CO<sub>2</sub>-RICH fluid inclusions have been found in 6 anhydrous peridotite xenolith minerals in Ceno-zoic basalts of 5 areas in East China.Electron probe backscattering electron image reveals thatsever...CO<sub>2</sub>-RICH fluid inclusions have been found in 6 anhydrous peridotite xenolith minerals in Ceno-zoic basalts of 5 areas in East China.Electron probe backscattering electron image reveals thatseveral inclusions appear in all the rock sections,completely filled with glass or with cavities attheir center part（CO<sub>2</sub> has escaped）.Some inclusions show devitrification and daughter miner-als appear.We have carried out the analysis on the non-devitrification glass in the inclusions.展开更多
The Mesozoic volcanic rocks of the Bodong Low Uplift in the Bohai Bay Basin have been studied and explored for years.In 2024,the LK7-A well drilled in this region tested high-yield oil and gas flows from volcanic weat...The Mesozoic volcanic rocks of the Bodong Low Uplift in the Bohai Bay Basin have been studied and explored for years.In 2024,the LK7-A well drilled in this region tested high-yield oil and gas flows from volcanic weathered crust.These volcanic rocks need to be further investigated in terms of distribution patterns,conditions for forming high-quality reservoirs,and main factors controlling hydrocarbon accumulation.Based on the logging,geochemical and mineralogical data from wells newly drilled to the Mesozoic volcanic rocks in the basin,and high-resolution 3D seismic data,a comprehensive study was conducted for this area.The research findings are as follows.First,the volcanic rocks in the LK7-A structure are adakites with a large source area depth,and the deep and large faults have provided channels for the emplacement of intermediate-acidic volcanic rocks.Second,volcanic rock reservoirs are mainly distributed in tectonic breccias and intermediate-acidic lavas,and they are dominantly fractured-porous reservoirs,with high-porosity and low-permeability or medium-porosity and low-permeability.Third,the dominant lithologies/lithofacies is the basic condition for forming large-scale volcanic rock reservoirs.Structural fractures and late-stage strong weathering are crucial mechanisms for the formation scale of reservoirs in the Mesozoic volcanic rocks.Fourth,the Bodong Low Uplift exhibits strong hydrocarbon charging by two sags and overpressure mudstone capping,which are favorable for forming high-abundance oil and gas reservoirs.The Mesozoic volcanic buried hills in the study area reflect good trap geometry,providing favorable conditions for large-scale reservoir formation,and also excellent migration and accumulation conditions.Areas with long-term exposure of intermediate-acidic volcanic rocks,particularly in active structural regions,are the key targets for future exploration.展开更多
The Ningzhen region of China is located in the easternmost part of the middle-lower Yangtze River Cu–Fe polymetallic metallogenic belt. From west to east, it comprises five main intermediate–acidic intrusive complex...The Ningzhen region of China is located in the easternmost part of the middle-lower Yangtze River Cu–Fe polymetallic metallogenic belt. From west to east, it comprises five main intermediate–acidic intrusive complexes: the Qilinmen, Anjishan, Xiashu–Gaozi, Shima, and Jianbi complexes. Geochemical investigations show that these five intrusive complexes exhibit high contents of SiO_2, at 64.74–73.40 wt%, Al_2O_3, at 14.15–17.37 wt%, and K_2O + Na_2O, at 6.49–8.68 wt%. The majority of the samples belong to the high-K calc-alkaline series, with a few samples plotting in the calc-alkaline and tholeiitic series. Trace element analysis shows that the samples are enriched in large ion lithophile elements(LILE) and are depleted in high field strength elements(HFSE).The chondrite-normalized rare earth element(REE) patterns are characterized by right-inclined curves, showing light rare earth element(LREE) enrichment. In addition,the(La/Yb)Nratios are high at 15.02–37.28, with an average of 29.13, and slightly negative or none Eu anomalies are present. In the(La/Yb)N–d Eu diagram, the samples plot within the crust-mantle type field. Laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) zircon U–Pb dating yielded ages of122.0 ± 1.0 Ma, 106.1 ± 0.8 Ma, 108.7 ± 1.4 Ma,103.5 ± 1.9 Ma, and 96.8 ± 1.7 Ma for the Qilinmen,Anjishan, Xiashu–Gaozi, Shima, and Jianbi complexes,respectively. On the basis of this research and knowledge of several known metal deposits related to these complexes, we suggest that the Mesozoic large-scale diagenesis and metallogenesis in the Ningzhen region may have ceased at 100 Ma or about 95 Ma.展开更多
