Two arylpyrazoles I andⅡwere synthesized and characterized by NMR and single-crystal X-ray diffraction.Compound I displayed 71.4%fungicidal inhibition rate against Rhizoctonia solani at 0.1 ppm,better than the contro...Two arylpyrazoles I andⅡwere synthesized and characterized by NMR and single-crystal X-ray diffraction.Compound I displayed 71.4%fungicidal inhibition rate against Rhizoctonia solani at 0.1 ppm,better than the control pyraclostrobin,whereasⅡhad little activity.Their fungicidal difference was discussed from theoretic level based on the crystal structure,density functional theory(DFT)calculation and molecular docking.The B3 LYP/6-31G^**level was employed to explore the HOMO-LUMO energy gap and charge distribution.Molecular docking was performed on the probable target protein bc1-enzyme complex.DFT calculation and docking studies supported the in vitro findings.展开更多
Inelastic electron scattering form factors has been calculated for different parity for the two （C3） transitions of 14^N for （5.83MeV） （f^π, T = 20） level and, （5.106MeV） （f^π, T = 30） level in the frame w...Inelastic electron scattering form factors has been calculated for different parity for the two （C3） transitions of 14^N for （5.83MeV） （f^π, T = 20） level and, （5.106MeV） （f^π, T = 30） level in the frame work of shell model. The model space wave functions are generated by using the Cohen-Kurath （CK） interaction, where 4He is assumed as a core and ten nucleons are distributed over the lp-shell which forms the model space. Core-polarization effects （CP） （the effects from outside lp-shell model space） are included through the first order perturbation theory. The core-polarization effects increase the form factor to be up near the experimental data which are not sufficient to give a good comparison with the calculating data.展开更多
During the sizing process,yarn congestion fault occurs at the reed teeth of a sizing machine.At present,the yarn congestion fault is generally handled by manual detection.The sizing production line operates on a large...During the sizing process,yarn congestion fault occurs at the reed teeth of a sizing machine.At present,the yarn congestion fault is generally handled by manual detection.The sizing production line operates on a large scale and runs continuously.Untimely handling of the yarn congestion fault causes a large amount of yarn waste.In this research,a machine vision-based algorithm for yarn congestion fault detection is developed.Through the analysis of the congestion fault and interference contour characteristics,the basic idea of image phase subtraction to identify the congestion fault is determined.To address the interference information appearing after image phase subtraction,the image pre-processing methods of Canny edge extraction and mean filtering are employed.According to the fault size and location characteristics,the fault contour detection algorithm based on inter-frame difference is designed.To mitigate the camera vibration interference,the anti-vibration interference algorithm based on affine transformation is studied,and the fault detection algorithm for the total yarn congestion fault is determined.The detection of 20 sets of field data is carried out,and the detection rate reaches 90%.This fault detection algorithm realizes the automatic detection of yarn congestion fault of sizing machine with certain real-time performance and accuracy.展开更多
基金supported by the Natural Science Foundation of Jiangsu Province(BK20161542)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(17KJB150006)Jiangsu Overseas Visiting Scholar Program for University Prominent Young&Middle-aged Teachers and Presidents(2017)
文摘Two arylpyrazoles I andⅡwere synthesized and characterized by NMR and single-crystal X-ray diffraction.Compound I displayed 71.4%fungicidal inhibition rate against Rhizoctonia solani at 0.1 ppm,better than the control pyraclostrobin,whereasⅡhad little activity.Their fungicidal difference was discussed from theoretic level based on the crystal structure,density functional theory(DFT)calculation and molecular docking.The B3 LYP/6-31G^**level was employed to explore the HOMO-LUMO energy gap and charge distribution.Molecular docking was performed on the probable target protein bc1-enzyme complex.DFT calculation and docking studies supported the in vitro findings.
文摘Inelastic electron scattering form factors has been calculated for different parity for the two （C3） transitions of 14^N for （5.83MeV） （f^π, T = 20） level and, （5.106MeV） （f^π, T = 30） level in the frame work of shell model. The model space wave functions are generated by using the Cohen-Kurath （CK） interaction, where 4He is assumed as a core and ten nucleons are distributed over the lp-shell which forms the model space. Core-polarization effects （CP） （the effects from outside lp-shell model space） are included through the first order perturbation theory. The core-polarization effects increase the form factor to be up near the experimental data which are not sufficient to give a good comparison with the calculating data.
基金National Key Research and Development Program of China(No.2017YFB1304001)。
文摘During the sizing process,yarn congestion fault occurs at the reed teeth of a sizing machine.At present,the yarn congestion fault is generally handled by manual detection.The sizing production line operates on a large scale and runs continuously.Untimely handling of the yarn congestion fault causes a large amount of yarn waste.In this research,a machine vision-based algorithm for yarn congestion fault detection is developed.Through the analysis of the congestion fault and interference contour characteristics,the basic idea of image phase subtraction to identify the congestion fault is determined.To address the interference information appearing after image phase subtraction,the image pre-processing methods of Canny edge extraction and mean filtering are employed.According to the fault size and location characteristics,the fault contour detection algorithm based on inter-frame difference is designed.To mitigate the camera vibration interference,the anti-vibration interference algorithm based on affine transformation is studied,and the fault detection algorithm for the total yarn congestion fault is determined.The detection of 20 sets of field data is carried out,and the detection rate reaches 90%.This fault detection algorithm realizes the automatic detection of yarn congestion fault of sizing machine with certain real-time performance and accuracy.
