Confined impinging jet reactor(CIJR)offers advantages for chemical rapid processes and has become an important new reactor used in the chemical industry.The micromixing efficiency in a T-shaped CIJR for two tubes of i...Confined impinging jet reactor(CIJR)offers advantages for chemical rapid processes and has become an important new reactor used in the chemical industry.The micromixing efficiency in a T-shaped CIJR for two tubes of inner diameter of 3 mm was studied by using a parallel competing iodide–iodate reaction as the working system.In this work,the effects of different operating conditions,such as impinging velocity and acid concentration,on segregation index were investigated.In addition,the effects of the inner nozzles diameter and the distance L between the jet axis and the top wall of the mixing chamber on the micromixing efficiency were also considered.It is concluded that the best range of L in this CIJR is 6.5–12.5 mm.Based on the incorporation model,the estimated minimum micromixing time tmof CIJR approximately equals to 2×10-4s.These experimental results indicate clearly that CIJR possesses a much better micromixing performance compared with the conventional stirred tank(micromixing time of 2×10-3to 2×10-2s).Hence,it can be envisioned that CIJR has more promising applications in various industrial processes.展开更多
The extraction fraction E and overall volumetric mass transfer coefficient kka of TBP extracting butyric acid pro- cess in confined impinging jet reactors （CIJR） with two jets were investigated. The main variables t...The extraction fraction E and overall volumetric mass transfer coefficient kka of TBP extracting butyric acid pro- cess in confined impinging jet reactors （CIJR） with two jets were investigated. The main variables tested were the concentration of tri-butyl-phosphate （TBP） and butyric acid, the impinging velocity V, the impinging velocityratio of two phases Vorg/Vaq, the nozzle inner diameter di and the distance L between the jet axes and the top wall of the impinging chamber. The results showed that E and kLa increase with an increase of the impinging velocity V, the concentration ofTBP Corg, and the impinging velocity ratio Vor/Vaq. However, E and kta decrease with an increase of the inner diameter d1 from 1 to 2 mm, the concentration of butyric acid Caq from 0.5% （v/v） to 2% （v/v）. The factor L ranging from 3 to 11 mm has a negligible effect on E and kLa. A correlation on these variables and kLa was proposed based on the experimental data. These results indicated good mass transfer oerformance of CIJR in the extraction operation.展开更多
Methyl anthranilate(MA)is an important material for the synthesis of sodium saccharin,but the yield and quality of MA are not stable due to the batch operation conditions.In this study,the optimum conditions obtained ...Methyl anthranilate(MA)is an important material for the synthesis of sodium saccharin,but the yield and quality of MA are not stable due to the batch operation conditions.In this study,the optimum conditions obtained by an orthogonal test in a batch reactor were a volume ratio of methanol to amide solution of 5:4,volume ratio of sodium hypochlorite to amide solution of 7:4,Hoffmann degradation reaction duration of 10 min,Hoffmann degradation reaction temperature of 10℃,esterification reaction duration of 10 min,and esterification reaction temperature of 40℃.The working flow velocity and allowable working viscosity range of a Venturi ejector inlet were both determined by a computational fluid dynamics(CFD)simulation.Based on the above experimental data,the continuous operation of the process was tested in a three-stage continuous reactor,which improved the product yield and quality of the process.展开更多
Hursts rescaled range (R/S) analysis and Wolfs attractor reconstruction technique have been adopted to estimate the local fractal dimensions and the local largest Lyapunov exponents in terms of the time series pressur...Hursts rescaled range (R/S) analysis and Wolfs attractor reconstruction technique have been adopted to estimate the local fractal dimensions and the local largest Lyapunov exponents in terms of the time series pressure fluctuations obtained from a gas liquid solid three phase self aspirated reversed flow jet loop reactor,respectively.The results indicate that the local fractal dimensions and the local largest Lyapunov exponents in both the jet region and the tubular region inside the draft tube increase with the increase in the jet liquid flowrates and the solid loadings,the local fractal dimension profiles are similar to those of the largest Lyapunov exponent,the local largest lyapunov exponents are positive for all cases,and the flow behavior of such a reactor is chaotic.The local nonlinear characteristic parameters such as the local fractal dimension and the local largest Lyapunov exponent could be applied to further study the flow properties such as the flow regime transitions and flow structures of this three phase jet loop reactor.展开更多
