The high energy density and stability of solid-state lithium metal batteries(SSLMBs)have garnered great attention.Garnet-type oxides,especially Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO),with high ionic conductivity,...The high energy density and stability of solid-state lithium metal batteries(SSLMBs)have garnered great attention.Garnet-type oxides,especially Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO),with high ionic conductivity,wide electrochemical window,and stability to Li metal anode,are promising solid-state electrolyte(SSEs)materials for SSLMBs.However,Li/LLZTO interface issues including high interface resistance,inhomogeneous Li deposition,and Li dendrite growth have hindered the practical application of SSLMBs.Herein,a multi-functional Li–SnF_(2) composite anode with Li,LiF,and Li-Sn alloy was specifically designed and prepared.The composite anode improves the wettability to LLZTO,constructing an intimate contact interface between it and LLZTO.Meanwhile,ionic/electronic conductive paths in situ formed at the interface can effectively uniform Li deposition and suppress Li dendrite.The solid-state symmetric cell exhibits low interface resistance(11Ω·cm^(2)) and high critical current density(1.3 mA·cm^(−2))at 25℃.The full SSLMB based on LiFePO_(4) or LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode also shows stable cycling performance and high rate capability.This work provides a new composite anode strategy for achieving high-energy density and high-safety SSLMBs.展开更多
Lithium(Li)dendrite issue,which is usually caused by inhomogeneous Li nucleation and fragile solid electrolyte interphase(SEI),impedes the further development of high-energy Li metal batteries.However,the integrated c...Lithium(Li)dendrite issue,which is usually caused by inhomogeneous Li nucleation and fragile solid electrolyte interphase(SEI),impedes the further development of high-energy Li metal batteries.However,the integrated construction of a high-stable SEI layer that can regulate uniform nucleation and facilitate fast Li-ion diffusion kinetics for Li metal anode still falls short.Herein,we designed an artificial SEI with hybrid ionic/electronic interphase to regulate Li deposition by in-situ constructing metal Co clusters embedded in LiF matrix.The generated Co and LiF both enable fast Li-ion diffusion kinetics,meanwhile,the lithiophilic properties of Co clusters can serve as Li-ion nucleation sites,thereby contributing to uniform Li nucleation and non-dendritic growth.As a result,a dendrite-free Li deposition with a low overpotential(16.1 mV)is achieved,which enables an extended lifespan over 750 h under strict conditions.The full cells with high-mass-loading LiFePO_(4)(11.5 mg/cm^(2))as cathodes exhibit a remarkable rate capacity of 84.1 mAh/g at 5 C and an improved cycling performance with a capacity retention of 96.4%after undergoing 180 cycles.展开更多
Low-cost silicon microparticles(SiMP),as a substitute for nanostructured silicon,easily suffer from cracks and fractured during the electrochemical cycle.A novel n-type conductive polymer binder with excellent electro...Low-cost silicon microparticles(SiMP),as a substitute for nanostructured silicon,easily suffer from cracks and fractured during the electrochemical cycle.A novel n-type conductive polymer binder with excellent electronic and ionic conductivities as well as good adhesion,has been successfully designed and applied for high-performance SiMP anodes in lithium-ion batteries to address this problem.Its unique features are attributed to the stro ng electron-withdrawing oxadiazole ring structure with sulfonate polar groups.The combination of rigid and flexible components in the polymer ensures its good mechanical strength and ductility,which is beneficial to suppress the expansion and contraction of SiMP s during the charge/discharge process.By fine-tuning the monomer ratio,the conjugation and sulfonation degrees of the polymer can be precisely controlled to regulate its ionic and electronic conductivities,which has been systematically analyzed with the help of an electrochemical test method,filling in the gap on the conductivity measurement of the polymer in the doping state.The experimental results indicate that the cell with the developed n-type polymer binder and SiMP(~0.5 μm) anodes achieves much better cycling performance than traditional non-conductive binders.It has been considered that the initial capacity of the SiMP anode is controlled by the synergetic effect of ionic and electronic conductivity of the binder,and the capacity retention mainly depends on its electronic conductivity when the ionic conductivity is sufficient.It is worth noting that the fundamental research of this wo rk is also applicable to other battery systems using conductive polymers in order to achieve high energy density,broadening their practical applications.展开更多
An indium-zinc-oxide （IZO） based ionic/electronic hybrid synaptic transistor gated by field-configurable nanogranular SiO2 films was reported. The devices exhibited a high current ON/OFF ratio of above 107, a high e...An indium-zinc-oxide （IZO） based ionic/electronic hybrid synaptic transistor gated by field-configurable nanogranular SiO2 films was reported. The devices exhibited a high current ON/OFF ratio of above 107, a high electron mobility of ～14 cm2 V^-1 s^-1 and a low subthreshold swing of ～80 mV/decade. The gate bias would modulate the interplay between protons and electrons at the channel/dielectric interface. Due to the dynamic modulation of the transient protons flux within the nanogranular SiO2 films, the channel current would be modified dynamically. Short-term synaptic plasticities, such as short-term potentiation and short- term depression, were mimicked on the proposed IZO synaptic transistor. The results indicate that the synaptic transistor proposed here has potential applications in future neuromorphic devices.展开更多
