL REACTIVE LADDER-LIKE POLYSILSESQUIOXANE WITH LATERAL BROMOPHENYL GROUPS 被引量:1
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作者 张榕本 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2004年第5期445-451,共7页
A novel soluble, reactive ladder-like polysilsesquioxane (L) with lateral bromophenyl groups was synthesized successfully by stepwise coupling polymerization (SCP) method including preaminolysis, hydrolysis and polyco... A novel soluble, reactive ladder-like polysilsesquioxane (L) with lateral bromophenyl groups was synthesized successfully by stepwise coupling polymerization (SCP) method including preaminolysis, hydrolysis and polycondensation steps. The monomer 3-trichlorosilylpropoxy-4-bromobenzene (M) was first prepared via hydrosilylation reaction catalyzed by dicyclopentadienylplatinum dichloride (Cp2PtCl2). The title polymer (L) was characterized by 1H-NMR, 29Si-NMR, FTIR, X-ray diffraction (XRD), DSC and vapor pressure osmometry (VPO). The experimental results indicate that the polymer (L) possesses a typical ladder-like structure. 展开更多
关键词 ladder-like POLYSILSESQUIOXANE Stepwise coupling polymerization HYDROSILYLATION
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Synthesis and Crystal Structure of a Novel Double Ladder-like Cadmium Coordination Polymer Constructed by Isophthalate and Imidazole 被引量:1
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作者 郭锋 于伟 张秀玲 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2009年第5期602-606,共5页
A novel double ladder-like cadmium coordination polymer with isophthalate as bridging ligands and imidazole as non-chelating capping ligands was obtained by a hydrothermal reaction. The crystal is of triclinic, space ... A novel double ladder-like cadmium coordination polymer with isophthalate as bridging ligands and imidazole as non-chelating capping ligands was obtained by a hydrothermal reaction. The crystal is of triclinic, space group P1 with a = 10.266(2), b = 11.573(2), c = 12.651(3) A, α = 89.95(3), β= 74.64(3),γ = 68.54(3)°, C50H44Cd4N12O18, Mr = 1550.57, V= 1341.1(5)A3, Dc = 1.920 g/cm3, F(000) = 764, p = 1.651 cm-1 and Z = 1. The final refinement gave R = 0.0342 and wR = 0.0738 for 5925 observed reflections with I 〉 2σ(I). The crystal structure involves two different ladder-like chains, which are further connected to form a ladder-like double chain architecture via hydrogen bonding interactions, extending along the b axis. The weak interactions including hydrogen bonds and π-π staking interactions contribute to the alignment of the complex in the crystalline state. 展开更多
关键词 double ladder-like coordination polymer IMIDAZOLE ISOPHTHALATE cadmium
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Synthesis and Structure of a Ladder-like Co-crystal Cu^ICl with 3,5-Dipropyl-4-amino-1,2,4-triazole 被引量:5
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作者 闫娟枝 卢丽萍 +1 位作者 苏峰 朱苗力 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2015年第3期401-407,共7页
Redox reaction of a mixture of CuC12·2H2O, HaPO3 and dpatrz (3,5-dipropyl- 4-amino-1,2,4-triazole) at room temperature yields one new compound, [Cu(1)(/.t2-dpatrz)aCu(1)CI2], with two independent cis- and... Redox reaction of a mixture of CuC12·2H2O, HaPO3 and dpatrz (3,5-dipropyl- 4-amino-1,2,4-triazole) at room temperature yields one new compound, [Cu(1)(/.t2-dpatrz)aCu(1)CI2], with two independent cis- and trans-propyl side chain molecules. Compound 1 crystallizes in monoclinic, space group P21/c with a = 7.474(1), b = 17.807(1), c = 18.851(1) A, β = 108.32(1)°, V = 2381.7(2) A3, Z = 4, C16H32CI2Cu2Ns, Mr = 534.48, Dc = 1.491 g.cm-3,μ = 2.03 mm-1, F(000) = 1104, GOOF = 1.050, the final R = 0.0445 and wR = 0.1162 for 3162 observed reflections (I 〉 2σ(I)). Compound 1 shows discrete dimeric structures (A and B) containing inversion centers and the Cu(l) ions are coordinated in triangle geometries. The isomers are connected by N-H…CI hydrogen bonds, chains with graph-set C(7) and rings R22(14) and C-H..'Jr interactions into stair-step chains (Tapes A and B) running parallel to the [01-1] direction. The N-H…C1 hydrogen bonds result in chain and cyclic structures with graph-sets C22(17) and R34(18) linking tapes A and B to form two-dimensional networks along the [031] direction. Packing of crystal 1 is stabilized by rings R34(18) and weak C-H…C1 hydrogen bonds parallel to the [01-2] direction. Bond valence sum (BVS) and UV-Vis absorption spectra support the existence of Cu(I) ions. Compound 1 exhibits extensive green blue phosphorescence in the solid state at room temperature. 展开更多