The local chaos characteristics of the time series pressure fluctuations of gas liquid two phase flow in a self aspirated reversed flow jet loop reactor are studied by the deterministic chaos analysis technique. It...The local chaos characteristics of the time series pressure fluctuations of gas liquid two phase flow in a self aspirated reversed flow jet loop reactor are studied by the deterministic chaos analysis technique. It is found that the estimated local largest Lyapunov exponent is positive in all cases and the profile is similar to that of the local fractal dimension in this reactor. The positive largest Lyapunov exponent shows that the reactor is a nonlinear chaotic system. The obvious distribution indicates that the local nonlinear characteristic parameters such as the Lyapunov exponent and the fractal dimension could be applied to further study the flow characteristics such as the flow regine transitions and flow structures of the multi phase reactors.展开更多
MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4· H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2^...MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4· H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2^＋ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate（ L/S）, pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2^＋ extraction rate decreased from 98.1% to 82.2% and from 82.8% to 61.7%, respectively. The content of MnO2 in pyrolusite had a neglectable effect on SO2, absorption efficiency. Low L/S was good for both removal of SO2 and Mn2^＋ extraction. The absorption liquid was filtrated and purified to remove Si, Mg, Ca, Fe, Al and heavy metals, last product MnSO4· H2O was obtained which quality could reach China GB1622-86, the industry grade standards.展开更多
The hydrodynamics and mass transfer characteristics of a lab-scale jet bubbling reactor(JBR)including the gas holdup,volumetric mass transfer coefficient and specific interfacial area were assessed experimentally inve...The hydrodynamics and mass transfer characteristics of a lab-scale jet bubbling reactor(JBR)including the gas holdup,volumetric mass transfer coefficient and specific interfacial area were assessed experimentally investigating the influence of temperature,pH and superficial gas velocity.The reactor diameter and height were 11 and 30 cm,respectively.It was equipped with a single sparger,operating at atmospheric pressure,20 and 40℃,and two pH values of 3 and 6.The height of the liquid was 23 cm,while the superficial gas velocity changed within 0.010-0.040 m·s^(-1)range.Experiments were conducted with pure oxygen as the gas phase and saturated lime solution as the liquid phase.The liquid-side volumetric mass transfer coefficient was determined under unsteady-state oxygen absorption in a saturated lime solution.The gas holdup was calculated based on the liquid height change,while the specific interfacial area was obtained by a physical method based on the bubble size distribution(BSD)in different superficial gas velocities.The results indicated that at the same temperature but different pH,the gas holdup variation was negligible,while the liquid-side volumetric mass transfer coefficient at the pH value of 6 was higher than that at the pH=3.At a constant pH but different temperatures,the gas holdup and the liquid-side volumetric mass transfer coefficients at 40℃were higher than that of the same at 20℃.A reasonable and appropriate estimation of the liquid-side volumetric mass transfer coefficient(kla)in a pilot-scale JBR was provided which can be applied to the design and scale-up of JBRs.展开更多
1 INTRODUCTIONGas and liquid distributions in a self-aspirated reverse flow jet loop reactor dependchiefly on the aspiration and the breakup against gas phase by the liquid nozzle aswell as the redistribution in the d...1 INTRODUCTIONGas and liquid distributions in a self-aspirated reverse flow jet loop reactor dependchiefly on the aspiration and the breakup against gas phase by the liquid nozzle aswell as the redistribution in the draft tube.It has also been noted that effective diffu-sion or backmixing in the reactor has great influence on the flow and mass transferrates.In this case,accurate descriptions about the fluid flow and diffusion conditions inthe reactor are most necessary for effective amplification of them.展开更多
