The present paper presents a concise summary of our recent studies on the Asian summer monsoon,with highting decadal and inter- decadal scales. The studies on the long- term variations of the Asian summer monsoon and ...The present paper presents a concise summary of our recent studies on the Asian summer monsoon,with highting decadal and inter- decadal scales. The studies on the long- term variations of the Asian summer monsoon and its impacts on the change in the summer precipitation in China are reviewed. Moreover,recent changes in the Asian summer monsoon and summer precipitation in East Asia(including Meiyu precipitation)are discussed. Finally,the future changes of the Asian summer monsoon are also pointed out in this paper.展开更多
By using the 40-year NCEP (1958-1997) grid point reanalysis meteorological data, we analyzed the inter-decadal variation on the climatic characteristics of the onset of South China Sea summer monsoon. The results are ...By using the 40-year NCEP (1958-1997) grid point reanalysis meteorological data, we analyzed the inter-decadal variation on the climatic characteristics of the onset of South China Sea summer monsoon. The results are as follows. (1) There was great difference on the onset date of the SCS summer monsoon between the first two decades and the last two decades. It was late on the 6th pentad of May for the first two decades and was on the 4th and 5th pentad of May for the next two decades. (2) Except for the third decade (1978-1987), the establishment of the monsoon rainfall was one to two pentads earlier than the onset of the summer monsoon in all other three decades. (3) The onset of the SCS monsoon is the result of the abrupt development and eastward advancement of the southwesterly monsoon over the Bay of Bengal. The four-decade analysis shows that there were abrupt development of the southwesterly monsoon over the Bay of Bengal between the 3rd and 4th pentad of May, but there was great difference between its eastward movement and its onset intensity. These may have important effect to the earlier or later onset of the SCS summer monsoon. (4) During the onset of the SCS summer monsoon, there were great difference in the upper and lower circulation feature between the first two and the next two decades. At the lower troposphere of the first two decades, the Indian-Burma trough was stronger and the center of the subtropical high was located more eastward. At the upper troposphere, the northward movement of the center of subtropical high was large and located more northward after it landed on the Indo-China Peninsula. After comparison, we can see that the circulation feature of the last two decades was favorable to the establishment and development of the SCS summer monsoon.展开更多
This study investigates the Stratosphere-Troposphere Exchange(STE)of water vapor,emphasizes its interdecadal variations over Asia in boreal summer,and discusses the influences of atmospheric heat sources over the Tibe...This study investigates the Stratosphere-Troposphere Exchange(STE)of water vapor,emphasizes its interdecadal variations over Asia in boreal summer,and discusses the influences of atmospheric heat sources over the Tibetan Plateau and the tropical western North Pacific(WNP)on them by using the Wei method with reanalysis data from the European Centre for Medium-Range Weather Forecasts(ECMWF)for the years of 1958-2001.The climatology shows that the upward transport of water vapor across the tropopause in boreal summer is the most robust over the joining area of the South Asian Peninsula and Indian-Pacific Oceans(defined as AIPO).The upward transport over there can persistently convey the abundant water vapor into the stratosphere and then influence the distribution and variation of the stratospheric water vapor.The analysis shows that interdecadal variations of the water vapor exchange over the AIPO are significant,and its abrupt change occurred in the mid-1970s and the early 1990s.In these three periods,as important channels of the water vapor exchange,the effect of Bay of Bengal-East Asia as well as South China Sea was gradually weakening,while the role of the WNP becomes more and more important.Further studies show that atmospheric heat sources over the Tibetan Plateau and the WNP are two main factors in determining the interdecadal variations of water vapor exchange.The thermal influences over the Tibetan Plateau and the WNP have been greatly adjusted over the pass 44 years.Their synthesis influences the interdecadal variations of the water vapor exchange by changing the Asian summer monsoon,but their roles vary with time and regions.Especially after 1992,the influence of heat source over the Tibetan Plateau remarkably weakens,while the heat source over the WNP dominates the across-tropopause water vapor exchange.Results have important implications for understanding the transport of other components in the atmosphere and estimating the impact of human activities(emission)on global climate.展开更多
This study analyzes the inter-decadal variations of rainfall over southern China in spring (March-April-May) using the observed precipitation data for 1979-2004. The result shows that the variations of spring rainfall...This study analyzes the inter-decadal variations of rainfall over southern China in spring (March-April-May) using the observed precipitation data for 1979-2004. The result shows that the variations of spring rainfall over southeastern China are opposite to those over and southwestern China in both inter-annual and inter-decadal time scales. The precipitation over south- ern China exhibits an apparent inter-decadal shift in the late 1980s. The accumulated spring rainfall has reduced 30% over southeastern China after the late 1980s, whereas it has increased twice as much over southwestern China. The atmospheric circulations related to this shift show that an abnormal high at lower and middle troposphere appears over Asian middle and high latitudes, accompanied by stronger-than-normal northerly wind over eastern China. Consequently, the wet air flows from tropical oceans are weakened over southern China, resulting in less rainfall over southeastern China and more rainfall over southwestern China. Furthermore, the anomalous atmospheric circulation over Asian middle and high latitudes is closely related to the inter-decadal downward shift of Eurasian spring snow in the late 1980s, indicating that the inter-decadal shift of Eurasian spring snow in the late 1980s is probably an important factor in the decadal shift of spring rainfall over southern China.展开更多
Carbonyls play an important role in the atmospheric chemistry as the main precursor for reactive radicals and peroxyacetyl nitrate.However,little research has been conducted so far on the seasonal variations of carbon...Carbonyls play an important role in the atmospheric chemistry as the main precursor for reactive radicals and peroxyacetyl nitrate.However,little research has been conducted so far on the seasonal variations of carbonyls in China’s urban atmosphere.In this study,ambient carbonyls were 24-hourly observed in four seasons in Hangzhou,a mega-city in the Yangtze River Delta Region,China.The concentration of total carbonyls was the highest in summer(44.35μg/m^(3)),the second in winter(44.05μg/m^(3)),the third in spring(29.31μg/m^(3))and autumn(27.11μg/m^(3)).The most abundant species were found to be acetone in spring,summer,and winter,while formaldehyde in autumn.Rainfall can significantly reduce the concentrations of most ambient carbonyls,with the largest decrease observed in the wet precipitation events occurring in spring and summer,while acetone concentrations remained invariable due to its lower water solubility.Multiple linear regression analysis and carbonyls ratios indicated that anthropogenic emissions were the predominant sources of carbonyls,and atmospheric formaldehyde was mainly emitted from primary sources other than secondary sources.Vehicular exhaust was identified as the primary source of ambient carbonyls,particularly in winter,and its contribution reached 92.80%to formaldehyde.Additionally,photochemical reactions were closely associated with the secondary production of formaldehyde in summer.Carbonyls showed strong ozone formation potential in all four seasons.Based on the health risk assessment,the exposure to ambient carbonyls is harmful to outdoor pedestrians.The results could provide essential information and references for simulating regional air quality and analyzing ozone pollution,which is essential for improving air quality in the Yangtze River Delta region.展开更多
