Driven by the trend of device miniaturization and high-density integration,the interaction between adjacent electrodes has become a critical factor affecting the interfacial reliability of thermoelectric(TE)structures...Driven by the trend of device miniaturization and high-density integration,the interaction between adjacent electrodes has become a critical factor affecting the interfacial reliability of thermoelectric(TE)structures.This study investigates the influence of adjoining electrode interactions on the interfacial response of a multi-electrode/TE substrate structure,including interfacial stresses and stress intensity factors at the electrode ends.To solve the corresponding boundary-value problem,the Fourier transforms are adopted to derive a governing integro-differential equation for the interfacial shear stress in multi-electrode systems,incorporating the TE effects as generalized forces on the right-hand side.The results show that both the interfacial tension and transverse stress in the electrodes are significantly affected by the presence of adjacent electrodes.The interaction between neighboring electrodes diminishes as their spacing increases or when an adhesive interlayer is introduced.Furthermore,the softer and thinner electrodes,the softer and thicker adhesive interlayer,and the smaller TE loads are found to be beneficial for improving the interfacial performance.These findings may contribute to the accurate measurement in surface sensors and layout design of multi-point health monitoring systems for TE structures.展开更多
Lithium metal batteries(LMBs)have attracted huge attention due to super-high capacity and low reduction potential of lithium anode constructing high-energy/power density.However,the practical application of LMBs is si...Lithium metal batteries(LMBs)have attracted huge attention due to super-high capacity and low reduction potential of lithium anode constructing high-energy/power density.However,the practical application of LMBs is significantly constrained by lithium dendrite growth and high reactivity of lithium anode.Herein,a novel functionalized interlayer that SbF3 is tandem on HKUST-1 skeleton forming favorable Sb-terminated groups structure(HKSF@PE),which were proposed and fabricated to construct highly stable LMBs.Theoretical calculations demonstrate that the Sb-terminated groups structure in this configuration display strong interaction with lithium,which can act as a cation receptor and adsorption sites,thereby promoting lithium-ion desolvation and improving lithium-ion transport kinetics.Meanwhile,in-situ XRD,Raman,and DRT analyses indicate that the HKSF assist the formation of LiF-rich and lithiophilic Li3Sb alloys at SEI/Li interface,regulating lithium depo-sition morphology and reconstructing a reinforced SEI interlayer.Consequently,Li|HKSF@PE|Li symmetric cell exhibits exceptional stability over 2500 h at 2 mA cm^(-2) with 1 mAh cm^(-2),and Li|HKSF@PE|LFP full cell demonstrates a high-capacity retention of 92.0%after 220 cycles even at a high rate of 5C.This work reveals the important role of terminated groups to achieve homogeneous lithium deposition and provide a way to construct stable LMBs.展开更多
A thorny problem in the miscible Ti/Fe system is the unavoidable formation of numerous brittle intermetallic compounds(IMCs).Adding H62 interlayer is an essential method to reduce the brittle IMCs or decrease the brit...A thorny problem in the miscible Ti/Fe system is the unavoidable formation of numerous brittle intermetallic compounds(IMCs).Adding H62 interlayer is an essential method to reduce the brittle IMCs or decrease the brittleness.A joint with good formability and tensile properties was obtained.The microstructure and element distribution of the joint were observed by metallographic microscopy,scanning electron microscopy and electron probe microanalysis.The shear resistance exhibited an initial increase,followed by a subsequent decrease,with an increase in heat input.It reached a maximum value of 2470 N at a welding energy of 267 kJ/m.The Fe-Ti brittle IMCs in TC4/DP780 joints are replaced by Fe-Cu phase and Cu-Ti phase,which reduces the brittleness at TC4/DP780 interface.The results show that the TC4/DP780 joint forms numerousα-Cu andγ-Fe solid solutions through the mutual diffusion and solid solution between H62 and TC4 layers of metals,which effectively inhibits the diffusion of Ti atoms and reduces the formation of brittle Ti-Fe IMCs.At the H62/TC4 interface,a composite layer composed of Cu-Ti IMCs and Cu-based solid solutions is formed.The composite layer grows dendritically from the TC4 alloy to the H62 interlayer.The microstructure at the TC4/DP780 interface changes from fine dendrites to coarse dendrites with the increase in Ti content and heat input.When the heat input is lower,the interfacial elements do not react sufficiently.When the heat input is excessive,microcracks appear at the TC4/DP780 interface,which limits the improvement of mechanical properties of TC4/DP780 joint.展开更多
Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling ...Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.展开更多
Regulating interlayer distance is a crucial factor in the development of two‐dimensional(2D)nanomaterials.A 2D metal‐free photocatalyst,such as graphitic carbon nitride(g‐C3N4),exhibits morphology‐and microstruct...Regulating interlayer distance is a crucial factor in the development of two‐dimensional(2D)nanomaterials.A 2D metal‐free photocatalyst,such as graphitic carbon nitride(g‐C3N4),exhibits morphology‐and microstructure‐dependent photocatalytic activity.Herein,we report a straightforward and facile route for the preparation of unique lamellar g‐C3N4,by co‐firing melamine and ammonium chloride via microwave‐assisted heating.Through the decomposition of NH4Cl,the evaporation of NH3 gas can effectively overcome van der Waals forces,expanding the interlayer distance of g‐C3N4,thereby creating a lamellar structure consisting of nanosheets.Compared with bulk g‐C3N4,the NH3‐derived lamellar g‐C3N4 exhibits a larger specific surface area and enhanced optical absorption capability,which increase photocatalytic hydrogen production because of the highly active structure,excellent utilization efficiency of photon energy,and low recombination efficiency of photogenerated charge carriers.This study provides a simple strategy for the regulation of the g‐C3N4 microstructure toward highly efficient photocatalytic applications.展开更多
Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SO...Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SOECs with Zr-rich electrolyte,called Zr-rich side P-SOECs,possess high thermodynamically stability under high steam concentrations but the large reaction resistances and the current leakage,thus the inferior performances.In this study,an efficient functional interlayer Ba_(0.95)La_(0.05)Fe_(0.8)Zn_(0.2)O_(3-δ)(BLFZ)in-between the anode and the electrolyte is developed.The electrochemical performances of P-SOECs are greatly enhanced because the BLFZ can greatly increase the interface contact,boost anode reaction kinetics,and increase proton injection into electrolyte.As a result,the P-SOEC yields high current density of 0.83 A cm^(-2) at 600℃ in 1.3 Vamong all the reported Zr-rich side cells.This work not only offers an efficient functional interlayer for P-SOECs but also holds the potential to achieve P-SOECs with high performances and long-term stability.展开更多