1 INTRODUCTIONSelf-aspirated reversed flow jet loop reactors,characterized by a well defined flow pat-tern,well better dispersing effects,relatively low power consumption and a high masstransfer coefficient,are widely...1 INTRODUCTIONSelf-aspirated reversed flow jet loop reactors,characterized by a well defined flow pat-tern,well better dispersing effects,relatively low power consumption and a high masstransfer coefficient,are widely used in chemical engineering,especially in biochemicalengineering.The characteristics of such reactors are highly random or stochastic due tothe influence of a variety of phenomena such as jetting and bubbling of the展开更多
The hydrodynamic and mass transfer characteristics of a downflow liquid jet loop reactor (D-JLR) were studied experimentally with water/air and CMC (carboxymethyl cellulose) solution/air systems. The effects of the ge...The hydrodynamic and mass transfer characteristics of a downflow liquid jet loop reactor (D-JLR) were studied experimentally with water/air and CMC (carboxymethyl cellulose) solution/air systems. The effects of the geometry, the operating parameters and the physical properties of the liquid phase on gas hold-up and mass transfer coefficient were measuered. Compared with other types of gas-liquid reactor, D-JLR shows higher mass transfer coefficient and lower energy dissipation rate, the optimum diameter ratio was found to be about 0.42-0.6. A model for gas hold-up in D-JLR with Newtonian and non-Newtonian fluids has been developed on the basis of the equation of motion and the concept of average mixing length. The prediction of gas hold-up with the model agreed with the experimental results of this work.展开更多
Ultrafine rare-earth oxides(REOs) are widely applied in all fields of daily life,but the conventional preparation methods are limited by a long procedure,low efficiency and severe environmental pollution.Our team has ...Ultrafine rare-earth oxides(REOs) are widely applied in all fields of daily life,but the conventional preparation methods are limited by a long procedure,low efficiency and severe environmental pollution.Our team has independently developed a jet pyrolysis reactor for the preparation of ultrafine cerium oxides,and this process has theoretical significance and practical application values.In this study,gas-solid pyrolysis reactions inside the jet-flow pyrolysis reactor were numerically simulated.We performed a coupling computation of the combustion,phase transformation and gas-solid reaction on Fluent and userdefined functions.We characterized the flows of different phases as well as the compositions and distributive laws of the reactants/products in the reactor.The gas-phase inlet velocity and dynamic pressure/additional pressure were related by a quadratic function.The velocity at the throat inlet changed the most,and the outlet velocity was very stable.The CeO2 concentrations were obviously stratified.This study enriches theories of jet-flow pyrolysis and theoretically underlies the optimization and popularization of self-developed pyrolysis reactors.展开更多
A new anaerobic reactor, Jet-loop anaerobic fluidized bed （JLAFB）, was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and...A new anaerobic reactor, Jet-loop anaerobic fluidized bed （JLAFB）, was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and sulfide inhibition in reactors, were discussed for a JLAFB and a general anaerobic fiuidized bed （AFB） reactor used as sulfate-reducing phase and methane-producing phase, respectively, in two-phase anaerobic digestion process. The formation of granules in the two reactors was also examined. The results indicated that COD and sulfate removal had different demand of influent COD/SO4^2- ratios. When total COD removal was up to 85%, the ratio was only required up to 1.2, whereas, total sulfate removal up to 95% required it exceeding 3.0. The alkalinity in the two reactors increased linearly with the growth of influent alkalinity. Moreover, the change of influent alkalinity had no significant effect on pH and volatile fatty acids （VFA） in the two reactors. Influent alkalinity kept at 400-500 mg/L could meet the requirement of the treating process. The JLAFB reactor had great advantage in avoiding sulfide and free-H2S accumulation and toxicity inhibition on microorganisms. When sulfate loading rate was up to 8. 1 kg/（m^3.d）, the sulfide and free-H2S concentrations in JLAFB reactor were 58.6 and 49.7 mg/L, respectively. Furthermore, the granules, with offwhite color, ellipse shape and diameters of 1.0-3.0 mm, could be developed in JLAFB reactor. In granules, different groups of bacteria were distributed in different layers, and some inorganic metal compounds such as Fe, Ca, Mg etc. were found.展开更多