Replicating the chaotic characteristics inherent in nonlinear dynamical systems via machine learning(ML)is a key challenge in this rapidly advancing interdisciplinary field.In this work,we explore the potential of var...Replicating the chaotic characteristics inherent in nonlinear dynamical systems via machine learning(ML)is a key challenge in this rapidly advancing interdisciplinary field.In this work,we explore the potential of variational quantum circuits(VQC)for learning the stochastic properties of classical nonlinear dynamical systems.Specifically,we focus on the one-and two-dimensional logistic maps,which,while simple,remain under-explored in the context of learning dynamical characteristics.Our findings reveal that,even for such simple dynamical systems,accurately replicating longterm characteristics is hindered by a pronounced sensitivity to overfitting.While increasing the parameter complexity of the ML model typically enhances short-term prediction accuracy,it also leads to a degradation in the model’s ability to replicate long-term characteristics,primarily due to the detrimental effects of overfitting on generalization power.By comparing the VQC with two widely recognized classical ML techniques,which are long short-term memory(LSTM)networks for timeseries processing and reservoir computing,we demonstrate that VQC outperforms these methods in terms of replicating long-term characteristics.Our results suggest that for the ML of dynamics,it is demanded to develop more compact and efficient models(such as VQC)rather than more complicated and large-scale ones.展开更多
Plastome variation,including single spontaneous nucleotide substitutions and single insertions/deletions,is the major source of leaf variegation in plants.Additionally,one recent study has showed that a simple plastom...Plastome variation,including single spontaneous nucleotide substitutions and single insertions/deletions,is the major source of leaf variegation in plants.Additionally,one recent study has showed that a simple plastome structural variation,which is induced by one pair of small inverted repeats,can also result in leaf variegation.Here we show a complex plastome structural variation caused by intermolecular and intramolecular recombination across three pairs of small inverted repeats accounts for leaf variegation in a widely cultivated shrub Heptapleurum ellipticum(Araliaceae).This plastome structural variation contains two deletions and two duplications,resulting in dramatic expansion of IRs,substantial contraction of LSC and loss of 11 genes that essential for photosynthesis.Plastome heteroplasmy was detected in both green and albino sectors of variegated leaves.Relative to green sectors,albino sectors in the variegated leaves exhibit significantly reduced expression for the 11 genes lost in the mutated plastome as well as 26 other genes,but significantly increased expression for one gene related to translation apparatus.Optical and transmission electron microscopy observations showed that mesophyll cells of albino sectors possess plastids lacking grana lamellae,which likely carry the mutated plastome and contribute to albinism.In both sectors,the first layer of spongy mesophyll cells beneath the lower epidermis contains normal chloroplasts,suggesting periclinal division of the lower epidermis during development.Our study demonstrates that multiple small repeats can collectively mediate intra-and inter-molecular recombination in plastome and offers a new mechanism accounting for leaf variegation in plants.展开更多
Structural variation is an important source of genetic variation in wheat and have been important in the evolution of the wheat's genome.Few studies have examined the relationship between structural variations and...Structural variation is an important source of genetic variation in wheat and have been important in the evolution of the wheat's genome.Few studies have examined the relationship between structural variations and agronomy and drought tolerance.The present study identified structural chromosome variations(SCVs)in a doubled haploid(DH)population and backcross introgression lines(BC5F3)derived from Jinmai 47 and Jinmai 84 using fluorescence in situ hybridization(FISH).There are one simple translocation,10 present/absent variations(PAVs),and one copy number variation(CNV)between Jinmai 47 and Jinmai 84,which distributed in 10 chromosomes.Eight SCVs were associated with 15 agronomic traits.A PAV recombination occurred on chromosome 2A,which was associated with grain number per spike(GNS).The 1BL/1RS translocation and PAV.2D were associated with significant reductions in plant height,deriving from the effects on LI2-LI4,LI2-LI4 and UI,respectively respectively.PAV.2D was also contributed to an increase of 3.13%for GNS,1BL/1RS significantly increased spikelet number,grain length(GL),and grain thickness(GT).The effect of PAV.4A.1 on GL,PAV.6A on spike length(SL)and thousand-grain weight(TGW),PAV.6B on SL,GT and TGW were identified and verified.PAVs on chromosomes 2A,6A,1D,2D,and a CNV on chromosome 4B were associated with the drought tolerance coefficients.Additive and interaction effects among SCVs were observed.Many previously cloned key genes and yield-related QTL were found in polymorphic regions of PAV.2B,PAV.2D,and CNV.4B.Altogether,this study confirmed the genetic effect of SCVs on agronomy and drought tolerance,and identification of these SCVs will facilitate genetic improvement of wheat through marker-assisted selection.展开更多
Signal transduction in a cell is mostly mediated with biochemical reactions which are noisy and often modeled with chemical master equations or Langevin type of dynamics.Thus stochastic simulation constitutes a major ...Signal transduction in a cell is mostly mediated with biochemical reactions which are noisy and often modeled with chemical master equations or Langevin type of dynamics.Thus stochastic simulation constitutes a major part of computation in cell signaling.Nevertheless,the presence of a wide span of time scales or molecular numbers in various pathways may lead to trouble in computation efficiency or accuracy.To avoid this problem,the commonly employed variational method evolves the whole probability distribution and reduces the stochastic equations to deterministic ones of only a few parameters.However,the design of the left variational basis is essential for its successful application,especially to large networks.In this paper,we extend the conventional polynomial basis to the Fourier and further the Gaussian basis,much facilitating description of multi-peaked or localized non-Gaussian distributions and at the same time avoiding numerical instability and computational complexity frequently encountered with conventional basis.The extension here is demonstrated in several typical biochemical signaling networks and achieves similar accuracy as the benchmark Gillespie algorithm,but with much less running time,which seems to open new opportunities in the variational approach to efficient analysis of noisy dynamics.展开更多
