Accurate acquisition and prediction of acoustic parameters of seabed sediments are crucial in marine sound propagation research.While the relationship between sound velocity and physical properties of sediment has bee...Accurate acquisition and prediction of acoustic parameters of seabed sediments are crucial in marine sound propagation research.While the relationship between sound velocity and physical properties of sediment has been extensively studied,there is still no consensus on the correlation between acoustic attenuation coefficient and sediment physical properties.Predicting the acoustic attenuation coefficient remains a challenging issue in sedimentary acoustic research.In this study,we propose a prediction method for the acoustic attenuation coefficient using machine learning algorithms,specifically the random forest(RF),support vector machine(SVR),and convolutional neural network(CNN)algorithms.We utilized the acoustic attenuation coefficient and sediment particle size data from 52 stations as training parameters,with the particle size parameters as the input feature matrix,and measured acoustic attenuation as the training label to validate the attenuation prediction model.Our results indicate that the error of the attenuation prediction model is small.Among the three models,the RF model exhibited the lowest prediction error,with a mean squared error of 0.8232,mean absolute error of 0.6613,and root mean squared error of 0.9073.Additionally,when we applied the models to predict the data collected at different times in the same region,we found that the models developed in this study also demonstrated a certain level of reliability in real prediction scenarios.Our approach demonstrates that constructing a sediment acoustic characteristics model based on machine learning is feasible to a certain extent and offers a novel perspective for studying sediment acoustic properties.展开更多
Graphene-copper(Gr-Cu)composites exhibit significant potential for industrial applications.Among the methods for fabricating Gr-Cu composites,the in-situ growth method stands out as a simple yet effective approach.How...Graphene-copper(Gr-Cu)composites exhibit significant potential for industrial applications.Among the methods for fabricating Gr-Cu composites,the in-situ growth method stands out as a simple yet effective approach.However,graphene converted from liquid or solid molecules by the traditional in-situ growth method often exhibits numerous defects,thereby reducing its effectiveness in enhancing the electrical properties of the composites.To address this issue,we developed an innovative and efficient method,referred to as the“confinedparallel-space in-situ growth(CPS)method,”to grow highquality graphene and fabricate high-conductivity Gr-Cu composites.Oleic acid was chosen as the small molecular carbon source and confined between copper sheets obtained by rolling dendritic copper powder.This carbon source underwent conversion into oriented,high-quality graphene in the confined space at high temperature.The high-quality graphene sheets serve as continuous electron transport channels,significantly improving the conductivity of the composite.The composite prepared by the CPS method(CPS-composite)demonstrates unique conductivity,exceeding that of standard annealed copper at temperatures above 40℃and notably outperforming it by 3.2%at160℃.In addition,compared to the composite with a similar carbon content prepared by the traditional in-situ growth method,the yield strength of the CPS-composite increased by 23.6%,while the strengthening efficiency of graphene improved by 146.6%,achieving an ultrahigh value of 489 at a carbon volume fraction of 0.086 vol%.The CPS method emerges as a novel strategy for fabricating high-performance,low-cost,and large-scale graphene-copper composites using small molecular carbon sources,making it suitable for industrial production.展开更多
The utilization of lunar regolith for construction on the lunar surface presents a critical challenge in-situ resource utilization.This study proposes a lunar regolith manufacturing method that uses a high-performance...The utilization of lunar regolith for construction on the lunar surface presents a critical challenge in-situ resource utilization.This study proposes a lunar regolith manufacturing method that uses a high-performance resin binder characterized by a high regolith content and strong forming capabilities.A combined resin material with both thermosetting and photosetting properties was developed and mixed with lunar regolith to create a slurry.This slurry can be directly molded or additively extruded into green bodies with specific structures.These green bodies can self-cure under the high temperatures and ultraviolet radiation experienced during the lunar day,reducing energy consumption and fulfilling the requirements of lunar construction.The material-forming processes and effects of various additive types and concentrations,regolith mass ratios,and processing parameters on the properties of the slurry and the formed specimens were thoroughly investigated.The mechanical performance and microstructure of the fabricated samples were analyzed.The lunar regolith mass ratio reached 90 wt%(approximately 79 vol%),with the highest compressive strengths exceeding 60 MPa for cast specimens and 30 MPa for printed samples.This technology shows significant potential for enabling in-situ lunar regolith-based construction in future lunar missions.展开更多
To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,t...To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,the effects of carrier gas types,regeneration temperatures,and granular activated carbon(GAC)addition on iron-based catalyst regeneration were investigated.The Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regenerated at 550°C with additional GAC and 15%water vapor exhibited the optimal degradation efficiency towards polychlorinated biphenyls(PCBs),with an increase from 41.2%to 93.5%,compared with non-regenerated Fe_(3)O_(4)/𝛾-Al_(2)O_(3).In addition,the 60-hour stability test revealed a well-recovered catalytic activity.During the Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regeneration,the coke on the catalyst surface was oxidized and removed in the form of CO_(2),and meanwhile the oxidized Fe(III)was reduced into Fe(II)in the catalyst.This study provides a safe and efficient iron-based catalyst regeneration technology for PCB off-gas degradation and reveals the catalytic activity recovery mechanism during catalyst regeneration.展开更多
In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to ...In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method.展开更多
