By using high-power and high-efficiency propulsion systems,current hybrid electric vehicles(HEVs)in market can achieve excellent fuel economy and kinetic performance.However,it is the cost of current HEVs that hinders...By using high-power and high-efficiency propulsion systems,current hybrid electric vehicles(HEVs)in market can achieve excellent fuel economy and kinetic performance.However,it is the cost of current HEVs that hinders HEVs coming into widespread use.A novel hybrid electric propulsion system is designed to balance HEV cost and performance for developing markets.A battery/supercapacitor-based hybrid energy storage system(HESS)is used to improve energy conversion efficiency and reduce battery size and cost.An all-in-one-controller(AIOC)which integrates engine electronic control unit(ECU),motor ECU,and HESS management system is developed to save materials and energy,and reduce the influence of distribution parameters on circuit.As for the powertrain configuration,four schemes are presented:belt-driven starter generator(BSG)scheme,four-wheel drive HEV scheme,full HEV scheme,and ranger-extender electric vehicle(EV)scheme.Component selection and parameter matching for the propulsion system are performed,and an energy management strategy is developed based on powertrain configuration and selected components.Forward-facing simulation models are built,comprehending the control strategy based on the optimal engine torque for the low-cost hybrid electric propulsion system.Co-simulation of AVL CRUISE and Matlab/Simulink is presented and the best scheme is selected.The simulation results indicate that,for the best design,fuel consumption in urban driving condition is 4.11 L/(100 km)and 0-50 km/h accelerating time is 10.95 s.The proposed research can realize low-cost concept for HEV while achieving satisfactory fuel economy and kinetic performance,and help to improve commercialization of HEVs.展开更多
Platinated W/Zr mixed oxides supported on mesoporous silica with various amounts of Si/Zr, namely PtWO_3/ZrO_2（[76_TD$IF]x）-HMS, were prepared and studied for n-heptane isomerization reaction at 200–350 C. The vari...Platinated W/Zr mixed oxides supported on mesoporous silica with various amounts of Si/Zr, namely PtWO_3/ZrO_2（[76_TD$IF]x）-HMS, were prepared and studied for n-heptane isomerization reaction at 200–350 C. The various methods such as XRD, XRF, FT-IR, UV–vis DRS, NH_3-TPD, H_2 chemisorption, nitrogen adsorption–desorption, Py-IR, SEM and TGA techniques were used for characterization of these materials. Kinetics of n-heptane isomerization was also investigated under various hydrogen. n-Heptane pressures and the influence of reaction conditions on catalytic performance were studied. The ideal catalytic performance was observed on HMS with 0.6%Pt/12%WO_3/ZrO_2 and Si/Zr = 10.展开更多
The microstructure, hydrogen storage thermodynamics and kinetics of La5Mg95-xNix (x=5, 10, 15) ternary alloys with different Ni contents were investigated. The evolutions of the microstructure and phase of experimenta...The microstructure, hydrogen storage thermodynamics and kinetics of La5Mg95-xNix (x=5, 10, 15) ternary alloys with different Ni contents were investigated. The evolutions of the microstructure and phase of experimental alloys were characterized by X-ray diffractometry and scanning electron microscopy. The hydrogen storage kinetics and thermodynamics, and P-C-I curves were tested using a Sievert apparatus. It is found that increasing Ni content remarkably improves hydrogen storage kinetics but reduces the hydrogen storage capacity of alloys. The highest hydrogen absorption/desorption rate is observed in the La5Mg80Ni15 alloy, with the lowest hydrogen desorption activation value being 57.7 kJ/mol. By means of P-C-I curves and the van’t Hoff equation, it is determined that the thermodynamic performance of the alloy is initially improved and then degraded with increasing Ni content. The La5Mg85Ni10 alloy has the best thermodynamics properties with a hydrogenation enthalpy of -72.1 kJ/mol and hydrogenation entropy of -123.2 J/(mol·K).展开更多