Variational quantum algorithms(VQAs)with random structures have poor trainability due to the exponentially vanishing gradient as the circuit depth and the qubit number increase.This result leads to a general belief th...Variational quantum algorithms(VQAs)with random structures have poor trainability due to the exponentially vanishing gradient as the circuit depth and the qubit number increase.This result leads to a general belief that a deep circuit will not be feasible.In this work,we provide a viable solution to the vanishing gradient problem for deep VQAs with theoretical guarantees.Specifically,we prove that for quantum controlled-layer and quantum residual network(QResNet),architectures,the expectation of the gradient norm can be lower bounded by a value that is independent of the qubit number and the circuit depth.Our results follow from a careful analysis of the gradient behavior on parameter space consisting of rotation angles,as employed in almost all VQAs,instead of relying on impractical 2-design assumptions.We conduct several numerical experiments as verifications,where only our circuits are trainable and converge,while hardware-efficient and random circuits with similar number of parameters in comparison cannot converge.展开更多
Cirrus clouds play a crucial role in the energy balance of the Earth-atmosphere system.We investigated the spatiotemporal variations of cirrus over the South China Sea(SCS)using satellite data(MOD08,MYD08,CALIPSO)and ...Cirrus clouds play a crucial role in the energy balance of the Earth-atmosphere system.We investigated the spatiotemporal variations of cirrus over the South China Sea(SCS)using satellite data(MOD08,MYD08,CALIPSO)and reanalysis data(MERRA-2)from March 2007 to February 2015(eight years).The horizontal distribution reveals lower cirrus fraction values in the northern SCS and higher values in the southern region,with minima observed in March and April and maxima sequentially occurring in August(northern SCS,NSCS),September(middle SCS,MSCS),and December(southern SCS,SSCS).Vertically,the cirrus fraction peaks in summer and reaches its lowest levels in spring.Opaque cirrus dominates during summer in the NSCS and MSCS,comprising 53.6%and 55.9%,respectively,while the SSCS exhibits a higher frequency of opaque cirrus relative to other cloud types.Subvisible cirrus clouds have the lowest frequency year-round,whereas thin cirrus is most prominent in winter in the NSCS(46.3%)and in spring in the MSCS(45.3%).A case study from September 2021 further explores the influence of ice crystal habits on brightness temperature(BT)over the SCS.Simulations utilizing five ice crystal shapes from the ARTS DDA(Atmospheric Radiative Transfer Simulator Discrete Dipole Approximation)database and the RTTOV 12.4 radiative transfer model reveal that the 8-column-aggregate shape best represents BT in the NSCS and SSCS,while the large-block-aggregate shape performs better in the SSCS.展开更多
Understanding the spatial distributions and corresponding variation mechanisms of key soil nutrients in fragile karst ecosystems can assist in promoting sustainable development.However,due to the implementation of eco...Understanding the spatial distributions and corresponding variation mechanisms of key soil nutrients in fragile karst ecosystems can assist in promoting sustainable development.However,due to the implementation of ecological restoration initiatives such as land-use conversions,novel changes in the spatial characteristics of soil nutrients remain unknown.To address this gap,we explored nutrient variations and the drivers of the variation in the 0–15 cm topsoil layer using a regional-scale sampling method in a typical karst area in northwest Guangxi Zhuang Autonomous Region,Southwest China.Descriptive statistics,geostatistics,and spatial analysis were used to assess the soil nutrient variability.The results indicated that soil organic carbon(SOC),total nitrogen(TN),total phosphorus(TP),and total potassium(TK)concentrations showed moderate variations,with coefficients of variance being 0.60,0.60,0.71,and 0.72,respectively.Moreover,they demonstrated positive spatial autocorrelations,with global Moran's indices being 0.68,0.77,0.64,and 0.68,respectively.However,local Moran's index values were low,indicating large spatial variations in soil nutrients.The best-fitting semi-variogram models for SOC,TN,TP,and TK concentrations were spherical,Gaussian,exponential,and exponential,respectively.According to the classification criteria of the Second National Soil Census in China,SOC and TN concentrations were relatively sufficient,with the proportions of rich and very rich levels being up to 90.9 and 96.0%,respectively.TP concentration was in the mediumdeficient level,with the areas of medium and deficient levels accounting for 33.7 and 30.1%of the total,respectively.TK concentration was deficient,with the cumulative area of extremely deficient,very deficient,and deficient levels accounting for 87.6%of the total area.Consequently,the terrestrial ecosystems in the study area were more vulnerable to soil P and K than soil N deficiencies.Furthermore,variance partitioning analysis of the influencing factors showed that,except for the interactions,the single effect of other soil properties accounted more for soil nutrient variations than spatial and environmental variables.These results will aid in the future management of terrestrial ecosystems.展开更多
The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-bas...The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-based observations remain insufficient to clearly reflect the characteristics of the region’s lithospheric magnetism.In this study,we evaluate the lithospheric magnetism of the Tibetan Plateau by using a 3D surface spline model based on observations from>200 newly constructed repeat stations(portable stations)to determine the spatial distribution of plateau geomagnetism,as well as its correlation with the tectonic features of the region.We analyze the relationships between M≥5 earthquakes and lithospheric magnetic field variations on the Tibetan Plateau and identify regions susceptible to strong earthquakes.We compare the geomagnetic results with those from an enhanced magnetic model(EMM2015)developed by the NGDC and provide insights into improving lithospheric magnetic field calculations in the Tibetan Plateau region.Further research reveals that these magnetic anomalies exhibit distinct differences from the magnetic-seismic correlation mechanisms observed in other tectonic settings;here,they are governed primarily by the combined effects of compressional magnetism,thermal magnetism,and deep thermal stress.This study provides new evidence of geomagnetic anomalies on the Tibetan Plateau,interprets them physically,and demonstrates their potential for identifying seismic hazard zones on the Plateau.展开更多
In this manuscript,we consider a non-autonomous dynamical system.Using the Carathéodory structure,we define a BS dimension on an arbitrary subset and obtain a Bowen’s equation that illustrates the relation of th...In this manuscript,we consider a non-autonomous dynamical system.Using the Carathéodory structure,we define a BS dimension on an arbitrary subset and obtain a Bowen’s equation that illustrates the relation of the BS dimension to the Pesin-Pitskel topological pressure given by Nazarian[24].Moreover,we establish a variational principle and an inverse variational principle for the BS dimension of non-autonomous dynamical systems.Finally,we also get an analogue of Billingsley’s theorem for the BS dimension of non-autonomous dynamical systems.展开更多
