Accurate acquisition and prediction of acoustic parameters of seabed sediments are crucial in marine sound propagation research.While the relationship between sound velocity and physical properties of sediment has bee...Accurate acquisition and prediction of acoustic parameters of seabed sediments are crucial in marine sound propagation research.While the relationship between sound velocity and physical properties of sediment has been extensively studied,there is still no consensus on the correlation between acoustic attenuation coefficient and sediment physical properties.Predicting the acoustic attenuation coefficient remains a challenging issue in sedimentary acoustic research.In this study,we propose a prediction method for the acoustic attenuation coefficient using machine learning algorithms,specifically the random forest(RF),support vector machine(SVR),and convolutional neural network(CNN)algorithms.We utilized the acoustic attenuation coefficient and sediment particle size data from 52 stations as training parameters,with the particle size parameters as the input feature matrix,and measured acoustic attenuation as the training label to validate the attenuation prediction model.Our results indicate that the error of the attenuation prediction model is small.Among the three models,the RF model exhibited the lowest prediction error,with a mean squared error of 0.8232,mean absolute error of 0.6613,and root mean squared error of 0.9073.Additionally,when we applied the models to predict the data collected at different times in the same region,we found that the models developed in this study also demonstrated a certain level of reliability in real prediction scenarios.Our approach demonstrates that constructing a sediment acoustic characteristics model based on machine learning is feasible to a certain extent and offers a novel perspective for studying sediment acoustic properties.展开更多
In the present work,the porous Ti particle reinforced Mg-based bulk metallic glass matrix composites(BMGCs)have been successfully fabricated via a novel in-situ dealloying method in metallic melt.A dual reinforcing st...In the present work,the porous Ti particle reinforced Mg-based bulk metallic glass matrix composites(BMGCs)have been successfully fabricated via a novel in-situ dealloying method in metallic melt.A dual reinforcing structure,including large-scale between porous particles and fine-scale inside one particle,was induced to further overcome the strength-plasticity tradeoff.The microstructure and mechanical properties of such dual-scale structure-reinforced BMGCs with various volume fractions and diameters of porous Ti particles were investigated in detail.It is found that with more and finer porous Ti particles,the BMGC showed both high fracture strength(1131.9±39.1 MPa)and good plastic deformability(1.48±0.38%).The characteristic of the reinforcing structure(0.48μm)inside the porous particles was close to the plastic processing zone size of the matrix(0.1~0.2μm),which generated a locally ideal reinforcing structure.Such dual-scale reinforcing structures with more interfaces can effectively promote the multiplication of shear bands at the interfaces.Due to the size effect,the refined submicron matrix between the Ti ligaments inside the porous particles should exhibit homogeneous shearing events.Such delocalization behavior from the dual-scale reinforcing structures should help to enhance the role of the interactions between shear bands,thus improving the yield strength of the composites.Based on the in-situ dealloying method,the dual-scale structure design provides a novel approach to fabricate various BMGCs with both high strength and good plasticity.展开更多
Graphene-copper(Gr-Cu)composites exhibit significant potential for industrial applications.Among the methods for fabricating Gr-Cu composites,the in-situ growth method stands out as a simple yet effective approach.How...Graphene-copper(Gr-Cu)composites exhibit significant potential for industrial applications.Among the methods for fabricating Gr-Cu composites,the in-situ growth method stands out as a simple yet effective approach.However,graphene converted from liquid or solid molecules by the traditional in-situ growth method often exhibits numerous defects,thereby reducing its effectiveness in enhancing the electrical properties of the composites.To address this issue,we developed an innovative and efficient method,referred to as the“confinedparallel-space in-situ growth(CPS)method,”to grow highquality graphene and fabricate high-conductivity Gr-Cu composites.Oleic acid was chosen as the small molecular carbon source and confined between copper sheets obtained by rolling dendritic copper powder.This carbon source underwent conversion into oriented,high-quality graphene in the confined space at high temperature.The high-quality graphene sheets serve as continuous electron transport channels,significantly improving the conductivity of the composite.The composite prepared by the CPS method(CPS-composite)demonstrates unique conductivity,exceeding that of standard annealed copper at temperatures above 40℃and notably outperforming it by 3.2%at160℃.In addition,compared to the composite with a similar carbon content prepared by the traditional in-situ growth method,the yield strength of the CPS-composite increased by 23.6%,while the strengthening efficiency of graphene improved by 146.6%,achieving an ultrahigh value of 489 at a carbon volume fraction of 0.086 vol%.The CPS method emerges as a novel strategy for fabricating high-performance,low-cost,and large-scale graphene-copper composites using small molecular carbon sources,making it suitable for industrial production.展开更多
