In recent years,many cities have taken measures to reduce volatile organic compounds(VOCs),an important precursor of ozone(O_(3)),to alleviate O_(3) pollution in China.116 VOC species were measured by online and offli...In recent years,many cities have taken measures to reduce volatile organic compounds(VOCs),an important precursor of ozone(O_(3)),to alleviate O_(3) pollution in China.116 VOC species were measured by online and offline methods in the urban area of Jiaozuo from May to October in 2021 to analyze the compositional characteristics.VOC sources were analyzed by a positive matrix factorization(PMF)model,and the sensitivity of ozone generation was determined by ozone isopleth plotting research(OZIPR)simulation.The results showed that the average volume concentration of total VOCs was 30.54 ppbv and showed a bimodal feature due to the rush-hour traffic in the morning and at nightfall.The most dominant VOC groups were oxygenated VOCs(OVOCs,29.3%)and alkanes(26.7%),and the most abundant VOC species were acetone and acetylene.However,based on the maximum incremental reactivity(MIR)method,the major VOC groups in terms of ozone formation potential(OFP)contribution were OVOCs(68.09μg/m^(3),31.5%),aromatics(62.90μg/m^(3),29.1%)and alkene/alkynes(54.90μg/m^(3),25.4%).This indicates that the control of OVOCs,aromatics and alkene/alkynes should take priority.Five sources of VOCs were quantified by PMF,including fixed sources of fossil fuel combustion(27.8%),industrial processes(25.9%),vehicle exhaust(19.7%),natural and secondary formation(13.9%)and solvent usage(12.7%).The empirical kinetic modeling approach(EKMA)curve obtained by OZIPR on O_(3) exceedance days indicated that the O_(3) sensitivity varied in different months.The results provide theoretical support for O_(3) pollution prevention and control in Jiaozuo.展开更多
Owing to the lack of information about geomagnetic anomaly fields,conventional geomagnetic matching algorithms in near space are prone to divergence.Therefore,geomagnetic matching navigation algorithms for hypersonic ...Owing to the lack of information about geomagnetic anomaly fields,conventional geomagnetic matching algorithms in near space are prone to divergence.Therefore,geomagnetic matching navigation algorithms for hypersonic vehicles are also prone to divergence or mismatch.To address this problem,we propose a multi-geomagnetic-component assisted localization(MCAL)algorithm to improve positioning accuracy using only the information of the main geomagnetic field.First,the main components of the geomagnetic field and a mathematical representation of the Earth’s geomagnetic field(World Magnetic Model 2015)are introduced.The mathematical relationships between the geomagnetic components are given,and the source of geomagnetic matching error is explained.We then propose the MCAL algorithm.The algorithm uses the intersections of the isopleths of the geomagnetic components and a decision method to estimate the real position of a carrier with high positioning accuracy.Finally,inertial/geomagnetic integrated navigation is simulated for hypersonic boost-glide vehicles.The simulation results demonstrate that the proposed algorithm can provide higher positioning accuracy than conventional geomagnetic matching algorithms.When the random error range is±30 nT,the average absolute latitude error and longitude error of the MCAL algorithm are 151 m and 511 m lower,respectively,than those of the Sandia inertial magnetic aided navigation(SIMAN)algorithm.展开更多
基金supported by the Research Project Entrusted by Henan Ecological Environment Monitoring and Safety Center,China(No.20201557)the Study of Collaborative Prevention and Control of Fine Particulate Matter and Ozone Pollution of Jiaozuo(No.DQGG202134)。
文摘In recent years,many cities have taken measures to reduce volatile organic compounds(VOCs),an important precursor of ozone(O_(3)),to alleviate O_(3) pollution in China.116 VOC species were measured by online and offline methods in the urban area of Jiaozuo from May to October in 2021 to analyze the compositional characteristics.VOC sources were analyzed by a positive matrix factorization(PMF)model,and the sensitivity of ozone generation was determined by ozone isopleth plotting research(OZIPR)simulation.The results showed that the average volume concentration of total VOCs was 30.54 ppbv and showed a bimodal feature due to the rush-hour traffic in the morning and at nightfall.The most dominant VOC groups were oxygenated VOCs(OVOCs,29.3%)and alkanes(26.7%),and the most abundant VOC species were acetone and acetylene.However,based on the maximum incremental reactivity(MIR)method,the major VOC groups in terms of ozone formation potential(OFP)contribution were OVOCs(68.09μg/m^(3),31.5%),aromatics(62.90μg/m^(3),29.1%)and alkene/alkynes(54.90μg/m^(3),25.4%).This indicates that the control of OVOCs,aromatics and alkene/alkynes should take priority.Five sources of VOCs were quantified by PMF,including fixed sources of fossil fuel combustion(27.8%),industrial processes(25.9%),vehicle exhaust(19.7%),natural and secondary formation(13.9%)and solvent usage(12.7%).The empirical kinetic modeling approach(EKMA)curve obtained by OZIPR on O_(3) exceedance days indicated that the O_(3) sensitivity varied in different months.The results provide theoretical support for O_(3) pollution prevention and control in Jiaozuo.
基金Project supported by the Space Science and Technology Innovation Fund of China(No.2016KC020028)the Fund of China Space Science and Technology(No.2017-HT-XG)。
文摘Owing to the lack of information about geomagnetic anomaly fields,conventional geomagnetic matching algorithms in near space are prone to divergence.Therefore,geomagnetic matching navigation algorithms for hypersonic vehicles are also prone to divergence or mismatch.To address this problem,we propose a multi-geomagnetic-component assisted localization(MCAL)algorithm to improve positioning accuracy using only the information of the main geomagnetic field.First,the main components of the geomagnetic field and a mathematical representation of the Earth’s geomagnetic field(World Magnetic Model 2015)are introduced.The mathematical relationships between the geomagnetic components are given,and the source of geomagnetic matching error is explained.We then propose the MCAL algorithm.The algorithm uses the intersections of the isopleths of the geomagnetic components and a decision method to estimate the real position of a carrier with high positioning accuracy.Finally,inertial/geomagnetic integrated navigation is simulated for hypersonic boost-glide vehicles.The simulation results demonstrate that the proposed algorithm can provide higher positioning accuracy than conventional geomagnetic matching algorithms.When the random error range is±30 nT,the average absolute latitude error and longitude error of the MCAL algorithm are 151 m and 511 m lower,respectively,than those of the Sandia inertial magnetic aided navigation(SIMAN)algorithm.