In this study,grey cast iron matrix composites reinforced by different volume fractions of tungsten fibers(Vr=0.95%,1.90%,2.85%,3.80%)were investigated in as-cast and under the heat treatment temperatures of 1,000℃an...In this study,grey cast iron matrix composites reinforced by different volume fractions of tungsten fibers(Vr=0.95%,1.90%,2.85%,3.80%)were investigated in as-cast and under the heat treatment temperatures of 1,000℃and 1,100℃.The microstructure and mechanical properties of the composites were analyzed and tested by means of SEM,micro-hardness tester and three-point bend testing.The results show that with increasing of the volume fraction of tungsten fibers,the composites reinforced by the tungsten fiber have higher flexural strength and modulus than that of cast iron without reinforcement,and the flexural strength increases with the increasing of heat treatment temperatures.Due to diffusion reaction between matrix and reinforcing phases,the process of heat treatment,the number of graphite flakes in the matrix seemingly becomes lower;and some hard carbide particles are formed around the residual tungsten fibers.Not only does the hardness of both matrix and reinforcement change tremendously,but also the region of reinforcement is also extended from the original 0.11 mm to 0.19 mm in radius.展开更多
In this paper the Expendable Pattern Casting with dry sand Vacuum(EPC-V) process is used to manufacture iron matrix composites with tungsten carbide particle.Microstructures of the composites layers were analyzed.The ...In this paper the Expendable Pattern Casting with dry sand Vacuum(EPC-V) process is used to manufacture iron matrix composites with tungsten carbide particle.Microstructures of the composites layers were analyzed.The abrasive wear resistance of the composites layers were tested and compared with that of high chromium cast iron.The results show that the iron matrix composites with tungsten carbide particle have high hardness.The abrasive wear resistance of composites with tungsten carbide particle is higher than that of high chromium cast iron.The properties of the matrix materials have been improved remarkably.展开更多
Effect of nitrogen on matrix structure of 3 different varieties of gray cast iron,i.e., sub-eutectic Fe-C-Si,near-eutectic Fe-C-Si and Fe-C-Si-Mn,has been investigated. The eutectie colony structure of gray cast iron ...Effect of nitrogen on matrix structure of 3 different varieties of gray cast iron,i.e., sub-eutectic Fe-C-Si,near-eutectic Fe-C-Si and Fe-C-Si-Mn,has been investigated. The eutectie colony structure of gray cast iron may be refined,the pearlite content increased and the micro-hardness of pearlite and ferrite raised with an addition of nitrogen.The influ- ence of nitrogen on the transformation temperature of the equilibrium and non-equilibrium phases,as well as,the solution of nitrogen in ferrite and cementite seem to be the major rea- sons to strengthening the matrix structure of gray cast iron.展开更多
In graphite furnace atomic absorption spectrometry (GF-AAS), the atomization process of lead occurring in graphite atomizers with/without a platform plate was investigated when palladium was added to an iron-matrix sa...In graphite furnace atomic absorption spectrometry (GF-AAS), the atomization process of lead occurring in graphite atomizers with/without a platform plate was investigated when palladium was added to an iron-matrix sample solution containing trace amounts of lead. Absorption profiles of a lead line were meas- ured at various compositions of iron and palladium. Variations in the gas temperature were also estimated with the progress of atomization, by using a two-line method under the assumption of a Boltzmann distribu- tion. Each addition of iron and palladium increased the lead absorbance in both the atomizers, indicating that iron or palladium became an effective matrix modifier for the determination of lead. Especially, palladium played a significant role for controlling chemical species of lead at the charring stage in the platform-type atomizer, to change several chemical species to a single species and eventually to yield a dominant peak of the lead absorbance at the atomizing stage. Furthermore, the addition of palladium delayed the peak after the gas atmosphere in the atomizer was heated to a higher temperature. These phenomena would be because the temperature of the platform at the charring stage was elevated more slowly compared to that of the furnace wall, and also because a thermally-stable compound, such as a palladium-lead solid solution, was produced by their metallurgical reaction during heating of the charring stage. A platform-type atomizer with palladium as the matrix modifier is recommended for the determination of lead in GF-AAS. The optimum condition for this was obtained in a coexistence of 1.0 × 10–2 g/dm3 palladium, when the charring at 973 K and then the atomizing at 3073 K were conducted.展开更多