Structural variations(SVs≥50 bp)are a critical but underexplored source of genetic diversity in cattle,shaping traits vital for productivity,adaptability,and health.Advances in long-read sequencing,pangenome graph co...Structural variations(SVs≥50 bp)are a critical but underexplored source of genetic diversity in cattle,shaping traits vital for productivity,adaptability,and health.Advances in long-read sequencing,pangenome graph construction,and near-complete genome assemblies now allow accurate SV detection and genotyping.These innovations overcome the limitations of single-reference genomes,enabling the discovery of complex SVs,including nested and overlapping variants,and providing access to previously inaccessible genomic regions such as centromeres and telomeres.This review highlights the current landscape of cattle SV research,with emphasis on integrating longread sequencing and pangenome frameworks to uncover breed-specific and population-level variation.While many SVs are linked to economically important traits such as feed efficiency and disease resistance,their broader regulatory impacts remain an active area of investigation.Emerging functional genomics approaches,including transcriptomics,epigenomics,and genome editing,will clarify how SVs influence gene regulation and phenotype.Looking forward,the integration of SV catalogs with multi-omics data,imputation resources,and artificial intelligence-driven models will be essential for translating discoveries into breeding and conservation applications.Integrating structural variants into breeding pipelines promises to revolutionize livestock genomics,enabling precision selection and sustainable agriculture despite challenges in cost,data sharing,and functional validation.展开更多
Prevention of biological invasion requires understanding how alien species invade native communities.Although studies have identified mechanisms that underlie plant invasion in some habitats,limited attention has focu...Prevention of biological invasion requires understanding how alien species invade native communities.Although studies have identified mechanisms that underlie plant invasion in some habitats,limited attention has focused on invasion patterns along elevational gradients.In this study,we asked which factors drive the global and regional distribution of the invasive plant Galinsoga quadriradiata along elevational gradients.To answer this question,we examined whether human activities(i.e.,roads)promote G.quadriradiata invasion,how seed dispersal-related traits of G.quadriradiata change along elevation gradients,and whether G.quadriradiata has adapted to high-elevation environments through phenotypic plasticity or genetic variation.On the global scale,we found that human activities and road density positively contribute to the G.quadriradiata expansion in mountainous areas.Field surveys in China revealed significant elevational differences in the seed dispersal traits of G.quadriradiata,with higher-elevation populations exhibiting lower dispersal ability and generally lower genetic diversity.Under common conditions,high-elevation populations showed higher leaf mass ratio but lower root mass ratio and reproductive allocation.This suggests that high-elevation environments create a barrier to dispersal for G.quadriradiata,and that G.quadriradiata has adapted phenotypically to these conditions.Our study indicates that the elevational invasion pattern of G.quadriradiata is shaped by multiple factors,particularly human activities and phenotypic adaptability.In addition,our finding that G.quadriradiata invasion at high elevations is not constrained by low genetic diversity indicates that monitoring and management of G.quadriradiata in mountainous areas should be strengthened.展开更多
Amyotrophic lateral sclerosis (ALS) is a fatal neurodegenerative disorder characterized by the progressive degeneration of upper and lower motor neurons in the brainstem and spinal cord,leading to muscle weakness,para...Amyotrophic lateral sclerosis (ALS) is a fatal neurodegenerative disorder characterized by the progressive degeneration of upper and lower motor neurons in the brainstem and spinal cord,leading to muscle weakness,paralysis,and respiratory failure (Morgan and Orrell,2016).展开更多
The strongest change in Meiyu periods in the mid-lower Yangtze Basin （MLY） since 1885 occurred in the late 1970s： a stage of weak Meiyu from 1958 to 1978 abruptly transformed into a stage of plentiful Meiyu from 19...The strongest change in Meiyu periods in the mid-lower Yangtze Basin （MLY） since 1885 occurred in the late 1970s： a stage of weak Meiyu from 1958 to 1978 abruptly transformed into a stage of plentiful Meiyu from 1979 to 1999. The average Meiyu amount of the latter 21 years increased by 66% compared with that of the former 21 years, accompanied by a significant increase in the occurrence of summer floods in the MLY. This change was closely related with the frequent phenomenon of postponed Meiyu ending dates （MED） and later onset dates of high summer （ODHS） in the MLY. To a considerable degree, this reflects an abrupt change of the summer climate in East China. Further analysis showed that the preceding factors contributing to inter-annual changes in Meiyu in the two 21-year stages delimited above were also very different from each other. The causes of change were associated with the following： China’s industrialization has greatly accelerated since the 1970s, accompanied by an increase in atmospheric pollution and a reduction of the solar radiation reaching the ground. The sand area of North China has also expanded due to overgrazing. The enhanced greenhouse effect is manifested in warm winters （especially in February）. Meanwhile, the January precipitation of the MLY has for the most part increased, and El Ni？o events have occurred more frequently since the late 1970s. A correlative scatter diagram consisting of these five factors mentioned above clearly shows that the two stages with opposite Meiyu characteristics are grouped in two contrasting locations with very different environmental （land-atmosphere） conditions. It is quite possible that we are now entering a new stage of lesser Meiyu, beginning in 2000.展开更多
Halocarbons play a vital role in ozone depletion and global warming,and are regulated by the Montreal Protocol(MP)and its amendments.China has been identified as an important contributor to the halocarbon emissions,bu...Halocarbons play a vital role in ozone depletion and global warming,and are regulated by the Montreal Protocol(MP)and its amendments.China has been identified as an important contributor to the halocarbon emissions,but the regional sources of halocarbons in China are not yet well comprehended.To investigate the characteristics,emissions,and source profiles,this study conducted a field campaign in Xiamen,a coastal city in southeastern China.Higher enhancements were found in the unregulated halocarbons(CH_(3)Cl,CH_(2)Cl_(2),CHCl_(3))than in the MP eliminated species(CCl_(4),CH_(3)Br)and theMP controlled species(HCFCs,HFCs).Many of the measured halocarbons varied seasonally and regionally,depending on the anthropogenic sources and atmospheric transport.Backward trajectory analysis showed that the air masses from inland were polluted over Shandong,Hebei,and northern Fujian in the cold season,while the air masses fromthe sea in the warm season were clean.Different air masses in two seasons were associated with the halocarbon patterns in the study area.Industrial activities,especially solvent usage,were the primary sources of halocarbons.The emission hot spots in Fujian Province were concentrated in Sanming,Fuzhou,and Xiamen,and the unregulated halocarbons made the largest contribution.This study provides an insight for a deep understanding of the characteristics and potential sources of halocarbons,and for strengthened management of halocarbons in China.展开更多
基金National Basic Research Program of China(No.2010CB950404,No.2013CB430202)National Natural Science Foundation of China(No.41130960)
文摘The present paper presents a concise summary of our recent studies on the Asian summer monsoon,with highting decadal and inter- decadal scales. The studies on the long- term variations of the Asian summer monsoon and its impacts on the change in the summer precipitation in China are reviewed. Moreover,recent changes in the Asian summer monsoon and summer precipitation in East Asia(including Meiyu precipitation)are discussed. Finally,the future changes of the Asian summer monsoon are also pointed out in this paper.
