Based on a new bilinear equation,we investigated some new dynamic behaviors of the(2+1)-dimensional shallow water wave model,such as hybridization behavior between different solitons,trajectory equations for lump coll...Based on a new bilinear equation,we investigated some new dynamic behaviors of the(2+1)-dimensional shallow water wave model,such as hybridization behavior between different solitons,trajectory equations for lump collisions,and evolution behavior of multi-breathers.Firstly,the N-soliton solution of Ito equation is studied,and some high-order breather waves can be obtained from the N-soliton solutions through paired-complexification of parameters.Secondly,the high-order lump solutions and the hybrid solutions are obtained by employing the long-wave limit method,and the motion velocity and trajectory equations of high-order lump waves are analyzed.Moreover,based on the trajectory equations of the higher-order lump solutions,we give and prove the trajectory theorem of 1-lump before and after interaction with nsoliton.Finally,we obtain some new lump solutions from the multi-solitons by constructing a new test function and using the parameter limit method.Meanwhile,some evolutionary behaviors of the obtained solutions are shown through a large number of three-dimensional graphs with different and appropriate parameters.展开更多
为了解决火法和无机酸法对废弃ITO玻璃粉末中铟锡分离效果差以及草酸法对铟浸出率较低的问题,提出采用草酸-草酸盐A浸出分离ITO玻璃粉末中的铟和锡,并采用响应面法对铟的浸出条件进行优化,建立预测铟的浸出率回归模型,确定浸出液中铟的...为了解决火法和无机酸法对废弃ITO玻璃粉末中铟锡分离效果差以及草酸法对铟浸出率较低的问题,提出采用草酸-草酸盐A浸出分离ITO玻璃粉末中的铟和锡,并采用响应面法对铟的浸出条件进行优化,建立预测铟的浸出率回归模型,确定浸出液中铟的存在形式,探索水解法回收铟的可行性。结果表明,草酸-草酸盐A浸出铟的优化条件为:c(C_(2)O_(4)^(2-))_(TOT)为0.09 mol/L,n(H_(2)C_(2)O_(4))∶n(A)为0.988∶1,液固比6.5 m L/g。在该条件下,铟的浸出率预测值和实验值分别为96.51%和97.69%,锡的浸出率仅为2.18%,铟锡分离效果较好。浸出液中的铟以In(C_(2)O_(4))_(3)^(3-)和In(C_(2)O_(4))_(2)^(2-)形式存在,可溶锡以Sn^(2+)和SnOH^(+)形式进入浸出液,且可采用水解法分离浸出液中的铟和锡,铟以In(OH)_(3)形式沉淀析出,锡留于浸出液。研究结果证明,采用草酸-草酸盐A浸出-浸出液水解工艺能提高铟的浸出率和铟锡的分离效果,解决了现有火法和湿法分离铟锡过程存在的技术缺陷。展开更多
A redox-active monolayer on an optically transparent electrode constitutes a typical platform for spectroelectrochemical sensing.The necessity for its sophistication arises from the availability of multi-dimensional s...A redox-active monolayer on an optically transparent electrode constitutes a typical platform for spectroelectrochemical sensing.The necessity for its sophistication arises from the availability of multi-dimensional sensing signals.Simultaneous monitoring of the redox current and color change synchronized with the oxidation state change significantly enhances sen-sitivity and selectivity.This study aimed to elucidate the modification of an indium tin oxide(ITO)electrode with a viologen monolayer with an ordered orientation.Novel methods were developed to immobilize a viologen molecule bearing a car-boxyl group to form assembled monolayers through a condensation reaction using 1-ethyl-3-(3-dimethylaminopropyl)-car-bodiimide with N-hydroxy-succinimide(EDC/NHS).In the two methods of immobilization,one utilizes a two-step process to firstly form an aromatic siloxane base layer and subsequently attach the viologen derivative through an amide linkage by post-amidation.The other employs a direct ester linkage between the hydroxyl groups of the ITO surface and the car-boxyl group of the viologen derivative.The latter method was also applied to immobilize a ferrocenyl group at a very short distance from the ITO surface.Potential-modulated UV-visible transmission absorption spectral measurement techniques with oblique incidence of plane-polarized light were employed to determine the orientation of the longitudinal axis of the reduced form of the viologen.The frequency dependence data of the potential-modulated transmission absorption signals were utilized to analyze the electron transfer kinetics.The performance of the two viologen-modified electrodes was com-pared to that of an ITO modified by post-amidation to the most commonly used base layer prepared with 3-aminopropyl triethoxysilane.展开更多