In this paper,a novel method for investigating the particle-crushing behavior of breeding particles in a fusion blanket is proposed.The fractal theory and Weibull distribution are combined to establish a theoretical m...In this paper,a novel method for investigating the particle-crushing behavior of breeding particles in a fusion blanket is proposed.The fractal theory and Weibull distribution are combined to establish a theoretical model,and its validity was verified using a simple impact test.A crushable discrete element method(DEM)framework is built based on the previously established theoretical model.The tensile strength,which considers the fractal theory,size effect,and Weibull variation,was assigned to each generated particle.The assigned strength is then used for crush detection by comparing it with its maximum tensile stress.Mass conservation is ensured by inserting a series of sub-particles whose total mass was equal to the quality loss.Based on the crushable DEM framework,a numerical simulation of the crushing behavior of a pebble bed with hollow cylindrical geometry under a uniaxial compression test was performed.The results of this investigation showed that the particle withstands the external load by contact and sliding at the beginning of the compression process,and the results confirmed that crushing can be considered an important method of resisting the increasing external load.A relatively regular particle arrangement aids in resisting the load and reduces the occurrence of particle crushing.However,a limit exists to the promotion of resistance.When the strain increases beyond this limit,the distribution of the crushing position tends to be isotropic over the entire pebble bed.The theoretical model and crushable DEM framework provide a new method for exploring the pebble bed in a fusion reactor,considering particle crushing.展开更多
Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision...Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision process is formulated as a Markov decision process(MDP)model to maximize the modularity.Corresponding key partitioning constraints on parallel restoration are considered.Second,based on the partitioning objective and constraints,the reward function of the partitioning MDP model is set by adopting a relative deviation normalization scheme to reduce mutual interference between the reward and penalty in the reward function.The soft bonus scaling mechanism is introduced to mitigate overestimation caused by abrupt jumps in the reward.Then,the deep Q network method is applied to solve the partitioning MDP model and generate partitioning schemes.Two experience replay buffers are employed to speed up the training process of the method.Finally,case studies on the IEEE 39-bus test system demonstrate that the proposed method can generate a high-modularity partitioning result that meets all key partitioning constraints,thereby improving the parallelism and reliability of the restoration process.Moreover,simulation results demonstrate that an appropriate discount factor is crucial for ensuring both the convergence speed and the stability of the partitioning training.展开更多
The application of nitrogen fertilizers in agricultural fields can lead to the release of nitrogen-containing gases(NCGs),such as NO_(x),NH_(3) and N_(2)O,which can significantly impact regional atmospheric environmen...The application of nitrogen fertilizers in agricultural fields can lead to the release of nitrogen-containing gases(NCGs),such as NO_(x),NH_(3) and N_(2)O,which can significantly impact regional atmospheric environment and con-tribute to global climate change.However,there remain considerable research gaps in the accurate measurement of NCGs emissions from agricultural fields,hindering the development of effective emission reduction strategies.We improved an open-top dynamic chambers(OTDCs)system and evaluated the performance by comparing the measured and given fluxes of the NCGs.The results showed that the measured fluxes of NO,N_(2)O and NH_(3)were 1%,2%and 7%lower than the given fluxes,respectively.For the determination of NH_(3) concentration,we employed a stripping coil-ion chromatograph(SC-IC)analytical technique,which demonstrated an absorption efficiency for atmospheric NH_(3) exceeding 96.1%across sampling durations of 6 to 60 min.In the summer maize season,we utilized the OTDCs system to measure the exchange fluxes of NO,NH_(3),and N_(2)O from the soil in the North China Plain.Substantial emissions of NO,NH_(3) and N_(2)O were recorded following fertilization,with peaks of 107,309,1239 ng N/(m^(2)·s),respectively.Notably,significant NCGs emissions were observed following sus-tained heavy rainfall one month after fertilization,particularly with NH_(3) peak being 4.5 times higher than that observed immediately after fertilization.Our results demonstrate that the OTDCs system accurately reflects the emission characteristics of soil NCGs and meets the requirements for long-term and continuous flux observation.展开更多
Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The t...Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.展开更多
At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systema...At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater.展开更多
The effect of maleic anhydride grafted styrene-ethylene- buty-lene-styrene block copolymer (SEBS-g-MAH) and in-situ grafting MAH on mechanical, dynamic mechanical properties of wood flour/recycled plastic blends com...The effect of maleic anhydride grafted styrene-ethylene- buty-lene-styrene block copolymer (SEBS-g-MAH) and in-situ grafting MAH on mechanical, dynamic mechanical properties of wood flour/recycled plastic blends composites was investigated. Recycled plastic polypro-pylene (PP), high-density polyethylene (HDPE) and polystyrene (PS), were mixed with wood flour in a high speed blender and then extruded by a twin/single screw tandem extruder system to form wood flour/recycled plastic blends composites. Results show that the impact properties of the composites were improved more significantly by using SEBS-g-MAH compatibilizer than by using the mixtures of MAH and DCP via reactive blending in situ. However, contrary results were ob-served on the tensile and flexural properties of the corresponding com-posites. In General, the mechanical properties of composites made from recycled plastic blends were inferior to those made from virgin plastic blends, especially in elongation break. The morphological study verified that the interfacial adhesion or the compatibility of plastic blends with wood flour was improved by adding SEBS-g-MAH or in-situ grafting MAH. A better interfacial bonding between PP, HDPE, PS and wood flour was obtained by in-situ grafting MAH than the addition of SEBS-g-MAH. In-situ grafting MAH can be considered as a potential way of increasing the interfacial compatibility between plastic blends and wood flour. The storage modulus and damping factor of composites were also characterized through dynamic mechanical analysis (DMA).展开更多
