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氧化法合成烃基磺酰氯 被引量:1
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作者 康汝洪 武瑞涛 甄小丽 《有机化学》 SCIE CAS CSCD 北大核心 1998年第6期559-561,共3页
以S-烃基异硫脲盐、硫氰酸酯、硫醚为底物,在盐酸介质中,温和条件下,通过氧化法高产率地合成了烃基磺酰氯;探讨了氧化剂作用机理;合成中采用PTC技术,使产品收率可提高30%。
关键词 磺酰氯 氧化剂 S-烃基异硫脲盐 相转移催化
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“Breathing”organic cation to stabilize multiple structures in low-dimensional Ge-,Sn-,and Pb-based hybrid iodide perovskites
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作者 Congcong Chen Emily E.Morgan +3 位作者 Yang Liu Jian Chen Ram Seshadri Lingling Mao 《Inorganic Chemistry Frontiers》 2022年第19期4892-4898,共7页
Low-dimensional hybrid inorganic-organic perovskites are excellent candidates for stable optoelectronic devices.The dimensionality of these perovskites depends largely on the organic and inorganic compositions,as well... Low-dimensional hybrid inorganic-organic perovskites are excellent candidates for stable optoelectronic devices.The dimensionality of these perovskites depends largely on the organic and inorganic compositions,as well as the synthetic conditions.Here,we report five new hybrid iodides,(ETU)_(4)Ge_(5)I_(18),(ETU)GeI_(4),(ETU)SnI_(4),(ETU)PbI_(4),and(ETU)_(3)Pb_(2)I_(10)using only one type of organic cation,namely,S-(2-aminoethyl)isothiouronium(ETU). 展开更多
关键词 sn based perovskites hybrid iodides etu ge i etu gei etu sni etu pbi etu pb i using ge based perovskites organic cation organic inorganic hybrid perovskites organic cationnamelys aminoethyl isothiouronium etu stable optoelectronic devicesthe
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