Solid oxide fuel cell is attracting more attention in recent years for its lower pollution emission and high energy convert efficiency. La0.9Sr0.1Ga0.8Mg0.2O3-δis a new kind of electrolyte for intermediate temperatur...Solid oxide fuel cell is attracting more attention in recent years for its lower pollution emission and high energy convert efficiency. La0.9Sr0.1Ga0.8Mg0.2O3-δis a new kind of electrolyte for intermediate temperature SOFC. In this paper, La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM) was prepared by solid state reaction method and formed by tape casting process to make a planar electrolyte. The appropriate amount of the dispersive was obtained by viscosity test. The densities of sintered samples increase with the increasing sintering temperature. It was found that the relative density of electrolyte can approach the value of 95 % by the isostatic pressing treatment of the green tape. The average thermal expansion coefficient of the LSGM is 11 .4×10-6 /℃at temperature range (200 ~ 1200℃). Measurements of the current-voltage and power-current characteristics of the Hi-Air cell show that the open-circuit voltage is 1.067 V at 800℃, peak current density is 0.56 A·cm -2 and the maximum power output is 0.147 W·cm -2.展开更多
基金Project supported by the National Natural Science Foundation of China (90510006)
文摘Solid oxide fuel cell is attracting more attention in recent years for its lower pollution emission and high energy convert efficiency. La0.9Sr0.1Ga0.8Mg0.2O3-δis a new kind of electrolyte for intermediate temperature SOFC. In this paper, La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM) was prepared by solid state reaction method and formed by tape casting process to make a planar electrolyte. The appropriate amount of the dispersive was obtained by viscosity test. The densities of sintered samples increase with the increasing sintering temperature. It was found that the relative density of electrolyte can approach the value of 95 % by the isostatic pressing treatment of the green tape. The average thermal expansion coefficient of the LSGM is 11 .4×10-6 /℃at temperature range (200 ~ 1200℃). Measurements of the current-voltage and power-current characteristics of the Hi-Air cell show that the open-circuit voltage is 1.067 V at 800℃, peak current density is 0.56 A·cm -2 and the maximum power output is 0.147 W·cm -2.