Achieving high-energy density remains a key objective for advanced energy storage systems.However,challenges,such as poor cathode conductivity,anode dendrite formation,polysulfide shuttling,and electrolyte degradation...Achieving high-energy density remains a key objective for advanced energy storage systems.However,challenges,such as poor cathode conductivity,anode dendrite formation,polysulfide shuttling,and electrolyte degradation,continue to limit performance and stability.Molecular and ionic dipole interactions have emerged as an effective strategy to address these issues by regulating ionic transport,modulating solvation structures,optimizing interfacial chemistry,and enhancing charge transfer kinetics.These interactions also stabilize electrode interfaces,suppress side reactions,and mitigate anode corrosion,collectively improving the durability of high-energy batteries.A deeper understanding of these mechanisms is essential to guide the design of next-generation battery materials.Herein,this review summarizes the development,classification,and advantages of dipole interactions in high-energy batteries.The roles of dipoles,including facilitating ion transport,controlling solvation dynamics,stabilizing the electric double layer,optimizing solid electrolyte interphase and cathode–electrolyte interface layers,and inhibiting parasitic reactions—are comprehensively discussed.Finally,perspectives on future research directions are proposed to advance dipole-enabled strategies for high-performance energy storage.This review aims to provide insights into the rational design of dipole-interactive systems and promote the progress of electrochemical energy storage technologies.展开更多
Stretchable electronics have been recognized as intriguing next-generation electronics that possess huge market value,and stretchable electronic conductors(SECs)are essential for stretchable electronics,which not only...Stretchable electronics have been recognized as intriguing next-generation electronics that possess huge market value,and stretchable electronic conductors(SECs)are essential for stretchable electronics,which not only can serve as critical functional components but also are the indispensable electronic connections bridging various electronic components within stretchable electronic systems.Herein,we offer a comprehensive review of recent progress in SECs including the material categories,structure designs,fabrication techniques,and applications.The characteristics,performance enhancement strategies,and application requirements are emphasized.Based on the recent advances,the existing challenges and future prospects are outlined and discussed.展开更多
Permeable electronics promise improved physiological comfort,but remain constrained by limited functional integration and poor mechanical robustness.Here,we report a three-dimensional(3D)permeable electronic system th...Permeable electronics promise improved physiological comfort,but remain constrained by limited functional integration and poor mechanical robustness.Here,we report a three-dimensional(3D)permeable electronic system that overcomes these challenges by combining electrospun SEBS nanofiber mats,high-resolution liquid metal conductors patterned via thermal imprinting(50μm),and a strain isolators(SIL)that protects vertical interconnects(VIAs)from stress concentration.This architecture achieves ultrahigh air permeability(>5.09 m L cm^(-2)min^(-1)),exceptional stretchability(750%fracture strain),and reliable conductivity maintained through more than 32,500 strain cycles.Leveraging these advances,we have integrated multilayer circuits,strain sensors,and a three-axis accelerometer to achieve a fully integrated,stretchable,permeable wireless real-time gesture recognition glove.The system enables accurate sign language interpretation(98%)and seamless robotic hand control,demonstrating its potential for assistive technologies.By uniting comfort,durability,and high-density integration,this work establishes a versatile platform for nextgeneration wearable electronics and interactive human-robot interfaces.展开更多
Flexible polymer electronics have emerged as an important research frontier in materials science due to their unique advantages,including mechanical flexibility,lightweight characteristics,and solution processability....Flexible polymer electronics have emerged as an important research frontier in materials science due to their unique advantages,including mechanical flexibility,lightweight characteristics,and solution processability.These features enable a wide range of emerging applications such as wearable electronics,electronic skins,and biomedical devices,etc.In recent years,much advances in polymer chemistry,device physics,and interface engineering have significantly improved the performance of flexible polymer electronic devices,accelerating their transition from fundamental research to practical applications.展开更多
The rapid advancement of machine learning based tight-binding Hamiltonian(MLTB)methods has opened new avenues for efficient and accurate electronic structure simulations,particularly in large-scale systems and long-ti...The rapid advancement of machine learning based tight-binding Hamiltonian(MLTB)methods has opened new avenues for efficient and accurate electronic structure simulations,particularly in large-scale systems and long-time scenarios.This review begins with a concise overview of traditional tight-binding(TB)models,including both(semi-)empirical and first-principles approaches,establishing the foundation for understanding MLTB developments.We then present a systematic classification of existing MLTB methodologies,grouped into two major categories:direct prediction of TB Hamiltonian elements and inference of empirical parameters.A comparative analysis with other ML-based electronic structure models is also provided,highlighting the advancement of MLTB approaches.Finally,we explore the emerging MLTB application ecosystem,highlighting how the integration of MLTB models with a diverse suite of post-processing tools from linear-scaling solvers to quantum transport frameworks and molecular dynamics interfaces is essential for tackling complex scientific problems across different domains.The continued advancement of this integrated paradigm promises to accelerate materials discovery and open new frontiers in the predictive simulation of complex quantum phenomena.展开更多
Traditional digitizers for signal readout of PET detectors are based on commercial analog-to-digital converters(ADC).However,the cost and power consumption of an entire electronic readout system based on digitizers fo...Traditional digitizers for signal readout of PET detectors are based on commercial analog-to-digital converters(ADC).However,the cost and power consumption of an entire electronic readout system based on digitizers for a PET scanner are high.To address this problem,a soft-core ADC based on a field-programmable gate array(FPGA)was proposed.An FPGA-based ADC(FPGA-ADC)combines low loss and high performance.To achieve good performance,the FPGA-ADC requires three calibrations:time-to-digital converter(TDC)length calibration,TDC alignment calibration,and TDC-to-ADC calibration.A prototype front-end electronics based on FPGA-ADC was built to evaluate the performance of time-of-flight positron emission tomography(TOF PET)detectors.Each PET detector consists of a LYSO crystal single-ended coupled to a silicon photomultiplier(SiPM).The experimental results show that the full-width at half-maximum(FWHM)energy resolution for 511 keV gamma photons after saturation correction of the SiPM was 12.3%.The FWHM coincidence timing resolution(CTR)of the TOF PET detector with the readout of the front-end electronic prototype is 385.2 ps.FPGA-ADCbased front-end electronics are very promising for multichannel,low-cost,highly integrated,and power-efficient readout electronic systems for radiation detector applications.展开更多