关键词 copper(I)-halide complex 1 2 4-triazole isomer ladder-like assembly luminescence
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Luminescent Composite Films Based on Mechanically Strong Ladder-like Polyphenylsilsesquioxane and Oligophenyleuropiumsiloxane
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作者 E.E.Kim T.O.Ershova +7 位作者 A.S.Belova D.A.Khanin E.V.Bashkova G.G.Nikiforova Yu.N.Kononevich A.A.Anisimov O.I.Shchegolikhina A.M.Muzafarov 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2024年第11期1793-1801,I0013,共10页
Nowadays organosilicon luminescent materials are of increasing interest due to the variety of their synthetic or modification techniques and application fields.Ladder polyphenylsilsesquioxanes(L-PPSQ)are a unique clas... Nowadays organosilicon luminescent materials are of increasing interest due to the variety of their synthetic or modification techniques and application fields.Ladder polyphenylsilsesquioxanes(L-PPSQ)are a unique class of organosilicon polymers,which can be ideal matrices for the luminescent composites due to their high thermal stability,optical transparency and mechanical strength.In this work,new mechanically strong,heat-resistant,transparent and sensitive to ammonia vapor luminescent composite films based on L-PPSQ have been obtained.As the source of Europium ions oligophenyleuropiumsiloxane was used,demonstrating perfect compatibility to the matrix due to the similar nature.To improve luminescent properties of the films,new organosilicon ligands were introduced into the composites and their influence on the properties of the materials was studied.Valuable properties of described composites may allow their further application as multifunctional coatings. 展开更多
关键词 Luminescent composite films ladder-like polyphenylsilsesquioxane Oligophenyleuropiumsiloxane
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SYNTHESIS AND CHARACTERIZATION OF AMINO FUNCTIONALIZED LADDER-LIKE POLYSILSESQUIOXANES AND THEIR HYBRID FILMS WITH POLYIMIDE
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作者 Qiu-shuang Gao Guo-feng Tian +2 位作者 Sheng-li Qi Zhan-peng Wu 武德珍 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2013年第3期427-433,共7页
Ladder-like polysilsesquioxanes (LPSQs) with different amino contents have been synthesized by controlling of the dosage of Pd/C catalyst. The concentration and activity of amino groups were investigated by Fourier ... Ladder-like polysilsesquioxanes (LPSQs) with different amino contents have been synthesized by controlling of the dosage of Pd/C catalyst. The concentration and activity of amino groups were investigated by Fourier transform infrared spectroscopy. Polyimide (PI)/LPSQ hybrid films have been prepared by incorporating of the obtained LPSQs with different amino contents into PI matrix, respectively. The interfacial interactions between PI matrix and LPSQ were studied with scanning electron microscopy and X-ray photoelectron spectroscopy, meanwhile the thermal and mechanical properties of the hybrid films were studied using dynamic mechanical analysis and tensile tests. The results indicate that the functionality of LPSQ has great effects on the interfacial interactions and the properties of hybrid films. With the increase of amino content, both the interracial interactions and the cross-linking density of hybrids enhanced, which results in the decline of surface silicon concentration, increase of Young's modulus and drop of elongation at break. Excessive amino content makes the hybrid films brittle and leads to incomplete imidization. 展开更多
关键词 Organic-inorganic Hybrid Amino functionalized ladder-like polysilsesquioxane Polyimide.