The local liquid--phase characteristics of the gas--liquid two-phase and gas--liquid--solid threephase self-aspirated reversed flow jet loop reactor with a concentric gas--liquid injection nozzle were studied experime...The local liquid--phase characteristics of the gas--liquid two-phase and gas--liquid--solid threephase self-aspirated reversed flow jet loop reactor with a concentric gas--liquid injection nozzle were studied experimentally. They facilitate the evaluation of local phenomena. The local instantaneous liquid velocities at different axial positions of the reactor were measured by using the modified pilot tube.The local liquid-phase turbulent structural parameters such as time-averaged velocity. turbulent nuctuating velocity and turbulent micro scale were calculated with the aid of the statistical theory of turbulence. In particular, effects of liquid jet flowrates and solid loadings on the profiles of the liquid--phase turbulent structural parameter both in the jet effective region and in the tubular region inside the draft tube were discussed.展开更多
The performance of the flat jet with an inclination angle was investigated bya water model. A mathematical model for the shrinkage and the trajectory of the flat jet with aninclination angle was derived theoretically ...The performance of the flat jet with an inclination angle was investigated bya water model. A mathematical model for the shrinkage and the trajectory of the flat jet with aninclination angle was derived theoretically and verified by experimental data of the water model.The experimental results indicate that the inclination angle (alpha) has no influence on theshrinkage of the flat jet, the shrinkage of the flat jet along the width direction decreases withthe increasing of the initial velocity at the exit (u_0) and the initial thickness of the flat jet(t_0). Enough bigger initial exit velocity (u_0) and initial thickness can suppress the shrinkage ofthe flat jet along the width direction and keep the flat jet stabilized. In addition, thetrajectory of the flat jet with an inclination angle is parabolic and must be taking intoconsideration when to determine the striking distance.展开更多
通过施加超声强化受限撞击流反应器内共沉淀反应和结晶过程,优化氧化锆纳米颗粒制备过程。采用实验和数值模拟方法研究了超声空化效应和流体动力学因素对氧化锆纳米颗粒反应沉淀过程的协同作用,以及对所制备颗粒性能的影响。利用扫描电...通过施加超声强化受限撞击流反应器内共沉淀反应和结晶过程,优化氧化锆纳米颗粒制备过程。采用实验和数值模拟方法研究了超声空化效应和流体动力学因素对氧化锆纳米颗粒反应沉淀过程的协同作用,以及对所制备颗粒性能的影响。利用扫描电镜(scanning electron microscope,SEM)、X-射线衍射(X-ray diffraction,XRD)对有、无超声作用下制备颗粒的形貌、结构和粒度分布进行表征。结果表明,施加超声后,撞击流反应器撞击区域上方“三角区域”与出口侧方流动不佳区域的流动混合性能得到加强,能有效防止流体回流;且反应器内湍流耗散率与化学反应速率均有明显提升,反应器流动混合性能得到加强。相较于无超声条件下,超声强化后撞击流反应器制备的氧化锆颗粒为微球形,且颗粒尺寸更小、尺寸分布更窄,氧化锆更趋向于以四方相结构出现。当超声功率超过210 W后,所制备的氧化锆超细粉体为高纯度四方氧化锆。展开更多
基金Supported by the National Natural Science Foundation of China(21206002,21121064,20990224)the State Key Laboratory of Chemical Engineering(SKL-Ch E-13A03)
文摘Confined impinging jet reactor(CIJR)offers advantages for chemical rapid processes and has become an important new reactor used in the chemical industry.The micromixing efficiency in a T-shaped CIJR for two tubes of inner diameter of 3 mm was studied by using a parallel competing iodide–iodate reaction as the working system.In this work,the effects of different operating conditions,such as impinging velocity and acid concentration,on segregation index were investigated.In addition,the effects of the inner nozzles diameter and the distance L between the jet axis and the top wall of the mixing chamber on the micromixing efficiency were also considered.It is concluded that the best range of L in this CIJR is 6.5–12.5 mm.Based on the incorporation model,the estimated minimum micromixing time tmof CIJR approximately equals to 2×10-4s.These experimental results indicate clearly that CIJR possesses a much better micromixing performance compared with the conventional stirred tank(micromixing time of 2×10-3to 2×10-2s).Hence,it can be envisioned that CIJR has more promising applications in various industrial processes.
