Non-isothermal kinetic research has been carried out on oxidation behavior of β-Sialon in diphaseβ-Sialon/Al_2O_3 composite at high temperatures. A kinetic formula is established for non-isothermal oxidation process...Non-isothermal kinetic research has been carried out on oxidation behavior of β-Sialon in diphaseβ-Sialon/Al_2O_3 composite at high temperatures. A kinetic formula is established for non-isothermal oxidation process of β-Sialon. The rate of oxidation process is controlled by chemicalreaction at the initial stage and then by diffusion. The apparent activation energies and appar-ent rate constants at different temperatures are determined by treating TG data of the overallprocess.展开更多
Investigation by using LAS 3000 surface analysis system showed that the oxide of Fe, Cr,Al formed during oxidation were Cr_2O_3,Fe_2O_3 and Al_2O_3,but only small amount of nickel oxide was found. The composition of o...Investigation by using LAS 3000 surface analysis system showed that the oxide of Fe, Cr,Al formed during oxidation were Cr_2O_3,Fe_2O_3 and Al_2O_3,but only small amount of nickel oxide was found. The composition of oxide layers for different oxidation durations varied in a similar way. In all cases,there exists an oxygen concentration peak in the composition profile of oxide layer. There is a transitional zone between oxide layer and alloy film.The thickness of oxide layer increases logarithmically with the time of oxida- tion.The ion plated Ni-Cr alloy film has very dense oxide layer and good oxidation resistance.展开更多
文摘Non-isothermal kinetic research has been carried out on oxidation behavior of β-Sialon in diphaseβ-Sialon/Al_2O_3 composite at high temperatures. A kinetic formula is established for non-isothermal oxidation process of β-Sialon. The rate of oxidation process is controlled by chemicalreaction at the initial stage and then by diffusion. The apparent activation energies and appar-ent rate constants at different temperatures are determined by treating TG data of the overallprocess.
文摘Investigation by using LAS 3000 surface analysis system showed that the oxide of Fe, Cr,Al formed during oxidation were Cr_2O_3,Fe_2O_3 and Al_2O_3,but only small amount of nickel oxide was found. The composition of oxide layers for different oxidation durations varied in a similar way. In all cases,there exists an oxygen concentration peak in the composition profile of oxide layer. There is a transitional zone between oxide layer and alloy film.The thickness of oxide layer increases logarithmically with the time of oxida- tion.The ion plated Ni-Cr alloy film has very dense oxide layer and good oxidation resistance.
