The exploration and discovery of new POM species with novel structural motifs are core prerequisites and permanent missions in the field of POM chemistry.It has been nearly 30 years since the first butterflyshaped And...The exploration and discovery of new POM species with novel structural motifs are core prerequisites and permanent missions in the field of POM chemistry.It has been nearly 30 years since the first butterflyshaped Anderson-type hetreopolyanions with a centred pentavalent Sb atom,[Sb(OH)_(2)Mo_(6)O_(22)]^(5-),named as the β isomer,was discovered in 1988.Yet the corresponding β isomers with a lower valence metal as the central heteroatom and its triol-functionalized organic derivatives have never been obtained.Herein,for the first time,two novel triol-functionalized butterfly-shaped heteropolyanions,β-{Cr[RC(CH_(2)O)_(3)]_(2)Mo_(6)O_(18)}^(3-)(R=NH_(2),1;C_(2)H_(5),2),were synthesized by the reaction of common flat Anderson-type POM,α-[Cr(OH)_(6)Mo_(6)O_(18)]^(3-),and triol ligands in hot DMF.Single crystal XRD analysis reveals that β-{Cr[RC(CH_(2)O)_(3)]_(2)Mo_(6)O_(18)}^(3-)is the first triol-functionalized β isomer of common α-type Anderson POMs.This study will enrich the family of POMs and provide an oportunity for the discovery of more potential POMs-based organic–inorganic hybrid materials.展开更多
基金the financial support from the National Natural Science Foundation of China(NSFC No.21471087,21225103,21631007 and 21221062)the State Key Laboratory of Natural and Biomimetic Drugs+1 种基金the Specialized Research Fund for the Doctoral Program of Higher Education of ChinaTsinghua University Initiative Foundation Research Program(No.20131089204).
文摘The exploration and discovery of new POM species with novel structural motifs are core prerequisites and permanent missions in the field of POM chemistry.It has been nearly 30 years since the first butterflyshaped Anderson-type hetreopolyanions with a centred pentavalent Sb atom,[Sb(OH)_(2)Mo_(6)O_(22)]^(5-),named as the β isomer,was discovered in 1988.Yet the corresponding β isomers with a lower valence metal as the central heteroatom and its triol-functionalized organic derivatives have never been obtained.Herein,for the first time,two novel triol-functionalized butterfly-shaped heteropolyanions,β-{Cr[RC(CH_(2)O)_(3)]_(2)Mo_(6)O_(18)}^(3-)(R=NH_(2),1;C_(2)H_(5),2),were synthesized by the reaction of common flat Anderson-type POM,α-[Cr(OH)_(6)Mo_(6)O_(18)]^(3-),and triol ligands in hot DMF.Single crystal XRD analysis reveals that β-{Cr[RC(CH_(2)O)_(3)]_(2)Mo_(6)O_(18)}^(3-)is the first triol-functionalized β isomer of common α-type Anderson POMs.This study will enrich the family of POMs and provide an oportunity for the discovery of more potential POMs-based organic–inorganic hybrid materials.