In the context of deep rock engineering,the in-situ stress state is of major importance as it plays an important role in rock dynamic response behavior.Thus,stress initialization becomes crucial and is the first step ...In the context of deep rock engineering,the in-situ stress state is of major importance as it plays an important role in rock dynamic response behavior.Thus,stress initialization becomes crucial and is the first step for the dynamic response simulation of rock mass in a high in-situ stress field.In this paper,stress initialization methods,including their principles and operating procedures for reproducing steady in-situ stress state in LS-DYNA,are first introduced.Then the most popular four methods,i.e.,explicit dynamic relaxation(DR)method,implicit-explicit sequence method,Dynain file method and quasi-static method,are exemplified through a case analysis by using the RHT and plastic hardening rock material models to simulate rock blasting under in-situ stress condition.Based on the simulations,it is concluded that the stress initialization results obtained by implicit-explicit sequence method and dynain file method are closely related to the rock material model,and the explicit DR method has an obvious advantage in solution time when compared to other methods.Besides that,it is recommended to adopt two separate analyses for the whole numerical simulation of rock mass under the combined action of in-situ stress and dynamic disturbance.展开更多
With the rapid increase of energy demand and the increasingly highlighted environmental problems, clean, safe and widely distributed geothermal resources have become a hot spot for renewable resources development. The...With the rapid increase of energy demand and the increasingly highlighted environmental problems, clean, safe and widely distributed geothermal resources have become a hot spot for renewable resources development. The state of in-situ stress is a major control parameter for multiple links including well location, fracture inspiration and reservoir assessment, so how to determine the accurate state of in-situ stress in the deep thermal reservoir becomes a core problem drawing widely attention and urgent to be solved. Based on features of hot dry rock reservoir in terms of temperature and pressure and the comparison analysis, this article proposes the method of Anelastic Strain Recovery(ASR) as an effective method for determining the state of in-situ stress in the area with HDR resources distributed and explains the availability of ASR method by application examples.展开更多
Double packer equipment for hydraulic test can be used to measure pressure of test zone directly, and it is frequently used to perform many kinds of hydraulic tests and take groundwater sample from borehole. The test ...Double packer equipment for hydraulic test can be used to measure pressure of test zone directly, and it is frequently used to perform many kinds of hydraulic tests and take groundwater sample from borehole. The test method of this equipment mainly includes the test design, implementation, interpretation and synthetic analysis. By adopting the double packer equipment for hydraulic test, the parameter distribution of rock permeability along borehole can be acquired, as well as the connectivity, water conductivity and water bearing capacity of the disclosed structure and the chemical characteristics of the deep groundwater. It is a necessary method for the research and evaluation of the complex hypotonicity terrace site selection under geological conditions. This method is not only suitable for the geological disposal of high level radioactive waste, but also can be used in the site selection of underground facilities such as storage of petroleum and carbon dioxide. Meanwhile, it has a good application prospect in other hydrogeological investigation fields.展开更多
Moisture content is a fundamental physical index that quantifies soil property and is closely associatedwith the hydrological, ecological and engineering behaviors of soil. To measure in-situ soil moisturecontents, a ...Moisture content is a fundamental physical index that quantifies soil property and is closely associatedwith the hydrological, ecological and engineering behaviors of soil. To measure in-situ soil moisturecontents, a distributed measurement system for in-situ soil moisture content (SM-DTS) is introduced.The system is based on carbon-fiber heated cable (CFHC) technology that has been developed to enhancethe measuring accuracy of in-situ soil moisture content. Using CFHC technique, a temperature characteristicvalue (Tt) can be defined from temperatureetime curves. A relationship among Tt, soil thermalimpedance coefficient and soil moisture content is then established in laboratory. The feasibility of theSM-DTS technology to provide distributed measurements of in-situ soil moisture content is verifiedthrough field tests. The research reported herein indicates that the proposed SM-DTS is capable ofmeasuring in-situ soil moisture content over long distances and large areas.展开更多
Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reacti...Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reactions process.TiC and Ti5Si3 were two important intermediate phases during the whole reactions.The microstructure characteristics of the Ti3SiC2/TiB2 composites were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The experimental results show that the grains of Ti3SiC2/TiB2 composite are structured in a layered form,and the formation of TiB2 particles as reinforcements with elongated or equiaxed shape distributes in Ti3SiC2 matrix.展开更多
