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Kinetic Model Heterogeneous Reaction Self-assembly on Nanocomposit Sorbent and Their Peculiarity
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作者 Kibalnikova Olga V. 《Journal of Chemistry and Chemical Engineering》 2018年第3期124-128,共5页
Kinetic modeling of self-assembly reactions occurring on a nanocomposite with the formation of dimers in a solvent cell and molecular complexes in micelles is presented.In this self-organization occurs due to the syne... Kinetic modeling of self-assembly reactions occurring on a nanocomposite with the formation of dimers in a solvent cell and molecular complexes in micelles is presented.In this self-organization occurs due to the synergistic effect,due to a combination of nonvalent interactions.This approach opens up new possibilities in the field of chromatographic and separation technologies related to the analysis of complex mixtures.The coefficientαof the self-assembling processes at the nanocomposite.It is shown thatαcan have different values,for example,for pyridine dimer in cage solvent this coefficient is2.5~3.4.Quantum chemical calculations show that the surface of the nanocomposite is doped with alkaline metal,which restores hydrogen atoms,turning them into H-.This is used in a chromate-mass spectrometer in identify environmental toxicants,the technique of determining metaphase in food products. 展开更多
关键词 SELF-ASSEMBLY reaction nanocomposit equation N.I.Brensted intercaljacia chromate-mass-spectrometrija metaphos helium
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