基金National Scaling Project A The Scientific Experiment on South China Sea Monsoon Part I from the fund for (G1998040900)
文摘By using the 40-year NCEP (1958-1997) grid point reanalysis meteorological data, we analyzed the inter-decadal variation on the climatic characteristics of the onset of South China Sea summer monsoon. The results are as follows. (1) There was great difference on the onset date of the SCS summer monsoon between the first two decades and the last two decades. It was late on the 6th pentad of May for the first two decades and was on the 4th and 5th pentad of May for the next two decades. (2) Except for the third decade (1978-1987), the establishment of the monsoon rainfall was one to two pentads earlier than the onset of the summer monsoon in all other three decades. (3) The onset of the SCS monsoon is the result of the abrupt development and eastward advancement of the southwesterly monsoon over the Bay of Bengal. The four-decade analysis shows that there were abrupt development of the southwesterly monsoon over the Bay of Bengal between the 3rd and 4th pentad of May, but there was great difference between its eastward movement and its onset intensity. These may have important effect to the earlier or later onset of the SCS summer monsoon. (4) During the onset of the SCS summer monsoon, there were great difference in the upper and lower circulation feature between the first two and the next two decades. At the lower troposphere of the first two decades, the Indian-Burma trough was stronger and the center of the subtropical high was located more eastward. At the upper troposphere, the northward movement of the center of subtropical high was large and located more northward after it landed on the Indo-China Peninsula. After comparison, we can see that the circulation feature of the last two decades was favorable to the establishment and development of the SCS summer monsoon.
基金the National Basic Science Key Program in China(Grant No.2006CB403600)the National Natural Science Foundation of China(Grant Nos.40633018 and 40705023)
文摘This study investigates the Stratosphere-Troposphere Exchange(STE)of water vapor,emphasizes its interdecadal variations over Asia in boreal summer,and discusses the influences of atmospheric heat sources over the Tibetan Plateau and the tropical western North Pacific(WNP)on them by using the Wei method with reanalysis data from the European Centre for Medium-Range Weather Forecasts(ECMWF)for the years of 1958-2001.The climatology shows that the upward transport of water vapor across the tropopause in boreal summer is the most robust over the joining area of the South Asian Peninsula and Indian-Pacific Oceans(defined as AIPO).The upward transport over there can persistently convey the abundant water vapor into the stratosphere and then influence the distribution and variation of the stratospheric water vapor.The analysis shows that interdecadal variations of the water vapor exchange over the AIPO are significant,and its abrupt change occurred in the mid-1970s and the early 1990s.In these three periods,as important channels of the water vapor exchange,the effect of Bay of Bengal-East Asia as well as South China Sea was gradually weakening,while the role of the WNP becomes more and more important.Further studies show that atmospheric heat sources over the Tibetan Plateau and the WNP are two main factors in determining the interdecadal variations of water vapor exchange.The thermal influences over the Tibetan Plateau and the WNP have been greatly adjusted over the pass 44 years.Their synthesis influences the interdecadal variations of the water vapor exchange by changing the Asian summer monsoon,but their roles vary with time and regions.Especially after 1992,the influence of heat source over the Tibetan Plateau remarkably weakens,while the heat source over the WNP dominates the across-tropopause water vapor exchange.Results have important implications for understanding the transport of other components in the atmosphere and estimating the impact of human activities(emission)on global climate.
基金supported by National Basic Research Program of China (Grant No. 2007CB411505)National Natural Science Foundation of China (Grant No. 40921003)Basic Research Fund of Chinese Academy of Meteorological Sciences (Grant No. 2010Z001)
文摘This study analyzes the inter-decadal variations of rainfall over southern China in spring (March-April-May) using the observed precipitation data for 1979-2004. The result shows that the variations of spring rainfall over southeastern China are opposite to those over and southwestern China in both inter-annual and inter-decadal time scales. The precipitation over south- ern China exhibits an apparent inter-decadal shift in the late 1980s. The accumulated spring rainfall has reduced 30% over southeastern China after the late 1980s, whereas it has increased twice as much over southwestern China. The atmospheric circulations related to this shift show that an abnormal high at lower and middle troposphere appears over Asian middle and high latitudes, accompanied by stronger-than-normal northerly wind over eastern China. Consequently, the wet air flows from tropical oceans are weakened over southern China, resulting in less rainfall over southeastern China and more rainfall over southwestern China. Furthermore, the anomalous atmospheric circulation over Asian middle and high latitudes is closely related to the inter-decadal downward shift of Eurasian spring snow in the late 1980s, indicating that the inter-decadal shift of Eurasian spring snow in the late 1980s is probably an important factor in the decadal shift of spring rainfall over southern China.
基金supported by the National Natural Science Founda-tion of China(Nos.42327806 and 52370108)Zhejiang Provincial Leading Project for Leading Geese Plan(No.2025C03073).
文摘Carbonyls play an important role in the atmospheric chemistry as the main precursor for reactive radicals and peroxyacetyl nitrate.However,little research has been conducted so far on the seasonal variations of carbonyls in China’s urban atmosphere.In this study,ambient carbonyls were 24-hourly observed in four seasons in Hangzhou,a mega-city in the Yangtze River Delta Region,China.The concentration of total carbonyls was the highest in summer(44.35μg/m^(3)),the second in winter(44.05μg/m^(3)),the third in spring(29.31μg/m^(3))and autumn(27.11μg/m^(3)).The most abundant species were found to be acetone in spring,summer,and winter,while formaldehyde in autumn.Rainfall can significantly reduce the concentrations of most ambient carbonyls,with the largest decrease observed in the wet precipitation events occurring in spring and summer,while acetone concentrations remained invariable due to its lower water solubility.Multiple linear regression analysis and carbonyls ratios indicated that anthropogenic emissions were the predominant sources of carbonyls,and atmospheric formaldehyde was mainly emitted from primary sources other than secondary sources.Vehicular exhaust was identified as the primary source of ambient carbonyls,particularly in winter,and its contribution reached 92.80%to formaldehyde.Additionally,photochemical reactions were closely associated with the secondary production of formaldehyde in summer.Carbonyls showed strong ozone formation potential in all four seasons.Based on the health risk assessment,the exposure to ambient carbonyls is harmful to outdoor pedestrians.The results could provide essential information and references for simulating regional air quality and analyzing ozone pollution,which is essential for improving air quality in the Yangtze River Delta region.