Due to the long-term plate tectonic movements in southwestern China,the in-situ stress field in deep formations is complex.When passing through deep soft-rock mass under non-hydrostatic high in-situ stress field,tunne...Due to the long-term plate tectonic movements in southwestern China,the in-situ stress field in deep formations is complex.When passing through deep soft-rock mass under non-hydrostatic high in-situ stress field,tunnels will suffer serious asymmetric deformation.There is no available support design method for tunnels under such a situation in existing studies to clarify the support time and support stiffness.This study first analyzed the mechanical behavior of tunnels in non-hydrostatic in-situ stress field and derived the theoretical equations of the ground squeezing curve(GSC)and ground loosening curve(GLC).Then,based on the convergence confinement theory,the support design method of deep soft-rock tunnels under non-hydrostatic high in-situ stress field was established considering both squeezing and loosening pressures.In addition,this method can provide the clear support time and support stiffness of the second layer of initial support.The proposed design method was applied to the Wanhe tunnel of the China-Laos railway in China.Monitoring data indicated that the optimal support scheme had a good effect on controlling the tunnel deformation in non-hydrostatic high in-situ stress field.Field applications showed that the secondary lining could be constructed properly.展开更多
Tungsten nanoparticle-strengthened Cu composites were prepared from nanopowder synthesized by a sol–gel method and in-situ hydrogen reduction.The tungsten particles in the Cu matrix were well-dispersed with an averag...Tungsten nanoparticle-strengthened Cu composites were prepared from nanopowder synthesized by a sol–gel method and in-situ hydrogen reduction.The tungsten particles in the Cu matrix were well-dispersed with an average size of approximately 100–200 nm.The addition of nanosized W particles remarkably improves the mechanical properties,while the electrical conductivity did not substantially decrease.The Cu–W composite with 6 wt%W has the most comprehensive properties with an ultimate strength of 310 MPa,yield strength of 238 MPa,hardness of HV 108 and electrical conductivity of 90%IACS.The enhanced mechanical property and only a small loss of electrical conductivity demonstrate the potential of this new strategy to prepare W nanoparticle-strengthened Cu composites.展开更多
Based on the characteristics of pile-soil interaction and the Mohr-Coulomb strength theory,a new method of determining the side friction at a pile-soil interaction is proposed.Combined with the actual engineering case...Based on the characteristics of pile-soil interaction and the Mohr-Coulomb strength theory,a new method of determining the side friction at a pile-soil interaction is proposed.Combined with the actual engineering cases,the effectiveness of the analogue test method is verified by comparing it with the traditional anchor pile method and self-balanced method.Taking the self-balanced test of the bridge pile foundation in the Songhua River as an example,the conversion factor of sandy soil and weathered mudstone are confirmed by the analogue test method.The results show that the conversion factor of sandy soil and weathered mudstone in the Songhua River area should consider the geological conditions and the construction technology,etc.The standard values are relatively conservative.It is suggested that the engineering application should be properly revised.The recommended range of the conversion factor of sandy soil in this area is 0.65 to 0.85,and that of weathered mudstone is 1.0.展开更多
Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based...Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based composites reinforced with a volume fraction of 10% to 25%(TiB+TiC)were prepared using powder metallurgy and casting technique.Microstructural characterization and phase constitution were examined using optical microscopy(OM),scanning electron microscopy(SEM),and X-ray diffraction(XRD).In addition,the microhardness,room temperature(RT)and high temperature(HT)tensile properties of the composites were evaluated.Results revealed that the reinforcements are distributed uniformly even in the composites with a high volume of TiB and TiC.However,as the volume fraction exceeds 15%,TiB and TiC particles become coarsening and exhibit rod-like and dendritic-like morphology.Microhardness increases gradually from 321.2 HV for the base alloy to a maximum of 473.3 HV as the reinforcement increases to 25vol.%.Tensile test results indicate that a reinforcement volume fraction above 20% is beneficial for enhancing tensile strength and yield strength at high temperatures,but it has an adverse effect on room temperature elongation.Conversely,if the reinforcement volume fraction is below 20%,it can improve high-temperature elongation when the temperature exceeds 600℃.展开更多
基金funded by the Basic Scientific Fund for National Public Research Institutes of China(No.2022 S01)the National Natural Science Foundation of China(Nos.42176191,42049902,and U22A2012)+5 种基金the Shandong Provincial Natural Science Foundation,China(No.ZR2022YQ40)the National Key R&D Program of China(No.2021YFF0501202)the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2023 SP232)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.241gqb006)Data acquisition and sample collections were supported by the National Natural Science Foundation of China Open Research Cruise(Cruise No.NORC2021-02+NORC2021301)funded by the Shiptime Sharing Project of the National Natural Science Foundation of China。
文摘Accurate acquisition and prediction of acoustic parameters of seabed sediments are crucial in marine sound propagation research.While the relationship between sound velocity and physical properties of sediment has been extensively studied,there is still no consensus on the correlation between acoustic attenuation coefficient and sediment physical properties.Predicting the acoustic attenuation coefficient remains a challenging issue in sedimentary acoustic research.In this study,we propose a prediction method for the acoustic attenuation coefficient using machine learning algorithms,specifically the random forest(RF),support vector machine(SVR),and convolutional neural network(CNN)algorithms.We utilized the acoustic attenuation coefficient and sediment particle size data from 52 stations as training parameters,with the particle size parameters as the input feature matrix,and measured acoustic attenuation as the training label to validate the attenuation prediction model.Our results indicate that the error of the attenuation prediction model is small.Among the three models,the RF model exhibited the lowest prediction error,with a mean squared error of 0.8232,mean absolute error of 0.6613,and root mean squared error of 0.9073.Additionally,when we applied the models to predict the data collected at different times in the same region,we found that the models developed in this study also demonstrated a certain level of reliability in real prediction scenarios.Our approach demonstrates that constructing a sediment acoustic characteristics model based on machine learning is feasible to a certain extent and offers a novel perspective for studying sediment acoustic properties.