A rapidly growing field is piezoresistive sensor for accurate respiration rate monitoring to suppress the worldwide respiratory illness.However,a large neglected issue is the sensing durability and accuracy without in...A rapidly growing field is piezoresistive sensor for accurate respiration rate monitoring to suppress the worldwide respiratory illness.However,a large neglected issue is the sensing durability and accuracy without interference since the expiratory pressure always coupled with external humidity and temperature variations,as well as mechanical motion artifacts.Herein,a robust and biodegradable piezoresistive sensor is reported that consists of heterogeneous MXene/cellulose-gelation sensing layer and Ag-based interdigital electrode,featuring customizable cylindrical interface arrangement and compact hierarchical laminated architecture for collectively regulating the piezoresistive response and mechanical robustness,thereby realizing the long-term breath-induced pressure detection.Notably,molecular dynamics simulations reveal the frequent angle inversion and reorientation of MXene/cellulose in vacuum filtration,driven by shear forces and interfacial interactions,which facilitate the establishment of hydrogen bonds and optimize the architecture design in sensing layer.The resultant sensor delivers unprecedented collection features of superior stability for off-axis deformation(0-120°,~2.8×10^(-3) A)and sensing accuracy without crosstalk(humidity 50%-100%and temperature 30-80).Besides,the sensor-embedded mask together with machine learning models is achieved to train and classify the respiration status for volunteers with different ages(average prediction accuracy~90%).It is envisioned that the customizable architecture design and sensor paradigm will shed light on the advanced stability of sustainable electronics and pave the way for the commercial application in respiratory monitory.展开更多
Electron beam injectors are pivotal components of large-scale scientific instruments,such as synchrotron radiation sources,free-electron lasers,and electron-positron colliders.The quality of the electron beam produced...Electron beam injectors are pivotal components of large-scale scientific instruments,such as synchrotron radiation sources,free-electron lasers,and electron-positron colliders.The quality of the electron beam produced by the injector critically influences the performance of the entire accelerator-based scientific research apparatus.The injectors of such facilities usually use photocathode and thermionic-cathode electron guns.Although the photocathode injector can produce electron beams of excellent quality,its associated laser system is massive and intricate.The thermionic-cathode electron gun,especially the gridded electron gun injector,has a simple structure capable of generating numerous electron beams.However,its emittance is typically high.In this study,methods to reduce beam emittance are explored through a comprehensive analysis of various grid structures and preliminary design results,examining the evolution of beam phase space at different grid positions.An optimization method for reducing the emittance of a gridded thermionic-cathode electron gun is proposed through theoretical derivation,electromagnetic-field simulation,and beam-dynamics simulation.A 50%reduction in emittance was achieved for a 50 keV,1.7 A electron gun,laying the foundation for the subsequent design of a high-current,low-emittance injector.展开更多
SiO_(2)–CaO–Al_(2)O_(3)ternary inclusions are among the most common complex oxide inclusions in steel.Nevertheless,the chemical and physical properties of these composite inclusions,particularly with detailed compos...SiO_(2)–CaO–Al_(2)O_(3)ternary inclusions are among the most common complex oxide inclusions in steel.Nevertheless,the chemical and physical properties of these composite inclusions,particularly with detailed composition changes,have not been sufficiently investigated.In this study,first-principles density functional theory calculations were used to determine the electronic,mechanical,and thermodynamic properties of two stable phases in the SiO_(2)–CaO–Al_(2)O_(3)ternary inclusion system:anorthite(CaAl_(2)Si_(2)O_(8))and gehlenite(Ca_(2)Al_(2)SiO_(7)).Based on the electronic density of states analysis and band structure calculations,oxygen atoms play important roles in the electron reactivity of both phases.Young’s modulus and Poisson’s ratios were calculated and compared with those of the SiO_(2)–CaO inclusions.The Young’s moduli of CaAl_(2)Si_(2)O_(8)(101.32 GPa)and Ca_(2)Al_(2)SiO_(7)(131.43 GPa)were close to the maximum and minimum Young’s moduli of the binary oxide inclusions,respectively.With increasing temperature,the Young’s moduli of CaAl_(2)Si_(2)O_(8)and Ca_(2)Al_(2)SiO_(7)showed slight increasing and decreasing trends,respectively,whereas the Poisson’s ratio decreased.Furthermore,the thermodynamic properties,particularly temperature-related thermal expansion coefficients,were also deeply investigated.The thermal expansion coefficients of both CaAl_(2)Si_(2)O_(8)and Ca_(2)Al_(2)SiO_(7)increased rapidly with increasing temperature in the low-temperature regime above 300K.As the temperature increased,the increasing trend slowed.When the temperature reached 2000 K,the thermal expansion coefficients of CaAl_(2)Si_(2)O_(8)and Ca_(2)Al_(2)SiO_(7)respectively were 12×10^(−6)and 8.5×10^(−6)K^(−1).These findings enhance the understanding of the physical nature of ternary inclusions in steels and provide a scientific foundation for analyzing their effects on steel performance using a more comprehensive inclusion database,thereby contributing to inclusion engineering in the development of materials with superior mechanical integrity.展开更多