Sulphide inclusions, which represent melts trapped in the minerals of magmatic rocks and xenoliths, provide important clues to the behaviour of immiscible sulphide liquids during the evolution of magmas and the format...Sulphide inclusions, which represent melts trapped in the minerals of magmatic rocks and xenoliths, provide important clues to the behaviour of immiscible sulphide liquids during the evolution of magmas and the formation of NieCueFe deposits. We describe sulphide inclusions from unique ultramafic clots within mafic xenoliths, from the mafic xenoliths themselves, and from the three silica-rich host plutons in Tongling, China. For the first time, we are able to propose a general framework model for the evolution of sulphide melts during the evolution of mafic to felsic magmas from the upper mantle to the upper crust. The model improves our understanding of the sulphide melt evolution in upper mantle to upper crust magmas, and provides insight into the formation of stratabound skarn-type FeeCu polymetallic deposits associated with felsic magmatism, thus promising to play an important role during prospecting for such deposits.展开更多
As an active back-arc basin, the Okinawa Trough is located in the southeastern region of the East China Sea shelf and is strongly influenced by the subduction of the Philippine Sea Plate. Major element, trace element ...As an active back-arc basin, the Okinawa Trough is located in the southeastern region of the East China Sea shelf and is strongly influenced by the subduction of the Philippine Sea Plate. Major element, trace element and Sr-NdPb isotopic composition data are presented for volcanic rocks from the Iheya Ridge（IR）, the middle Okinawa Trough. The IR rocks record large variations in major elements and range from basalts to rhyolites. Similar trace element distribution characteristics together with small variations in ^87Sr/^86Sr（0.703 862–0.704 884）, ^144Nd/^143Nd（0.512 763–0.512 880） and Pb isotopic ratios, demonstrate that the IR rocks are derived from a similar magma source. The fractional crystallization of olivine, clinopyroxene, plagioclase, and amphibole, as well as accessory minerals, can reasonably explain the compositional variations of these IR rocks. The simulations suggest that approximately 60% and 75% fractionation of an evolved basaltic magma can produce trace element compositions similar to those of the intermediate rocks and acid rocks, respectively. The analysis of their Sr-Nd-Pb isotopic content ratios suggest that the source of the rocks from the IR is close to the depleted mantle（DM） but extends to the enriched mantle（EMII）, indicating that the mantle source of these rocks is a mixture between the DM and EMII end members. The simulations show that the source of the IR volcanic rocks can be best interpreted as the result of the mixing of approximately 0.8%–2.0% subduction sediment components and 98.0%–99.2% mantlederived melts.展开更多
The copper deposits in the mid-lower reaches of the Changjiang River consist mainly of porphyry, skarn and massive sulphide deposits. According to the geological background, the types of ore deposits and the mineraliz...The copper deposits in the mid-lower reaches of the Changjiang River consist mainly of porphyry, skarn and massive sulphide deposits. According to the geological background, the types of ore deposits and the mineralization, the metallogenic model of the copper deposits is discussed. It is pointed out that the ore-forming hydrother-mal fluids came mainly from magmatic water and were related to the intermediate-acid intrusions, and that the formation of skarn and massive sulphide deposits coincided with the mineralization of porphyry deposits.展开更多
A new genetic type of deposits, intrusive massive sulphide deposits, is found to be genetically linked with intermediate-acid intrusive rocks. Copper is the main industrial element, and gold is also important and can ...A new genetic type of deposits, intrusive massive sulphide deposits, is found to be genetically linked with intermediate-acid intrusive rocks. Copper is the main industrial element, and gold is also important and can sometimes make up single gold deposits. This type of massive sulphide deposits is widely distributed in middle-lower reaches of the Yangtze River. The famous mines are Wushan, Chengmenshan and Dingjiashan in Jiangxi Province, Xinqiao and Dongguashan in Anhui Province. The deposits are mostly hosted in展开更多
文摘CO<sub>2</sub>-RICH fluid inclusions have been found in 6 anhydrous peridotite xenolith minerals in Ceno-zoic basalts of 5 areas in East China.Electron probe backscattering electron image reveals thatseveral inclusions appear in all the rock sections,completely filled with glass or with cavities attheir center part（CO<sub>2</sub> has escaped）.Some inclusions show devitrification and daughter miner-als appear.We have carried out the analysis on the non-devitrification glass in the inclusions.