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SYNTHESIS AND CHARACERIZATION OF LADDER-LIKE POLYDECYLSILSESQUIOXANE
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作者 戴道荣 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1999年第1期71-74,共4页
Ladder-like polydecylsilsesquioxane (LPDS) was synthesized by a preamminolysis reaction ofdecyltrichlorosilane with ethylene diamine, followed by hydrolysis and polycondensation reaction. LPDS issoluble in a nonpolar ... Ladder-like polydecylsilsesquioxane (LPDS) was synthesized by a preamminolysis reaction ofdecyltrichlorosilane with ethylene diamine, followed by hydrolysis and polycondensation reaction. LPDS issoluble in a nonpolar solvent such as heptane and insoluble in a high polar solvent such as methanol. It wascharaterized by IR, ~1H-NMR, ^(29)Si-NMR, GPC and X-ray diffraction. 展开更多
关键词 ladder-like polydecylsilsesquioxane Preamminolysis reaction
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Synthesis and characterization of a ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide
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作者 Jing Chen You-Juan Zhang +1 位作者 Kun-Tao Huang Qiang Huang 《Open Journal of Inorganic Chemistry》 2013年第3期55-58,共4页
A ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide, [Cd2(NITpBA)4(H2O)4] (where NITpBA = 2-(4-carboxyphenyl)4,4,5,5-tetramethyl-4,5-dihydro-imidazol-1-oxyl-3-oxide), has been synthe... A ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide, [Cd2(NITpBA)4(H2O)4] (where NITpBA = 2-(4-carboxyphenyl)4,4,5,5-tetramethyl-4,5-dihydro-imidazol-1-oxyl-3-oxide), has been synthesized and characterized. X-ray analysis reveals that the compound 1 crystallizes in the monoclinic P21/c (No. 14) space group, and [Cd2(NITpBA)4(H2O)4] units are linked into infinite chains by radical bridging ligands. 展开更多
关键词 Nitronyl Nitroxide ANIONIC Radical ladder-like STRUCTURE Cd (II) Complex
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应用染色放大内镜进行JNET分型与Pit pattern分型在结直肠侧向发育型肿瘤中的诊断价值分析
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作者 黄波 赵丽然 +4 位作者 张晓旭 张玲 涂征艳 王春晖 高天霞 《中国实用医药》 2025年第7期19-23,共5页
目的应用染色放大内镜对结直肠侧向发育型肿瘤(LST)患者进行日本内镜窄带光成像(NBI)技术专家小组(JNET)分型、Pit pattern分型,探究其诊断价值和临床意义。方法108例疑似结直肠LST并接受内镜黏膜下剥离术(ESD)患者,通过术前应用染色放... 目的应用染色放大内镜对结直肠侧向发育型肿瘤(LST)患者进行日本内镜窄带光成像(NBI)技术专家小组(JNET)分型、Pit pattern分型,探究其诊断价值和临床意义。方法108例疑似结直肠LST并接受内镜黏膜下剥离术(ESD)患者,通过术前应用染色放大内镜进行JNET、Pit pattern分型,并与ESD术后病理结果进行一致性分析,对比JNET分型及Pit pattern分型对结直肠LST的诊断效能。结果108例患者最终术后病理分型为非肿瘤性病变25例,肿瘤性病变83例。Pitpattern分型诊断结果与病理诊断结果有一定的一致性,差异具有显著统计学意义(Kappa值=0.519,P<0.001)。JNET分型诊断结果与病理诊断结果有一定的一致性,差异具有显著统计学意义(Kappa值=0.452,P<0.001)。JNET分型及Pit pattern分型诊断结直肠LST的特异度、阳性预测值、阴性预测值对比无显著差异(P>0.05)。JNET分型诊断结直肠LST的敏感度98.8%、准确率88.9%明显高于Pit pattern分型的91.6%、78.7%,差异具有统计学意义(P<0.05)。结论应用染色放大内镜进行JNET分型与Pit pattern分型对结直肠LST诊断具有良好价值,JNET分型优于Pitpattern分型。 展开更多
关键词 染色放大内镜 侧向发育型肿瘤 日本内镜窄带光成像技术专家小组分型 Pit pattern分型 诊断价值
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Recent advances of photolithography patterning of quantum dots for micro-display applications 被引量:1
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作者 Xuemin Kong Xiaotong Fan +6 位作者 Yuhui Wang Yunshu Luo Yihang Chen Tingzhu Wu Zhong Chen Yue Lin Shuli Wang 《Nano Materials Science》 2025年第1期49-64,共16页