The utilization of lunar regolith for construction on the lunar surface presents a critical challenge in-situ resource utilization.This study proposes a lunar regolith manufacturing method that uses a high-performance...The utilization of lunar regolith for construction on the lunar surface presents a critical challenge in-situ resource utilization.This study proposes a lunar regolith manufacturing method that uses a high-performance resin binder characterized by a high regolith content and strong forming capabilities.A combined resin material with both thermosetting and photosetting properties was developed and mixed with lunar regolith to create a slurry.This slurry can be directly molded or additively extruded into green bodies with specific structures.These green bodies can self-cure under the high temperatures and ultraviolet radiation experienced during the lunar day,reducing energy consumption and fulfilling the requirements of lunar construction.The material-forming processes and effects of various additive types and concentrations,regolith mass ratios,and processing parameters on the properties of the slurry and the formed specimens were thoroughly investigated.The mechanical performance and microstructure of the fabricated samples were analyzed.The lunar regolith mass ratio reached 90 wt%(approximately 79 vol%),with the highest compressive strengths exceeding 60 MPa for cast specimens and 30 MPa for printed samples.This technology shows significant potential for enabling in-situ lunar regolith-based construction in future lunar missions.展开更多
Exploring cost-effective and efficient catalysts for oxygen reduction reaction(ORR)poses a significant challenge,espe-cially in the pursuit of alternatives to precious metals like platinum.Significant advancements hav...Exploring cost-effective and efficient catalysts for oxygen reduction reaction(ORR)poses a significant challenge,espe-cially in the pursuit of alternatives to precious metals like platinum.Significant advancements have driven electrochem-ists to develop efficient ORR catalysts using abundant materials,particularly iron(Fe)-based,known for their exceptional performance in ORR.While the crucial function of Fe in boosting ORR catalytic activity is recognized,the connection between material attributes and catalytic performance remains enigmatic.Understanding the dynamic processes involved in oxygen electrocatalysis is paramount for designing precious-metals-free ORR electrocatalysts.Mössbauer spectroscopy stands out as a powerful technique for deciphering the structural characteristics of Fe species in catalysis,facilitating the identification of active sites and the clarification of catalytic mechanisms.By showcasing noteworthy case studies within this review,we demonstrate the application of in-situ/operando 57Fe Mössbauer spectroscopy across diverse Fe-involved materials in ORR catalysis.This sheds light on various aspects of ORR catalysis,such as identifying active sites,assessing stability,and understanding the reaction mechanism.Our inquiry drives towards the opportunities and hurdles associ-ated with Mössbauer spectroscopy,unveiling potential breakthroughs and avenues for enhancement within this pivotal research realm.展开更多
To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,t...To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,the effects of carrier gas types,regeneration temperatures,and granular activated carbon(GAC)addition on iron-based catalyst regeneration were investigated.The Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regenerated at 550°C with additional GAC and 15%water vapor exhibited the optimal degradation efficiency towards polychlorinated biphenyls(PCBs),with an increase from 41.2%to 93.5%,compared with non-regenerated Fe_(3)O_(4)/𝛾-Al_(2)O_(3).In addition,the 60-hour stability test revealed a well-recovered catalytic activity.During the Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regeneration,the coke on the catalyst surface was oxidized and removed in the form of CO_(2),and meanwhile the oxidized Fe(III)was reduced into Fe(II)in the catalyst.This study provides a safe and efficient iron-based catalyst regeneration technology for PCB off-gas degradation and reveals the catalytic activity recovery mechanism during catalyst regeneration.展开更多
In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of roc...In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of rocks after stress relief introduces errors.To improve accuracy,this study proposes an in-situ stress solution theory that incorporates time-dependent stress relief effects.Triaxial stepwise loadingunloading rheological tests on granite and siltstone established quantitative relationships between instantaneous elastic recovery and viscoelastic recovery under different stress levels,confirming their impact on measurement accuracy.By integrating a dual-class elastic deformation recovery model,an improved in-situ stress solution theory was derived.Additionally,accounting for the nonlinear characteristics of rock masses,a determination method for time-dependent nonlinear mechanical parameters was proposed.Based on the CSIRO hollow inclusion strain cell,time-dependent strain correction equations and long-term confining pressure calibration equations were formulated.Finally,the proposed theory was successfully applied at one iron mine(736 m depth)in Xinjiang,China,and one coal mine(510 m depth)in Ningxia,China.Compared to classical theory,the calculated mean stress values showed accuracy improvements of 6.0%and 9.4%,respectively,validating the applicability and reliability of the proposed theory.展开更多
This study systematically conducted preparation optimization and performance investigations on Co-modified Ce/TiO_(2) catalysts,with a focus on examining how preparation methods and Co loading regulate the catalyst’s...This study systematically conducted preparation optimization and performance investigations on Co-modified Ce/TiO_(2) catalysts,with a focus on examining how preparation methods and Co loading regulate the catalyst’s low-temperature denitrification activity.After identifying optimal preparation parameters via condition screening,multiple characterization techniques-including BET,XRD,XPS,H_(2)-TPR and in situ DRIFTS-were employed to deeply analyze the catalyst’s physicochemical properties and reaction mechanism.Results demonstrated that compared to the impregnation and co-precipitation methods,the Ce-Co_(0.025)/TiO_(2)-SG catalyst(prepared by the sol-gel method with a Co/Ti mass ratio of 0.025)exhibited significantly superior denitrification activity:NO conversion remained stably above 95%in the 225−350℃ temperature range,and it displayed high N_(2) selectivity.Characterization analysis revealed that abundant surface oxygen vacancies,a high proportion of Ce^(3+) species,and prominent acidic sites collectively contributed to enhancing its low-temperature denitrification performance.This work provides reference value for the development of highly efficient low-temperature denitrification catalysts.展开更多
Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating p...Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating packed bed(RPB)in premixing and crystallization on crystallinity and RE utilization rate was further investigated.The results indicate that lanthanide(La)cations are successfully introduced into the sodalite cage of Y-type zeolite.The optimized conditions are that the molar ratio of Si/La is 150,premixing for 5 h,crystallization at 90℃ for 18 h,and calcination at 550℃ for 3.5 h.At this stage,the RE utilization rate reaches 74.5%.Compared with the conventional stirred tank reactor(STR),RPB can effectively shorten the premixing time and crystallization time by 4.3 h and 6 h,improve the crystallinity by 23%and RE utilization rate by 7.5%.The RE utilization rate is more than 80%by RPB,surpassing the effectiveness of using the one-exchange one-calcination process in the traditional liquid ion exchange process.It is expected to provide a reference for the in-situ efficient and green synthesis of RE zeolite.展开更多
In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to ...In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method.展开更多
The main purpose of using geothermal energy piles(GEPs)is to enable the exploitation of geothermal energy for meeting the heating/cooling demands of buildings efficiently.However,the installation process of convention...The main purpose of using geothermal energy piles(GEPs)is to enable the exploitation of geothermal energy for meeting the heating/cooling demands of buildings efficiently.However,the installation process of conventional GEPs is inconvenient compared with that of traditional foundation piles.The pre-bored grouted planted geothermal energy pile(PGP GEP)is an innovative technology to simplify the installation process.Most investigations of in-situ experiments for conventional GEPs have focused on summer conditions.An in-situ test for a PGP GEP was conducted to analyze the temperature changes and thermo-mechanical characteristics under winter conditions.The results show that the average temperature of the pile decreased by 5.1℃,and the pile exhibited a general trend of high temperatures at both ends and low temperatures in the middle.In mechanics,strong pile end restraints resulted in smaller observed axial strain and higher axial thermal-induced force in the pile ends than at the middle of the pile.展开更多
This study presents an effective hybrid simulation approach for simulating broadband ground motion in complex near-fault locations.The approach utilizes a deterministic approach based on the spectral element method(SE...This study presents an effective hybrid simulation approach for simulating broadband ground motion in complex near-fault locations.The approach utilizes a deterministic approach based on the spectral element method(SEM),which is used to simulate low-frequency ground motion(f<1 Hz)by incorporating an innovative efficient discontinuous Galerkin(DG)method for grid division to accurately model basin sedimentary layers at reduced costs.It also introduces a comprehensive hybrid source model for high-frequency random scattering and a nonlinear analysis module for basin sedimentary layers.Deterministic outcomes are combined with modified three-dimensional stochastic finite fault method(3D-EXSIM)simulations of high-frequency ground motion(f>1 Hz).A fourth-order Butterworth filter with zero phase shift is employed for time-domain filtering of low-and high-frequency time series at a crossover frequency of 1 Hz,merging the low and high-frequency ground motions into a broadband time series.Taking an Ms 6.8 Luding earthquake,as an example,this hybrid method was used for a rapid and efficient simulation analysis of broadband ground motion in the region.The accuracy and efficiency of this hybrid method were verified through comparisons with actually observed station data and empirical attenuation curves.Deterministic method simulation results revealed the effects of mountainous topography,basin effects,nonlinear effects within the basin’s sedimentary layers,and a coupling interaction between the basin and the mountains.The findings are consistent with similar studies,showing that near-fault sedimentary basins significantly focus and amplify strong ground motion,and the soil’s nonlinear behavior in the basin influences ground motion to varying extents at different distances from the fault.The mountainous topography impacts the basin’s response to ground motion,leading to barrier effects.This research provides a scientific foundation for seismic zoning,urban planning,and seismic design in nearfault mountain basin regions.展开更多
Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrate...Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.展开更多
Cold deformation treatment of Cu-bearing stainless steel through a cold rolling process combined with electric pulse treatment(EPT)can significantly improve the microstructure and formability of cold-rolled Cu-bearing...Cold deformation treatment of Cu-bearing stainless steel through a cold rolling process combined with electric pulse treatment(EPT)can significantly improve the microstructure and formability of cold-rolled Cu-bearing stainless steel.The microstructure after EPT was characterized by scanning electron microscopy,transmission electron microscopy,and in-situ tensile testing.It is found that compared with conventional heat treatment,EPT process can significantly promote the nucleation rate and mobility at grain boundaries of the deformed samples,greatly accelerating the recovery and static recrystallization of Cu-bearing stainless steel samples at lower temperatures and contributing to the recovery of anisotropy and the re-molding of deformed samples.Microstructural characterization and theoretical analyses show that the rapid recrystallization during EPT process is caused not only by Joule heating effects but also by non-thermal effects that accelerate grain boundary migration and dislocation destruction and regeneration.In addition,EPT process significantly accelerated the nucleation and precipitation growth of Cu-rich phase.The coarsening of Cu-rich phase during EPT process is due to not only the high vacancy diffusion coefficient under the action of the electric pulse but also the increase in the vacancy diffusion flux induced by the electromigration in the process of the electric pulse.展开更多
