Corrosion and electrochemical behavior of 316L stainless steel was investigated in the presence of aerobic iron-oxidizing bacteria IOB and anaerobic sulfate-reducing bacteria SRB isolated from cooling water systems in...Corrosion and electrochemical behavior of 316L stainless steel was investigated in the presence of aerobic iron-oxidizing bacteria IOB and anaerobic sulfate-reducing bacteria SRB isolated from cooling water systems in an oil refinery using electrochemical measurement, scanning electron microscopy SEM and energy dispersive atom X-ray analysisEDAX. The results show the corrosion potential and pitting potential of 316L stainless steel decrease distinctly in the presence of bacteria, in comparison with those observed in sterile medium under the same exposure time. SEM morphologies have shown that 316L stainless steel reveals no signs of pitting attack in the sterile medium. However, micrometer-scale corrosion pits were observed on 316L stainless steel sur- face in the presence of bacteria. The presence of SRB leads to higher corrosion rates than IOB. The interactions between the stainless steel surface, abiotic corrosion products, and bacterial cells and their metabolic products in- creased the corrosion damage degree of the passive film and accelerated pitting propagation.展开更多
The effect of hydraulic retention time (HRT) and pH on the biooxidation of ferrous iron during simulated acid mine drainage (AMD) treatment was investigated.The simulated AMD was highly acidic (pH 2.5), rich in iron (...The effect of hydraulic retention time (HRT) and pH on the biooxidation of ferrous iron during simulated acid mine drainage (AMD) treatment was investigated.The simulated AMD was highly acidic (pH 2.5), rich in iron (about 1700 mg/L) and copper (about 200 mg/L), and contained high concentrations of sulfate (about 4700 mg/L).The biooxidation of ferrous iron was studied in a laboratory-scale upflow packed bed bioreactor (PBR).The HRT was shortened stepwise from 40 h to 20 h, 13 h, and 8 h under the acidic environment at a pH value of 2.2.Then, the influent pH value was changed from 2.2 to 1.2 at a constant suitable HRT.Physiochemical and microbial community structure analyses were performed on water samples and stuffing collected from the bioreactor under different conditions.The results indicate that the efficiency of ferrous iron oxidation gradually decreased with the decrease of HRT, and when the HRT exceeded 13 h, ferrous iron in AMD was almost completely oxidized.In addition, the best efficiency of ferrous iron oxidation was achieved at the influent pH value of 1.8.Microbial community structure analyses show that Leptospirillum is the predominant genus attached in the bioreactor, and low influent pH values are suitable for the growth of Leptospirillum.展开更多
基金the National Natural Science Foundation of China (No.20576108).
文摘Corrosion and electrochemical behavior of 316L stainless steel was investigated in the presence of aerobic iron-oxidizing bacteria IOB and anaerobic sulfate-reducing bacteria SRB isolated from cooling water systems in an oil refinery using electrochemical measurement, scanning electron microscopy SEM and energy dispersive atom X-ray analysisEDAX. The results show the corrosion potential and pitting potential of 316L stainless steel decrease distinctly in the presence of bacteria, in comparison with those observed in sterile medium under the same exposure time. SEM morphologies have shown that 316L stainless steel reveals no signs of pitting attack in the sterile medium. However, micrometer-scale corrosion pits were observed on 316L stainless steel sur- face in the presence of bacteria. The presence of SRB leads to higher corrosion rates than IOB. The interactions between the stainless steel surface, abiotic corrosion products, and bacterial cells and their metabolic products in- creased the corrosion damage degree of the passive film and accelerated pitting propagation.
基金supported by the National Natural Science Foundation of China(Grant No.U1402234)the Guangxi Scientific Research and Technology Development Plan(Grants No.GuikeAB16380287 and GuikeAB17129025)+2 种基金the Public Welfare Fund of the Ministry of Environmental Protection of China(Grant No.201509049)the Program of International S & T Cooperation(Grant No.2016YFE0130700)the Fund of the General Research Institute for Nonferrous Metals(Grants No.53321 and 53348)
文摘The effect of hydraulic retention time (HRT) and pH on the biooxidation of ferrous iron during simulated acid mine drainage (AMD) treatment was investigated.The simulated AMD was highly acidic (pH 2.5), rich in iron (about 1700 mg/L) and copper (about 200 mg/L), and contained high concentrations of sulfate (about 4700 mg/L).The biooxidation of ferrous iron was studied in a laboratory-scale upflow packed bed bioreactor (PBR).The HRT was shortened stepwise from 40 h to 20 h, 13 h, and 8 h under the acidic environment at a pH value of 2.2.Then, the influent pH value was changed from 2.2 to 1.2 at a constant suitable HRT.Physiochemical and microbial community structure analyses were performed on water samples and stuffing collected from the bioreactor under different conditions.The results indicate that the efficiency of ferrous iron oxidation gradually decreased with the decrease of HRT, and when the HRT exceeded 13 h, ferrous iron in AMD was almost completely oxidized.In addition, the best efficiency of ferrous iron oxidation was achieved at the influent pH value of 1.8.Microbial community structure analyses show that Leptospirillum is the predominant genus attached in the bioreactor, and low influent pH values are suitable for the growth of Leptospirillum.