The preparation of red,green,and blue quantum dot(QD)pixelated arrays with high precision,resolution,and brightness poses a significant challenge on the development of advanced micro-displays for virtual,augmented,and... The preparation of red,green,and blue quantum dot(QD)pixelated arrays with high precision,resolution,and brightness poses a significant challenge on the development of advanced micro-displays for virtual,augmented,and mixed reality applications.Alongside the controlled synthesis of high-performance QDs,a reliable QD patterning technology is crucial in overcoming this challenge.Among the various methods available,photolithography-based patterning technologies show great potentials in producing ultra-fine QD patterns at micron scale.This review article presents the recent advancements in the field of QD patterning using photolithography techniques and explores their applications in micro-display technology.Firstly,we discuss QD patterning through photolithography techniques employing photoresist(PR),which falls into two categories:PRassisted photolithography and photolithography of QDPR.Subsequently,direct photolithography techniques based on photo-induced crosslinking of photosensitive groups and photo-induced ligand cleavage mechanisms are thoroughly reviewed.Meanwhile,we assess the performance of QD arrays fabricated using these photolithography techniques and their integration into QD light emitting diode display devices as well as color conversionbased micro light emitting diode display devices.Lastly,we summarize the most recent developments in this field and outline future prospects. 展开更多
关键词 Quantum dot PHOTOLITHOGRAPHY patterning technology Micro-display
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Construction and optimization of ecological security pattern in karst basin considering lithology and geological disasters 被引量:2
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作者 LU Hongxing ZHAO Yuluan +1 位作者 CHEN Zhengshan LI Yuan 《Journal of Mountain Science》 2025年第3期983-1000,共18页
Ecological security provides the basis of maintaining both a sustainable regional ecosystem and economic development.However,few studies have focused on how the features such as topography and geomorphology,lithologic... Ecological security provides the basis of maintaining both a sustainable regional ecosystem and economic development.However,few studies have focused on how the features such as topography and geomorphology,lithologic stratigraphic assemblages,and geohazard distribution affect the construction of ecological security patterns and the layout of optimization measures.In order to comprehensively reveal the key areas and key objects of ecological restoration in karst basins,this study takes the Beipan River Basin(BRB)as an example,constructs an ecological security pattern(ESP)based on the methods of morphological spatial pattern analysis(MSPA),landscape connectivity analysis and circuit theory,and lays out the optimization measures in combination with the spatial distribution characteristics of topographic and geomorphological differences and lithological stratigraphic combinations.The results show that 151 ecological sources,343 ecological corridors,121 pinch points and 178 barriers constitute the ESP of the BRB.Lithology is closely related to the spatial distribution characteristics of ecological source sites.Level 1 and 2 ecological sources(The ecological sources were categorized into level 1,level 2,and level 3 source from high to low importance.)are concentrated in the Emeishan basalt region of the upstream and the clastic and impure carbonate rock region of the downstream part of the BRB;level 3ecological sources are concentrated in the carbonate rock region of the midstream.Taking into account the outstanding ecological problems in the basin,and based on the characteristics of lithology and geohazard distribution,we propose the optimization scheme of“three axes,three zones and multiple points”for the ESP and the layout of specific measures of the BRB.The results can provide scientific references for maintaining ecological security maintenance in karst ecologically fragile areas. 展开更多
关键词 Beipan River Basin Ecological security pattern LITHOLOGY GEOHAZARDS Circuit theory Karst mountainous area
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