The E-iodohydroxylation of 1,2-allenylic sulfoxides with I2 in the presence of EtOH afforded 3-phenylsulfinyl- 2-iodo-2(E)-alkenols in good yields and regio/stereo-selectivities under very mild conditions.
基金the National Natural Science Foundation of China(No.?)the Major State Basic Research Development Program(No.G2000077500)Cheung Kong Scholar Programme.
文摘The E-iodohydroxylation of 1,2-allenylic sulfoxides with I2 in the presence of EtOH afforded 3-phenylsulfinyl- 2-iodo-2(E)-alkenols in good yields and regio/stereo-selectivities under very mild conditions.
