The promising magnetic behavior of heterospin systems has spurred the research of 2p-3d-4f heterotri-spin compounds.Such a magnetic system has crucial advantages:the strongest possible magnetic interactions resulting ...The promising magnetic behavior of heterospin systems has spurred the research of 2p-3d-4f heterotri-spin compounds.Such a magnetic system has crucial advantages:the strongest possible magnetic interactions resulting from the direct binding of the radicals to the metal ions,access to strong magnetic anisotropies arising from 4f ions,and novel magnetic behavior derived from the synergic or competitive magnetic interactions between three different spin carriers.Herein we review recent advances made toward a rational development of 2p-3d-4f complexes.Special attention is given to the 2p-3d-4f compounds exhibiting slow magnetic relaxation.展开更多
基金supported by the National Natural Science Foundation of China(no.21471083)MOE Innovation Team(IRT13022)of China.
文摘The promising magnetic behavior of heterospin systems has spurred the research of 2p-3d-4f heterotri-spin compounds.Such a magnetic system has crucial advantages:the strongest possible magnetic interactions resulting from the direct binding of the radicals to the metal ions,access to strong magnetic anisotropies arising from 4f ions,and novel magnetic behavior derived from the synergic or competitive magnetic interactions between three different spin carriers.Herein we review recent advances made toward a rational development of 2p-3d-4f complexes.Special attention is given to the 2p-3d-4f compounds exhibiting slow magnetic relaxation.