Robotic electronic skin(e-skin)is inspired by human skin and endows robots with tactile perception,temperature detection,and environmental interaction capabilities.However,its development is hampered by prolonged desi...Robotic electronic skin(e-skin)is inspired by human skin and endows robots with tactile perception,temperature detection,and environmental interaction capabilities.However,its development is hampered by prolonged design cycles,limited signal enhancement,and weak cognitive abilities.Given that the convergence of artificial intelligence(AI)with e-skin is fundamentally transforming this landscape,the present review highlights the pivotal contributions of AI across the entire development spectrum of robotic e-skin,including design optimization,signal processing,and cognitive enhancement.AI-driven design paradigms dramatically shorten development time and enable the discovery of optimal sensor materials and structures.In signal processing,AI algorithms notably improve the ability to decouple complex sensory data,enabling robust,multimodal,super-resolution sensing.AI endows e-skin with advanced cognitive capabilities,allowing it to interpret intricate tactile information and intelligently respond to external environments.By underscoring the potential of AI throughout the entire development pipeline,this review aims to drive the creation of e-skin with minimal hardware and maximal cognition and thus achieve revolutionary breakthroughs in cutting-edge fields such as human-robot interactions,precise robot control,and soft robotics for environmental exploration.展开更多
This study presents a comprehensive theoretical investigation of the electronic and structural properties of a series of fractal molecular architectures derived from benzene and progressively extended toward circumcor...This study presents a comprehensive theoretical investigation of the electronic and structural properties of a series of fractal molecular architectures derived from benzene and progressively extended toward circumcoronene-like graphene analogues.Molecular geometries were constructed using GaussView 6,while all quantum-chemical calculations were carried out within the Gaussian 09 package using density functional theory(DFT)at the B3LYP/6-31G level,ensuring a reliable balance between computational accuracy and efficiency.The gradual expansion of the hexagonal framework resulted in a systematic reduction in the energy gap between the highest occupied molecular orbital(HOMO)and the lowest unoccupied molecular orbital(LUMO),indicating enhanced electronic delocalization and improved charge-transport characteristics in higher-order fractal structures.Electron density contour maps revealed an increasedπ-electron symmetry in the central regions of the larger systems,whereas smaller units exhibited an edge-localized electron density,consistent with the development of extendedπ–πconjugation.In addition,the density of states(DOS)spectra demonstrated a pronounced broadening of both occupied and virtual states with an increasing structural size,confirming the strong correlation between the fractal growth and electronic transport behavior.Furthermore,the analysis of the HOMO and LUMO distributions showed an orbital broadening and enhanced spatial symmetry in advanced fractal geometries,accounting for the observed reduction in the energy gap.These results indicate that coronene-based fractal structures exhibit significant potential for applications in conductive nanomaterials and molecular electronics,as their electronic and structural properties can be finely tuned through controlled fractal branching,enabling tailored performance in next-generation nanoscale devices.展开更多
Continuous monitoring of biosignals is essential for advancing early disease detection,personalized treatment,and health management.Flexible electronics,capable of accurately monitoring biosignals in daily life,have g...Continuous monitoring of biosignals is essential for advancing early disease detection,personalized treatment,and health management.Flexible electronics,capable of accurately monitoring biosignals in daily life,have garnered considerable attention due to their softness,conformability,and biocompatibility.However,several challenges remain,including imperfect skin-device interfaces,limited breathability,and insufficient mechanoelectrical stability.On-skin epidermal electronics,distinguished by their excellent conformability,breathability,and mechanoelectrical robustness,offer a promising solution for high-fidelity,long-term health monitoring.These devices can seamlessly integrate with the human body,leading to transformative advancements in future personalized healthcare.This review provides a systematic examination of recent advancements in on-skin epidermal electronics,with particular emphasis on critical aspects including material science,structural design,desired properties,and practical applications.We explore various materials,considering their properties and the corresponding structural designs developed to construct high-performance epidermal electronics.We then discuss different approaches for achieving the desired device properties necessary for long-term health monitoring,including adhesiveness,breathability,and mechanoelectrical stability.Additionally,we summarize the diverse applications of these devices in monitoring biophysical and physiological signals.Finally,we address the challenges facing these devices and outline future prospects,offering insights into the ongoing development of on-skin epidermal electronics for long-term health monitoring.展开更多
Sodium superionic conductor(NASICON)-type materials are promising cathodes for sodium-ion batteries due to their stable multi-channel frameworks and exceptional ionic conductivity.Among them,Na_(3)V_2(PO_4)_(2)F_(3)(N...Sodium superionic conductor(NASICON)-type materials are promising cathodes for sodium-ion batteries due to their stable multi-channel frameworks and exceptional ionic conductivity.Among them,Na_(3)V_2(PO_4)_(2)F_(3)(NVPF)has attracted significant attention.However,the low electronic conductivity and phase impurities limit its sodium storage capability.Herein,we present a Fe and Mn dual-doped NVPF(FM-NVPF)cathode with improved phase purity,electronic conductivity,and electrochemical activities.Detailed ex-situ analyses and density functional theory calculations reveal that Fe and Mn dopants induce defect energy levels and modulate the electronic structure,resulting in a direct-to-indirect bandgap transition in NVPF,which in turn increases carrier concentration and lifetime,accelerates ionic/electronic transport,and improves structural stability.As a result,the FM-NVPF cathode delivers a high capacity of 126.6 mAh g^(-1)at 0.1 C(1 C=128 mAh g^(-1))and outstanding high-rate capability of 67.6 mAh g^(-1)at 50 C,corresponding to 1.2 min per charge.Furthermore,Na ion full cells assembled with the FM-NVPF cathodes and hard carbon anodes exhibit a high energy density of about 175 Wh kg^(-1)_(cathode+anode mass)and appealing cyclic stability.This work provides an efficient strategy for developing high-purity and high-performance NVPF cathode materials for advanced sodium-ion batteries.展开更多
基金This study was financially supported by the National Natural Science Foundation of China(Nos.52177208,52171202,51971055 and 51871046)the National Safety Academic Fund(Nos.U1930208,U2030206 and U1730136).