The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized.However,challenges remain in terms of low thermal efficiency and high carbon ...The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized.However,challenges remain in terms of low thermal efficiency and high carbon emissions in reservoirs with interlayers.Currently,there is limited research on the low-carbon strategy of coupling exhaust gas from steam boilers with the VH-SAGD technique.Herein,considering heterogeneity,a series of flue gas-assisted VH-SAGD experiments were conducted employing a high-performance 2D visualization model.The mechanism of enhanced recovery of flue gas in VH-SAGD and the effect of its injection methods were studied,with a focus on steam chamber development and oil saturation distribution.Crucially,the interlayer length was optimized to enhance oil recovery,providing a new perspective for well location design in heavy oil reservoirs with interlayers.The results showed that flue gas,as an additive,could fully exploit the well-type advantage of VH-SAGD.By supplementing energy at the reservoir top,flue gas effectively promoted steam chamber development,expanded the oil drainage area of VH-SAGD,and increased the oil recovery from 58.9%to 71.7%.The flow channels formed by pre-injection flue gas accelerated the early-stage expansion of the steam chamber while also inducing lateral migration of steam,slowing steam rise,and consequently increasing the heating range within the low-permeability layer.When the distance between the vertical and horizontal wells was set to twice the interlayer length,the negative effects of the interlayer were more effectively turned into advantages.Because when the lateral development distance of the steam chamber in the low-permeability layer slightly exceeds the interlayer,enhanced heating of the lower part of the reservoir occurred through vertical convection of rising steam and returning condensate.The research results contribute to reducing carbon emissions from steam-based heavy oil extraction while advancing the maturity of VH-SAGD.展开更多
Regulating lithium(Li)plating/stripping behavior in three-dimensional(3D)conductive scaffolds is critical to stabilizing Li metal batteries(LMBs).Surface protrusions and roughness in these scaffolds can induce uneven ...Regulating lithium(Li)plating/stripping behavior in three-dimensional(3D)conductive scaffolds is critical to stabilizing Li metal batteries(LMBs).Surface protrusions and roughness in these scaffolds can induce uneven distributions of the electric fields and ionic concentrations,forming“hot spots.”Hot spots may cause uncontrollable Li dendrites growth,presenting significant challenges to the cycle stability and safety of LMBs.To address these issues,we construct a Li ionic conductive-dielectric gradient bifunctional interlayer(ICDL)onto a 3D Li-injected graphene/carbon nanotube scaffold(LGCF)via in situ reaction of exfoliated hexagonal boron nitride(fhBN)and molten Li.Microscopic and spectroscopic analyses reveal that ICDL consists of fhBN-rich outer layer and inner layer enriched with Li_(3)N and Li-boron composites(Li-B).The outer layer utilizes dielectric properties to effectively homogenize the electric field,while the inner layer ensures high Li ion conductivity.Moreover,DFT calculations indicate that ICDL can effectively adsorb Li and decrease the Li diffusion barrier,promoting enhanced Li ion transport.The modulation of Li kinetics by ICDL increases the critical length of the Li nucleus,enabling suppression of Li dendrite growth.Attributing to these advantages,the ICDL-coated LGCF(ICDL@LGCF)demonstrates impressive long-term cycle performances in both symmetric cells and full cells.展开更多
As artificial intelligence and big data become increasingly prevalent, resistive random-access memory (RRAM) has become one of the most promising alternatives for storing massive amounts of data. In this study, we emp...As artificial intelligence and big data become increasingly prevalent, resistive random-access memory (RRAM) has become one of the most promising alternatives for storing massive amounts of data. In this study, we employed high-quality crystalline TiN/Al_(2)O_(3)/BaTiO_(3)/Pt RRAM with an optimized thin Al_(2)O_(3) interlayer around 12 nm thick prepared using atomic layer deposition since the thickness of the interlayer affects the memory window size. After insertion of the Al_(2)O_(3) interlayer, the novel RRAM exhibited outstanding uniform resistive switching voltage and the ON/OFF memory window drastically increased from 10 to 103 without any discernible decline in performance. Moreover, the low-resistance state and high-resistance state operating current values decreased by almost one order and three orders of magnitude, respectively, thereby decreasing the power consumption for the RESET and SET processes by more than three and almost one order of magnitude, respectively. The device also exhibits multilevel resistive switching behavior when varying the applied voltage. Finally, we also developed a 6 6 crossbar array which demonstrated consistent and reliable resistive switching behavior with minimal variation. Hence, our approach holds great promise for producing state-of-the-art non-volatile resistive switching devices.展开更多
A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface...A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.展开更多
Due to its unique layered structure and excellent electrochemical properties,molybdenum disulfide(MoS_(2))demonstrates significant potential for applications in the energy storage field,particularly in supercapacitors...Due to its unique layered structure and excellent electrochemical properties,molybdenum disulfide(MoS_(2))demonstrates significant potential for applications in the energy storage field,particularly in supercapacitors.It is widely regarded as one of the most representative transition metal dichalcogenides.MoS_(2)possesses a high theoretical specific capacitance,abundant edge active sites,and favorable tunability and structural diversity,which provide it with a distinct advantage in the construction of advanced electrode structures.Additionally,the anisotropic characteristics of MoS_(2)concerning electron and ion transport offer more dimensions for regulating its electrochemical behavior.This work will systematically review various synthesis strategies for MoS_(2)and its recent advancements in energy storage,with a particular focus on the mechanisms by which interlayer spacing modulation affects energy storage behavior in supercapacitor configurations.The discussion will encompass a comprehensive logical framework that spans material structure modifications,electronic configuration evolution,and enhancements in macroscopic device performance.This review aims to provide theoretical support and practical guidance for the application of MoS_(2)in the next generation of highperformance energy storage devices.展开更多