The complicated structure of electronic devices makes the conventional annealing method,which involves placing the entire device in a furnace,insufficient for achieving the desired quality.This issue is currently addr...The complicated structure of electronic devices makes the conventional annealing method,which involves placing the entire device in a furnace,insufficient for achieving the desired quality.This issue is currently addressed through the use of pulsed laser annealing,where a specific target layer is heated,preventing the overheating of other layers or the substrate.However,this method is only applicable to a very limited range of materials and requires very expensive,powerful pulsed laser sources.Herein,a novel approach for the selective local thermal treatment of thin films is proposed;in this method,short,powerful current pulses are applied to the target conductive layer.The application of two current pulses with a length of 1.5 s induced the crystallization of a 160-nm thick indium tin oxide(ITO)film,resulting in a sheet resistance of 8.68Ω·sq^(-1),an average visible light transmittance of 86.69%,and a figure of merit(FoM)of 293.61.This FoM is an order of magnitude higher than that of the as-prepared ITO film,and to the best of our knowledge,is among the highest reported values for the polycrystalline ITO films.Simulations have shown that even faster and more localized crystallization could be achieved by increasing the power of pulsed current.This novel annealing method is applicable to most semi-conductive or metallic thin films and requires only a relatively inexpensive pulsed current source,making it potentially more attractive than pulsed laser annealing.展开更多
为研究氧化铟锡(indium tin oxide,ITO)导电玻璃材料的去除机理,采用单磨粒对材料进行切削仿真,建立了ITO导电玻璃的材料模型,根据加工表面形貌、应力和切削力情况分析了材料去除机理,之后研究了切削参数对切削力和残余应力的影响,并与...为研究氧化铟锡(indium tin oxide,ITO)导电玻璃材料的去除机理,采用单磨粒对材料进行切削仿真,建立了ITO导电玻璃的材料模型,根据加工表面形貌、应力和切削力情况分析了材料去除机理,之后研究了切削参数对切削力和残余应力的影响,并与钠钙玻璃进行对比分析。结果表明:在磨粒的切削过程中,材料的去除受ITO薄膜层、玻璃基底和内聚力接触行为的共同影响,会产生分层、通道开裂和层间断裂等失效形式;随着磨粒的进给,切削力在一定范围内波动,且呈现上升、稳定、降低的变化,同时磨粒的切削力与切削速度和切削深度呈正相关;薄膜上残余应力相比玻璃基底,数值更大且波动更剧烈;当切削深度接近ITO薄膜厚度时,薄膜的存在对磨粒切削行为的影响显著。展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.12461047)the Scientific Research Project of the Hunan Education Department(Grant No.24B0478).
文摘Based on a new bilinear equation,we investigated some new dynamic behaviors of the(2+1)-dimensional shallow water wave model,such as hybridization behavior between different solitons,trajectory equations for lump collisions,and evolution behavior of multi-breathers.Firstly,the N-soliton solution of Ito equation is studied,and some high-order breather waves can be obtained from the N-soliton solutions through paired-complexification of parameters.Secondly,the high-order lump solutions and the hybrid solutions are obtained by employing the long-wave limit method,and the motion velocity and trajectory equations of high-order lump waves are analyzed.Moreover,based on the trajectory equations of the higher-order lump solutions,we give and prove the trajectory theorem of 1-lump before and after interaction with nsoliton.Finally,we obtain some new lump solutions from the multi-solitons by constructing a new test function and using the parameter limit method.Meanwhile,some evolutionary behaviors of the obtained solutions are shown through a large number of three-dimensional graphs with different and appropriate parameters.
文摘为了解决火法和无机酸法对废弃ITO玻璃粉末中铟锡分离效果差以及草酸法对铟浸出率较低的问题,提出采用草酸-草酸盐A浸出分离ITO玻璃粉末中的铟和锡,并采用响应面法对铟的浸出条件进行优化,建立预测铟的浸出率回归模型,确定浸出液中铟的存在形式,探索水解法回收铟的可行性。结果表明,草酸-草酸盐A浸出铟的优化条件为:c(C_(2)O_(4)^(2-))_(TOT)为0.09 mol/L,n(H_(2)C_(2)O_(4))∶n(A)为0.988∶1,液固比6.5 m L/g。在该条件下,铟的浸出率预测值和实验值分别为96.51%和97.69%,锡的浸出率仅为2.18%,铟锡分离效果较好。浸出液中的铟以In(C_(2)O_(4))_(3)^(3-)和In(C_(2)O_(4))_(2)^(2-)形式存在,可溶锡以Sn^(2+)和SnOH^(+)形式进入浸出液,且可采用水解法分离浸出液中的铟和锡,铟以In(OH)_(3)形式沉淀析出,锡留于浸出液。研究结果证明,采用草酸-草酸盐A浸出-浸出液水解工艺能提高铟的浸出率和铟锡的分离效果,解决了现有火法和湿法分离铟锡过程存在的技术缺陷。
基金supports by the Grant-in-Aid of Scientific Research of Challenging Research(Exploratory)(JP23K17738)to TS from MEXT of Japanthe 41st grant of research from Nippon Sheet Glass Foundation for Materials Science and Engineering to TS.