[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and pun...[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and puncture,the index data of the fruit were obtained by setting different trigger forces,deformation levels,test speeds,as well as puncture speeds and puncture depths.The data included TPA hardness,adhesiveness,springiness,cohesiveness,gumminess,chewiness,resilience,as well as skin hardness,skin toughness,flesh hardness,fracturability,and compactness.[Results]Different deformation levels had a significant impact on all parameters.Hardness,adhesiveness,gumminess and chewiness showed a trend of first increasing and then decreasing with the deformation level increasing.When the deformation level was 30%,the adhesiveness,gumminess and chewiness reached their maximum values.When the deformation level was 50%,TPA hardness reached its maximum.When the compression speed was 3 mm/s,the measured values of TPA hardness,adhesiveness,chewiness,and resilience were at their maximums.The skin hardness varied significantly under different trigger forces.When the trigger force was 15 g,the skin hardness reached a maximum value of 944.63 g,and the skin toughness,flesh hardness,fracturability,and compactness also reach their maximum values respectively.When the puncture depth was 12 mm,the flesh hardness and skin toughness reached their maximums of 682.51 g and 1.82 mm,respectively.In the TPA mode,the flesh hardness of chieh-qua showed an extremely significant negative correlation with springiness,cohesiveness,and resilience(P<0.01).The fruit fracturability detected by puncture had an extremely significant positive correlation with compactness(P<0.01).[Conclusions]The evaluation method for measuring chieh-qua texture by combining TPA and the puncture mode could accurately and quantitatively reflect the differences in the flesh texture quality of chieh-qua.The optimal parameters for texture measurement of chieh-qua fruit were determined as a 15 g trigger force with 50%deformation and a 3 mm/s compression speed in TPA mode,and a 15 g trigger force with a 12 mm puncture depth in puncture mode.Puncture speed was found to have no significant effect on the texture indices of chieh-qua.展开更多
The testing of large structures is limited by high costs and long cycles, making scaling methods an attractive solution. However, the scaling process of elastic rings introduces complexities in multi-parameter geometr...The testing of large structures is limited by high costs and long cycles, making scaling methods an attractive solution. However, the scaling process of elastic rings introduces complexities in multi-parameter geometric distortions, leading to a diminution in the predictive accuracy of the distorted similitude. To address this challenge, this study formulates a novel set of scaling laws, tailored to account for the intricate geometric distortions associated with elastic rings. The proposed scaling laws are formulated based on the intrinsic deformation characteristics of elastic rings, rather than the traditional systemic governing equations. Numerical and experimental cases are conducted to assess the efficacy and precision of the proposed scaling laws, and the obtained results are compared with those achieved by traditional methods. The outcomes demonstrate that the scaling laws put forth by this study significantly enhance the predictive capabilities for deformations of elastic rings.展开更多
This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,Calcu...This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.展开更多
As a novel class of purely organic fluores-cent materials,multiple resonance thermal-ly activated delayed fluorescence(MR-TADF)compounds hold significant promise for next-generation display technologies.The efficiency...As a novel class of purely organic fluores-cent materials,multiple resonance thermal-ly activated delayed fluorescence(MR-TADF)compounds hold significant promise for next-generation display technologies.The efficiency of exciton utilization and the overall performance of organic light-emit-ting devices are closely linked to the singlet-triplet energy gap(ΔE_(ST))of MR-TADF emitters.Identifying an economic and accu-rate theoretical approach to predictΔE_(ST)would be beneficial for high-throughput screening and facilitate the inverse design of MR-TADF molecules.In this study,we evaluated the S_(1)state energy(E(S_(1))),T_(1)state ener-gy(E(T_(1))),andΔE_(ST)using three different physical interpretations:adiabatic excitation ener-gy,vertical absorption energy,and vertical emission energy.We employed the time-depen-dent density functional theory(TDDFT)and delta self-consistent field(ΔSCF)methods to calculate E(S_(1)),E(T_(1)),andΔE_(ST)for 20 MR-TADF molecules reported in the literature.We compared these calculated values with experimental data obtained from fluorescence spec-troscopy at room-temperature(or 77 K)and phosphorescence spectroscopy conducted at 77 K.Our findings indicate that the vertical absorption energy at the S0 state minimum,deter-mined by theΔSCF method,accurately predicts the S_(1)state energy.Similarly,the vertical absorption energy at the S0 state minimum,calculated using the TDDFT method,effectively predicts the T_(1)state energy.TheΔE_(ST)derived from the difference between these two excita-tion energies exhibited the smallest mean absolute error of only 0.039 eV compared to the ex-perimental values.This combination represents the most accurate and cost-effective method reported to date for predicting theΔE_(ST)of MR-TADF molecules,and can be integrated into AI-driven inverse design workflows for new emitters.展开更多