The transient liquid-phase(TLP)diffusion bonding of GH5188 with a BNi-5 interlayer was focused on.Parameters were chosen and optimized for GH5188 alloy according to the TLP joining mechanism.The microstructure evoluti...The transient liquid-phase(TLP)diffusion bonding of GH5188 with a BNi-5 interlayer was focused on.Parameters were chosen and optimized for GH5188 alloy according to the TLP joining mechanism.The microstructure evolution and mechanical properties of the joints were studied.Results show that the relatively complete isothermal solidification zone(ISZ)ensures a reliable connection of the base metal(BM).Within the temperature range of 1110–1190°C,higher bonding temperatures can widen ISZ and promote joint composition homogenization,thus improving mechanical properties.However,the increase in precipitated phase has an adverse effect on the mechanical properties of the joint.The maximum shear strength,reaching 482 MPa,is achieved at 1130°C,representing 84.6%of BM strength.Within the pressure range of 5–15 MPa,both precipitated phases in adiabatic solidification zone(ASZ)and voids generated by partial melting increase.On the contrary,their sizes decrease significantly under higher bonding pressure,resulting in an upward trend in alloy mechanical properties.The maximum shear strength of 490 MPa is attained at a bonding pressure of 15 MPa.The joint exhibits a typical mixed fracture pattern,with the small brittle M_(23)C_(6) phase and voids significantly impacting mechanical properties.Nano-indentation tests indicate that ASZ is a potential source of cracks.展开更多
Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic ...Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic antiferromagnets and synthetic ferromagnets.The antiferromagnetic and ferromagnetic coupling states are precisely engineered through Ruderman-Kittel-Kasuya-Yosida(RKKY)interactions by modulating the Ir spacer thickness.Experimental results reveal that the critical switching current density exhibits a strong positive correlation with the IEC strength,regardless of the coupling type.A comprehensive theoretical framework based on the Landau-Lifshitz-Gilbert equation elucidates how IEC contributes to the effective energy barrier that must be overcome during SOT-induced magnetization switching.Significantly,the antiferromagnetically coupled samples demonstrate enhanced SOT efficiency,with the spin Hall angle being directly proportional to the antiferromagnetic exchange coupling field.These insights establish a coherent physical paradigm for understanding IEC-dependent SOT dynamics and provide strategic design principles for the development of energy-efficient next-generation spintronic devices.展开更多
Surface adsorption plays a crucial role in various natural and industrial processes,particularly in the field of energy storage.The adsorption of sodium atoms on 2D layered materials can significantly impact their per...Surface adsorption plays a crucial role in various natural and industrial processes,particularly in the field of energy storage.The adsorption of sodium atoms on 2D layered materials can significantly impact their performance as carriers and electrodes in ion batteries.While it is commonly acknowledged that pristine graphene is not favorable for sodium ion adsorption,the suitability of other 2D materials with similar honeycomb symmetry remains unclear.In this study,we employ systematic first-principles calculations to explore interlayer interactions and electron transfer effects on sodium adsorption on 2D van der Waals(vdW)heterostructures(HTSs)surfaces.Our results demonstrate that sodium adsorption is energetically favorable on these substrates.Moreover,we find that the adsorption strength can be effectively tuned by manipulation of the electron accumulation or depletion of the layer directly interacting with the sodium atom.By stacking these layered materials with different electron abundancy to form vd W HTSs,the charge density of the substrate becomes tunable through interlayer charge transfer.In these vdW HTSs,the adsorption behavior of sodium is primarily controlled by the absorption layer and exhibits a linear correlation with its pz-band center.Additionally,we identify linear correlations between the sodium adsorption energies,the electron loss of the sodium atom,the interlayer charge transfer,and the heights of the adsorbed sodium atom.These discoveries underscore the impact of interlayer electron transfer and interactions on sodium ion adsorption on 2D vd W HTSs and providing new insights into material design for alkali atom adsorption.展开更多
An imbalanced dataset often challenges machine learning, particularly classification methods. Underrepresented minority classes can result in biased and inaccurate models. The Synthetic Minority Over-Sampling Techniqu...An imbalanced dataset often challenges machine learning, particularly classification methods. Underrepresented minority classes can result in biased and inaccurate models. The Synthetic Minority Over-Sampling Technique (SMOTE) was developed to address the problem of imbalanced data. Over time, several weaknesses of the SMOTE method have been identified in generating synthetic minority class data, such as overlapping, noise, and small disjuncts. However, these studies generally focus on only one of SMOTE’s weaknesses: noise or overlapping. Therefore, this study addresses both issues simultaneously by tackling noise and overlapping in SMOTE-generated data. This study proposes a combined approach of filtering, clustering, and distance modification to reduce noise and overlapping produced by SMOTE. Filtering removes minority class data (noise) located in majority class regions, with the k-nn method applied for filtering. The use of Noise Reduction (NR), which removes data that is considered noise before applying SMOTE, has a positive impact in overcoming data imbalance. Clustering establishes decision boundaries by partitioning data into clusters, allowing SMOTE with modified distance metrics to generate minority class data within each cluster. This SMOTE clustering and distance modification approach aims to minimize overlap in synthetic minority data that could introduce noise. The proposed method is called “NR-Clustering SMOTE,” which has several stages in balancing data: (1) filtering by removing minority classes close to majority classes (data noise) using the k-nn method;(2) clustering data using K-means aims to establish decision boundaries by partitioning data into several clusters;(3) applying SMOTE oversampling with Manhattan distance within each cluster. Test results indicate that the proposed NR-Clustering SMOTE method achieves the best performance across all evaluation metrics for classification methods such as Random Forest, SVM, and Naїve Bayes, compared to the original data and traditional SMOTE. The proposed method (NR-Clustering SMOTE) improves accuracy by 15.34% on the Pima dataset and 20.96% on the Haberman dataset compared to SMOTE-LOF. Compared to Radius-SMOTE, this method increases accuracy by 3.16% on the Pima dataset and 13.24% on the Haberman dataset. Meanwhile, compared to RN-SMOTE, the accuracy improvement reaches 15.56% on the Pima dataset and 19.84% on the Haberman dataset. This research result implies that the proposed method experiences consistent performance improvement compared to traditional SMOTE and its latest variants, such as SMOTE-LOF, Radius-SMOTE, and RN-SMOTE, in solving imbalanced health data with class binaries.展开更多