基金financially supported by Harbin Ship Boiler and Turbine Research Institute Stability Support Project and Heilongjiang Province Young Scientific and Technological Talent Lift Project(No.2023QNTJ)
文摘Graphene-copper(Gr-Cu)composites exhibit significant potential for industrial applications.Among the methods for fabricating Gr-Cu composites,the in-situ growth method stands out as a simple yet effective approach.However,graphene converted from liquid or solid molecules by the traditional in-situ growth method often exhibits numerous defects,thereby reducing its effectiveness in enhancing the electrical properties of the composites.To address this issue,we developed an innovative and efficient method,referred to as the“confinedparallel-space in-situ growth(CPS)method,”to grow highquality graphene and fabricate high-conductivity Gr-Cu composites.Oleic acid was chosen as the small molecular carbon source and confined between copper sheets obtained by rolling dendritic copper powder.This carbon source underwent conversion into oriented,high-quality graphene in the confined space at high temperature.The high-quality graphene sheets serve as continuous electron transport channels,significantly improving the conductivity of the composite.The composite prepared by the CPS method(CPS-composite)demonstrates unique conductivity,exceeding that of standard annealed copper at temperatures above 40℃and notably outperforming it by 3.2%at160℃.In addition,compared to the composite with a similar carbon content prepared by the traditional in-situ growth method,the yield strength of the CPS-composite increased by 23.6%,while the strengthening efficiency of graphene improved by 146.6%,achieving an ultrahigh value of 489 at a carbon volume fraction of 0.086 vol%.The CPS method emerges as a novel strategy for fabricating high-performance,low-cost,and large-scale graphene-copper composites using small molecular carbon sources,making it suitable for industrial production.
基金supported by International Partnership Program of the Chinese Academy of Sciences(Grant No.310GJH2024010GC)National Natural Science Foundation of China(Grant No.52005479)the China Building Materials Federation(Grant No.2023JBGS0401)。
文摘The utilization of lunar regolith for construction on the lunar surface presents a critical challenge in-situ resource utilization.This study proposes a lunar regolith manufacturing method that uses a high-performance resin binder characterized by a high regolith content and strong forming capabilities.A combined resin material with both thermosetting and photosetting properties was developed and mixed with lunar regolith to create a slurry.This slurry can be directly molded or additively extruded into green bodies with specific structures.These green bodies can self-cure under the high temperatures and ultraviolet radiation experienced during the lunar day,reducing energy consumption and fulfilling the requirements of lunar construction.The material-forming processes and effects of various additive types and concentrations,regolith mass ratios,and processing parameters on the properties of the slurry and the formed specimens were thoroughly investigated.The mechanical performance and microstructure of the fabricated samples were analyzed.The lunar regolith mass ratio reached 90 wt%(approximately 79 vol%),with the highest compressive strengths exceeding 60 MPa for cast specimens and 30 MPa for printed samples.This technology shows significant potential for enabling in-situ lunar regolith-based construction in future lunar missions.
基金supported by the Fundamental Research Funds for the Central Publicinterest Scientific Institution(No.2024YSKY-44)the National Key R&D Program of China(No.2023YFC3708003).
文摘To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,the effects of carrier gas types,regeneration temperatures,and granular activated carbon(GAC)addition on iron-based catalyst regeneration were investigated.The Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regenerated at 550°C with additional GAC and 15%water vapor exhibited the optimal degradation efficiency towards polychlorinated biphenyls(PCBs),with an increase from 41.2%to 93.5%,compared with non-regenerated Fe_(3)O_(4)/𝛾-Al_(2)O_(3).In addition,the 60-hour stability test revealed a well-recovered catalytic activity.During the Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regeneration,the coke on the catalyst surface was oxidized and removed in the form of CO_(2),and meanwhile the oxidized Fe(III)was reduced into Fe(II)in the catalyst.This study provides a safe and efficient iron-based catalyst regeneration technology for PCB off-gas degradation and reveals the catalytic activity recovery mechanism during catalyst regeneration.
基金Supported in part by Natural Science Foundation of Guangxi(2023GXNSFAA026246)in part by the Central Government's Guide to Local Science and Technology Development Fund(GuikeZY23055044)in part by the National Natural Science Foundation of China(62363003)。
文摘In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method.
基金supported by Anhui Provincial Natural Science Foundation(2408085QA030)Natural Science Research Project of Anhui Educational Committee,China(2022AH050825)+3 种基金Medical Special Cultivation Project of Anhui University of Science and Technology(YZ2023H2C008)the Excellent Research and Innovation Team of Anhui Province,China(2022AH010052)the Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology,China(2021yjrc51)Collaborative Innovation Program of Hefei Science Center,CAS,China(2019HSC-CIP006).
文摘In this paper,a novel method for investigating the particle-crushing behavior of breeding particles in a fusion blanket is proposed.The fractal theory and Weibull distribution are combined to establish a theoretical model,and its validity was verified using a simple impact test.A crushable discrete element method(DEM)framework is built based on the previously established theoretical model.The tensile strength,which considers the fractal theory,size effect,and Weibull variation,was assigned to each generated particle.The assigned strength is then used for crush detection by comparing it with its maximum tensile stress.Mass conservation is ensured by inserting a series of sub-particles whose total mass was equal to the quality loss.Based on the crushable DEM framework,a numerical simulation of the crushing behavior of a pebble bed with hollow cylindrical geometry under a uniaxial compression test was performed.The results of this investigation showed that the particle withstands the external load by contact and sliding at the beginning of the compression process,and the results confirmed that crushing can be considered an important method of resisting the increasing external load.A relatively regular particle arrangement aids in resisting the load and reduces the occurrence of particle crushing.However,a limit exists to the promotion of resistance.When the strain increases beyond this limit,the distribution of the crushing position tends to be isotropic over the entire pebble bed.The theoretical model and crushable DEM framework provide a new method for exploring the pebble bed in a fusion reactor,considering particle crushing.