As binary geological media,soil-rock mixtures(SRMs)exhibit a distinct gradational composition,leading to their unique mechanical behaviors.To appraise the stability of SRM slopes,it is essential to determine equivalen...As binary geological media,soil-rock mixtures(SRMs)exhibit a distinct gradational composition,leading to their unique mechanical behaviors.To appraise the stability of SRM slopes,it is essential to determine equivalent parameters of SRMs,which are typically obtained through experimental and numerical methods.In contrasted to other numerical methods,the numerical manifold method(NMM)is more effective in addressing SRM problems.This is because the high-precision regular mathematical meshes in NMM can be used without aligning with the soil-rock interfaces and boundaries of SRMs.In the current research,the equivalent strength parameters of SRMs,i.e.the equivalent cohesion ce and internal friction angleϕ_(e),are determined using NMM.Initially,an NMM triaxial numerical model is established and validated based on triaxial experiments.Subsequently,the soil and rock parameters are derived through parameter inversion.Moreover,the impacts of rock content,size,shape and rock blocks'major-axis orientation on ce andϕ_(e) of SRMs are thoroughly examined using the NMM triaxial numerical model.Additionally,a fitting function is proposed to linkϕ_(e) to the rock content and size of SRMs.When other influencing factors are fixed,the above fitting model leads to the following conclusions:(1)the predictedϕ_(e) of SRMs increase with the increase of rock content;and(2)SRM samples with smaller rocks display a higher predictedϕ_(e).展开更多
This paper develops a semi-analytical solution for pile penetration in natural soft clays using the strain path method(SPM).The stress-strain behavior of soils is characterized by the S-CLAY1S model,which can capture ...This paper develops a semi-analytical solution for pile penetration in natural soft clays using the strain path method(SPM).The stress-strain behavior of soils is characterized by the S-CLAY1S model,which can capture the anisotropic evolution and destructuring nature of soft clays.By integrating the S-CLAY1S model into the theoretical framework of the SPM,a set of ordinary differential equations is formulated with respect to the vertical coordinate of soil particles.The distribution of excess pore water pressure(EPWP)following pile installation is approximated through one-dimensional(1D)radial integration around the pile shaft.The distribution of stresses and EPWP,along with the evolution of fabric anisotropy within the soil surrounding the pile,is presented to illustrate the response of pile penetration in natural soft clays.The proposed solution is validated against existing theoretical solutions using the SPM and cavity expansion method(CEM),along with experimental data.The findings demonstrate that the SPM reveals lower radial effective stresses and EPWP at the pile shaft than that of CEM.Pile penetration alters the soil's anisotropic properties,inducing rotational hardening and affecting post-installation stress distribution.Soil destructuration eliminates bonding among particles near the pile,resulting in a complete disruption of soil structure at the pile surface,which is particularly pronounced for higher initial soil structure ratios.Minimal variation was observed in the three principal stresses and shear stress on the cone side surface as the angle increased from 18°to 60°,except for a slight reduction in EPWP.展开更多
基金funded by the Basic Scientific Fund for National Public Research Institutes of China(No.2022 S01)the National Natural Science Foundation of China(Nos.42176191,42049902,and U22A2012)+5 种基金the Shandong Provincial Natural Science Foundation,China(No.ZR2022YQ40)the National Key R&D Program of China(No.2021YFF0501202)the Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2023 SP232)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(No.241gqb006)Data acquisition and sample collections were supported by the National Natural Science Foundation of China Open Research Cruise(Cruise No.NORC2021-02+NORC2021301)funded by the Shiptime Sharing Project of the National Natural Science Foundation of China。
文摘Accurate acquisition and prediction of acoustic parameters of seabed sediments are crucial in marine sound propagation research.While the relationship between sound velocity and physical properties of sediment has been extensively studied,there is still no consensus on the correlation between acoustic attenuation coefficient and sediment physical properties.Predicting the acoustic attenuation coefficient remains a challenging issue in sedimentary acoustic research.In this study,we propose a prediction method for the acoustic attenuation coefficient using machine learning algorithms,specifically the random forest(RF),support vector machine(SVR),and convolutional neural network(CNN)algorithms.We utilized the acoustic attenuation coefficient and sediment particle size data from 52 stations as training parameters,with the particle size parameters as the input feature matrix,and measured acoustic attenuation as the training label to validate the attenuation prediction model.Our results indicate that the error of the attenuation prediction model is small.Among the three models,the RF model exhibited the lowest prediction error,with a mean squared error of 0.8232,mean absolute error of 0.6613,and root mean squared error of 0.9073.Additionally,when we applied the models to predict the data collected at different times in the same region,we found that the models developed in this study also demonstrated a certain level of reliability in real prediction scenarios.Our approach demonstrates that constructing a sediment acoustic characteristics model based on machine learning is feasible to a certain extent and offers a novel perspective for studying sediment acoustic properties.
