Microbially induced calcium carbonate precipitation(MICP)is an eco-friendly technology for soil improvement.Although numerous experiments have been conducted to solidify sand foundations using MICP,the mechanisms by w...Microbially induced calcium carbonate precipitation(MICP)is an eco-friendly technology for soil improvement.Although numerous experiments have been conducted to solidify sand foundations using MICP,the mechanisms by which grain interfacial morphologies influencethe MICP process remain unclear.This study utilized 3D-printed flowcells with different boundary morphologies to investigate the effects of interfacial morphologies on the MICP process.CaCO_(3)precipitation characteristics were investigated through microscopic observation and image quantificationanalysis.The results indicate that low flowvelocities near the interface promote bacterial accumulation due to reduced hydrodynamic shear forces.Rough interfaces,compared to smooth ones,enhance bacterial adsorption owing to the larger regions of low flowvelocity,increased surface area,and the formation of local eddies,which promote greater CaCO_(3)precipitation.Compared to the regions away from the interface,a higher abundance of small CaCO_(3)crystals is observed near the interface because of the high urease activity from bacteria and the reduced shear-induced entrainment due to the low flowvelocity.Besides,larger crystals also preferentially precipitate in proximity to interfaces as the low flowvelocity enhances crystal growth according to the particle attachment theory.The presence of rough interfaces further reduces flowvelocities,leading to the precipitation of larger and more densely packed CaCO_(3)crystals.Therefore,rough interfaces promote the microbially induced calcium carbonate precipitation.This work is expected to enhance the understanding of microbially induced calcium carbonate precipitation characteristics on solid surfaces such as soil grains and contribute to the optimization of MICP applications.展开更多
Matrix/fiber composites of,β-form isotactic polypropylene （iPP） matrix and α-iPP or PA6 fibers were prepared by laminating technique under different preparation temperatures. The mechanical properties and interrac...Matrix/fiber composites of,β-form isotactic polypropylene （iPP） matrix and α-iPP or PA6 fibers were prepared by laminating technique under different preparation temperatures. The mechanical properties and interracial morphologies of these composites were studied by tensile test, optical microscopy and scanning electron microscopy, respectively. The experimental results show that the tensile yield load and tensile modulus of β-iPP/PA6 matrix/fiber systems increased significantly at the expense of elongation at break. These mechanical properties show essentially no dependence on the sample preparation temperature. On the other hand, the mechanical properties of iPP matrix/fiber single polymer composites depend strongly on the sample preparation temperature. At low sample preparation temperature, e.g., 172 ℃, the solid cr-iPP fiber induces tr-iPP crystallization, leading to the formation of a-iPP transcrystalline layer around the fiber. This results in a remarkable increment of the tensile yield load and tensile modulus. The elongation at break is also much better than that of the iPP/PA6 matrix/fiber system. It reflects a better interracial adhesion of the single polymer composite compared with the iPP/PA6 composite. At higher sample preparation temperature, e.g., 174 ℃ or 176 ℃, the partial surface melting of the oriented fiber allows interdiffusion of iPP molecular chains in the molten fiber and matrix melt. The penetration of matrix chains into the molten iPP fiber results in some iPP molecular chains being included partially in the recrystallized fiber and the induced β-transcrystalline layers. This kind of configuration leads to an improvement of interfacial adhesion between the fiber and matrix, which causes a simultaneous increase of the tensile yield load, tensile modulus and elongation at break of β-iPP.展开更多
Aluminium-copper hybrid parts, as a substitution to copper parts, result in weight and cost reduction, and are relevant in applications related to the electronic, heating and cooling sector. However, aluminium to copp...Aluminium-copper hybrid parts, as a substitution to copper parts, result in weight and cost reduction, and are relevant in applications related to the electronic, heating and cooling sector. However, aluminium to copper joined by thermal welding processes presents challenges in terms of achieving good joint quality. This is attributed to their dissimilar mechanical and thermal properties which result in large stress gradients during heating. This study investigated joining of aluminium to copper sheets by electromagnetic pulse welding, which is a solid-state process that uses electromagnetic forces for joining of dissimilar materials. Hybrid sheet welds were obtained for all parameters conditions, selected according to a Taguchi L18 design. The structural and mechanical characteristics were examined and related to the welding parameters by means of a Pareto analysis and response graphs. The welded zone started with a wavy interface with interfacial layers and defects and evolved to a flat interface without interfacial layers. The maximum transferable force depended on the minimum specimen thickness and the strength of the hybrid sheet weld. In case of aluminium sheet thickness reduction, the maximum transferable force was linearly correlated with the aluminium sheet thickness. High quality joints were obtained for no aluminium sheet thickness reduction and for a sheet weld strength which was at least as high as that of the base material. The most effective way to increase the transferable force was to lower the initial gap and to increase the free length, which resulted in no aluminium sheet thickness reduction. Alternatively, the use of a rounded spacer decreased the effect of the aluminium sheet thickness on the transferable force. An increase in weld width was achieved for an increase in capacitor charging energy and gap, whereas an increase in weld length was obtained for a decrease in gap. An increase in weld width did not necessarily result in an increase in the transferable force. In the regarded cases, a hybrid sheet with narrow weld width could therefore have higher quality.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2023YFC3707900)National Natural Science Foundation of China(Grant No.42230710,42525201)Key task project for joint research and development of the Yangtze River Delta Science and Technology Innovation Community(Grant No.2022CSJGG1200).