文摘A redox-active monolayer on an optically transparent electrode constitutes a typical platform for spectroelectrochemical sensing.The necessity for its sophistication arises from the availability of multi-dimensional sensing signals.Simultaneous monitoring of the redox current and color change synchronized with the oxidation state change significantly enhances sen-sitivity and selectivity.This study aimed to elucidate the modification of an indium tin oxide(ITO)electrode with a viologen monolayer with an ordered orientation.Novel methods were developed to immobilize a viologen molecule bearing a car-boxyl group to form assembled monolayers through a condensation reaction using 1-ethyl-3-(3-dimethylaminopropyl)-car-bodiimide with N-hydroxy-succinimide(EDC/NHS).In the two methods of immobilization,one utilizes a two-step process to firstly form an aromatic siloxane base layer and subsequently attach the viologen derivative through an amide linkage by post-amidation.The other employs a direct ester linkage between the hydroxyl groups of the ITO surface and the car-boxyl group of the viologen derivative.The latter method was also applied to immobilize a ferrocenyl group at a very short distance from the ITO surface.Potential-modulated UV-visible transmission absorption spectral measurement techniques with oblique incidence of plane-polarized light were employed to determine the orientation of the longitudinal axis of the reduced form of the viologen.The frequency dependence data of the potential-modulated transmission absorption signals were utilized to analyze the electron transfer kinetics.The performance of the two viologen-modified electrodes was com-pared to that of an ITO modified by post-amidation to the most commonly used base layer prepared with 3-aminopropyl triethoxysilane.
基金supported by the National Key R&D Program of China(No.2021YFB2801600)the National Natural Science Foundation of China(Nos.52072060,52202164 and 52021001)the Natural Science Foundation of Sichuan(Nos.2023NSFSC1950 and 2022NSFSC1990).
文摘The complicated structure of electronic devices makes the conventional annealing method,which involves placing the entire device in a furnace,insufficient for achieving the desired quality.This issue is currently addressed through the use of pulsed laser annealing,where a specific target layer is heated,preventing the overheating of other layers or the substrate.However,this method is only applicable to a very limited range of materials and requires very expensive,powerful pulsed laser sources.Herein,a novel approach for the selective local thermal treatment of thin films is proposed;in this method,short,powerful current pulses are applied to the target conductive layer.The application of two current pulses with a length of 1.5 s induced the crystallization of a 160-nm thick indium tin oxide(ITO)film,resulting in a sheet resistance of 8.68Ω·sq^(-1),an average visible light transmittance of 86.69%,and a figure of merit(FoM)of 293.61.This FoM is an order of magnitude higher than that of the as-prepared ITO film,and to the best of our knowledge,is among the highest reported values for the polycrystalline ITO films.Simulations have shown that even faster and more localized crystallization could be achieved by increasing the power of pulsed current.This novel annealing method is applicable to most semi-conductive or metallic thin films and requires only a relatively inexpensive pulsed current source,making it potentially more attractive than pulsed laser annealing.
文摘为研究氧化铟锡(indium tin oxide,ITO)导电玻璃材料的去除机理,采用单磨粒对材料进行切削仿真,建立了ITO导电玻璃的材料模型,根据加工表面形貌、应力和切削力情况分析了材料去除机理,之后研究了切削参数对切削力和残余应力的影响,并与钠钙玻璃进行对比分析。结果表明:在磨粒的切削过程中,材料的去除受ITO薄膜层、玻璃基底和内聚力接触行为的共同影响,会产生分层、通道开裂和层间断裂等失效形式;随着磨粒的进给,切削力在一定范围内波动,且呈现上升、稳定、降低的变化,同时磨粒的切削力与切削速度和切削深度呈正相关;薄膜上残余应力相比玻璃基底,数值更大且波动更剧烈;当切削深度接近ITO薄膜厚度时,薄膜的存在对磨粒切削行为的影响显著。