基金Supported by the the National Natural Science Foundation of China(U24B2017)。
文摘The Mesozoic volcanic rocks of the Bodong Low Uplift in the Bohai Bay Basin have been studied and explored for years.In 2024,the LK7-A well drilled in this region tested high-yield oil and gas flows from volcanic weathered crust.These volcanic rocks need to be further investigated in terms of distribution patterns,conditions for forming high-quality reservoirs,and main factors controlling hydrocarbon accumulation.Based on the logging,geochemical and mineralogical data from wells newly drilled to the Mesozoic volcanic rocks in the basin,and high-resolution 3D seismic data,a comprehensive study was conducted for this area.The research findings are as follows.First,the volcanic rocks in the LK7-A structure are adakites with a large source area depth,and the deep and large faults have provided channels for the emplacement of intermediate-acidic volcanic rocks.Second,volcanic rock reservoirs are mainly distributed in tectonic breccias and intermediate-acidic lavas,and they are dominantly fractured-porous reservoirs,with high-porosity and low-permeability or medium-porosity and low-permeability.Third,the dominant lithologies/lithofacies is the basic condition for forming large-scale volcanic rock reservoirs.Structural fractures and late-stage strong weathering are crucial mechanisms for the formation scale of reservoirs in the Mesozoic volcanic rocks.Fourth,the Bodong Low Uplift exhibits strong hydrocarbon charging by two sags and overpressure mudstone capping,which are favorable for forming high-abundance oil and gas reservoirs.The Mesozoic volcanic buried hills in the study area reflect good trap geometry,providing favorable conditions for large-scale reservoir formation,and also excellent migration and accumulation conditions.Areas with long-term exposure of intermediate-acidic volcanic rocks,particularly in active structural regions,are the key targets for future exploration.
基金financially supported by the Major State Basic Research Development Program of China(973 Program)(No.2014CB440906)
文摘The Ningzhen region of China is located in the easternmost part of the middle-lower Yangtze River Cu–Fe polymetallic metallogenic belt. From west to east, it comprises five main intermediate–acidic intrusive complexes: the Qilinmen, Anjishan, Xiashu–Gaozi, Shima, and Jianbi complexes. Geochemical investigations show that these five intrusive complexes exhibit high contents of SiO_2, at 64.74–73.40 wt%, Al_2O_3, at 14.15–17.37 wt%, and K_2O + Na_2O, at 6.49–8.68 wt%. The majority of the samples belong to the high-K calc-alkaline series, with a few samples plotting in the calc-alkaline and tholeiitic series. Trace element analysis shows that the samples are enriched in large ion lithophile elements(LILE) and are depleted in high field strength elements(HFSE).The chondrite-normalized rare earth element(REE) patterns are characterized by right-inclined curves, showing light rare earth element(LREE) enrichment. In addition,the(La/Yb)Nratios are high at 15.02–37.28, with an average of 29.13, and slightly negative or none Eu anomalies are present. In the(La/Yb)N–d Eu diagram, the samples plot within the crust-mantle type field. Laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) zircon U–Pb dating yielded ages of122.0 ± 1.0 Ma, 106.1 ± 0.8 Ma, 108.7 ± 1.4 Ma,103.5 ± 1.9 Ma, and 96.8 ± 1.7 Ma for the Qilinmen,Anjishan, Xiashu–Gaozi, Shima, and Jianbi complexes,respectively. On the basis of this research and knowledge of several known metal deposits related to these complexes, we suggest that the Mesozoic large-scale diagenesis and metallogenesis in the Ningzhen region may have ceased at 100 Ma or about 95 Ma.
