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微波加热和常规加热下功能化离子液体催化合成丁二酸二辛酯 被引量:7
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作者 龙俞霖 陈兵 +1 位作者 杨骏 尹万香 《化学研究与应用》 CAS CSCD 北大核心 2012年第4期588-593,共6页
分别在微波辐射和常规加热下,以具有丙烷磺酸基功能基团的离子液体为催化剂催化丁二酸和正辛醇合成丁二酸二辛酯,考察了其阴、阳离子对催化剂活性的影响。相比常规加热,微波加热提高了反应效率,缩短了反应时间。以[PyPS]HSO4为催化剂,... 分别在微波辐射和常规加热下,以具有丙烷磺酸基功能基团的离子液体为催化剂催化丁二酸和正辛醇合成丁二酸二辛酯,考察了其阴、阳离子对催化剂活性的影响。相比常规加热,微波加热提高了反应效率,缩短了反应时间。以[PyPS]HSO4为催化剂,研究了催化剂用量、醇酸比和反应时间对酯化率的影响。结果表明:当催化剂用量为丁二酸的3wt%,酸醇比(丁二酸∶正辛醇)1∶4,反应温度150℃,反应时间15 min,功率400W时,酯化率达到95.74%。此外,微波辐射下[PyPS]HSO4催化剂重复使用6次后活性没有明显降低,酯化率仍有93.58%。 展开更多
关键词 功能化离子液体 丁二酸二辛酯 酯化反应 微波辐射
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Verification of Beam Models for Ionic Polymer-Metal Composite Actuator 被引量:4
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作者 Hoon Cheol Park Quoc Viet Nguyen +1 位作者 Jang Woo Lee Young Tai Yoo 《Journal of Bionic Engineering》 SCIE EI CSCD 2009年第3期232-238,共7页
Ionic Polymer-Metal Composite (IPMC) can work as an actuator by applying a few voltages.A thick IPMC actuator,where Nafion-117 membrane was synthesized with polypyrrole/alumina composite filler,was analyzed to verify ... Ionic Polymer-Metal Composite (IPMC) can work as an actuator by applying a few voltages.A thick IPMC actuator,where Nafion-117 membrane was synthesized with polypyrrole/alumina composite filler,was analyzed to verify the equivalent beam and equivalent bimorph beam models.The blocking force and tip displacement of the IPMC actuator were measured with a DC power supply and Young's modulus of the IPMC strip was measured by bending and tensile tests respectively.The calculated maximum tip displacement and the Young's modulus by the equivalent beam model were almost identical to the corresponding measured data.Finite element analysis with thermal analogy technique was utilized in the equivalent bimorph beam model to numerically reproduce the force-displacement relationship of the IPMC actuator.The results by the equivalent bimorph beam model agreed well with the force-displacement relationship acquired by the measured data.It is confirmed that the equivalent beam and equivalent bimorph beam models are practically and effectively suitable for predicting the tip displacement,blocking force and Young's modulus of IPMC actuators with different thickness and different composite of ionic polymer membrane. 展开更多
关键词 jonic polymer-metal composite BEAM model DISPLACEMENT FORCE
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