The effect of LaNi and Ti on thermal storage properties of MgH_(2)was investigated.The thermal storage performances of Mg are significantly improved by adding LaNi and Ti.The pressure-composition-temperature(PCT)curve...The effect of LaNi and Ti on thermal storage properties of MgH_(2)was investigated.The thermal storage performances of Mg are significantly improved by adding LaNi and Ti.The pressure-composition-temperature(PCT)curves indicate that the formation enthalpy for Mg-15 wt%Ti-5 wt%LaNi sample is 73.00 kJ·mol^(-1),which approaches to the theoretical values of pure MgH_(2).The isothermal measurement indicates that,for the Mg-15wt%Ti-5 wt%LaNi,the first absorption reaction fraction within 2 min is 93.77%,increasing by 0.32%,0.24%and0.08%compared with those for Mg,Mg-5 wt%LaNi and Mg-15 wt%Ti,respectively.The first desorption reaction fraction within 2 min is 73.18%,increasing by 55.91%,9.79%and 8.12%compared with those for Mg,Mg-5wt%LaNi and Mg-15 wt%Ti,respectively.Moreover,Mg-15 wt%Ti-5 wt%LaNi has the best cyclic stability in all the samples.The thermal storage performances of Mg by adding both LaNi and Ti are improved mainly ascribed to synergistic effect of in situ formed La_(4)H_(12.19),Mg_(2)NiH_(4),H_(0.3)Mg_(2)Ni and TiH_(2)particles during cyclic process.The above analysis demonstrates that Mg-15 wt%Ti-5wt%LaNi is suitable for using as a heat storage material.展开更多
LaMgNi（4-x）Cox（x = 0-0.8） electrode alloys used for MH/Ni batteries were prepared by induction melting. The structures and electrochemical hydrogen storage properties of the alloys were investigated in detail.X-ra...LaMgNi（4-x）Cox（x = 0-0.8） electrode alloys used for MH/Ni batteries were prepared by induction melting. The structures and electrochemical hydrogen storage properties of the alloys were investigated in detail.X-ray diffraction（XRD） and scanning electron microscopy（SEM） analysis show that LaMgNi4 phase and LaNi5 phase are obtained. The lattice parameters of the two phases increase first and then decrease with Co content increasing.The electrochemical properties of the alloy electrodes were measured by means of simulated battery tests. Results show that the addition of Co does not change the discharge voltage plateau of the alloy electrodes. However, the maximum discharge capacity increases from 319.9 mAh·g^-1（x = 0）to 347.5 mAh·g^-1（x = 0.4） and then decreases to331.7 mAh·g^-1（x = 0.8）. The effects of Co content on electrochemical kinetics of the alloy electrodes were also performed. The high rate dischargeability（HRD） first increases and then decreases with Co content increasing and reaches the maximum value（95.0 %） when x = 0.4. Test results of the electrochemical impedance spectra（EIS）,potentiodynamic polarization curves and constant potential step measurements of the alloy electrodes all demonstrate that when Co content is 0.4 at%, the alloy exhibits the best comprehensive electrochemical properties.展开更多
Rechargeable aqueous zinc-sulfur batteries(ZSBs)hold significant potential for energy storage due to their stable voltage platform and high capacity,yet suffer from sluggish reaction kinetics and poor reversibility.Th...Rechargeable aqueous zinc-sulfur batteries(ZSBs)hold significant potential for energy storage due to their stable voltage platform and high capacity,yet suffer from sluggish reaction kinetics and poor reversibility.This study introduces a novel dualsolvent electrolyte,combining air-stable N,N-dimethylformamide(DMF)and water with zinc trifluoromethanesulfonate(Zn(OTF)_2)and trace iodine(I_(2)),to address these issues by enhancing the solid/liquid interactions at the cathode,reducing polarization at the zinc anode interface,and immobilizing the I_(2)catalyst to prevent sublimation.The DMF-I_(2)interaction promotes the formation of I_(3)^(-),enhancing catalytic activity while preventing I_(2)sublimation.Moreover,DMF's high desolvation ability optimizes electrode wettability and minimizes the by-products at both the cathode and anode.Moreover,the Zn-Zn symmetric cell used in the dual solvent electrolyte exhibits significantly reduced polarization,extended calendar life,and suppressed dendrite growth,thereby improving both battery reversibility and kinetic performance.These advancements underscore the electrolyte's potential for advancing the commercial viability of ZSBs.展开更多