The impact-abrasive wear behavior of ZTA(zirconia toughened alumina)particle(ZTAp)and NbC particle(NbCp)reinforced Fe60 matrix composites(ZTAp-NbCp/Fe60)were investigated.Specimens of pure Fe60 matrix material,NbCp re...The impact-abrasive wear behavior of ZTA(zirconia toughened alumina)particle(ZTAp)and NbC particle(NbCp)reinforced Fe60 matrix composites(ZTAp-NbCp/Fe60)were investigated.Specimens of pure Fe60 matrix material,NbCp reinforced Fe60 composite(NbCp/Fe60)and ZTAp-NbCp/Fe60 with different contents of ZTAp were prepared through vacuum sintering and tested on an MLD-10B Impact Wear Rig.As revealed by the results,NbCp could strengthen Fe60 matrix,and had fine grain strengthening effect on Fe60matrix.When the mass fraction of ZTAp was 5%-15%,the impact-abrasive wear performance of ZTAp-NbCp/Fe60 composites was better than that of Fe60 and NbCp/Fe60.When the mass fraction was 15%,the ZTApNbCp/Fe60 had the best performance.ZTAp could weaken the impact and wear effect of abrasive particles on the composite and protect the matrix.Cracks occured at the interface and at defects in the ZTAp.The former leaded to ZTAp shedding,while the latter leaded to ZTAp fracturing.In both cases,the performance of the composite material would decrease.展开更多
A method is described for the direct determination of iron in high purity sodium fluoride using graphite furnace atomic absorption spectrometry. Interferences caused by the matrix are investigated. It is shown that th...A method is described for the direct determination of iron in high purity sodium fluoride using graphite furnace atomic absorption spectrometry. Interferences caused by the matrix are investigated. It is shown that the ashing temperature can be increased to 1 400°C and matrix interferences eliminated, the sensitivity of iron increased in 1. 27 fold by the addition of nickel nitrate. The method is applied to the determination of iron in sodium fluoride and satisfactory results are obtained.展开更多
Iron-plating technology used for restoration of axis parts was applied to the manufacture of diamond bits in this paper.The technology for electroplating diamond bit of iron matrix was mastered through repeated experi...Iron-plating technology used for restoration of axis parts was applied to the manufacture of diamond bits in this paper.The technology for electroplating diamond bit of iron matrix was mastered through repeated experiments and research.The productive practice indicated that the DC-electroplated iron matrix of diamond bit has high hardness and good diamond exposure ability;the drilling rate of electroplated iron-based diamond bit was 2 m/h when drilling in grade 9 granite and bit life can reach 44 m,which can satisfy the drilling production requirements.展开更多
Mechanical properties of iron matrix composites reinforced by different types of ceramic particles(SiC,Cr3C2,TiC and Ti(C,N)) prepared by the two-stage resistance sintering were studied experimentally.It was found tha...Mechanical properties of iron matrix composites reinforced by different types of ceramic particles(SiC,Cr3C2,TiC and Ti(C,N)) prepared by the two-stage resistance sintering were studied experimentally.It was found that tensile strength of SiC/Fe composite shows the highest among the four types of composites.The elongation of all the composites decreases as increasing of reinforcement volume fraction.The stress-strain curves of the composites were simulated by Eshelby approach modeling to reveal the strengthening mechanisms.The modeling and microstructure observations suggest that the strengthening mechanism of the iron matrix composites relies not only on load sharing of the reinforcements but also on reinforcement increasing matrix strength.展开更多
基金supported by the Key Innovation Plan in Science & Technology,Shaanxi Province,China(Project No.2004ZKC05-02)the Research Center for"13115"Innovation Engineering in Science & Technology,Shaanxi Province,China(Project No.2007ZDGC-17)
文摘In this study,grey cast iron matrix composites reinforced by different volume fractions of tungsten fibers(Vr=0.95%,1.90%,2.85%,3.80%)were investigated in as-cast and under the heat treatment temperatures of 1,000℃and 1,100℃.The microstructure and mechanical properties of the composites were analyzed and tested by means of SEM,micro-hardness tester and three-point bend testing.The results show that with increasing of the volume fraction of tungsten fibers,the composites reinforced by the tungsten fiber have higher flexural strength and modulus than that of cast iron without reinforcement,and the flexural strength increases with the increasing of heat treatment temperatures.Due to diffusion reaction between matrix and reinforcing phases,the process of heat treatment,the number of graphite flakes in the matrix seemingly becomes lower;and some hard carbide particles are formed around the residual tungsten fibers.Not only does the hardness of both matrix and reinforcement change tremendously,but also the region of reinforcement is also extended from the original 0.11 mm to 0.19 mm in radius.
文摘In this paper the Expendable Pattern Casting with dry sand Vacuum(EPC-V) process is used to manufacture iron matrix composites with tungsten carbide particle.Microstructures of the composites layers were analyzed.The abrasive wear resistance of the composites layers were tested and compared with that of high chromium cast iron.The results show that the iron matrix composites with tungsten carbide particle have high hardness.The abrasive wear resistance of composites with tungsten carbide particle is higher than that of high chromium cast iron.The properties of the matrix materials have been improved remarkably.