基金Supported by the National Natural Science Foundation of China(21206002,21376016)the State Key Laboratory of Chemical Engineering(SKL-Ch E-13A03)
文摘The extraction fraction E and overall volumetric mass transfer coefficient kka of TBP extracting butyric acid pro- cess in confined impinging jet reactors （CIJR） with two jets were investigated. The main variables tested were the concentration of tri-butyl-phosphate （TBP） and butyric acid, the impinging velocity V, the impinging velocityratio of two phases Vorg/Vaq, the nozzle inner diameter di and the distance L between the jet axes and the top wall of the impinging chamber. The results showed that E and kLa increase with an increase of the impinging velocity V, the concentration ofTBP Corg, and the impinging velocity ratio Vor/Vaq. However, E and kta decrease with an increase of the inner diameter d1 from 1 to 2 mm, the concentration of butyric acid Caq from 0.5% （v/v） to 2% （v/v）. The factor L ranging from 3 to 11 mm has a negligible effect on E and kLa. A correlation on these variables and kLa was proposed based on the experimental data. These results indicated good mass transfer oerformance of CIJR in the extraction operation.
文摘Methyl anthranilate(MA)is an important material for the synthesis of sodium saccharin,but the yield and quality of MA are not stable due to the batch operation conditions.In this study,the optimum conditions obtained by an orthogonal test in a batch reactor were a volume ratio of methanol to amide solution of 5:4,volume ratio of sodium hypochlorite to amide solution of 7:4,Hoffmann degradation reaction duration of 10 min,Hoffmann degradation reaction temperature of 10℃,esterification reaction duration of 10 min,and esterification reaction temperature of 40℃.The working flow velocity and allowable working viscosity range of a Venturi ejector inlet were both determined by a computational fluid dynamics(CFD)simulation.Based on the above experimental data,the continuous operation of the process was tested in a three-stage continuous reactor,which improved the product yield and quality of the process.
文摘Hursts rescaled range (R/S) analysis and Wolfs attractor reconstruction technique have been adopted to estimate the local fractal dimensions and the local largest Lyapunov exponents in terms of the time series pressure fluctuations obtained from a gas liquid solid three phase self aspirated reversed flow jet loop reactor,respectively.The results indicate that the local fractal dimensions and the local largest Lyapunov exponents in both the jet region and the tubular region inside the draft tube increase with the increase in the jet liquid flowrates and the solid loadings,the local fractal dimension profiles are similar to those of the largest Lyapunov exponent,the local largest lyapunov exponents are positive for all cases,and the flow behavior of such a reactor is chaotic.The local nonlinear characteristic parameters such as the local fractal dimension and the local largest Lyapunov exponent could be applied to further study the flow properties such as the flow regime transitions and flow structures of this three phase jet loop reactor.
文摘The local chaos characteristics of the time series pressure fluctuations of gas liquid two phase flow in a self aspirated reversed flow jet loop reactor are studied by the deterministic chaos analysis technique. It is found that the estimated local largest Lyapunov exponent is positive in all cases and the profile is similar to that of the local fractal dimension in this reactor. The positive largest Lyapunov exponent shows that the reactor is a nonlinear chaotic system. The obvious distribution indicates that the local nonlinear characteristic parameters such as the Lyapunov exponent and the fractal dimension could be applied to further study the flow characteristics such as the flow regine transitions and flow structures of the multi phase reactors.
基金The Chinese Technology Department ( No. 85-912-04-01-02) the National Engineering Research Center for Flue Gas Desulfurization ( No.2001DC105003-1)
文摘MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4· H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2^＋ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate（ L/S）, pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2^＋ extraction rate decreased from 98.1% to 82.2% and from 82.8% to 61.7%, respectively. The content of MnO2 in pyrolusite had a neglectable effect on SO2, absorption efficiency. Low L/S was good for both removal of SO2 and Mn2^＋ extraction. The absorption liquid was filtrated and purified to remove Si, Mg, Ca, Fe, Al and heavy metals, last product MnSO4· H2O was obtained which quality could reach China GB1622-86, the industry grade standards.