基金supported by General Motors(Low-cost Hybrid Electric Propulsion System)
文摘By using high-power and high-efficiency propulsion systems,current hybrid electric vehicles(HEVs)in market can achieve excellent fuel economy and kinetic performance.However,it is the cost of current HEVs that hinders HEVs coming into widespread use.A novel hybrid electric propulsion system is designed to balance HEV cost and performance for developing markets.A battery/supercapacitor-based hybrid energy storage system(HESS)is used to improve energy conversion efficiency and reduce battery size and cost.An all-in-one-controller(AIOC)which integrates engine electronic control unit(ECU),motor ECU,and HESS management system is developed to save materials and energy,and reduce the influence of distribution parameters on circuit.As for the powertrain configuration,four schemes are presented:belt-driven starter generator(BSG)scheme,four-wheel drive HEV scheme,full HEV scheme,and ranger-extender electric vehicle(EV)scheme.Component selection and parameter matching for the propulsion system are performed,and an energy management strategy is developed based on powertrain configuration and selected components.Forward-facing simulation models are built,comprehending the control strategy based on the optimal engine torque for the low-cost hybrid electric propulsion system.Co-simulation of AVL CRUISE and Matlab/Simulink is presented and the best scheme is selected.The simulation results indicate that,for the best design,fuel consumption in urban driving condition is 4.11 L/(100 km)and 0-50 km/h accelerating time is 10.95 s.The proposed research can realize low-cost concept for HEV while achieving satisfactory fuel economy and kinetic performance,and help to improve commercialization of HEVs.
文摘Platinated W/Zr mixed oxides supported on mesoporous silica with various amounts of Si/Zr, namely PtWO_3/ZrO_2（[76_TD$IF]x）-HMS, were prepared and studied for n-heptane isomerization reaction at 200–350 C. The various methods such as XRD, XRF, FT-IR, UV–vis DRS, NH_3-TPD, H_2 chemisorption, nitrogen adsorption–desorption, Py-IR, SEM and TGA techniques were used for characterization of these materials. Kinetics of n-heptane isomerization was also investigated under various hydrogen. n-Heptane pressures and the influence of reaction conditions on catalytic performance were studied. The ideal catalytic performance was observed on HMS with 0.6%Pt/12%WO_3/ZrO_2 and Si/Zr = 10.
基金Projects(51761032,51471054) supported by the National Natural Science Foundation of China
文摘The microstructure, hydrogen storage thermodynamics and kinetics of La5Mg95-xNix (x=5, 10, 15) ternary alloys with different Ni contents were investigated. The evolutions of the microstructure and phase of experimental alloys were characterized by X-ray diffractometry and scanning electron microscopy. The hydrogen storage kinetics and thermodynamics, and P-C-I curves were tested using a Sievert apparatus. It is found that increasing Ni content remarkably improves hydrogen storage kinetics but reduces the hydrogen storage capacity of alloys. The highest hydrogen absorption/desorption rate is observed in the La5Mg80Ni15 alloy, with the lowest hydrogen desorption activation value being 57.7 kJ/mol. By means of P-C-I curves and the van’t Hoff equation, it is determined that the thermodynamic performance of the alloy is initially improved and then degraded with increasing Ni content. The La5Mg85Ni10 alloy has the best thermodynamics properties with a hydrogenation enthalpy of -72.1 kJ/mol and hydrogenation entropy of -123.2 J/(mol·K).
