An efficient and practical electrochemical method for the three-component reaction cascade Mumm rearrangement of imides has been developed using a simple undivided cell with carbon electrodes at room temperature,which...An efficient and practical electrochemical method for the three-component reaction cascade Mumm rearrangement of imides has been developed using a simple undivided cell with carbon electrodes at room temperature,which provides a useful strategy for the rapid synthesis of sulfur-containing imides with broad substrate scope and high functional tolerance.It is a rare example of in situ generation of O-acyl isoamide precursor for Mumm rearrangement.展开更多
基金support from the Science and Technology Innovation Program of Hunan Province(No.2021RC2079)China Postdoctoral Science Foundation(Nos.2022T150075 and 2022M720541)+2 种基金Hunan Provincial Department of Education Outstanding Youth Project(No.22B0212)Tianjin Synthetic Biotechnology Innovation Capacity Improvement Project(No.TSBI-CIP-CXRC-038)National College Students Innovation and Entrepreneurship Training Program(No.S202210537024).
文摘An efficient and practical electrochemical method for the three-component reaction cascade Mumm rearrangement of imides has been developed using a simple undivided cell with carbon electrodes at room temperature,which provides a useful strategy for the rapid synthesis of sulfur-containing imides with broad substrate scope and high functional tolerance.It is a rare example of in situ generation of O-acyl isoamide precursor for Mumm rearrangement.