基金Project supported in part by Beijing Natural Science Foundation(Grant No.1232025)Peng Huanwu Visiting Pro-fessor Program,and Academy for Multidisciplinary Studies,Capital Normal University.
文摘Replicating the chaotic characteristics inherent in nonlinear dynamical systems via machine learning(ML)is a key challenge in this rapidly advancing interdisciplinary field.In this work,we explore the potential of variational quantum circuits(VQC)for learning the stochastic properties of classical nonlinear dynamical systems.Specifically,we focus on the one-and two-dimensional logistic maps,which,while simple,remain under-explored in the context of learning dynamical characteristics.Our findings reveal that,even for such simple dynamical systems,accurately replicating longterm characteristics is hindered by a pronounced sensitivity to overfitting.While increasing the parameter complexity of the ML model typically enhances short-term prediction accuracy,it also leads to a degradation in the model’s ability to replicate long-term characteristics,primarily due to the detrimental effects of overfitting on generalization power.By comparing the VQC with two widely recognized classical ML techniques,which are long short-term memory(LSTM)networks for timeseries processing and reservoir computing,we demonstrate that VQC outperforms these methods in terms of replicating long-term characteristics.Our results suggest that for the ML of dynamics,it is demanded to develop more compact and efficient models(such as VQC)rather than more complicated and large-scale ones.
基金supported financially by the National Natural Science Foundation of China(31811530297 and 32170217).
文摘Plastome variation,including single spontaneous nucleotide substitutions and single insertions/deletions,is the major source of leaf variegation in plants.Additionally,one recent study has showed that a simple plastome structural variation,which is induced by one pair of small inverted repeats,can also result in leaf variegation.Here we show a complex plastome structural variation caused by intermolecular and intramolecular recombination across three pairs of small inverted repeats accounts for leaf variegation in a widely cultivated shrub Heptapleurum ellipticum(Araliaceae).This plastome structural variation contains two deletions and two duplications,resulting in dramatic expansion of IRs,substantial contraction of LSC and loss of 11 genes that essential for photosynthesis.Plastome heteroplasmy was detected in both green and albino sectors of variegated leaves.Relative to green sectors,albino sectors in the variegated leaves exhibit significantly reduced expression for the 11 genes lost in the mutated plastome as well as 26 other genes,but significantly increased expression for one gene related to translation apparatus.Optical and transmission electron microscopy observations showed that mesophyll cells of albino sectors possess plastids lacking grana lamellae,which likely carry the mutated plastome and contribute to albinism.In both sectors,the first layer of spongy mesophyll cells beneath the lower epidermis contains normal chloroplasts,suggesting periclinal division of the lower epidermis during development.Our study demonstrates that multiple small repeats can collectively mediate intra-and inter-molecular recombination in plastome and offers a new mechanism accounting for leaf variegation in plants.
基金supported by the Science and Technology Major Project of Shanxi Province,China(202201140601025-2,202302140601001)the Agricultural Science Research Project of Shanxi Agricultural University,China(2023BQ108)+1 种基金the Senior Foreign Experts Introducing Project,China(G202204011L)the Science and Technology Innovation Young Talent Team of Shanxi Province,China(202204051001019)。
文摘Structural variation is an important source of genetic variation in wheat and have been important in the evolution of the wheat's genome.Few studies have examined the relationship between structural variations and agronomy and drought tolerance.The present study identified structural chromosome variations(SCVs)in a doubled haploid(DH)population and backcross introgression lines(BC5F3)derived from Jinmai 47 and Jinmai 84 using fluorescence in situ hybridization(FISH).There are one simple translocation,10 present/absent variations(PAVs),and one copy number variation(CNV)between Jinmai 47 and Jinmai 84,which distributed in 10 chromosomes.Eight SCVs were associated with 15 agronomic traits.A PAV recombination occurred on chromosome 2A,which was associated with grain number per spike(GNS).The 1BL/1RS translocation and PAV.2D were associated with significant reductions in plant height,deriving from the effects on LI2-LI4,LI2-LI4 and UI,respectively respectively.PAV.2D was also contributed to an increase of 3.13%for GNS,1BL/1RS significantly increased spikelet number,grain length(GL),and grain thickness(GT).The effect of PAV.4A.1 on GL,PAV.6A on spike length(SL)and thousand-grain weight(TGW),PAV.6B on SL,GT and TGW were identified and verified.PAVs on chromosomes 2A,6A,1D,2D,and a CNV on chromosome 4B were associated with the drought tolerance coefficients.Additive and interaction effects among SCVs were observed.Many previously cloned key genes and yield-related QTL were found in polymorphic regions of PAV.2B,PAV.2D,and CNV.4B.Altogether,this study confirmed the genetic effect of SCVs on agronomy and drought tolerance,and identification of these SCVs will facilitate genetic improvement of wheat through marker-assisted selection.
基金supported by the National Natural Science Foundation of China under Grants No.12375030。
文摘Signal transduction in a cell is mostly mediated with biochemical reactions which are noisy and often modeled with chemical master equations or Langevin type of dynamics.Thus stochastic simulation constitutes a major part of computation in cell signaling.Nevertheless,the presence of a wide span of time scales or molecular numbers in various pathways may lead to trouble in computation efficiency or accuracy.To avoid this problem,the commonly employed variational method evolves the whole probability distribution and reduces the stochastic equations to deterministic ones of only a few parameters.However,the design of the left variational basis is essential for its successful application,especially to large networks.In this paper,we extend the conventional polynomial basis to the Fourier and further the Gaussian basis,much facilitating description of multi-peaked or localized non-Gaussian distributions and at the same time avoiding numerical instability and computational complexity frequently encountered with conventional basis.The extension here is demonstrated in several typical biochemical signaling networks and achieves similar accuracy as the benchmark Gillespie algorithm,but with much less running time,which seems to open new opportunities in the variational approach to efficient analysis of noisy dynamics.
基金The national research foundation of Singapore(NRF-P2024-001).