Biodiversity has always been valued by ecology,Diversity is generally believed to lead to stability,and biodiversity is an important condition for ecosystems to maintain health.So what factors are related to forest ec...Biodiversity has always been valued by ecology,Diversity is generally believed to lead to stability,and biodiversity is an important condition for ecosystems to maintain health.So what factors are related to forest ecosystem biodiversity,and what kind of forest structure affects and determines the size of biodiversity.This study proposes the concept of contained uniformity based on the theory of uniformity,and uses the convergence of contained uniformity to obtain the judgment model of the forest station pattern type.At the same time,it proposes the concept of forest ecosystem distance diversity,and uses the judgment model of the stand pattern type to derive the mathematical definition of forest ecosystem distance diversity.Combining the ecological characteristics of different stand patterns and measurement indicators of forest ecosystem biodiversity,the connection between forest ecosystem distance diversity and biodiversity is derived,and this is used as an indicator to evaluate forest ecosystem biodiversity.Forest ecosystem distance diversity,as an indicator of biodiversity,can not only conduct early assessment and prediction of the biodiversity of immature forests(forests in the early succession or recovery stage),but also provide a quantitative basis for forest structure optimization.Ultimately realize the sustainable development of forestry production and operation and biodiversity protection.展开更多
In moiré-patterned van der Waals structures of transition metal dichalcogenides,correlated insulators can form under integer and fractional fillings,whose transport properties are governed by various quasiparticl...In moiré-patterned van der Waals structures of transition metal dichalcogenides,correlated insulators can form under integer and fractional fillings,whose transport properties are governed by various quasiparticle excitations including holons,doublons and interlayer exciton insulators.Here we theoretically investigate the nearest-neighbor inter-site hoppings of holons and interlayer exciton insulators.Our analysis indicates that these hopping strengths are significantly enhanced compared to that of a single carrier.The underlying mechanism can be attributed to the strong Coulomb interaction between carriers at different sites.For the interlayer exciton insulator consisting of a holon and a carrier in different layers,we have also obtained its effective Bohr radius and energy splitting between the ground and the first-excited states.展开更多
Buried coastal sandstones would be of high-quality hydrocarbon reservoirs.Controlled by deposition and diagenesis,coastal sandstones mixed with muddy and calcareous materials are usually low in porosity and permeabili...Buried coastal sandstones would be of high-quality hydrocarbon reservoirs.Controlled by deposition and diagenesis,coastal sandstones mixed with muddy and calcareous materials are usually low in porosity and permeability and small in layer thickness.These impermeable inte rlayers act as baffles and barriers between flow units and are crucial in hydrocarbon development.Donghe Sandstone in the Hade Oilfield of Tarim Basin,NW China,belongs to coastal clastic reservoirs of high oil productivity.Following nearly 30 years of development,the distribution of remaining hydrocarbon resources is affected by the muddy,calcareous,and marlaceous interlayers.Taking the Donghe Sandstone as an example,a quantitative recognition method of interlayers in coastal sandstone reservoirs is proposed in this paper.Based on cores from 26 wells,the sensitive conventional log curves of different interlayers,namely the natural gamma-ray(GR),density(DEN),compensated neutron(CNL),and acoustic(AC),are extracted by the Extreme Gradient Boosting(XGBoost).Multi-mineral model(MMM)is used to calculate continuous curves for muddy,sandy,and calcareous contents by the mentioned sensitive logs.A set of quantitative standard system is established for identifying muddy,calcareous,and marlaceous interlayers based on their respective contents.The types of inte rlayers are identified across all vertical wells.The interlayers exhibit lateral continuity at the top of each bed-set.Interlayers are currently more developed in the slope region than in the coastal region.Muddy and marlaceous interlayers are more developed at high relative sea-level,while calcareous interlayers are more developed at low relative sea-level.The extended interlayers at the top of BS6 lead to two different oil-water contacts in the Donghe Sandstone.The proposed quantitative recognition method for interlayers provides valuable insights into the exploitation potential of petroleum systems in the Donghe Sandstone of the Hade Oilfield.The flexible and easy-to-use method can be applied to other marine sandstone reservoirs or similar formations.展开更多
With the ever-increasing energy density requirements for sulfide-based all-solid-state batteries,lithium metal is regarded as an ideal candidate for anode materials.However,the dynamic degradation of solidsolid contac...With the ever-increasing energy density requirements for sulfide-based all-solid-state batteries,lithium metal is regarded as an ideal candidate for anode materials.However,the dynamic degradation of solidsolid contact between lithium anode and solid electrolyte remains a major challenge for the application of all-solid-state lithium metal batteries(ASSLMBs).The poor solid-solid contact problem is caused by the continuous accumulation of lithium voids,which results from the limited diffusion rate of lithium in the bulk phase.In this study,we design a three-dimensional(3D)lithiophilic graphitized carbon nanotubebased(LNT)interlayer to address interfacial issues.The interlayers effectively regulate lithium stripping and suppress the growth of lithium voids via improved lithium diffusion,leading to a conformal interface during continuous cycling.The lithium metal anode with the interlayer delivers an areal capacity of 12.96 mA h cm^(-2),and when paired with a LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2)(NCM9)cathode,the battery retains over 91%capacity retention after 100 cycles at room temperature.This work provides an effective strategy for interface stabilization in high-capacity and long-life ASSLMBs.展开更多
基金Project supported by the National Natural Science Foundation of China(Nos.12502117,12272269,11972257)the Natural Science Foundation of Ningxia of China(No.2024AAC03018)+1 种基金the Fundamental Research Funds for the Central Universitiesthe Shanghai Gaofeng Project for University Academic Program Development。
文摘Driven by the trend of device miniaturization and high-density integration,the interaction between adjacent electrodes has become a critical factor affecting the interfacial reliability of thermoelectric(TE)structures.This study investigates the influence of adjoining electrode interactions on the interfacial response of a multi-electrode/TE substrate structure,including interfacial stresses and stress intensity factors at the electrode ends.To solve the corresponding boundary-value problem,the Fourier transforms are adopted to derive a governing integro-differential equation for the interfacial shear stress in multi-electrode systems,incorporating the TE effects as generalized forces on the right-hand side.The results show that both the interfacial tension and transverse stress in the electrodes are significantly affected by the presence of adjacent electrodes.The interaction between neighboring electrodes diminishes as their spacing increases or when an adhesive interlayer is introduced.Furthermore,the softer and thinner electrodes,the softer and thicker adhesive interlayer,and the smaller TE loads are found to be beneficial for improving the interfacial performance.These findings may contribute to the accurate measurement in surface sensors and layout design of multi-point health monitoring systems for TE structures.