基金supported by National Natural Science Foundation of China(No.52101138)Natural Science Foundation of Hubei Province(No.2023AFB798)+1 种基金Shenzhen Science and Technology Program(No.JCYJ20220530160813032)State Key Laboratory of Solidification Processing in NWPU(No.SKLSP202309).
文摘In the present work,the porous Ti particle reinforced Mg-based bulk metallic glass matrix composites(BMGCs)have been successfully fabricated via a novel in-situ dealloying method in metallic melt.A dual reinforcing structure,including large-scale between porous particles and fine-scale inside one particle,was induced to further overcome the strength-plasticity tradeoff.The microstructure and mechanical properties of such dual-scale structure-reinforced BMGCs with various volume fractions and diameters of porous Ti particles were investigated in detail.It is found that with more and finer porous Ti particles,the BMGC showed both high fracture strength(1131.9±39.1 MPa)and good plastic deformability(1.48±0.38%).The characteristic of the reinforcing structure(0.48μm)inside the porous particles was close to the plastic processing zone size of the matrix(0.1~0.2μm),which generated a locally ideal reinforcing structure.Such dual-scale reinforcing structures with more interfaces can effectively promote the multiplication of shear bands at the interfaces.Due to the size effect,the refined submicron matrix between the Ti ligaments inside the porous particles should exhibit homogeneous shearing events.Such delocalization behavior from the dual-scale reinforcing structures should help to enhance the role of the interactions between shear bands,thus improving the yield strength of the composites.Based on the in-situ dealloying method,the dual-scale structure design provides a novel approach to fabricate various BMGCs with both high strength and good plasticity.
基金financially supported by Harbin Ship Boiler and Turbine Research Institute Stability Support Project and Heilongjiang Province Young Scientific and Technological Talent Lift Project(No.2023QNTJ)
文摘Graphene-copper(Gr-Cu)composites exhibit significant potential for industrial applications.Among the methods for fabricating Gr-Cu composites,the in-situ growth method stands out as a simple yet effective approach.However,graphene converted from liquid or solid molecules by the traditional in-situ growth method often exhibits numerous defects,thereby reducing its effectiveness in enhancing the electrical properties of the composites.To address this issue,we developed an innovative and efficient method,referred to as the“confinedparallel-space in-situ growth(CPS)method,”to grow highquality graphene and fabricate high-conductivity Gr-Cu composites.Oleic acid was chosen as the small molecular carbon source and confined between copper sheets obtained by rolling dendritic copper powder.This carbon source underwent conversion into oriented,high-quality graphene in the confined space at high temperature.The high-quality graphene sheets serve as continuous electron transport channels,significantly improving the conductivity of the composite.The composite prepared by the CPS method(CPS-composite)demonstrates unique conductivity,exceeding that of standard annealed copper at temperatures above 40℃and notably outperforming it by 3.2%at160℃.In addition,compared to the composite with a similar carbon content prepared by the traditional in-situ growth method,the yield strength of the CPS-composite increased by 23.6%,while the strengthening efficiency of graphene improved by 146.6%,achieving an ultrahigh value of 489 at a carbon volume fraction of 0.086 vol%.The CPS method emerges as a novel strategy for fabricating high-performance,low-cost,and large-scale graphene-copper composites using small molecular carbon sources,making it suitable for industrial production.
基金supported by International Partnership Program of the Chinese Academy of Sciences(Grant No.310GJH2024010GC)National Natural Science Foundation of China(Grant No.52005479)the China Building Materials Federation(Grant No.2023JBGS0401)。
文摘The utilization of lunar regolith for construction on the lunar surface presents a critical challenge in-situ resource utilization.This study proposes a lunar regolith manufacturing method that uses a high-performance resin binder characterized by a high regolith content and strong forming capabilities.A combined resin material with both thermosetting and photosetting properties was developed and mixed with lunar regolith to create a slurry.This slurry can be directly molded or additively extruded into green bodies with specific structures.These green bodies can self-cure under the high temperatures and ultraviolet radiation experienced during the lunar day,reducing energy consumption and fulfilling the requirements of lunar construction.The material-forming processes and effects of various additive types and concentrations,regolith mass ratios,and processing parameters on the properties of the slurry and the formed specimens were thoroughly investigated.The mechanical performance and microstructure of the fabricated samples were analyzed.The lunar regolith mass ratio reached 90 wt%(approximately 79 vol%),with the highest compressive strengths exceeding 60 MPa for cast specimens and 30 MPa for printed samples.This technology shows significant potential for enabling in-situ lunar regolith-based construction in future lunar missions.