文摘The high energy density and stability of solid-state lithium metal batteries(SSLMBs)have garnered great attention.Garnet-type oxides,especially Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO),with high ionic conductivity,wide electrochemical window,and stability to Li metal anode,are promising solid-state electrolyte(SSEs)materials for SSLMBs.However,Li/LLZTO interface issues including high interface resistance,inhomogeneous Li deposition,and Li dendrite growth have hindered the practical application of SSLMBs.Herein,a multi-functional Li–SnF_(2) composite anode with Li,LiF,and Li-Sn alloy was specifically designed and prepared.The composite anode improves the wettability to LLZTO,constructing an intimate contact interface between it and LLZTO.Meanwhile,ionic/electronic conductive paths in situ formed at the interface can effectively uniform Li deposition and suppress Li dendrite.The solid-state symmetric cell exhibits low interface resistance(11Ω·cm^(2)) and high critical current density(1.3 mA·cm^(−2))at 25℃.The full SSLMB based on LiFePO_(4) or LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode also shows stable cycling performance and high rate capability.This work provides a new composite anode strategy for achieving high-energy density and high-safety SSLMBs.
基金financially supported by the National Natural Science Foundation of China(Nos.22279097,52172217)Natural Science Foundation of Guangdong Province(No.2021A1515010144)Shenzhen Science and Technology Program(No.JCYJ20210324120400002).
文摘Lithium(Li)dendrite issue,which is usually caused by inhomogeneous Li nucleation and fragile solid electrolyte interphase(SEI),impedes the further development of high-energy Li metal batteries.However,the integrated construction of a high-stable SEI layer that can regulate uniform nucleation and facilitate fast Li-ion diffusion kinetics for Li metal anode still falls short.Herein,we designed an artificial SEI with hybrid ionic/electronic interphase to regulate Li deposition by in-situ constructing metal Co clusters embedded in LiF matrix.The generated Co and LiF both enable fast Li-ion diffusion kinetics,meanwhile,the lithiophilic properties of Co clusters can serve as Li-ion nucleation sites,thereby contributing to uniform Li nucleation and non-dendritic growth.As a result,a dendrite-free Li deposition with a low overpotential(16.1 mV)is achieved,which enables an extended lifespan over 750 h under strict conditions.The full cells with high-mass-loading LiFePO_(4)(11.5 mg/cm^(2))as cathodes exhibit a remarkable rate capacity of 84.1 mAh/g at 5 C and an improved cycling performance with a capacity retention of 96.4%after undergoing 180 cycles.
基金supported by the Fundamental Research Funds for Central Universities of China and the Key Research and Development Projects of Sichuan(No.2020YFG0127)。
文摘Low-cost silicon microparticles(SiMP),as a substitute for nanostructured silicon,easily suffer from cracks and fractured during the electrochemical cycle.A novel n-type conductive polymer binder with excellent electronic and ionic conductivities as well as good adhesion,has been successfully designed and applied for high-performance SiMP anodes in lithium-ion batteries to address this problem.Its unique features are attributed to the stro ng electron-withdrawing oxadiazole ring structure with sulfonate polar groups.The combination of rigid and flexible components in the polymer ensures its good mechanical strength and ductility,which is beneficial to suppress the expansion and contraction of SiMP s during the charge/discharge process.By fine-tuning the monomer ratio,the conjugation and sulfonation degrees of the polymer can be precisely controlled to regulate its ionic and electronic conductivities,which has been systematically analyzed with the help of an electrochemical test method,filling in the gap on the conductivity measurement of the polymer in the doping state.The experimental results indicate that the cell with the developed n-type polymer binder and SiMP(~0.5 μm) anodes achieves much better cycling performance than traditional non-conductive binders.It has been considered that the initial capacity of the SiMP anode is controlled by the synergetic effect of ionic and electronic conductivity of the binder,and the capacity retention mainly depends on its electronic conductivity when the ionic conductivity is sufficient.It is worth noting that the fundamental research of this wo rk is also applicable to other battery systems using conductive polymers in order to achieve high energy density,broadening their practical applications.
基金supported by the National Program on Key Basic Research Project (No.2012CB933004)the Zhejiang Provincial Natural Science Foundation of China (No.LY14A040009)the Ningbo Natural Science Foundation (No.2013A610001)
文摘An indium-zinc-oxide （IZO） based ionic/electronic hybrid synaptic transistor gated by field-configurable nanogranular SiO2 films was reported. The devices exhibited a high current ON/OFF ratio of above 107, a high electron mobility of ～14 cm2 V^-1 s^-1 and a low subthreshold swing of ～80 mV/decade. The gate bias would modulate the interplay between protons and electrons at the channel/dielectric interface. Due to the dynamic modulation of the transient protons flux within the nanogranular SiO2 films, the channel current would be modified dynamically. Short-term synaptic plasticities, such as short-term potentiation and short- term depression, were mimicked on the proposed IZO synaptic transistor. The results indicate that the synaptic transistor proposed here has potential applications in future neuromorphic devices.
基金supported by the introduction of Talent Research Fund in Nanjing Institute of Technology(YKJ202204)the National Natural Science Foundation of China(52401282 and 52300206)the Natural Science Foundation of Jiangsu Province(BK20230701 and BK20230705).
文摘Achieving high-energy density remains a key objective for advanced energy storage systems.However,challenges,such as poor cathode conductivity,anode dendrite formation,polysulfide shuttling,and electrolyte degradation,continue to limit performance and stability.Molecular and ionic dipole interactions have emerged as an effective strategy to address these issues by regulating ionic transport,modulating solvation structures,optimizing interfacial chemistry,and enhancing charge transfer kinetics.These interactions also stabilize electrode interfaces,suppress side reactions,and mitigate anode corrosion,collectively improving the durability of high-energy batteries.A deeper understanding of these mechanisms is essential to guide the design of next-generation battery materials.Herein,this review summarizes the development,classification,and advantages of dipole interactions in high-energy batteries.The roles of dipoles,including facilitating ion transport,controlling solvation dynamics,stabilizing the electric double layer,optimizing solid electrolyte interphase and cathode–electrolyte interface layers,and inhibiting parasitic reactions—are comprehensively discussed.Finally,perspectives on future research directions are proposed to advance dipole-enabled strategies for high-performance energy storage.This review aims to provide insights into the rational design of dipole-interactive systems and promote the progress of electrochemical energy storage technologies.