基金supported by National Natural Science Foundation of China(52372180,92572105)The Natural Science Foundation of Jiangsu Province(BK20250069)+3 种基金Project on Carbon Emission Peak and Neutrality of Jiangsu Province(BE2022031-4)the Fundamental Research Funds for the Central Universities(2242022K40001)The Start-up Research Fund of Southeast University(RF1028623081)Natural Science Foundation of Chongqing(CSTB2025NSCQ-GPX0662).
文摘Lithium metal batteries(LMBs)have attracted huge attention due to super-high capacity and low reduction potential of lithium anode constructing high-energy/power density.However,the practical application of LMBs is significantly constrained by lithium dendrite growth and high reactivity of lithium anode.Herein,a novel functionalized interlayer that SbF3 is tandem on HKUST-1 skeleton forming favorable Sb-terminated groups structure(HKSF@PE),which were proposed and fabricated to construct highly stable LMBs.Theoretical calculations demonstrate that the Sb-terminated groups structure in this configuration display strong interaction with lithium,which can act as a cation receptor and adsorption sites,thereby promoting lithium-ion desolvation and improving lithium-ion transport kinetics.Meanwhile,in-situ XRD,Raman,and DRT analyses indicate that the HKSF assist the formation of LiF-rich and lithiophilic Li3Sb alloys at SEI/Li interface,regulating lithium depo-sition morphology and reconstructing a reinforced SEI interlayer.Consequently,Li|HKSF@PE|Li symmetric cell exhibits exceptional stability over 2500 h at 2 mA cm^(-2) with 1 mAh cm^(-2),and Li|HKSF@PE|LFP full cell demonstrates a high-capacity retention of 92.0%after 220 cycles even at a high rate of 5C.This work reveals the important role of terminated groups to achieve homogeneous lithium deposition and provide a way to construct stable LMBs.
基金supported by the National Natural Science Foundation of China(Grant Nos.52001141 and 52475360).
文摘A thorny problem in the miscible Ti/Fe system is the unavoidable formation of numerous brittle intermetallic compounds(IMCs).Adding H62 interlayer is an essential method to reduce the brittle IMCs or decrease the brittleness.A joint with good formability and tensile properties was obtained.The microstructure and element distribution of the joint were observed by metallographic microscopy,scanning electron microscopy and electron probe microanalysis.The shear resistance exhibited an initial increase,followed by a subsequent decrease,with an increase in heat input.It reached a maximum value of 2470 N at a welding energy of 267 kJ/m.The Fe-Ti brittle IMCs in TC4/DP780 joints are replaced by Fe-Cu phase and Cu-Ti phase,which reduces the brittleness at TC4/DP780 interface.The results show that the TC4/DP780 joint forms numerousα-Cu andγ-Fe solid solutions through the mutual diffusion and solid solution between H62 and TC4 layers of metals,which effectively inhibits the diffusion of Ti atoms and reduces the formation of brittle Ti-Fe IMCs.At the H62/TC4 interface,a composite layer composed of Cu-Ti IMCs and Cu-based solid solutions is formed.The composite layer grows dendritically from the TC4 alloy to the H62 interlayer.The microstructure at the TC4/DP780 interface changes from fine dendrites to coarse dendrites with the increase in Ti content and heat input.When the heat input is lower,the interfacial elements do not react sufficiently.When the heat input is excessive,microcracks appear at the TC4/DP780 interface,which limits the improvement of mechanical properties of TC4/DP780 joint.
基金supported by the National Key Research and Development Program of China (MOST)(Grant No.2022YFA1402800)the Chinese Academy of Sciences (CAS) Presidents International Fellowship Initiative (PIFI)(Grant No.2025PG0006)+3 种基金the National Natural Science Foundation of China (NSFC)(Grant Nos.51831012,12274437,and 52161160334)the CAS Project for Young Scientists in Basic Research (Grant No.YSBR-084)the CAS Youth Interdisciplinary Teamthe China Postdoctoral Science Foundation (Grant No.2025M773402)。
文摘Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.
文摘Regulating interlayer distance is a crucial factor in the development of two‐dimensional(2D)nanomaterials.A 2D metal‐free photocatalyst,such as graphitic carbon nitride(g‐C3N4),exhibits morphology‐and microstructure‐dependent photocatalytic activity.Herein,we report a straightforward and facile route for the preparation of unique lamellar g‐C3N4,by co‐firing melamine and ammonium chloride via microwave‐assisted heating.Through the decomposition of NH4Cl,the evaporation of NH3 gas can effectively overcome van der Waals forces,expanding the interlayer distance of g‐C3N4,thereby creating a lamellar structure consisting of nanosheets.Compared with bulk g‐C3N4,the NH3‐derived lamellar g‐C3N4 exhibits a larger specific surface area and enhanced optical absorption capability,which increase photocatalytic hydrogen production because of the highly active structure,excellent utilization efficiency of photon energy,and low recombination efficiency of photogenerated charge carriers.This study provides a simple strategy for the regulation of the g‐C3N4 microstructure toward highly efficient photocatalytic applications.
基金financial support from the JSPS KAKENHI Grant-in-Aid for Scientific Research(B),No.21H02035KAKENHI Grant-in-Aid for Challenging Research(Exploratory),No.21K19017+2 种基金KAKENHI Grant-in-Aid for Transformative Research Areas(B),No.21H05100National Natural Science Foundation of China,No.22409033 and No.22409035Basic and Applied Basic Research Foundation of Guangdong Province,No.2022A1515110470.
文摘Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green hydrogen.However,there are still challenges related key materials and anode/electrolyte interface.P-SOECs with Zr-rich electrolyte,called Zr-rich side P-SOECs,possess high thermodynamically stability under high steam concentrations but the large reaction resistances and the current leakage,thus the inferior performances.In this study,an efficient functional interlayer Ba_(0.95)La_(0.05)Fe_(0.8)Zn_(0.2)O_(3-δ)(BLFZ)in-between the anode and the electrolyte is developed.The electrochemical performances of P-SOECs are greatly enhanced because the BLFZ can greatly increase the interface contact,boost anode reaction kinetics,and increase proton injection into electrolyte.As a result,the P-SOEC yields high current density of 0.83 A cm^(-2) at 600℃ in 1.3 Vamong all the reported Zr-rich side cells.This work not only offers an efficient functional interlayer for P-SOECs but also holds the potential to achieve P-SOECs with high performances and long-term stability.
基金support for this work is received from the National Natural Science Foundation of China(Grant No.U22B20144).