基金funded by the Beijing Engineering Research Center of Electric Rail Transportation.
文摘Effective partitioning is crucial for enabling parallel restoration of power systems after blackouts.This paper proposes a novel partitioning method based on deep reinforcement learning.First,the partitioning decision process is formulated as a Markov decision process(MDP)model to maximize the modularity.Corresponding key partitioning constraints on parallel restoration are considered.Second,based on the partitioning objective and constraints,the reward function of the partitioning MDP model is set by adopting a relative deviation normalization scheme to reduce mutual interference between the reward and penalty in the reward function.The soft bonus scaling mechanism is introduced to mitigate overestimation caused by abrupt jumps in the reward.Then,the deep Q network method is applied to solve the partitioning MDP model and generate partitioning schemes.Two experience replay buffers are employed to speed up the training process of the method.Finally,case studies on the IEEE 39-bus test system demonstrate that the proposed method can generate a high-modularity partitioning result that meets all key partitioning constraints,thereby improving the parallelism and reliability of the restoration process.Moreover,simulation results demonstrate that an appropriate discount factor is crucial for ensuring both the convergence speed and the stability of the partitioning training.
基金supported by the National Key Research and Develop-ment Program(No.2022YFC3701103)the National Natural Science Foundation of China(Nos.42130714 and 41931287).
文摘The application of nitrogen fertilizers in agricultural fields can lead to the release of nitrogen-containing gases(NCGs),such as NO_(x),NH_(3) and N_(2)O,which can significantly impact regional atmospheric environment and con-tribute to global climate change.However,there remain considerable research gaps in the accurate measurement of NCGs emissions from agricultural fields,hindering the development of effective emission reduction strategies.We improved an open-top dynamic chambers(OTDCs)system and evaluated the performance by comparing the measured and given fluxes of the NCGs.The results showed that the measured fluxes of NO,N_(2)O and NH_(3)were 1%,2%and 7%lower than the given fluxes,respectively.For the determination of NH_(3) concentration,we employed a stripping coil-ion chromatograph(SC-IC)analytical technique,which demonstrated an absorption efficiency for atmospheric NH_(3) exceeding 96.1%across sampling durations of 6 to 60 min.In the summer maize season,we utilized the OTDCs system to measure the exchange fluxes of NO,NH_(3),and N_(2)O from the soil in the North China Plain.Substantial emissions of NO,NH_(3) and N_(2)O were recorded following fertilization,with peaks of 107,309,1239 ng N/(m^(2)·s),respectively.Notably,significant NCGs emissions were observed following sus-tained heavy rainfall one month after fertilization,particularly with NH_(3) peak being 4.5 times higher than that observed immediately after fertilization.Our results demonstrate that the OTDCs system accurately reflects the emission characteristics of soil NCGs and meets the requirements for long-term and continuous flux observation.
基金Supported by the National Natural Science Foundation of China under Grant No.51975138the High-Tech Ship Scientific Research Project from the Ministry of Industry and Information Technology under Grant No.CJ05N20the National Defense Basic Research Project under Grant No.JCKY2023604C006.
文摘Marine thin plates are susceptible to welding deformation owing to their low structural stiffness.Therefore,the efficient and accurate prediction of welding deformation is essential for improving welding quality.The traditional thermal elastic-plastic finite element method(TEP-FEM)can accurately predict welding deformation.However,its efficiency is low because of the complex nonlinear transient computation,making it difficult to meet the needs of rapid engineering evaluation.To address this challenge,this study proposes an efficient prediction method for welding deformation in marine thin plate butt welds.This method is based on the coupled temperature gradient-thermal strain method(TG-TSM)that integrates inherent strain theory with a shell element finite element model.The proposed method first extracts the distribution pattern and characteristic value of welding-induced inherent strain through TEP-FEM analysis.This strain is then converted into the equivalent thermal load applied to the shell element model for rapid computation.The proposed method-particularly,the gradual temperature gradient-thermal strain method(GTG-TSM)-achieved improved computational efficiency and consistent precision.Furthermore,the proposed method required much less computation time than the traditional TEP-FEM.Thus,this study lays the foundation for future prediction of welding deformation in more complex marine thin plates.
基金supported by the National Natural Science Foundation of China(Project No.42307555).
文摘At present,there is currently a lack of unified standard methods for the determination of antimony content in groundwater in China.The precision and trueness of related detection technologies have not yet been systematically and quantitatively evaluated,which limits the effective implementation of environmental monitoring.In response to this key technical gap,this study aimed to establish a standardized method for determining antimony in groundwater using Hydride Generation–Atomic Fluorescence Spectrometry(HG-AFS).Ten laboratories participated in inter-laboratory collaborative tests,and the statistical analysis of the test data was carried out in strict accordance with the technical specifications of GB/T 6379.2—2004 and GB/T 6379.4—2006.The consistency and outliers of the data were tested by Mandel's h and k statistics,the Grubbs test and the Cochran test,and the outliers were removed to optimize the data,thereby significantly improving the reliability and accuracy.Based on the optimized data,parameters such as the repeatability limit(r),reproducibility limit(R),and method bias value(δ)were determined,and the trueness of the method was statistically evaluated.At the same time,precision-function relationships were established,and all results met the requirements.The results show that the lower the antimony content,the lower the repeatability limit(r)and reproducibility limit(R),indicating that the measurement error mainly originates from the detection limit of the method and instrument sensitivity.Therefore,improving the instrument sensitivity and reducing the detection limit are the keys to controlling the analytical error and improving precision.This study provides reliable data support and a solid technical foundation for the establishment and evaluation of standardized methods for the determination of antimony content in groundwater.
