A new chromatographic method is described for the determination of specific refractive index increment（dn/dc）μ at a constant chemical potential,for polymer/mixed solvent systems.In this method the（dn/dc）is obtain...A new chromatographic method is described for the determination of specific refractive index increment（dn/dc）μ at a constant chemical potential,for polymer/mixed solvent systems.In this method the（dn/dc）is obtained by measuring the areas of solvated-polymer peaks when the mixed solvent is used as an eluent.Values of（dn/dc）μ for the poly（dimethylsiloxane）（PDMS）-benzene-methanol system,determined by the proposed method are in good agreement with those determined by the conventional dialysis method.The new approach has the advantages of simplicity,fast speed,and high reproducibility.The experimental results for stearic acid-chloroform-methanol system show that this method can also be applied to nonpolymer/mixed solvent systems for the determination of（dn/dc）μ.展开更多
The refractive index increment, dynamic and static laser light scattering, intrinsic viscosity [η] and Huggins constant （KH） of nylon 12 have been measured in m-cresol and sulphuric acid/water system at 10-60℃. Th...The refractive index increment, dynamic and static laser light scattering, intrinsic viscosity [η] and Huggins constant （KH） of nylon 12 have been measured in m-cresol and sulphuric acid/water system at 10-60℃. The intrinsic viscosity, Rn, Rg, A2, and （〈 S 〉2）^1/2 （calculated from viscosity data） and ＂a＂ values of nylon 12 are found to be higher in m-cresol than in sulphuric acid. All these parameters decrease with the increase in water contents in sulphuric acid. The refractive index increment, KH and activation energy show an opposite trend to that of [η]. The intrinsic viscosity, RH, Rg, A2, and （〈 S 〉2）^1/2 have maximum values around 30-40℃ in sulphuric acid/water system, whereas in m-cresol they fall at about 20℃. It has been concluded that the variation in size, interaction parameter （second virial coefficient）, [η] and KH of the polymer solutions with the alteration in solvent composition and temperature are the out come of change in thermodynamic quality of solvents, selective adsorption, hydrogen bonding and conformational transitions. It has also been concluded that the increase in temperature first enhances the quality of the solvent, encourages hydrogen bonding and specific adsorption, and then deteriorates, bringing conformational transitions in the polymer molecules. However, the addition of water to sulphuric acid continuously deteriorates the solvent quality. This characteristic of the solvent system brings conformational changes in the polymer especially at low temperatures.展开更多
Since the reform and opening up in 1978, the improving efficiency of resource allocation, particularly the flow and migration of agricultural workforce to non-agricultural sectors, has contributed greatly to China'...Since the reform and opening up in 1978, the improving efficiency of resource allocation, particularly the flow and migration of agricultural workforce to non-agricultural sectors, has contributed greatly to China's economic growth. However, scholars have seldom carried out continuous empirical study on the extent of such contribution mainly due to limited methods for the calculation of labor allocation effect. This paper employs the incremental analysis method of index to separate labor allocation effect from economic growth in order to conduct an analysis on such effect under the framework of economic growth. Using this approach, this paper has calculated the labor allocation effect during various periods of time in China between 1978 and 2014 and the results indicate that the flow and migration of labor constituted the major source of China's economic growth during the periods between 1978 and 1987, between 1992 and 1998 and between 2003 and 2014 and still have great potentials in the coming decade. After 2025, the labor allocation effect will diminish and is likely to become a factor that hinders economic growth.展开更多
Accurate estimations of grain output in the agriculturally important region of Northeast China are of great strategic significance for guaranteeing food security.New prediction models for maize and rice yields are bui...Accurate estimations of grain output in the agriculturally important region of Northeast China are of great strategic significance for guaranteeing food security.New prediction models for maize and rice yields are built in this paper based on the spring North Atlantic Oscillation index and the Bering Sea ice cover index.The year-to-year increment is first forecasted and then the original yield value is obtained by adding the historical yield of the previous year.The multivariate linear prediction model of maize shows good predictive ability,with a low normalized root-mean-square error（NRMSE）of 13.9%,and the simulated yield accounts for 81%of the total variance of the observation.To improve the performance of the multivariate linear model,a combined forecasting model of rice is built by considering the weight of the predictors.The NRMSE of the model is 12.9%and the predicted rice yield explains 71%of the total variance.The corresponding cross-validation test and independent samples test further demonstrate the efficiency of the models.It is inferred that the statistical models established here by applying year-to-year increment approach could make rational prediction for the maize and rice yield in Northeast China before harvest.The present study may shed new light on yield prediction in advance by use of antecedent large-scale climate signals adequately.展开更多
基金Supported by the National Natural Science Foundation of China(No.20474040).