文摘The potential of the vertical-horizontal well hybrid SAGD technique for developing shallow heavy oil reservoirs is gradually being realized.However,challenges remain in terms of low thermal efficiency and high carbon emissions in reservoirs with interlayers.Currently,there is limited research on the low-carbon strategy of coupling exhaust gas from steam boilers with the VH-SAGD technique.Herein,considering heterogeneity,a series of flue gas-assisted VH-SAGD experiments were conducted employing a high-performance 2D visualization model.The mechanism of enhanced recovery of flue gas in VH-SAGD and the effect of its injection methods were studied,with a focus on steam chamber development and oil saturation distribution.Crucially,the interlayer length was optimized to enhance oil recovery,providing a new perspective for well location design in heavy oil reservoirs with interlayers.The results showed that flue gas,as an additive,could fully exploit the well-type advantage of VH-SAGD.By supplementing energy at the reservoir top,flue gas effectively promoted steam chamber development,expanded the oil drainage area of VH-SAGD,and increased the oil recovery from 58.9%to 71.7%.The flow channels formed by pre-injection flue gas accelerated the early-stage expansion of the steam chamber while also inducing lateral migration of steam,slowing steam rise,and consequently increasing the heating range within the low-permeability layer.When the distance between the vertical and horizontal wells was set to twice the interlayer length,the negative effects of the interlayer were more effectively turned into advantages.Because when the lateral development distance of the steam chamber in the low-permeability layer slightly exceeds the interlayer,enhanced heating of the lower part of the reservoir occurred through vertical convection of rising steam and returning condensate.The research results contribute to reducing carbon emissions from steam-based heavy oil extraction while advancing the maturity of VH-SAGD.
基金the financial support from the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2023R1A2C2007699 and 2022R1A6A1A0306303912)the Nano Material Technology Development Program through the NRF funded by the Ministry of Science and ICT (NRF-2015M3A7B6027970)the Technology Innovation Program by the Ministry of Trade, Industry & Energy (RS-202300236794)
文摘Regulating lithium(Li)plating/stripping behavior in three-dimensional(3D)conductive scaffolds is critical to stabilizing Li metal batteries(LMBs).Surface protrusions and roughness in these scaffolds can induce uneven distributions of the electric fields and ionic concentrations,forming“hot spots.”Hot spots may cause uncontrollable Li dendrites growth,presenting significant challenges to the cycle stability and safety of LMBs.To address these issues,we construct a Li ionic conductive-dielectric gradient bifunctional interlayer(ICDL)onto a 3D Li-injected graphene/carbon nanotube scaffold(LGCF)via in situ reaction of exfoliated hexagonal boron nitride(fhBN)and molten Li.Microscopic and spectroscopic analyses reveal that ICDL consists of fhBN-rich outer layer and inner layer enriched with Li_(3)N and Li-boron composites(Li-B).The outer layer utilizes dielectric properties to effectively homogenize the electric field,while the inner layer ensures high Li ion conductivity.Moreover,DFT calculations indicate that ICDL can effectively adsorb Li and decrease the Li diffusion barrier,promoting enhanced Li ion transport.The modulation of Li kinetics by ICDL increases the critical length of the Li nucleus,enabling suppression of Li dendrite growth.Attributing to these advantages,the ICDL-coated LGCF(ICDL@LGCF)demonstrates impressive long-term cycle performances in both symmetric cells and full cells.
基金supported by the National Research Foundation of Korea funded by the Korean Government(grant No.RS-2023-00208801).
文摘As artificial intelligence and big data become increasingly prevalent, resistive random-access memory (RRAM) has become one of the most promising alternatives for storing massive amounts of data. In this study, we employed high-quality crystalline TiN/Al_(2)O_(3)/BaTiO_(3)/Pt RRAM with an optimized thin Al_(2)O_(3) interlayer around 12 nm thick prepared using atomic layer deposition since the thickness of the interlayer affects the memory window size. After insertion of the Al_(2)O_(3) interlayer, the novel RRAM exhibited outstanding uniform resistive switching voltage and the ON/OFF memory window drastically increased from 10 to 103 without any discernible decline in performance. Moreover, the low-resistance state and high-resistance state operating current values decreased by almost one order and three orders of magnitude, respectively, thereby decreasing the power consumption for the RESET and SET processes by more than three and almost one order of magnitude, respectively. The device also exhibits multilevel resistive switching behavior when varying the applied voltage. Finally, we also developed a 6 6 crossbar array which demonstrated consistent and reliable resistive switching behavior with minimal variation. Hence, our approach holds great promise for producing state-of-the-art non-volatile resistive switching devices.
文摘A functional interlayer based on two-dimensional(2D)porous modified vermiculite nanosheets(PVS)was obtained by acid-etching vermiculite nanosheets.The as-obtained 2D porous nanosheets exhibited a high specific surface area of 427 m^(2)·g^(-1)and rich surface active sites,which help restrain polysulfides(LiPSs)through good physi-cal and chemical adsorption,while simultaneously accelerating the nucleation and dissolution kinetics of Li_(2)S,effec-tively suppressing the shuttle effect.The assembled lithium-sulfur batteries(LSBs)employing the PVS-based inter-layer delivered a high initial discharge capacity of 1386 mAh·g^(-1)at 0.1C(167.5 mAh·g^(-1)),long-term cycling stabil-ity,and good rate property.
文摘Due to its unique layered structure and excellent electrochemical properties,molybdenum disulfide(MoS_(2))demonstrates significant potential for applications in the energy storage field,particularly in supercapacitors.It is widely regarded as one of the most representative transition metal dichalcogenides.MoS_(2)possesses a high theoretical specific capacitance,abundant edge active sites,and favorable tunability and structural diversity,which provide it with a distinct advantage in the construction of advanced electrode structures.Additionally,the anisotropic characteristics of MoS_(2)concerning electron and ion transport offer more dimensions for regulating its electrochemical behavior.This work will systematically review various synthesis strategies for MoS_(2)and its recent advancements in energy storage,with a particular focus on the mechanisms by which interlayer spacing modulation affects energy storage behavior in supercapacitor configurations.The discussion will encompass a comprehensive logical framework that spans material structure modifications,electronic configuration evolution,and enhancements in macroscopic device performance.This review aims to provide theoretical support and practical guidance for the application of MoS_(2)in the next generation of highperformance energy storage devices.