文摘Variational quantum algorithms(VQAs)with random structures have poor trainability due to the exponentially vanishing gradient as the circuit depth and the qubit number increase.This result leads to a general belief that a deep circuit will not be feasible.In this work,we provide a viable solution to the vanishing gradient problem for deep VQAs with theoretical guarantees.Specifically,we prove that for quantum controlled-layer and quantum residual network(QResNet),architectures,the expectation of the gradient norm can be lower bounded by a value that is independent of the qubit number and the circuit depth.Our results follow from a careful analysis of the gradient behavior on parameter space consisting of rotation angles,as employed in almost all VQAs,instead of relying on impractical 2-design assumptions.We conduct several numerical experiments as verifications,where only our circuits are trainable and converge,while hardware-efficient and random circuits with similar number of parameters in comparison cannot converge.
基金supported by the National Natural Science Foundation of China(Grant Nos.42027804,41775026,and 41075012)。
文摘Cirrus clouds play a crucial role in the energy balance of the Earth-atmosphere system.We investigated the spatiotemporal variations of cirrus over the South China Sea(SCS)using satellite data(MOD08,MYD08,CALIPSO)and reanalysis data(MERRA-2)from March 2007 to February 2015(eight years).The horizontal distribution reveals lower cirrus fraction values in the northern SCS and higher values in the southern region,with minima observed in March and April and maxima sequentially occurring in August(northern SCS,NSCS),September(middle SCS,MSCS),and December(southern SCS,SSCS).Vertically,the cirrus fraction peaks in summer and reaches its lowest levels in spring.Opaque cirrus dominates during summer in the NSCS and MSCS,comprising 53.6%and 55.9%,respectively,while the SSCS exhibits a higher frequency of opaque cirrus relative to other cloud types.Subvisible cirrus clouds have the lowest frequency year-round,whereas thin cirrus is most prominent in winter in the NSCS(46.3%)and in spring in the MSCS(45.3%).A case study from September 2021 further explores the influence of ice crystal habits on brightness temperature(BT)over the SCS.Simulations utilizing five ice crystal shapes from the ARTS DDA(Atmospheric Radiative Transfer Simulator Discrete Dipole Approximation)database and the RTTOV 12.4 radiative transfer model reveal that the 8-column-aggregate shape best represents BT in the NSCS and SSCS,while the large-block-aggregate shape performs better in the SSCS.
基金supported by the National Natural Science Foundation of China(U2344201 and 42101316)the Natural Science Foundation of Hunan Province,China(2022JJ40866)the Outstanding Youth Project of Education Bureau of Hunan Province,China(20B613)。
文摘Understanding the spatial distributions and corresponding variation mechanisms of key soil nutrients in fragile karst ecosystems can assist in promoting sustainable development.However,due to the implementation of ecological restoration initiatives such as land-use conversions,novel changes in the spatial characteristics of soil nutrients remain unknown.To address this gap,we explored nutrient variations and the drivers of the variation in the 0–15 cm topsoil layer using a regional-scale sampling method in a typical karst area in northwest Guangxi Zhuang Autonomous Region,Southwest China.Descriptive statistics,geostatistics,and spatial analysis were used to assess the soil nutrient variability.The results indicated that soil organic carbon(SOC),total nitrogen(TN),total phosphorus(TP),and total potassium(TK)concentrations showed moderate variations,with coefficients of variance being 0.60,0.60,0.71,and 0.72,respectively.Moreover,they demonstrated positive spatial autocorrelations,with global Moran's indices being 0.68,0.77,0.64,and 0.68,respectively.However,local Moran's index values were low,indicating large spatial variations in soil nutrients.The best-fitting semi-variogram models for SOC,TN,TP,and TK concentrations were spherical,Gaussian,exponential,and exponential,respectively.According to the classification criteria of the Second National Soil Census in China,SOC and TN concentrations were relatively sufficient,with the proportions of rich and very rich levels being up to 90.9 and 96.0%,respectively.TP concentration was in the mediumdeficient level,with the areas of medium and deficient levels accounting for 33.7 and 30.1%of the total,respectively.TK concentration was deficient,with the cumulative area of extremely deficient,very deficient,and deficient levels accounting for 87.6%of the total area.Consequently,the terrestrial ecosystems in the study area were more vulnerable to soil P and K than soil N deficiencies.Furthermore,variance partitioning analysis of the influencing factors showed that,except for the interactions,the single effect of other soil properties accounted more for soil nutrient variations than spatial and environmental variables.These results will aid in the future management of terrestrial ecosystems.
基金supported by the CAS Pioneer Hundred Talents Program and Second Tibetan Plateau Scientific Expedition Research Program(2019QZKK0708)as well as the Basic Research Program of Qinghai Province:Lithospheric Geomagnetic Field of the Qinghai-Tibet Plateau and the Relationship with Strong Earthquakes(2021-ZJ-969Q).
文摘The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-based observations remain insufficient to clearly reflect the characteristics of the region’s lithospheric magnetism.In this study,we evaluate the lithospheric magnetism of the Tibetan Plateau by using a 3D surface spline model based on observations from>200 newly constructed repeat stations(portable stations)to determine the spatial distribution of plateau geomagnetism,as well as its correlation with the tectonic features of the region.We analyze the relationships between M≥5 earthquakes and lithospheric magnetic field variations on the Tibetan Plateau and identify regions susceptible to strong earthquakes.We compare the geomagnetic results with those from an enhanced magnetic model(EMM2015)developed by the NGDC and provide insights into improving lithospheric magnetic field calculations in the Tibetan Plateau region.Further research reveals that these magnetic anomalies exhibit distinct differences from the magnetic-seismic correlation mechanisms observed in other tectonic settings;here,they are governed primarily by the combined effects of compressional magnetism,thermal magnetism,and deep thermal stress.This study provides new evidence of geomagnetic anomalies on the Tibetan Plateau,interprets them physically,and demonstrates their potential for identifying seismic hazard zones on the Plateau.
基金supported by the NSFC(12461012)and the NSF of Chongqing(CSTB2024NSCQ-MSX1246).
文摘In this manuscript,we consider a non-autonomous dynamical system.Using the Carathéodory structure,we define a BS dimension on an arbitrary subset and obtain a Bowen’s equation that illustrates the relation of the BS dimension to the Pesin-Pitskel topological pressure given by Nazarian[24].Moreover,we establish a variational principle and an inverse variational principle for the BS dimension of non-autonomous dynamical systems.Finally,we also get an analogue of Billingsley’s theorem for the BS dimension of non-autonomous dynamical systems.
