Rare earth oxide was prepared via direct pyrolysis of rare earth chloride solution. Based on this technique, a new-type jet-flow pyrolysis reactor was designed, and then the fluid dynamics (pressure and velocity) insi...Rare earth oxide was prepared via direct pyrolysis of rare earth chloride solution. Based on this technique, a new-type jet-flow pyrolysis reactor was designed, and then the fluid dynamics (pressure and velocity) inside the reactor was numerically simulated using a computational fluid dynamics method. The self-produced pressure (p) and the fuel inlet velocity (v) satisfied a quadratic function,p=0.06v2+0.23v?4.49. To fully utilize the combustion-generated heat in pyrolysis of rare earth chloride, an appropriate external pressure p=v2+3v?4.27 should be imposed at the feed inlet. The 1.25- and 1.5-fold increase of feed inlet diameter resulted in decline of adsorption dynamic pressure, but the intake of rare earth chloride increased by more than 30% and 60%, respectively. The fluid flow in the reactor was affected by the feeding rate; the fluid flow peaked near the throat of venturi and gradually smoothed down at the jet-flow reactor’s terminal along with the sharp decline of feeding rate.展开更多
Ultrafine rare-earth oxides(REOs) are widely applied in all fields of daily life,but the conventional preparation methods are limited by a long procedure,low efficiency and severe environmental pollution.Our team has ...Ultrafine rare-earth oxides(REOs) are widely applied in all fields of daily life,but the conventional preparation methods are limited by a long procedure,low efficiency and severe environmental pollution.Our team has independently developed a jet pyrolysis reactor for the preparation of ultrafine cerium oxides,and this process has theoretical significance and practical application values.In this study,gas-solid pyrolysis reactions inside the jet-flow pyrolysis reactor were numerically simulated.We performed a coupling computation of the combustion,phase transformation and gas-solid reaction on Fluent and userdefined functions.We characterized the flows of different phases as well as the compositions and distributive laws of the reactants/products in the reactor.The gas-phase inlet velocity and dynamic pressure/additional pressure were related by a quadratic function.The velocity at the throat inlet changed the most,and the outlet velocity was very stable.The CeO2 concentrations were obviously stratified.This study enriches theories of jet-flow pyrolysis and theoretically underlies the optimization and popularization of self-developed pyrolysis reactors.展开更多
A novel method to prepare macroporous TiO2 ceramic, based on membrane emulsification was reported.To solve the paradox between the instability of nonaqueous emulsion and long emulsification time required by themembran...A novel method to prepare macroporous TiO2 ceramic, based on membrane emulsification was reported.To solve the paradox between the instability of nonaqueous emulsion and long emulsification time required by themembrane emulsification, a two-stage ceramic membrane jet-flow emulsification .was. proposed. Discussion wasconducted on the evolution of droplet size with time, which followed the Ostwalcl npemng theory. And a monodispersed nonaqueous emulsion with an average droplet size of 1.6μm could beprepared. Using the emulsion, as atemplate, TiO2 ceramics with an average pore size ot 1.1 μm were obtaineed. Tne material could be prospectivelyused for preparation of catalysts, adsorbents, and membranes.展开更多
In aero-engines,mortise-tenon joint structures are often used to connect the blades to the turbine disk.The disadvantages associated with conventional manufacturing techniques mean that a low-cost,high-efficiency,and ...In aero-engines,mortise-tenon joint structures are often used to connect the blades to the turbine disk.The disadvantages associated with conventional manufacturing techniques mean that a low-cost,high-efficiency,and high-quality nickel-based mortise–tenon joint structure is an urgent requirement in the field of aviation engineering.Electrochemical cutting is a potential machining method for manufacturing these parts,as there is no tool degradation in the cutting process and high-quality surfaces can be obtained.To realize the electrochemical cutting of a mortise-tenon joint structure,a method using a tube electrode with helically distributed jet-flow holes on the side-wall is proposed.During feeding,the tube electrode rotates along its central axis.Flow field simulations show that the rotational speed of the tube electrode determines the direct spraying time of the high-speed electrolyte ejected from the jet-flow holes to the machining area,while the electrolyte pressure determines the flow rate of the electrolyte and the velocity of the electrolyte ejected from the jet-flow holes.The machining results using the proposed method are verified experimentally,and the machining parameters are optimized.Finally,mortise and tenon samples are successfully machined using 20 mm thick Inconel 718 alloy with a feeding rate of 5μm/s.展开更多
基金Projects(51204040,U1202274)supported by the National Natural Science Foundation of ChinaProjects(2010AA03A405,2102AA062303)supported by the National High-tech Research and Development Program of China+1 种基金Project(2012BAE01B02)supported by the National Science and Technology Support Program of ChinaProject(N130702001)supported by the Fundamental Research Funds for the Central Universities,China
文摘Rare earth oxide was prepared via direct pyrolysis of rare earth chloride solution. Based on this technique, a new-type jet-flow pyrolysis reactor was designed, and then the fluid dynamics (pressure and velocity) inside the reactor was numerically simulated using a computational fluid dynamics method. The self-produced pressure (p) and the fuel inlet velocity (v) satisfied a quadratic function,p=0.06v2+0.23v?4.49. To fully utilize the combustion-generated heat in pyrolysis of rare earth chloride, an appropriate external pressure p=v2+3v?4.27 should be imposed at the feed inlet. The 1.25- and 1.5-fold increase of feed inlet diameter resulted in decline of adsorption dynamic pressure, but the intake of rare earth chloride increased by more than 30% and 60%, respectively. The fluid flow in the reactor was affected by the feeding rate; the fluid flow peaked near the throat of venturi and gradually smoothed down at the jet-flow reactor’s terminal along with the sharp decline of feeding rate.