基金financially supported by the Beijing Municipal Commission of Science and Technology of China(D141100002014001)。
文摘The effect of LaNi and Ti on thermal storage properties of MgH_(2)was investigated.The thermal storage performances of Mg are significantly improved by adding LaNi and Ti.The pressure-composition-temperature(PCT)curves indicate that the formation enthalpy for Mg-15 wt%Ti-5 wt%LaNi sample is 73.00 kJ·mol^(-1),which approaches to the theoretical values of pure MgH_(2).The isothermal measurement indicates that,for the Mg-15wt%Ti-5 wt%LaNi,the first absorption reaction fraction within 2 min is 93.77%,increasing by 0.32%,0.24%and0.08%compared with those for Mg,Mg-5 wt%LaNi and Mg-15 wt%Ti,respectively.The first desorption reaction fraction within 2 min is 73.18%,increasing by 55.91%,9.79%and 8.12%compared with those for Mg,Mg-5wt%LaNi and Mg-15 wt%Ti,respectively.Moreover,Mg-15 wt%Ti-5 wt%LaNi has the best cyclic stability in all the samples.The thermal storage performances of Mg by adding both LaNi and Ti are improved mainly ascribed to synergistic effect of in situ formed La_(4)H_(12.19),Mg_(2)NiH_(4),H_(0.3)Mg_(2)Ni and TiH_(2)particles during cyclic process.The above analysis demonstrates that Mg-15 wt%Ti-5wt%LaNi is suitable for using as a heat storage material.
基金financially supported by the National Natural Science Foundations of China (Nos.51161015,51371094 and 51471054)
文摘LaMgNi（4-x）Cox（x = 0-0.8） electrode alloys used for MH/Ni batteries were prepared by induction melting. The structures and electrochemical hydrogen storage properties of the alloys were investigated in detail.X-ray diffraction（XRD） and scanning electron microscopy（SEM） analysis show that LaMgNi4 phase and LaNi5 phase are obtained. The lattice parameters of the two phases increase first and then decrease with Co content increasing.The electrochemical properties of the alloy electrodes were measured by means of simulated battery tests. Results show that the addition of Co does not change the discharge voltage plateau of the alloy electrodes. However, the maximum discharge capacity increases from 319.9 mAh·g^-1（x = 0）to 347.5 mAh·g^-1（x = 0.4） and then decreases to331.7 mAh·g^-1（x = 0.8）. The effects of Co content on electrochemical kinetics of the alloy electrodes were also performed. The high rate dischargeability（HRD） first increases and then decreases with Co content increasing and reaches the maximum value（95.0 %） when x = 0.4. Test results of the electrochemical impedance spectra（EIS）,potentiodynamic polarization curves and constant potential step measurements of the alloy electrodes all demonstrate that when Co content is 0.4 at%, the alloy exhibits the best comprehensive electrochemical properties.
基金supported by the National Natural Science Foundation of China(22202114)the Natural Science Foundation of Shandong Province(ZR2022MB124,ZR2022QB028)+1 种基金the China Postdoctoral Science Foundation(2021M701694)the Postdoctoral Science Foundation of Jiangsu Province(1006-YBA21038)。
文摘Rechargeable aqueous zinc-sulfur batteries(ZSBs)hold significant potential for energy storage due to their stable voltage platform and high capacity,yet suffer from sluggish reaction kinetics and poor reversibility.This study introduces a novel dualsolvent electrolyte,combining air-stable N,N-dimethylformamide(DMF)and water with zinc trifluoromethanesulfonate(Zn(OTF)_2)and trace iodine(I_(2)),to address these issues by enhancing the solid/liquid interactions at the cathode,reducing polarization at the zinc anode interface,and immobilizing the I_(2)catalyst to prevent sublimation.The DMF-I_(2)interaction promotes the formation of I_(3)^(-),enhancing catalytic activity while preventing I_(2)sublimation.Moreover,DMF's high desolvation ability optimizes electrode wettability and minimizes the by-products at both the cathode and anode.Moreover,the Zn-Zn symmetric cell used in the dual solvent electrolyte exhibits significantly reduced polarization,extended calendar life,and suppressed dendrite growth,thereby improving both battery reversibility and kinetic performance.These advancements underscore the electrolyte's potential for advancing the commercial viability of ZSBs.