基金supported in part by AFRI grant numbers 2019-7015-29321 and 2021-67015-33409 from the USDA National Institute of Food and Agriculture(NIFA)the SCINet project of the USDA ARS project number 0500-00093-001-00-D。
文摘Structural variations(SVs≥50 bp)are a critical but underexplored source of genetic diversity in cattle,shaping traits vital for productivity,adaptability,and health.Advances in long-read sequencing,pangenome graph construction,and near-complete genome assemblies now allow accurate SV detection and genotyping.These innovations overcome the limitations of single-reference genomes,enabling the discovery of complex SVs,including nested and overlapping variants,and providing access to previously inaccessible genomic regions such as centromeres and telomeres.This review highlights the current landscape of cattle SV research,with emphasis on integrating longread sequencing and pangenome frameworks to uncover breed-specific and population-level variation.While many SVs are linked to economically important traits such as feed efficiency and disease resistance,their broader regulatory impacts remain an active area of investigation.Emerging functional genomics approaches,including transcriptomics,epigenomics,and genome editing,will clarify how SVs influence gene regulation and phenotype.Looking forward,the integration of SV catalogs with multi-omics data,imputation resources,and artificial intelligence-driven models will be essential for translating discoveries into breeding and conservation applications.Integrating structural variants into breeding pipelines promises to revolutionize livestock genomics,enabling precision selection and sustainable agriculture despite challenges in cost,data sharing,and functional validation.
基金supported by the National Natural Science Foundation of China(32271584 and 31600445)the Natural Science Basic Research Plan in Shaanxi Province of China(2020JM-286)+2 种基金the Fundamental Research Funds for the Central Universities(GK202103072,GK202103073)the National College Students'Innovative Entrepreneurial Training Plan Program(202310718085)Special Research Project in Philosophy and Social Sciences of Shaanxi Province(2022HZ1795).
文摘Prevention of biological invasion requires understanding how alien species invade native communities.Although studies have identified mechanisms that underlie plant invasion in some habitats,limited attention has focused on invasion patterns along elevational gradients.In this study,we asked which factors drive the global and regional distribution of the invasive plant Galinsoga quadriradiata along elevational gradients.To answer this question,we examined whether human activities(i.e.,roads)promote G.quadriradiata invasion,how seed dispersal-related traits of G.quadriradiata change along elevation gradients,and whether G.quadriradiata has adapted to high-elevation environments through phenotypic plasticity or genetic variation.On the global scale,we found that human activities and road density positively contribute to the G.quadriradiata expansion in mountainous areas.Field surveys in China revealed significant elevational differences in the seed dispersal traits of G.quadriradiata,with higher-elevation populations exhibiting lower dispersal ability and generally lower genetic diversity.Under common conditions,high-elevation populations showed higher leaf mass ratio but lower root mass ratio and reproductive allocation.This suggests that high-elevation environments create a barrier to dispersal for G.quadriradiata,and that G.quadriradiata has adapted phenotypically to these conditions.Our study indicates that the elevational invasion pattern of G.quadriradiata is shaped by multiple factors,particularly human activities and phenotypic adaptability.In addition,our finding that G.quadriradiata invasion at high elevations is not constrained by low genetic diversity indicates that monitoring and management of G.quadriradiata in mountainous areas should be strengthened.
文摘Amyotrophic lateral sclerosis (ALS) is a fatal neurodegenerative disorder characterized by the progressive degeneration of upper and lower motor neurons in the brainstem and spinal cord,leading to muscle weakness,paralysis,and respiratory failure (Morgan and Orrell,2016).
基金supported by the National Natural Science Foundation of China (Grant No40233037)
文摘The strongest change in Meiyu periods in the mid-lower Yangtze Basin （MLY） since 1885 occurred in the late 1970s： a stage of weak Meiyu from 1958 to 1978 abruptly transformed into a stage of plentiful Meiyu from 1979 to 1999. The average Meiyu amount of the latter 21 years increased by 66% compared with that of the former 21 years, accompanied by a significant increase in the occurrence of summer floods in the MLY. This change was closely related with the frequent phenomenon of postponed Meiyu ending dates （MED） and later onset dates of high summer （ODHS） in the MLY. To a considerable degree, this reflects an abrupt change of the summer climate in East China. Further analysis showed that the preceding factors contributing to inter-annual changes in Meiyu in the two 21-year stages delimited above were also very different from each other. The causes of change were associated with the following： China’s industrialization has greatly accelerated since the 1970s, accompanied by an increase in atmospheric pollution and a reduction of the solar radiation reaching the ground. The sand area of North China has also expanded due to overgrazing. The enhanced greenhouse effect is manifested in warm winters （especially in February）. Meanwhile, the January precipitation of the MLY has for the most part increased, and El Ni？o events have occurred more frequently since the late 1970s. A correlative scatter diagram consisting of these five factors mentioned above clearly shows that the two stages with opposite Meiyu characteristics are grouped in two contrasting locations with very different environmental （land-atmosphere） conditions. It is quite possible that we are now entering a new stage of lesser Meiyu, beginning in 2000.
基金supported by the National Natural Science Foundation of China(Nos.42030707,72394404)the International Partnership Program of the Chinese Academy of Sciences(No.121311KYSB20190029)the Fundamental Research Fund for the Central Universities(Nos.20720210083,20720210082).
文摘Halocarbons play a vital role in ozone depletion and global warming,and are regulated by the Montreal Protocol(MP)and its amendments.China has been identified as an important contributor to the halocarbon emissions,but the regional sources of halocarbons in China are not yet well comprehended.To investigate the characteristics,emissions,and source profiles,this study conducted a field campaign in Xiamen,a coastal city in southeastern China.Higher enhancements were found in the unregulated halocarbons(CH_(3)Cl,CH_(2)Cl_(2),CHCl_(3))than in the MP eliminated species(CCl_(4),CH_(3)Br)and theMP controlled species(HCFCs,HFCs).Many of the measured halocarbons varied seasonally and regionally,depending on the anthropogenic sources and atmospheric transport.Backward trajectory analysis showed that the air masses from inland were polluted over Shandong,Hebei,and northern Fujian in the cold season,while the air masses fromthe sea in the warm season were clean.Different air masses in two seasons were associated with the halocarbon patterns in the study area.Industrial activities,especially solvent usage,were the primary sources of halocarbons.The emission hot spots in Fujian Province were concentrated in Sanming,Fuzhou,and Xiamen,and the unregulated halocarbons made the largest contribution.This study provides an insight for a deep understanding of the characteristics and potential sources of halocarbons,and for strengthened management of halocarbons in China.