基金financially supported by the China Geological Survey (Grant No. 12120113069900)the National Natural Science Foundation of China (Grant No. 40672045)
文摘Sulphide inclusions, which represent melts trapped in the minerals of magmatic rocks and xenoliths, provide important clues to the behaviour of immiscible sulphide liquids during the evolution of magmas and the formation of NieCueFe deposits. We describe sulphide inclusions from unique ultramafic clots within mafic xenoliths, from the mafic xenoliths themselves, and from the three silica-rich host plutons in Tongling, China. For the first time, we are able to propose a general framework model for the evolution of sulphide melts during the evolution of mafic to felsic magmas from the upper mantle to the upper crust. The model improves our understanding of the sulphide melt evolution in upper mantle to upper crust magmas, and provides insight into the formation of stratabound skarn-type FeeCu polymetallic deposits associated with felsic magmatism, thus promising to play an important role during prospecting for such deposits.
基金The National Basic Research Program(973 Program)of China under contract No.2013CB429700the National Natural Science Foundation of China under contract Nos 41325021 and 41706052+9 种基金the National Program on Global Change and AirSea Interaction under contract No.GASI-GEOGE-02the Strategic Priority Research Program of the Chinese Academy of Sciences under contract No.XDA11030302the Special Fund for the Taishan Scholar Program of Shandong Province under contract No.ts201511061the AoShan Talents Program supported by Qingdao National Laboratory for Marine Science and Technology under contract No.2015ASTP-0S17the Innovative Talent Promotion Program under contract No.2012RA2191the Science and Technology Development Program of Shandong Province under contract No.2013GRC31502the Scientific and Technological Innovation Project Financially supported by Qingdao National Laboratory for Marine Science and Technology under contract Nos 2015ASKJ03 and2016ASKJ13the National High Level Talent Special Support Programthe CAS/SAFEA International Partnership Program for Creative Research TeamsQingdao Collaborative Innovation Center of Marine Science and Technology
文摘As an active back-arc basin, the Okinawa Trough is located in the southeastern region of the East China Sea shelf and is strongly influenced by the subduction of the Philippine Sea Plate. Major element, trace element and Sr-NdPb isotopic composition data are presented for volcanic rocks from the Iheya Ridge（IR）, the middle Okinawa Trough. The IR rocks record large variations in major elements and range from basalts to rhyolites. Similar trace element distribution characteristics together with small variations in ^87Sr/^86Sr（0.703 862–0.704 884）, ^144Nd/^143Nd（0.512 763–0.512 880） and Pb isotopic ratios, demonstrate that the IR rocks are derived from a similar magma source. The fractional crystallization of olivine, clinopyroxene, plagioclase, and amphibole, as well as accessory minerals, can reasonably explain the compositional variations of these IR rocks. The simulations suggest that approximately 60% and 75% fractionation of an evolved basaltic magma can produce trace element compositions similar to those of the intermediate rocks and acid rocks, respectively. The analysis of their Sr-Nd-Pb isotopic content ratios suggest that the source of the rocks from the IR is close to the depleted mantle（DM） but extends to the enriched mantle（EMII）, indicating that the mantle source of these rocks is a mixture between the DM and EMII end members. The simulations show that the source of the IR volcanic rocks can be best interpreted as the result of the mixing of approximately 0.8%–2.0% subduction sediment components and 98.0%–99.2% mantlederived melts.
基金Project supported by the Doctorate Foundation of the State Education Commission of China
文摘The copper deposits in the mid-lower reaches of the Changjiang River consist mainly of porphyry, skarn and massive sulphide deposits. According to the geological background, the types of ore deposits and the mineralization, the metallogenic model of the copper deposits is discussed. It is pointed out that the ore-forming hydrother-mal fluids came mainly from magmatic water and were related to the intermediate-acid intrusions, and that the formation of skarn and massive sulphide deposits coincided with the mineralization of porphyry deposits.
文摘A new genetic type of deposits, intrusive massive sulphide deposits, is found to be genetically linked with intermediate-acid intrusive rocks. Copper is the main industrial element, and gold is also important and can sometimes make up single gold deposits. This type of massive sulphide deposits is widely distributed in middle-lower reaches of the Yangtze River. The famous mines are Wushan, Chengmenshan and Dingjiashan in Jiangxi Province, Xinqiao and Dongguashan in Anhui Province. The deposits are mostly hosted in