基金supported by the National Natural Science Foundation of China(52172170)Guangdong Natural Science Foundation for Distinguished Young Scholars(2023B1515020114)+2 种基金Fundamental Research Funds for the Central Universities(24lgqb003)Guangdong University Innovation and Enhancement Program(2024KTSCX003)Science and Technology Projects of Guangzhou(2025A04J4230).
文摘Stretchable electronics have been recognized as intriguing next-generation electronics that possess huge market value,and stretchable electronic conductors(SECs)are essential for stretchable electronics,which not only can serve as critical functional components but also are the indispensable electronic connections bridging various electronic components within stretchable electronic systems.Herein,we offer a comprehensive review of recent progress in SECs including the material categories,structure designs,fabrication techniques,and applications.The characteristics,performance enhancement strategies,and application requirements are emphasized.Based on the recent advances,the existing challenges and future prospects are outlined and discussed.
基金supported in part by the National Key R&D Program of China under Grant 2024YFB4405300 and 2022YFA1204300the Natural Science Foundation of Hunan Province under Grant 2023JJ20016+2 种基金the National Natural Science Foundation of China under Grants of 52221001 and 62090035the Key Research and Development Plan of Hunan Province under grants of 2022GK3002 and 2023GK2012the Key Program of Science and Technology Department of Hunan Province under grant of 2020XK2001。
文摘Permeable electronics promise improved physiological comfort,but remain constrained by limited functional integration and poor mechanical robustness.Here,we report a three-dimensional(3D)permeable electronic system that overcomes these challenges by combining electrospun SEBS nanofiber mats,high-resolution liquid metal conductors patterned via thermal imprinting(50μm),and a strain isolators(SIL)that protects vertical interconnects(VIAs)from stress concentration.This architecture achieves ultrahigh air permeability(>5.09 m L cm^(-2)min^(-1)),exceptional stretchability(750%fracture strain),and reliable conductivity maintained through more than 32,500 strain cycles.Leveraging these advances,we have integrated multilayer circuits,strain sensors,and a three-axis accelerometer to achieve a fully integrated,stretchable,permeable wireless real-time gesture recognition glove.The system enables accurate sign language interpretation(98%)and seamless robotic hand control,demonstrating its potential for assistive technologies.By uniting comfort,durability,and high-density integration,this work establishes a versatile platform for nextgeneration wearable electronics and interactive human-robot interfaces.
文摘Flexible polymer electronics have emerged as an important research frontier in materials science due to their unique advantages,including mechanical flexibility,lightweight characteristics,and solution processability.These features enable a wide range of emerging applications such as wearable electronics,electronic skins,and biomedical devices,etc.In recent years,much advances in polymer chemistry,device physics,and interface engineering have significantly improved the performance of flexible polymer electronic devices,accelerating their transition from fundamental research to practical applications.
基金supported by the Advanced Materials-National Science and Technology Major Project(Grant No.2025ZD0618401)the National Natural Science Foundation of China(Grant No.12504285)+1 种基金the Natural Science Foundation of Jiangsu Province(Grant No.BK20250472)NFSG grant from BITS-Pilani,Dubai campus。
文摘The rapid advancement of machine learning based tight-binding Hamiltonian(MLTB)methods has opened new avenues for efficient and accurate electronic structure simulations,particularly in large-scale systems and long-time scenarios.This review begins with a concise overview of traditional tight-binding(TB)models,including both(semi-)empirical and first-principles approaches,establishing the foundation for understanding MLTB developments.We then present a systematic classification of existing MLTB methodologies,grouped into two major categories:direct prediction of TB Hamiltonian elements and inference of empirical parameters.A comparative analysis with other ML-based electronic structure models is also provided,highlighting the advancement of MLTB approaches.Finally,we explore the emerging MLTB application ecosystem,highlighting how the integration of MLTB models with a diverse suite of post-processing tools from linear-scaling solvers to quantum transport frameworks and molecular dynamics interfaces is essential for tackling complex scientific problems across different domains.The continued advancement of this integrated paradigm promises to accelerate materials discovery and open new frontiers in the predictive simulation of complex quantum phenomena.
基金supported by the Key R&D Program of Shandong Province(No.2023SFGC0101)Shandong Excellent Young Scientists Fund Program(Overseas)(No.2023HWYQ-047)+1 种基金the Natural Science Foundation of Shandong Province(No.ZR2022QA039)the National Natural Science Foundation of China(NSFC)(No.U2106202).
文摘Traditional digitizers for signal readout of PET detectors are based on commercial analog-to-digital converters(ADC).However,the cost and power consumption of an entire electronic readout system based on digitizers for a PET scanner are high.To address this problem,a soft-core ADC based on a field-programmable gate array(FPGA)was proposed.An FPGA-based ADC(FPGA-ADC)combines low loss and high performance.To achieve good performance,the FPGA-ADC requires three calibrations:time-to-digital converter(TDC)length calibration,TDC alignment calibration,and TDC-to-ADC calibration.A prototype front-end electronics based on FPGA-ADC was built to evaluate the performance of time-of-flight positron emission tomography(TOF PET)detectors.Each PET detector consists of a LYSO crystal single-ended coupled to a silicon photomultiplier(SiPM).The experimental results show that the full-width at half-maximum(FWHM)energy resolution for 511 keV gamma photons after saturation correction of the SiPM was 12.3%.The FWHM coincidence timing resolution(CTR)of the TOF PET detector with the readout of the front-end electronic prototype is 385.2 ps.FPGA-ADCbased front-end electronics are very promising for multichannel,low-cost,highly integrated,and power-efficient readout electronic systems for radiation detector applications.