基金National Natural Science Foundation of China(52075449,5197052086)。
文摘The transient liquid-phase(TLP)diffusion bonding of GH5188 with a BNi-5 interlayer was focused on.Parameters were chosen and optimized for GH5188 alloy according to the TLP joining mechanism.The microstructure evolution and mechanical properties of the joints were studied.Results show that the relatively complete isothermal solidification zone(ISZ)ensures a reliable connection of the base metal(BM).Within the temperature range of 1110–1190°C,higher bonding temperatures can widen ISZ and promote joint composition homogenization,thus improving mechanical properties.However,the increase in precipitated phase has an adverse effect on the mechanical properties of the joint.The maximum shear strength,reaching 482 MPa,is achieved at 1130°C,representing 84.6%of BM strength.Within the pressure range of 5–15 MPa,both precipitated phases in adiabatic solidification zone(ASZ)and voids generated by partial melting increase.On the contrary,their sizes decrease significantly under higher bonding pressure,resulting in an upward trend in alloy mechanical properties.The maximum shear strength of 490 MPa is attained at a bonding pressure of 15 MPa.The joint exhibits a typical mixed fracture pattern,with the small brittle M_(23)C_(6) phase and voids significantly impacting mechanical properties.Nano-indentation tests indicate that ASZ is a potential source of cracks.
基金Project supported by the“Pioneer”and“Leading Goose”R&D Program of Zhejiang Province(Grant No.2022C01053)the Key Research and Development Program of Zhejiang Province(Grant No.2021C01039)+1 种基金the National Natural Science Foundation of China(Grant No.62293493)the Natural Science Foundation of Zhejiang Province,China(Grant No.LQ21A050001)。
文摘Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic antiferromagnets and synthetic ferromagnets.The antiferromagnetic and ferromagnetic coupling states are precisely engineered through Ruderman-Kittel-Kasuya-Yosida(RKKY)interactions by modulating the Ir spacer thickness.Experimental results reveal that the critical switching current density exhibits a strong positive correlation with the IEC strength,regardless of the coupling type.A comprehensive theoretical framework based on the Landau-Lifshitz-Gilbert equation elucidates how IEC contributes to the effective energy barrier that must be overcome during SOT-induced magnetization switching.Significantly,the antiferromagnetically coupled samples demonstrate enhanced SOT efficiency,with the spin Hall angle being directly proportional to the antiferromagnetic exchange coupling field.These insights establish a coherent physical paradigm for understanding IEC-dependent SOT dynamics and provide strategic design principles for the development of energy-efficient next-generation spintronic devices.
基金the financial support by the National Key Research and Development Program of China(No.2019YFA0708700)the National Natural Science Foundation of China(Nos.62305196,U23B2087 and 62375158)+4 种基金the China Postdoctoral Science Foundation(No.GZC20231498)the Qingdao Postdoctoral Innovation Project(No.QDBSH20240102078)the Postdoctoral Innovation Program of Shandong Province(No.SDCX-ZG-202400318)Science and Technology Research Project of Hubei Provincial Department of Education(No.D20212603)Hubei University of Arts and Science(No.2020kypytd002)。
文摘Surface adsorption plays a crucial role in various natural and industrial processes,particularly in the field of energy storage.The adsorption of sodium atoms on 2D layered materials can significantly impact their performance as carriers and electrodes in ion batteries.While it is commonly acknowledged that pristine graphene is not favorable for sodium ion adsorption,the suitability of other 2D materials with similar honeycomb symmetry remains unclear.In this study,we employ systematic first-principles calculations to explore interlayer interactions and electron transfer effects on sodium adsorption on 2D van der Waals(vdW)heterostructures(HTSs)surfaces.Our results demonstrate that sodium adsorption is energetically favorable on these substrates.Moreover,we find that the adsorption strength can be effectively tuned by manipulation of the electron accumulation or depletion of the layer directly interacting with the sodium atom.By stacking these layered materials with different electron abundancy to form vd W HTSs,the charge density of the substrate becomes tunable through interlayer charge transfer.In these vdW HTSs,the adsorption behavior of sodium is primarily controlled by the absorption layer and exhibits a linear correlation with its pz-band center.Additionally,we identify linear correlations between the sodium adsorption energies,the electron loss of the sodium atom,the interlayer charge transfer,and the heights of the adsorbed sodium atom.These discoveries underscore the impact of interlayer electron transfer and interactions on sodium ion adsorption on 2D vd W HTSs and providing new insights into material design for alkali atom adsorption.
基金funded by Universitas Negeri Malang,contract number 4.4.841/UN32.14.1/LT/2024.
文摘An imbalanced dataset often challenges machine learning, particularly classification methods. Underrepresented minority classes can result in biased and inaccurate models. The Synthetic Minority Over-Sampling Technique (SMOTE) was developed to address the problem of imbalanced data. Over time, several weaknesses of the SMOTE method have been identified in generating synthetic minority class data, such as overlapping, noise, and small disjuncts. However, these studies generally focus on only one of SMOTE’s weaknesses: noise or overlapping. Therefore, this study addresses both issues simultaneously by tackling noise and overlapping in SMOTE-generated data. This study proposes a combined approach of filtering, clustering, and distance modification to reduce noise and overlapping produced by SMOTE. Filtering removes minority class data (noise) located in majority class regions, with the k-nn method applied for filtering. The use of Noise Reduction (NR), which removes data that is considered noise before applying SMOTE, has a positive impact in overcoming data imbalance. Clustering establishes decision boundaries by partitioning data into clusters, allowing SMOTE with modified distance metrics to generate minority class data within each cluster. This SMOTE clustering and distance modification approach aims to minimize overlap in synthetic minority data that could introduce noise. The proposed method is called “NR-Clustering SMOTE,” which has several stages in balancing data: (1) filtering by removing minority classes close to majority classes (data noise) using the k-nn method;(2) clustering data using K-means aims to establish decision boundaries by partitioning data into several clusters;(3) applying SMOTE oversampling with Manhattan distance within each cluster. Test results indicate that the proposed NR-Clustering SMOTE method achieves the best performance across all evaluation metrics for classification methods such as Random Forest, SVM, and Naїve Bayes, compared to the original data and traditional SMOTE. The proposed method (NR-Clustering SMOTE) improves accuracy by 15.34% on the Pima dataset and 20.96% on the Haberman dataset compared to SMOTE-LOF. Compared to Radius-SMOTE, this method increases accuracy by 3.16% on the Pima dataset and 13.24% on the Haberman dataset. Meanwhile, compared to RN-SMOTE, the accuracy improvement reaches 15.56% on the Pima dataset and 19.84% on the Haberman dataset. This research result implies that the proposed method experiences consistent performance improvement compared to traditional SMOTE and its latest variants, such as SMOTE-LOF, Radius-SMOTE, and RN-SMOTE, in solving imbalanced health data with class binaries.