基金financially supported by the National Natural Science Foundation of China (22350410386,W2412116,22375200,U22A202175,21961142006)。
文摘Exploring cost-effective and efficient catalysts for oxygen reduction reaction(ORR)poses a significant challenge,espe-cially in the pursuit of alternatives to precious metals like platinum.Significant advancements have driven electrochem-ists to develop efficient ORR catalysts using abundant materials,particularly iron(Fe)-based,known for their exceptional performance in ORR.While the crucial function of Fe in boosting ORR catalytic activity is recognized,the connection between material attributes and catalytic performance remains enigmatic.Understanding the dynamic processes involved in oxygen electrocatalysis is paramount for designing precious-metals-free ORR electrocatalysts.Mössbauer spectroscopy stands out as a powerful technique for deciphering the structural characteristics of Fe species in catalysis,facilitating the identification of active sites and the clarification of catalytic mechanisms.By showcasing noteworthy case studies within this review,we demonstrate the application of in-situ/operando 57Fe Mössbauer spectroscopy across diverse Fe-involved materials in ORR catalysis.This sheds light on various aspects of ORR catalysis,such as identifying active sites,assessing stability,and understanding the reaction mechanism.Our inquiry drives towards the opportunities and hurdles associ-ated with Mössbauer spectroscopy,unveiling potential breakthroughs and avenues for enhancement within this pivotal research realm.
基金supported by the Fundamental Research Funds for the Central Publicinterest Scientific Institution(No.2024YSKY-44)the National Key R&D Program of China(No.2023YFC3708003).
文摘To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,the effects of carrier gas types,regeneration temperatures,and granular activated carbon(GAC)addition on iron-based catalyst regeneration were investigated.The Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regenerated at 550°C with additional GAC and 15%water vapor exhibited the optimal degradation efficiency towards polychlorinated biphenyls(PCBs),with an increase from 41.2%to 93.5%,compared with non-regenerated Fe_(3)O_(4)/𝛾-Al_(2)O_(3).In addition,the 60-hour stability test revealed a well-recovered catalytic activity.During the Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regeneration,the coke on the catalyst surface was oxidized and removed in the form of CO_(2),and meanwhile the oxidized Fe(III)was reduced into Fe(II)in the catalyst.This study provides a safe and efficient iron-based catalyst regeneration technology for PCB off-gas degradation and reveals the catalytic activity recovery mechanism during catalyst regeneration.
基金supported by the National Science and Technology Major Project of the Ministry of Science and Technology of China(No.2024ZD1700201)the National Natural Science Foundation of China(Nos.U2034206,51974014 and 51574014)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2024A1515011631)the National Key Research and Development Project of China(No.2022YFC3004601)。
文摘In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of rocks after stress relief introduces errors.To improve accuracy,this study proposes an in-situ stress solution theory that incorporates time-dependent stress relief effects.Triaxial stepwise loadingunloading rheological tests on granite and siltstone established quantitative relationships between instantaneous elastic recovery and viscoelastic recovery under different stress levels,confirming their impact on measurement accuracy.By integrating a dual-class elastic deformation recovery model,an improved in-situ stress solution theory was derived.Additionally,accounting for the nonlinear characteristics of rock masses,a determination method for time-dependent nonlinear mechanical parameters was proposed.Based on the CSIRO hollow inclusion strain cell,time-dependent strain correction equations and long-term confining pressure calibration equations were formulated.Finally,the proposed theory was successfully applied at one iron mine(736 m depth)in Xinjiang,China,and one coal mine(510 m depth)in Ningxia,China.Compared to classical theory,the calculated mean stress values showed accuracy improvements of 6.0%and 9.4%,respectively,validating the applicability and reliability of the proposed theory.
基金Supported by the National Key Research and Development Program of China (2023YFB4102903)。
文摘This study systematically conducted preparation optimization and performance investigations on Co-modified Ce/TiO_(2) catalysts,with a focus on examining how preparation methods and Co loading regulate the catalyst’s low-temperature denitrification activity.After identifying optimal preparation parameters via condition screening,multiple characterization techniques-including BET,XRD,XPS,H_(2)-TPR and in situ DRIFTS-were employed to deeply analyze the catalyst’s physicochemical properties and reaction mechanism.Results demonstrated that compared to the impregnation and co-precipitation methods,the Ce-Co_(0.025)/TiO_(2)-SG catalyst(prepared by the sol-gel method with a Co/Ti mass ratio of 0.025)exhibited significantly superior denitrification activity:NO conversion remained stably above 95%in the 225−350℃ temperature range,and it displayed high N_(2) selectivity.Characterization analysis revealed that abundant surface oxygen vacancies,a high proportion of Ce^(3+) species,and prominent acidic sites collectively contributed to enhancing its low-temperature denitrification performance.This work provides reference value for the development of highly efficient low-temperature denitrification catalysts.