文摘Effect of nitrogen on matrix structure of 3 different varieties of gray cast iron,i.e., sub-eutectic Fe-C-Si,near-eutectic Fe-C-Si and Fe-C-Si-Mn,has been investigated. The eutectie colony structure of gray cast iron may be refined,the pearlite content increased and the micro-hardness of pearlite and ferrite raised with an addition of nitrogen.The influ- ence of nitrogen on the transformation temperature of the equilibrium and non-equilibrium phases,as well as,the solution of nitrogen in ferrite and cementite seem to be the major rea- sons to strengthening the matrix structure of gray cast iron.
文摘In graphite furnace atomic absorption spectrometry (GF-AAS), the atomization process of lead occurring in graphite atomizers with/without a platform plate was investigated when palladium was added to an iron-matrix sample solution containing trace amounts of lead. Absorption profiles of a lead line were meas- ured at various compositions of iron and palladium. Variations in the gas temperature were also estimated with the progress of atomization, by using a two-line method under the assumption of a Boltzmann distribu- tion. Each addition of iron and palladium increased the lead absorbance in both the atomizers, indicating that iron or palladium became an effective matrix modifier for the determination of lead. Especially, palladium played a significant role for controlling chemical species of lead at the charring stage in the platform-type atomizer, to change several chemical species to a single species and eventually to yield a dominant peak of the lead absorbance at the atomizing stage. Furthermore, the addition of palladium delayed the peak after the gas atmosphere in the atomizer was heated to a higher temperature. These phenomena would be because the temperature of the platform at the charring stage was elevated more slowly compared to that of the furnace wall, and also because a thermally-stable compound, such as a palladium-lead solid solution, was produced by their metallurgical reaction during heating of the charring stage. A platform-type atomizer with palladium as the matrix modifier is recommended for the determination of lead in GF-AAS. The optimum condition for this was obtained in a coexistence of 1.0 × 10–2 g/dm3 palladium, when the charring at 973 K and then the atomizing at 3073 K were conducted.
基金Funded by the National Key Research and Development Program(No.2017YFB0305105)the National Natural Science Foundation of China(No.51571210)。
文摘The impact-abrasive wear behavior of ZTA(zirconia toughened alumina)particle(ZTAp)and NbC particle(NbCp)reinforced Fe60 matrix composites(ZTAp-NbCp/Fe60)were investigated.Specimens of pure Fe60 matrix material,NbCp reinforced Fe60 composite(NbCp/Fe60)and ZTAp-NbCp/Fe60 with different contents of ZTAp were prepared through vacuum sintering and tested on an MLD-10B Impact Wear Rig.As revealed by the results,NbCp could strengthen Fe60 matrix,and had fine grain strengthening effect on Fe60matrix.When the mass fraction of ZTAp was 5%-15%,the impact-abrasive wear performance of ZTAp-NbCp/Fe60 composites was better than that of Fe60 and NbCp/Fe60.When the mass fraction was 15%,the ZTApNbCp/Fe60 had the best performance.ZTAp could weaken the impact and wear effect of abrasive particles on the composite and protect the matrix.Cracks occured at the interface and at defects in the ZTAp.The former leaded to ZTAp shedding,while the latter leaded to ZTAp fracturing.In both cases,the performance of the composite material would decrease.
文摘A method is described for the direct determination of iron in high purity sodium fluoride using graphite furnace atomic absorption spectrometry. Interferences caused by the matrix are investigated. It is shown that the ashing temperature can be increased to 1 400°C and matrix interferences eliminated, the sensitivity of iron increased in 1. 27 fold by the addition of nickel nitrate. The method is applied to the determination of iron in sodium fluoride and satisfactory results are obtained.
文摘Iron-plating technology used for restoration of axis parts was applied to the manufacture of diamond bits in this paper.The technology for electroplating diamond bit of iron matrix was mastered through repeated experiments and research.The productive practice indicated that the DC-electroplated iron matrix of diamond bit has high hardness and good diamond exposure ability;the drilling rate of electroplated iron-based diamond bit was 2 m/h when drilling in grade 9 granite and bit life can reach 44 m,which can satisfy the drilling production requirements.
文摘Mechanical properties of iron matrix composites reinforced by different types of ceramic particles(SiC,Cr3C2,TiC and Ti(C,N)) prepared by the two-stage resistance sintering were studied experimentally.It was found that tensile strength of SiC/Fe composite shows the highest among the four types of composites.The elongation of all the composites decreases as increasing of reinforcement volume fraction.The stress-strain curves of the composites were simulated by Eshelby approach modeling to reveal the strengthening mechanisms.The modeling and microstructure observations suggest that the strengthening mechanism of the iron matrix composites relies not only on load sharing of the reinforcements but also on reinforcement increasing matrix strength.