基金supported by the National High Technology Research and Development Program of China(2010AA101703)the Natural Science Foundation of Heilongjiang Province of China (C200950)the Fundamental Research Fundsfor the Central Universities (DL09BB38)
文摘The effect of maleic anhydride grafted styrene-ethylene- buty-lene-styrene block copolymer (SEBS-g-MAH) and in-situ grafting MAH on mechanical, dynamic mechanical properties of wood flour/recycled plastic blends composites was investigated. Recycled plastic polypro-pylene (PP), high-density polyethylene (HDPE) and polystyrene (PS), were mixed with wood flour in a high speed blender and then extruded by a twin/single screw tandem extruder system to form wood flour/recycled plastic blends composites. Results show that the impact properties of the composites were improved more significantly by using SEBS-g-MAH compatibilizer than by using the mixtures of MAH and DCP via reactive blending in situ. However, contrary results were ob-served on the tensile and flexural properties of the corresponding com-posites. In General, the mechanical properties of composites made from recycled plastic blends were inferior to those made from virgin plastic blends, especially in elongation break. The morphological study verified that the interfacial adhesion or the compatibility of plastic blends with wood flour was improved by adding SEBS-g-MAH or in-situ grafting MAH. A better interfacial bonding between PP, HDPE, PS and wood flour was obtained by in-situ grafting MAH than the addition of SEBS-g-MAH. In-situ grafting MAH can be considered as a potential way of increasing the interfacial compatibility between plastic blends and wood flour. The storage modulus and damping factor of composites were also characterized through dynamic mechanical analysis (DMA).
基金Project(41630642)supported by the Key Project of National Natural Science Foundation of ChinaProject(51974360)supported by the National Natural Science Foundation of ChinaProject(2018JJ3656)supported by the Natural Science Foundation of Hunan Province,China。
文摘In the context of deep rock engineering,the in-situ stress state is of major importance as it plays an important role in rock dynamic response behavior.Thus,stress initialization becomes crucial and is the first step for the dynamic response simulation of rock mass in a high in-situ stress field.In this paper,stress initialization methods,including their principles and operating procedures for reproducing steady in-situ stress state in LS-DYNA,are first introduced.Then the most popular four methods,i.e.,explicit dynamic relaxation(DR)method,implicit-explicit sequence method,Dynain file method and quasi-static method,are exemplified through a case analysis by using the RHT and plastic hardening rock material models to simulate rock blasting under in-situ stress condition.Based on the simulations,it is concluded that the stress initialization results obtained by implicit-explicit sequence method and dynain file method are closely related to the rock material model,and the explicit DR method has an obvious advantage in solution time when compared to other methods.Besides that,it is recommended to adopt two separate analyses for the whole numerical simulation of rock mass under the combined action of in-situ stress and dynamic disturbance.
基金founded by Project of National Natural Science Foundation of China “Study on the Anelastic Strain Recovery Compliance in the In-situ Stress Measurement by ASR Method”, No 41404080the Project of Geological Survey “Survey on the In-situ Stress Field in Southern China”
文摘With the rapid increase of energy demand and the increasingly highlighted environmental problems, clean, safe and widely distributed geothermal resources have become a hot spot for renewable resources development. The state of in-situ stress is a major control parameter for multiple links including well location, fracture inspiration and reservoir assessment, so how to determine the accurate state of in-situ stress in the deep thermal reservoir becomes a core problem drawing widely attention and urgent to be solved. Based on features of hot dry rock reservoir in terms of temperature and pressure and the comparison analysis, this article proposes the method of Anelastic Strain Recovery(ASR) as an effective method for determining the state of in-situ stress in the area with HDR resources distributed and explains the availability of ASR method by application examples.
文摘Double packer equipment for hydraulic test can be used to measure pressure of test zone directly, and it is frequently used to perform many kinds of hydraulic tests and take groundwater sample from borehole. The test method of this equipment mainly includes the test design, implementation, interpretation and synthetic analysis. By adopting the double packer equipment for hydraulic test, the parameter distribution of rock permeability along borehole can be acquired, as well as the connectivity, water conductivity and water bearing capacity of the disclosed structure and the chemical characteristics of the deep groundwater. It is a necessary method for the research and evaluation of the complex hypotonicity terrace site selection under geological conditions. This method is not only suitable for the geological disposal of high level radioactive waste, but also can be used in the site selection of underground facilities such as storage of petroleum and carbon dioxide. Meanwhile, it has a good application prospect in other hydrogeological investigation fields.