基金supported by the National Natural Science Foundation of China(22074072,22274083,52376199)the Shandong Provincial Natural Science Foundation(ZR2023LZY005)+1 种基金the Exploration Project of the State Key Laboratory of BioFibers and EcoTextiles of Qingdao University(TSKT202101)the Fundamental Research Funds for the Central Universities(2022BLRD13,2023BLRD01).
文摘A rapidly growing field is piezoresistive sensor for accurate respiration rate monitoring to suppress the worldwide respiratory illness.However,a large neglected issue is the sensing durability and accuracy without interference since the expiratory pressure always coupled with external humidity and temperature variations,as well as mechanical motion artifacts.Herein,a robust and biodegradable piezoresistive sensor is reported that consists of heterogeneous MXene/cellulose-gelation sensing layer and Ag-based interdigital electrode,featuring customizable cylindrical interface arrangement and compact hierarchical laminated architecture for collectively regulating the piezoresistive response and mechanical robustness,thereby realizing the long-term breath-induced pressure detection.Notably,molecular dynamics simulations reveal the frequent angle inversion and reorientation of MXene/cellulose in vacuum filtration,driven by shear forces and interfacial interactions,which facilitate the establishment of hydrogen bonds and optimize the architecture design in sensing layer.The resultant sensor delivers unprecedented collection features of superior stability for off-axis deformation(0-120°,~2.8×10^(-3) A)and sensing accuracy without crosstalk(humidity 50%-100%and temperature 30-80).Besides,the sensor-embedded mask together with machine learning models is achieved to train and classify the respiration status for volunteers with different ages(average prediction accuracy~90%).It is envisioned that the customizable architecture design and sensor paradigm will shed light on the advanced stability of sustainable electronics and pave the way for the commercial application in respiratory monitory.
基金supported by the Hundred-person Program of Chinese Academy of Sciences and the National Natural Science Foundation of China(No.11905074).
文摘Electron beam injectors are pivotal components of large-scale scientific instruments,such as synchrotron radiation sources,free-electron lasers,and electron-positron colliders.The quality of the electron beam produced by the injector critically influences the performance of the entire accelerator-based scientific research apparatus.The injectors of such facilities usually use photocathode and thermionic-cathode electron guns.Although the photocathode injector can produce electron beams of excellent quality,its associated laser system is massive and intricate.The thermionic-cathode electron gun,especially the gridded electron gun injector,has a simple structure capable of generating numerous electron beams.However,its emittance is typically high.In this study,methods to reduce beam emittance are explored through a comprehensive analysis of various grid structures and preliminary design results,examining the evolution of beam phase space at different grid positions.An optimization method for reducing the emittance of a gridded thermionic-cathode electron gun is proposed through theoretical derivation,electromagnetic-field simulation,and beam-dynamics simulation.A 50%reduction in emittance was achieved for a 50 keV,1.7 A electron gun,laying the foundation for the subsequent design of a high-current,low-emittance injector.
基金financially supported by the National Nat-ural Science Foundation of China(No.52404337)the Chun-hui Plan Collaborative Research Project from Chinese Edu-cation Ministry(No.HZKY20220036)+1 种基金the Guangdong Ba-sic and Applied Basic Research Foundation,China(No.2022A1515110062)the Young Elite Scientists Spon-sorship Program by China Association for Science and Tech-nology(No.YESS20220231).
文摘SiO_(2)–CaO–Al_(2)O_(3)ternary inclusions are among the most common complex oxide inclusions in steel.Nevertheless,the chemical and physical properties of these composite inclusions,particularly with detailed composition changes,have not been sufficiently investigated.In this study,first-principles density functional theory calculations were used to determine the electronic,mechanical,and thermodynamic properties of two stable phases in the SiO_(2)–CaO–Al_(2)O_(3)ternary inclusion system:anorthite(CaAl_(2)Si_(2)O_(8))and gehlenite(Ca_(2)Al_(2)SiO_(7)).Based on the electronic density of states analysis and band structure calculations,oxygen atoms play important roles in the electron reactivity of both phases.Young’s modulus and Poisson’s ratios were calculated and compared with those of the SiO_(2)–CaO inclusions.The Young’s moduli of CaAl_(2)Si_(2)O_(8)(101.32 GPa)and Ca_(2)Al_(2)SiO_(7)(131.43 GPa)were close to the maximum and minimum Young’s moduli of the binary oxide inclusions,respectively.With increasing temperature,the Young’s moduli of CaAl_(2)Si_(2)O_(8)and Ca_(2)Al_(2)SiO_(7)showed slight increasing and decreasing trends,respectively,whereas the Poisson’s ratio decreased.Furthermore,the thermodynamic properties,particularly temperature-related thermal expansion coefficients,were also deeply investigated.The thermal expansion coefficients of both CaAl_(2)Si_(2)O_(8)and Ca_(2)Al_(2)SiO_(7)increased rapidly with increasing temperature in the low-temperature regime above 300K.As the temperature increased,the increasing trend slowed.When the temperature reached 2000 K,the thermal expansion coefficients of CaAl_(2)Si_(2)O_(8)and Ca_(2)Al_(2)SiO_(7)respectively were 12×10^(−6)and 8.5×10^(−6)K^(−1).These findings enhance the understanding of the physical nature of ternary inclusions in steels and provide a scientific foundation for analyzing their effects on steel performance using a more comprehensive inclusion database,thereby contributing to inclusion engineering in the development of materials with superior mechanical integrity.
