Four new phosphates,namely,PbZn(PO_(4))F(1),PbSn(PO_(4))Cl(2),PbSn(PO_(4))Br(_(3))and PbSn(PO_(4))I(_(4)),were successfully synthesized by hydrothermal and solid-state reaction methods.PbZn(PO_(4))F(1)was crystallized...Four new phosphates,namely,PbZn(PO_(4))F(1),PbSn(PO_(4))Cl(2),PbSn(PO_(4))Br(_(3))and PbSn(PO_(4))I(_(4)),were successfully synthesized by hydrothermal and solid-state reaction methods.PbZn(PO_(4))F(1)was crystallized in a polar space group Pna2_(1)and showed a significant SHG intensity of about 1.6×KDP.PbSn(PO_(4))Cl(2)and PbSn(PO_(4))Br(3)were isostructural compounds.展开更多
基金supported by the National Natural Science Foundation of China(Grants No.:91963105,22031009 and 21921001).
文摘Four new phosphates,namely,PbZn(PO_(4))F(1),PbSn(PO_(4))Cl(2),PbSn(PO_(4))Br(_(3))and PbSn(PO_(4))I(_(4)),were successfully synthesized by hydrothermal and solid-state reaction methods.PbZn(PO_(4))F(1)was crystallized in a polar space group Pna2_(1)and showed a significant SHG intensity of about 1.6×KDP.PbSn(PO_(4))Cl(2)and PbSn(PO_(4))Br(3)were isostructural compounds.