基金financially supported by the National Natural Science Foundation of China (No.51904069)the Natural Science Foundation of Hebei Province of China (No.E2019501085)+2 种基金the Colleges and Universities in Hebei Province Science and Technology Research Youth Fund (No.QN2019312)the Fundamental Research Funds for the Central Universities (No.N172303012)the National Science and Technology Support Program (No.2012BAE01B02)
文摘Ultrafine rare-earth oxides(REOs) are widely applied in all fields of daily life,but the conventional preparation methods are limited by a long procedure,low efficiency and severe environmental pollution.Our team has independently developed a jet pyrolysis reactor for the preparation of ultrafine cerium oxides,and this process has theoretical significance and practical application values.In this study,gas-solid pyrolysis reactions inside the jet-flow pyrolysis reactor were numerically simulated.We performed a coupling computation of the combustion,phase transformation and gas-solid reaction on Fluent and userdefined functions.We characterized the flows of different phases as well as the compositions and distributive laws of the reactants/products in the reactor.The gas-phase inlet velocity and dynamic pressure/additional pressure were related by a quadratic function.The velocity at the throat inlet changed the most,and the outlet velocity was very stable.The CeO2 concentrations were obviously stratified.This study enriches theories of jet-flow pyrolysis and theoretically underlies the optimization and popularization of self-developed pyrolysis reactors.
基金Supported by the National High Technology Research and Development Program of China （863 program, No.2006AA03Z534）, the Postdoctoral Science Foundation of China （No.20060400927）, the National Basic Research Program of China （No.2003CB6157070）, the National Natural Science Foundation of China （No.20436030）, Natural Science Foundation of Jiangsu Province （No.BK2006566）, and Jiangsu Planned Projects for Postdoctoral Research Funds （No.0601023B）.
文摘A novel method to prepare macroporous TiO2 ceramic, based on membrane emulsification was reported.To solve the paradox between the instability of nonaqueous emulsion and long emulsification time required by themembrane emulsification, a two-stage ceramic membrane jet-flow emulsification .was. proposed. Discussion wasconducted on the evolution of droplet size with time, which followed the Ostwalcl npemng theory. And a monodispersed nonaqueous emulsion with an average droplet size of 1.6μm could beprepared. Using the emulsion, as atemplate, TiO2 ceramics with an average pore size ot 1.1 μm were obtaineed. Tne material could be prospectivelyused for preparation of catalysts, adsorbents, and membranes.
基金supported by the National Natural Science Foundation of China(No.91960204)the Natural Science Foundation of Jiangsu Province(No.BK20191279)+1 种基金the Aeronautical Science Foundation of China(No.201907052002)the National Natural Science Foundation of China for Creative Research Groups(No.51921003)。
文摘In aero-engines,mortise-tenon joint structures are often used to connect the blades to the turbine disk.The disadvantages associated with conventional manufacturing techniques mean that a low-cost,high-efficiency,and high-quality nickel-based mortise–tenon joint structure is an urgent requirement in the field of aviation engineering.Electrochemical cutting is a potential machining method for manufacturing these parts,as there is no tool degradation in the cutting process and high-quality surfaces can be obtained.To realize the electrochemical cutting of a mortise-tenon joint structure,a method using a tube electrode with helically distributed jet-flow holes on the side-wall is proposed.During feeding,the tube electrode rotates along its central axis.Flow field simulations show that the rotational speed of the tube electrode determines the direct spraying time of the high-speed electrolyte ejected from the jet-flow holes to the machining area,while the electrolyte pressure determines the flow rate of the electrolyte and the velocity of the electrolyte ejected from the jet-flow holes.The machining results using the proposed method are verified experimentally,and the machining parameters are optimized.Finally,mortise and tenon samples are successfully machined using 20 mm thick Inconel 718 alloy with a feeding rate of 5μm/s.