基金funded by Research on Intelligent Control System of Variable Fertilization of Deep Application Liquid Fertilizer(GXKS2022GKY003)the Key Laboratory of Smart Agriculture Technology,Guangxi Science and Technology Normal University(GXKSKYPT2024008)+1 种基金Key Laboratory of Detection Technology for Sugarcane and Peanut Leaf Spot Disease,Guangxi Science and Technology Normal University(GXKSKYPT2025008)Research on the Application of Uniformity Theory and 3D Virtual Forest Phase in Harbin Normal University’s Science and Technology Innovation Climbing Program Funding Project(XKB202415)。
文摘Biodiversity has always been valued by ecology,Diversity is generally believed to lead to stability,and biodiversity is an important condition for ecosystems to maintain health.So what factors are related to forest ecosystem biodiversity,and what kind of forest structure affects and determines the size of biodiversity.This study proposes the concept of contained uniformity based on the theory of uniformity,and uses the convergence of contained uniformity to obtain the judgment model of the forest station pattern type.At the same time,it proposes the concept of forest ecosystem distance diversity,and uses the judgment model of the stand pattern type to derive the mathematical definition of forest ecosystem distance diversity.Combining the ecological characteristics of different stand patterns and measurement indicators of forest ecosystem biodiversity,the connection between forest ecosystem distance diversity and biodiversity is derived,and this is used as an indicator to evaluate forest ecosystem biodiversity.Forest ecosystem distance diversity,as an indicator of biodiversity,can not only conduct early assessment and prediction of the biodiversity of immature forests(forests in the early succession or recovery stage),but also provide a quantitative basis for forest structure optimization.Ultimately realize the sustainable development of forestry production and operation and biodiversity protection.
基金support by the National Natural Sci-ence Foundation of China(Grant No.12274477)the De-partment of Science and Technology of Guangdong Provincein China(Grant No.2019QN01X061)。
文摘In moiré-patterned van der Waals structures of transition metal dichalcogenides,correlated insulators can form under integer and fractional fillings,whose transport properties are governed by various quasiparticle excitations including holons,doublons and interlayer exciton insulators.Here we theoretically investigate the nearest-neighbor inter-site hoppings of holons and interlayer exciton insulators.Our analysis indicates that these hopping strengths are significantly enhanced compared to that of a single carrier.The underlying mechanism can be attributed to the strong Coulomb interaction between carriers at different sites.For the interlayer exciton insulator consisting of a holon and a carrier in different layers,we have also obtained its effective Bohr radius and energy splitting between the ground and the first-excited states.
基金funded by the National Natural Science Foundation of China(No.42202113)。
文摘Buried coastal sandstones would be of high-quality hydrocarbon reservoirs.Controlled by deposition and diagenesis,coastal sandstones mixed with muddy and calcareous materials are usually low in porosity and permeability and small in layer thickness.These impermeable inte rlayers act as baffles and barriers between flow units and are crucial in hydrocarbon development.Donghe Sandstone in the Hade Oilfield of Tarim Basin,NW China,belongs to coastal clastic reservoirs of high oil productivity.Following nearly 30 years of development,the distribution of remaining hydrocarbon resources is affected by the muddy,calcareous,and marlaceous interlayers.Taking the Donghe Sandstone as an example,a quantitative recognition method of interlayers in coastal sandstone reservoirs is proposed in this paper.Based on cores from 26 wells,the sensitive conventional log curves of different interlayers,namely the natural gamma-ray(GR),density(DEN),compensated neutron(CNL),and acoustic(AC),are extracted by the Extreme Gradient Boosting(XGBoost).Multi-mineral model(MMM)is used to calculate continuous curves for muddy,sandy,and calcareous contents by the mentioned sensitive logs.A set of quantitative standard system is established for identifying muddy,calcareous,and marlaceous interlayers based on their respective contents.The types of inte rlayers are identified across all vertical wells.The interlayers exhibit lateral continuity at the top of each bed-set.Interlayers are currently more developed in the slope region than in the coastal region.Muddy and marlaceous interlayers are more developed at high relative sea-level,while calcareous interlayers are more developed at low relative sea-level.The extended interlayers at the top of BS6 lead to two different oil-water contacts in the Donghe Sandstone.The proposed quantitative recognition method for interlayers provides valuable insights into the exploitation potential of petroleum systems in the Donghe Sandstone of the Hade Oilfield.The flexible and easy-to-use method can be applied to other marine sandstone reservoirs or similar formations.
基金the Shanxi Province Science Foundation(20210302123150)the National Key Research and Development Program(2021YFB2500300)+3 种基金the National Natural Science Foundation of China(223B1012,22409114)the Beijing Natural Science Foundation(L243019)the Anhui Science and Technology Innovation Tackling Key Problems Plan Project(202423h08050005)the China Postdoctoral Science Foundation(2023M731920)。
文摘With the ever-increasing energy density requirements for sulfide-based all-solid-state batteries,lithium metal is regarded as an ideal candidate for anode materials.However,the dynamic degradation of solidsolid contact between lithium anode and solid electrolyte remains a major challenge for the application of all-solid-state lithium metal batteries(ASSLMBs).The poor solid-solid contact problem is caused by the continuous accumulation of lithium voids,which results from the limited diffusion rate of lithium in the bulk phase.In this study,we design a three-dimensional(3D)lithiophilic graphitized carbon nanotubebased(LNT)interlayer to address interfacial issues.The interlayers effectively regulate lithium stripping and suppress the growth of lithium voids via improved lithium diffusion,leading to a conformal interface during continuous cycling.The lithium metal anode with the interlayer delivers an areal capacity of 12.96 mA h cm^(-2),and when paired with a LiNi_(0.9)Co_(0.05)Mn_(0.05)O_(2)(NCM9)cathode,the battery retains over 91%capacity retention after 100 cycles at room temperature.This work provides an effective strategy for interface stabilization in high-capacity and long-life ASSLMBs.