基金the authors appreciate the vice-chancellor of research and technology of the University of Isfahan for supporting this work under Grant No.911401707。
文摘The hydrodynamics and mass transfer characteristics of a lab-scale jet bubbling reactor(JBR)including the gas holdup,volumetric mass transfer coefficient and specific interfacial area were assessed experimentally investigating the influence of temperature,pH and superficial gas velocity.The reactor diameter and height were 11 and 30 cm,respectively.It was equipped with a single sparger,operating at atmospheric pressure,20 and 40℃,and two pH values of 3 and 6.The height of the liquid was 23 cm,while the superficial gas velocity changed within 0.010-0.040 m·s^(-1)range.Experiments were conducted with pure oxygen as the gas phase and saturated lime solution as the liquid phase.The liquid-side volumetric mass transfer coefficient was determined under unsteady-state oxygen absorption in a saturated lime solution.The gas holdup was calculated based on the liquid height change,while the specific interfacial area was obtained by a physical method based on the bubble size distribution(BSD)in different superficial gas velocities.The results indicated that at the same temperature but different pH,the gas holdup variation was negligible,while the liquid-side volumetric mass transfer coefficient at the pH value of 6 was higher than that at the pH=3.At a constant pH but different temperatures,the gas holdup and the liquid-side volumetric mass transfer coefficients at 40℃were higher than that of the same at 20℃.A reasonable and appropriate estimation of the liquid-side volumetric mass transfer coefficient(kla)in a pilot-scale JBR was provided which can be applied to the design and scale-up of JBRs.
基金This work was supported by the National Science Foundation of China.
文摘1 INTRODUCTIONGas and liquid distributions in a self-aspirated reverse flow jet loop reactor dependchiefly on the aspiration and the breakup against gas phase by the liquid nozzle aswell as the redistribution in the draft tube.It has also been noted that effective diffu-sion or backmixing in the reactor has great influence on the flow and mass transferrates.In this case,accurate descriptions about the fluid flow and diffusion conditions inthe reactor are most necessary for effective amplification of them.
基金Supported by the Science Foundation of the ChineseAcademy of Science.
文摘1 INTRODUCTIONSelf-aspirated reversed flow jet loop reactors,characterized by a well defined flow pat-tern,well better dispersing effects,relatively low power consumption and a high masstransfer coefficient,are widely used in chemical engineering,especially in biochemicalengineering.The characteristics of such reactors are highly random or stochastic due tothe influence of a variety of phenomena such as jetting and bubbling of the
文摘The hydrodynamic and mass transfer characteristics of a downflow liquid jet loop reactor (D-JLR) were studied experimentally with water/air and CMC (carboxymethyl cellulose) solution/air systems. The effects of the geometry, the operating parameters and the physical properties of the liquid phase on gas hold-up and mass transfer coefficient were measuered. Compared with other types of gas-liquid reactor, D-JLR shows higher mass transfer coefficient and lower energy dissipation rate, the optimum diameter ratio was found to be about 0.42-0.6. A model for gas hold-up in D-JLR with Newtonian and non-Newtonian fluids has been developed on the basis of the equation of motion and the concept of average mixing length. The prediction of gas hold-up with the model agreed with the experimental results of this work.
基金financially supported by the National Natural Science Foundation of China (No.51904069)the Natural Science Foundation of Hebei Province of China (No.E2019501085)+2 种基金the Colleges and Universities in Hebei Province Science and Technology Research Youth Fund (No.QN2019312)the Fundamental Research Funds for the Central Universities (No.N172303012)the National Science and Technology Support Program (No.2012BAE01B02)
文摘Ultrafine rare-earth oxides(REOs) are widely applied in all fields of daily life,but the conventional preparation methods are limited by a long procedure,low efficiency and severe environmental pollution.Our team has independently developed a jet pyrolysis reactor for the preparation of ultrafine cerium oxides,and this process has theoretical significance and practical application values.In this study,gas-solid pyrolysis reactions inside the jet-flow pyrolysis reactor were numerically simulated.We performed a coupling computation of the combustion,phase transformation and gas-solid reaction on Fluent and userdefined functions.We characterized the flows of different phases as well as the compositions and distributive laws of the reactants/products in the reactor.The gas-phase inlet velocity and dynamic pressure/additional pressure were related by a quadratic function.The velocity at the throat inlet changed the most,and the outlet velocity was very stable.The CeO2 concentrations were obviously stratified.This study enriches theories of jet-flow pyrolysis and theoretically underlies the optimization and popularization of self-developed pyrolysis reactors.