基金The financial supports provided by the National Natural Science Foundation of China(Grant Nos.41230636,41372265,41427801)National Basic Research Program of China(973 Project)(Grant No.2011CB710605)
文摘Moisture content is a fundamental physical index that quantifies soil property and is closely associatedwith the hydrological, ecological and engineering behaviors of soil. To measure in-situ soil moisturecontents, a distributed measurement system for in-situ soil moisture content (SM-DTS) is introduced.The system is based on carbon-fiber heated cable (CFHC) technology that has been developed to enhancethe measuring accuracy of in-situ soil moisture content. Using CFHC technique, a temperature characteristicvalue (Tt) can be defined from temperatureetime curves. A relationship among Tt, soil thermalimpedance coefficient and soil moisture content is then established in laboratory. The feasibility of theSM-DTS technology to provide distributed measurements of in-situ soil moisture content is verifiedthrough field tests. The research reported herein indicates that the proposed SM-DTS is capable ofmeasuring in-situ soil moisture content over long distances and large areas.
基金Funded by the National Natural Science Foundation of China (No. 50572080)Doctoral Foundation of Wuhan University of Technology (No. 471-38650142)
文摘Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reactions process.TiC and Ti5Si3 were two important intermediate phases during the whole reactions.The microstructure characteristics of the Ti3SiC2/TiB2 composites were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The experimental results show that the grains of Ti3SiC2/TiB2 composite are structured in a layered form,and the formation of TiB2 particles as reinforcements with elongated or equiaxed shape distributes in Ti3SiC2 matrix.
基金Project(52178402)supported by the National Natural Science Foundation of ChinaProject(2021-Key-09)supported by the Science and Technology Research and Development Program Project of China Railway Group LimitedProject(2021zzts0216)supported by the Innovation-Driven Project of Central South University,China。
文摘Due to the long-term plate tectonic movements in southwestern China,the in-situ stress field in deep formations is complex.When passing through deep soft-rock mass under non-hydrostatic high in-situ stress field,tunnels will suffer serious asymmetric deformation.There is no available support design method for tunnels under such a situation in existing studies to clarify the support time and support stiffness.This study first analyzed the mechanical behavior of tunnels in non-hydrostatic in-situ stress field and derived the theoretical equations of the ground squeezing curve(GSC)and ground loosening curve(GLC).Then,based on the convergence confinement theory,the support design method of deep soft-rock tunnels under non-hydrostatic high in-situ stress field was established considering both squeezing and loosening pressures.In addition,this method can provide the clear support time and support stiffness of the second layer of initial support.The proposed design method was applied to the Wanhe tunnel of the China-Laos railway in China.Monitoring data indicated that the optimal support scheme had a good effect on controlling the tunnel deformation in non-hydrostatic high in-situ stress field.Field applications showed that the secondary lining could be constructed properly.
基金supported by the Fundamental Research Funds for the Central Universities (No. FRF-TP-18-029A2)State Key Lab of Advanced Metals and Materials of China (No. 2019-Z10)
文摘Tungsten nanoparticle-strengthened Cu composites were prepared from nanopowder synthesized by a sol–gel method and in-situ hydrogen reduction.The tungsten particles in the Cu matrix were well-dispersed with an average size of approximately 100–200 nm.The addition of nanosized W particles remarkably improves the mechanical properties,while the electrical conductivity did not substantially decrease.The Cu–W composite with 6 wt%W has the most comprehensive properties with an ultimate strength of 310 MPa,yield strength of 238 MPa,hardness of HV 108 and electrical conductivity of 90%IACS.The enhanced mechanical property and only a small loss of electrical conductivity demonstrate the potential of this new strategy to prepare W nanoparticle-strengthened Cu composites.
基金The National Key Research and Development Program(No.2017YFC0703408)the National Natural Science Foundation of China(No.51478109,51678145,51878160)
文摘Based on the characteristics of pile-soil interaction and the Mohr-Coulomb strength theory,a new method of determining the side friction at a pile-soil interaction is proposed.Combined with the actual engineering cases,the effectiveness of the analogue test method is verified by comparing it with the traditional anchor pile method and self-balanced method.Taking the self-balanced test of the bridge pile foundation in the Songhua River as an example,the conversion factor of sandy soil and weathered mudstone are confirmed by the analogue test method.The results show that the conversion factor of sandy soil and weathered mudstone in the Songhua River area should consider the geological conditions and the construction technology,etc.The standard values are relatively conservative.It is suggested that the engineering application should be properly revised.The recommended range of the conversion factor of sandy soil in this area is 0.65 to 0.85,and that of weathered mudstone is 1.0.
基金financially supported by the National Key Research&Development Program of China(Nos.2020YFB2008300,2020YFB2008303)。
文摘Titanium matrix composites reinforced with ceramic particles are considered a promising engineering material due to their combination of high specific strength,low density,and high modulus.In this study,the TA15-based composites reinforced with a volume fraction of 10% to 25%(TiB+TiC)were prepared using powder metallurgy and casting technique.Microstructural characterization and phase constitution were examined using optical microscopy(OM),scanning electron microscopy(SEM),and X-ray diffraction(XRD).In addition,the microhardness,room temperature(RT)and high temperature(HT)tensile properties of the composites were evaluated.Results revealed that the reinforcements are distributed uniformly even in the composites with a high volume of TiB and TiC.However,as the volume fraction exceeds 15%,TiB and TiC particles become coarsening and exhibit rod-like and dendritic-like morphology.Microhardness increases gradually from 321.2 HV for the base alloy to a maximum of 473.3 HV as the reinforcement increases to 25vol.%.Tensile test results indicate that a reinforcement volume fraction above 20% is beneficial for enhancing tensile strength and yield strength at high temperatures,but it has an adverse effect on room temperature elongation.Conversely,if the reinforcement volume fraction is below 20%,it can improve high-temperature elongation when the temperature exceeds 600℃.