基金supported by the National Natural Science Foundation of China(No.52375031)the Dongfang Electric Corporation-Zhejiang University Joint Innovation Research Institutethe Bellwethers Research and Development Plan of Zhejiang Province(No.2023C01045)。
文摘Robotic electronic skin(e-skin)is inspired by human skin and endows robots with tactile perception,temperature detection,and environmental interaction capabilities.However,its development is hampered by prolonged design cycles,limited signal enhancement,and weak cognitive abilities.Given that the convergence of artificial intelligence(AI)with e-skin is fundamentally transforming this landscape,the present review highlights the pivotal contributions of AI across the entire development spectrum of robotic e-skin,including design optimization,signal processing,and cognitive enhancement.AI-driven design paradigms dramatically shorten development time and enable the discovery of optimal sensor materials and structures.In signal processing,AI algorithms notably improve the ability to decouple complex sensory data,enabling robust,multimodal,super-resolution sensing.AI endows e-skin with advanced cognitive capabilities,allowing it to interpret intricate tactile information and intelligently respond to external environments.By underscoring the potential of AI throughout the entire development pipeline,this review aims to drive the creation of e-skin with minimal hardware and maximal cognition and thus achieve revolutionary breakthroughs in cutting-edge fields such as human-robot interactions,precise robot control,and soft robotics for environmental exploration.
文摘This study presents a comprehensive theoretical investigation of the electronic and structural properties of a series of fractal molecular architectures derived from benzene and progressively extended toward circumcoronene-like graphene analogues.Molecular geometries were constructed using GaussView 6,while all quantum-chemical calculations were carried out within the Gaussian 09 package using density functional theory(DFT)at the B3LYP/6-31G level,ensuring a reliable balance between computational accuracy and efficiency.The gradual expansion of the hexagonal framework resulted in a systematic reduction in the energy gap between the highest occupied molecular orbital(HOMO)and the lowest unoccupied molecular orbital(LUMO),indicating enhanced electronic delocalization and improved charge-transport characteristics in higher-order fractal structures.Electron density contour maps revealed an increasedπ-electron symmetry in the central regions of the larger systems,whereas smaller units exhibited an edge-localized electron density,consistent with the development of extendedπ–πconjugation.In addition,the density of states(DOS)spectra demonstrated a pronounced broadening of both occupied and virtual states with an increasing structural size,confirming the strong correlation between the fractal growth and electronic transport behavior.Furthermore,the analysis of the HOMO and LUMO distributions showed an orbital broadening and enhanced spatial symmetry in advanced fractal geometries,accounting for the observed reduction in the energy gap.These results indicate that coronene-based fractal structures exhibit significant potential for applications in conductive nanomaterials and molecular electronics,as their electronic and structural properties can be finely tuned through controlled fractal branching,enabling tailored performance in next-generation nanoscale devices.
基金supported by National Natural Science Foundation of China(Grant Nos.52025055,52375576,52350349)Key Research and Development Program of Shaanxi(Program No.2022GXLH-01-12)+2 种基金Joint Fund of Ministry of Education for Equipment Pre-research(No.8091B03012304)Aeronautical Science Foundation of China(No.2022004607001)the Fundamental Research Funds for the Central Universities(No.xtr072024031).
文摘Continuous monitoring of biosignals is essential for advancing early disease detection,personalized treatment,and health management.Flexible electronics,capable of accurately monitoring biosignals in daily life,have garnered considerable attention due to their softness,conformability,and biocompatibility.However,several challenges remain,including imperfect skin-device interfaces,limited breathability,and insufficient mechanoelectrical stability.On-skin epidermal electronics,distinguished by their excellent conformability,breathability,and mechanoelectrical robustness,offer a promising solution for high-fidelity,long-term health monitoring.These devices can seamlessly integrate with the human body,leading to transformative advancements in future personalized healthcare.This review provides a systematic examination of recent advancements in on-skin epidermal electronics,with particular emphasis on critical aspects including material science,structural design,desired properties,and practical applications.We explore various materials,considering their properties and the corresponding structural designs developed to construct high-performance epidermal electronics.We then discuss different approaches for achieving the desired device properties necessary for long-term health monitoring,including adhesiveness,breathability,and mechanoelectrical stability.Additionally,we summarize the diverse applications of these devices in monitoring biophysical and physiological signals.Finally,we address the challenges facing these devices and outline future prospects,offering insights into the ongoing development of on-skin epidermal electronics for long-term health monitoring.
基金supported by the Innovation and Technology Fund-Innovation and Technology Support Program(ITF-ITSP)(Project No.ITS/126/21)Research Talent Hub for ITF project(RTH-ITF)(Project No.K-45-35-ZWC6)from the Innovation and Technology Commission of Hong Kong SARResearch Institute for Advanced Manufacturing(RIAM)at The Hong Kong Polytechnic University(Project No.1-CD9C)。
文摘Sodium superionic conductor(NASICON)-type materials are promising cathodes for sodium-ion batteries due to their stable multi-channel frameworks and exceptional ionic conductivity.Among them,Na_(3)V_2(PO_4)_(2)F_(3)(NVPF)has attracted significant attention.However,the low electronic conductivity and phase impurities limit its sodium storage capability.Herein,we present a Fe and Mn dual-doped NVPF(FM-NVPF)cathode with improved phase purity,electronic conductivity,and electrochemical activities.Detailed ex-situ analyses and density functional theory calculations reveal that Fe and Mn dopants induce defect energy levels and modulate the electronic structure,resulting in a direct-to-indirect bandgap transition in NVPF,which in turn increases carrier concentration and lifetime,accelerates ionic/electronic transport,and improves structural stability.As a result,the FM-NVPF cathode delivers a high capacity of 126.6 mAh g^(-1)at 0.1 C(1 C=128 mAh g^(-1))and outstanding high-rate capability of 67.6 mAh g^(-1)at 50 C,corresponding to 1.2 min per charge.Furthermore,Na ion full cells assembled with the FM-NVPF cathodes and hard carbon anodes exhibit a high energy density of about 175 Wh kg^(-1)_(cathode+anode mass)and appealing cyclic stability.This work provides an efficient strategy for developing high-purity and high-performance NVPF cathode materials for advanced sodium-ion batteries.