基金Project supported by the National Natural Science Foundation of China(No. 50278036)the Natural Science Foundation of Guangdong Province (No. 04105951)
文摘A new anaerobic reactor, Jet-loop anaerobic fluidized bed （JLAFB）, was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and sulfide inhibition in reactors, were discussed for a JLAFB and a general anaerobic fiuidized bed （AFB） reactor used as sulfate-reducing phase and methane-producing phase, respectively, in two-phase anaerobic digestion process. The formation of granules in the two reactors was also examined. The results indicated that COD and sulfate removal had different demand of influent COD/SO4^2- ratios. When total COD removal was up to 85%, the ratio was only required up to 1.2, whereas, total sulfate removal up to 95% required it exceeding 3.0. The alkalinity in the two reactors increased linearly with the growth of influent alkalinity. Moreover, the change of influent alkalinity had no significant effect on pH and volatile fatty acids （VFA） in the two reactors. Influent alkalinity kept at 400-500 mg/L could meet the requirement of the treating process. The JLAFB reactor had great advantage in avoiding sulfide and free-H2S accumulation and toxicity inhibition on microorganisms. When sulfate loading rate was up to 8. 1 kg/（m^3.d）, the sulfide and free-H2S concentrations in JLAFB reactor were 58.6 and 49.7 mg/L, respectively. Furthermore, the granules, with offwhite color, ellipse shape and diameters of 1.0-3.0 mm, could be developed in JLAFB reactor. In granules, different groups of bacteria were distributed in different layers, and some inorganic metal compounds such as Fe, Ca, Mg etc. were found.
文摘The local liquid--phase characteristics of the gas--liquid two-phase and gas--liquid--solid threephase self-aspirated reversed flow jet loop reactor with a concentric gas--liquid injection nozzle were studied experimentally. They facilitate the evaluation of local phenomena. The local instantaneous liquid velocities at different axial positions of the reactor were measured by using the modified pilot tube.The local liquid-phase turbulent structural parameters such as time-averaged velocity. turbulent nuctuating velocity and turbulent micro scale were calculated with the aid of the statistical theory of turbulence. In particular, effects of liquid jet flowrates and solid loadings on the profiles of the liquid--phase turbulent structural parameter both in the jet effective region and in the tubular region inside the draft tube were discussed.
文摘The performance of the flat jet with an inclination angle was investigated bya water model. A mathematical model for the shrinkage and the trajectory of the flat jet with aninclination angle was derived theoretically and verified by experimental data of the water model.The experimental results indicate that the inclination angle (alpha) has no influence on theshrinkage of the flat jet, the shrinkage of the flat jet along the width direction decreases withthe increasing of the initial velocity at the exit (u_0) and the initial thickness of the flat jet(t_0). Enough bigger initial exit velocity (u_0) and initial thickness can suppress the shrinkage ofthe flat jet along the width direction and keep the flat jet stabilized. In addition, thetrajectory of the flat jet with an inclination angle is parabolic and must be taking intoconsideration when to determine the striking distance.
文摘通过施加超声强化受限撞击流反应器内共沉淀反应和结晶过程,优化氧化锆纳米颗粒制备过程。采用实验和数值模拟方法研究了超声空化效应和流体动力学因素对氧化锆纳米颗粒反应沉淀过程的协同作用,以及对所制备颗粒性能的影响。利用扫描电镜(scanning electron microscope,SEM)、X-射线衍射(X-ray diffraction,XRD)对有、无超声作用下制备颗粒的形貌、结构和粒度分布进行表征。结果表明,施加超声后,撞击流反应器撞击区域上方“三角区域”与出口侧方流动不佳区域的流动混合性能得到加强,能有效防止流体回流;且反应器内湍流耗散率与化学反应速率均有明显提升,反应器流动混合性能得到加强。相较于无超声条件下,超声强化后撞击流反应器制备的氧化锆颗粒为微球形,且颗粒尺寸更小、尺寸分布更窄,氧化锆更趋向于以四方相结构出现。当超声功率超过210 W后,所制备的氧化锆超细粉体为高纯度四方氧化锆。