文摘A new chromatographic method is described for the determination of specific refractive index increment（dn/dc）μ at a constant chemical potential,for polymer/mixed solvent systems.In this method the（dn/dc）is obtained by measuring the areas of solvated-polymer peaks when the mixed solvent is used as an eluent.Values of（dn/dc）μ for the poly（dimethylsiloxane）（PDMS）-benzene-methanol system,determined by the proposed method are in good agreement with those determined by the conventional dialysis method.The new approach has the advantages of simplicity,fast speed,and high reproducibility.The experimental results for stearic acid-chloroform-methanol system show that this method can also be applied to nonpolymer/mixed solvent systems for the determination of（dn/dc）μ.
文摘The refractive index increment, dynamic and static laser light scattering, intrinsic viscosity [η] and Huggins constant （KH） of nylon 12 have been measured in m-cresol and sulphuric acid/water system at 10-60℃. The intrinsic viscosity, Rn, Rg, A2, and （〈 S 〉2）^1/2 （calculated from viscosity data） and ＂a＂ values of nylon 12 are found to be higher in m-cresol than in sulphuric acid. All these parameters decrease with the increase in water contents in sulphuric acid. The refractive index increment, KH and activation energy show an opposite trend to that of [η]. The intrinsic viscosity, RH, Rg, A2, and （〈 S 〉2）^1/2 have maximum values around 30-40℃ in sulphuric acid/water system, whereas in m-cresol they fall at about 20℃. It has been concluded that the variation in size, interaction parameter （second virial coefficient）, [η] and KH of the polymer solutions with the alteration in solvent composition and temperature are the out come of change in thermodynamic quality of solvents, selective adsorption, hydrogen bonding and conformational transitions. It has also been concluded that the increase in temperature first enhances the quality of the solvent, encourages hydrogen bonding and specific adsorption, and then deteriorates, bringing conformational transitions in the polymer molecules. However, the addition of water to sulphuric acid continuously deteriorates the solvent quality. This characteristic of the solvent system brings conformational changes in the polymer especially at low temperatures.
文摘Since the reform and opening up in 1978, the improving efficiency of resource allocation, particularly the flow and migration of agricultural workforce to non-agricultural sectors, has contributed greatly to China's economic growth. However, scholars have seldom carried out continuous empirical study on the extent of such contribution mainly due to limited methods for the calculation of labor allocation effect. This paper employs the incremental analysis method of index to separate labor allocation effect from economic growth in order to conduct an analysis on such effect under the framework of economic growth. Using this approach, this paper has calculated the labor allocation effect during various periods of time in China between 1978 and 2014 and the results indicate that the flow and migration of labor constituted the major source of China's economic growth during the periods between 1978 and 1987, between 1992 and 1998 and between 2003 and 2014 and still have great potentials in the coming decade. After 2025, the labor allocation effect will diminish and is likely to become a factor that hinders economic growth.
基金Supported by the National Natural Science Foundation of China(41210007 and 41421004)Basic Research and Operation Fund of Chinese Academy of Meteorological Sciences(2016Y007)
文摘Accurate estimations of grain output in the agriculturally important region of Northeast China are of great strategic significance for guaranteeing food security.New prediction models for maize and rice yields are built in this paper based on the spring North Atlantic Oscillation index and the Bering Sea ice cover index.The year-to-year increment is first forecasted and then the original yield value is obtained by adding the historical yield of the previous year.The multivariate linear prediction model of maize shows good predictive ability,with a low normalized root-mean-square error（NRMSE）of 13.9%,and the simulated yield accounts for 81%of the total variance of the observation.To improve the performance of the multivariate linear model,a combined forecasting model of rice is built by considering the weight of the predictors.The NRMSE of the model is 12.9%and the predicted rice yield explains 71%of the total variance.The corresponding cross-validation test and independent samples test further demonstrate the efficiency of the models.It is inferred that the statistical models established here by applying year-to-year increment approach could make rational prediction for the maize and rice yield in Northeast China before harvest.The present study may shed new light on yield prediction in advance by use of antecedent large-scale climate signals adequately.