文摘Microbially induced calcium carbonate precipitation(MICP)is an eco-friendly technology for soil improvement.Although numerous experiments have been conducted to solidify sand foundations using MICP,the mechanisms by which grain interfacial morphologies influencethe MICP process remain unclear.This study utilized 3D-printed flowcells with different boundary morphologies to investigate the effects of interfacial morphologies on the MICP process.CaCO_(3)precipitation characteristics were investigated through microscopic observation and image quantificationanalysis.The results indicate that low flowvelocities near the interface promote bacterial accumulation due to reduced hydrodynamic shear forces.Rough interfaces,compared to smooth ones,enhance bacterial adsorption owing to the larger regions of low flowvelocity,increased surface area,and the formation of local eddies,which promote greater CaCO_(3)precipitation.Compared to the regions away from the interface,a higher abundance of small CaCO_(3)crystals is observed near the interface because of the high urease activity from bacteria and the reduced shear-induced entrainment due to the low flowvelocity.Besides,larger crystals also preferentially precipitate in proximity to interfaces as the low flowvelocity enhances crystal growth according to the particle attachment theory.The presence of rough interfaces further reduces flowvelocities,leading to the precipitation of larger and more densely packed CaCO_(3)crystals.Therefore,rough interfaces promote the microbially induced calcium carbonate precipitation.This work is expected to enhance the understanding of microbially induced calcium carbonate precipitation characteristics on solid surfaces such as soil grains and contribute to the optimization of MICP applications.
基金financially supported by the National Natural Science Foundation of China(Nos.50833006,21274009 and 51221002)
文摘Matrix/fiber composites of,β-form isotactic polypropylene （iPP） matrix and α-iPP or PA6 fibers were prepared by laminating technique under different preparation temperatures. The mechanical properties and interracial morphologies of these composites were studied by tensile test, optical microscopy and scanning electron microscopy, respectively. The experimental results show that the tensile yield load and tensile modulus of β-iPP/PA6 matrix/fiber systems increased significantly at the expense of elongation at break. These mechanical properties show essentially no dependence on the sample preparation temperature. On the other hand, the mechanical properties of iPP matrix/fiber single polymer composites depend strongly on the sample preparation temperature. At low sample preparation temperature, e.g., 172 ℃, the solid cr-iPP fiber induces tr-iPP crystallization, leading to the formation of a-iPP transcrystalline layer around the fiber. This results in a remarkable increment of the tensile yield load and tensile modulus. The elongation at break is also much better than that of the iPP/PA6 matrix/fiber system. It reflects a better interracial adhesion of the single polymer composite compared with the iPP/PA6 composite. At higher sample preparation temperature, e.g., 174 ℃ or 176 ℃, the partial surface melting of the oriented fiber allows interdiffusion of iPP molecular chains in the molten fiber and matrix melt. The penetration of matrix chains into the molten iPP fiber results in some iPP molecular chains being included partially in the recrystallized fiber and the induced β-transcrystalline layers. This kind of configuration leads to an improvement of interfacial adhesion between the fiber and matrix, which causes a simultaneous increase of the tensile yield load, tensile modulus and elongation at break of β-iPP.
文摘Aluminium-copper hybrid parts, as a substitution to copper parts, result in weight and cost reduction, and are relevant in applications related to the electronic, heating and cooling sector. However, aluminium to copper joined by thermal welding processes presents challenges in terms of achieving good joint quality. This is attributed to their dissimilar mechanical and thermal properties which result in large stress gradients during heating. This study investigated joining of aluminium to copper sheets by electromagnetic pulse welding, which is a solid-state process that uses electromagnetic forces for joining of dissimilar materials. Hybrid sheet welds were obtained for all parameters conditions, selected according to a Taguchi L18 design. The structural and mechanical characteristics were examined and related to the welding parameters by means of a Pareto analysis and response graphs. The welded zone started with a wavy interface with interfacial layers and defects and evolved to a flat interface without interfacial layers. The maximum transferable force depended on the minimum specimen thickness and the strength of the hybrid sheet weld. In case of aluminium sheet thickness reduction, the maximum transferable force was linearly correlated with the aluminium sheet thickness. High quality joints were obtained for no aluminium sheet thickness reduction and for a sheet weld strength which was at least as high as that of the base material. The most effective way to increase the transferable force was to lower the initial gap and to increase the free length, which resulted in no aluminium sheet thickness reduction. Alternatively, the use of a rounded spacer decreased the effect of the aluminium sheet thickness on the transferable force. An increase in weld width was achieved for an increase in capacitor charging energy and gap, whereas an increase in weld length was obtained for a decrease in gap. An increase in weld width did not necessarily result in an increase in the transferable force. In the regarded cases, a hybrid sheet with narrow weld width could therefore have higher quality.