基金supported by the NationalKey Research and Development Program of China(2023YFA1507701)National Natural Science Foundation of China(U22B6011,22288102)“Announcement and Challenge”Science and Technology Project of Xinjiang Uygur Autonomous Region(XJKJTJBGS-2023).
文摘Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating packed bed(RPB)in premixing and crystallization on crystallinity and RE utilization rate was further investigated.The results indicate that lanthanide(La)cations are successfully introduced into the sodalite cage of Y-type zeolite.The optimized conditions are that the molar ratio of Si/La is 150,premixing for 5 h,crystallization at 90℃ for 18 h,and calcination at 550℃ for 3.5 h.At this stage,the RE utilization rate reaches 74.5%.Compared with the conventional stirred tank reactor(STR),RPB can effectively shorten the premixing time and crystallization time by 4.3 h and 6 h,improve the crystallinity by 23%and RE utilization rate by 7.5%.The RE utilization rate is more than 80%by RPB,surpassing the effectiveness of using the one-exchange one-calcination process in the traditional liquid ion exchange process.It is expected to provide a reference for the in-situ efficient and green synthesis of RE zeolite.
基金Supported in part by Natural Science Foundation of Guangxi(2023GXNSFAA026246)in part by the Central Government's Guide to Local Science and Technology Development Fund(GuikeZY23055044)in part by the National Natural Science Foundation of China(62363003)。
文摘In this paper,we consider the maximal positive definite solution of the nonlinear matrix equation.By using the idea of Algorithm 2.1 in ZHANG(2013),a new inversion-free method with a stepsize parameter is proposed to obtain the maximal positive definite solution of nonlinear matrix equation X+A^(*)X|^(-α)A=Q with the case 0<α≤1.Based on this method,a new iterative algorithm is developed,and its convergence proof is given.Finally,two numerical examples are provided to show the effectiveness of the proposed method.
文摘The main purpose of using geothermal energy piles(GEPs)is to enable the exploitation of geothermal energy for meeting the heating/cooling demands of buildings efficiently.However,the installation process of conventional GEPs is inconvenient compared with that of traditional foundation piles.The pre-bored grouted planted geothermal energy pile(PGP GEP)is an innovative technology to simplify the installation process.Most investigations of in-situ experiments for conventional GEPs have focused on summer conditions.An in-situ test for a PGP GEP was conducted to analyze the temperature changes and thermo-mechanical characteristics under winter conditions.The results show that the average temperature of the pile decreased by 5.1℃,and the pile exhibited a general trend of high temperatures at both ends and low temperatures in the middle.In mechanics,strong pile end restraints resulted in smaller observed axial strain and higher axial thermal-induced force in the pile ends than at the middle of the pile.
基金National Natural Science Foundation of China under Grant Nos.U2139208 and 52278516Key Laboratory of Earthquake Engineering and Engineering Vibration,China Earthquake Administration under Grant No.2024D15Key Laboratory of Soft Soil Characteristic and Engineering Environment,Tianjin Chengjian University under Grant No.2022SCEEKL003。
文摘This study presents an effective hybrid simulation approach for simulating broadband ground motion in complex near-fault locations.The approach utilizes a deterministic approach based on the spectral element method(SEM),which is used to simulate low-frequency ground motion(f<1 Hz)by incorporating an innovative efficient discontinuous Galerkin(DG)method for grid division to accurately model basin sedimentary layers at reduced costs.It also introduces a comprehensive hybrid source model for high-frequency random scattering and a nonlinear analysis module for basin sedimentary layers.Deterministic outcomes are combined with modified three-dimensional stochastic finite fault method(3D-EXSIM)simulations of high-frequency ground motion(f>1 Hz).A fourth-order Butterworth filter with zero phase shift is employed for time-domain filtering of low-and high-frequency time series at a crossover frequency of 1 Hz,merging the low and high-frequency ground motions into a broadband time series.Taking an Ms 6.8 Luding earthquake,as an example,this hybrid method was used for a rapid and efficient simulation analysis of broadband ground motion in the region.The accuracy and efficiency of this hybrid method were verified through comparisons with actually observed station data and empirical attenuation curves.Deterministic method simulation results revealed the effects of mountainous topography,basin effects,nonlinear effects within the basin’s sedimentary layers,and a coupling interaction between the basin and the mountains.The findings are consistent with similar studies,showing that near-fault sedimentary basins significantly focus and amplify strong ground motion,and the soil’s nonlinear behavior in the basin influences ground motion to varying extents at different distances from the fault.The mountainous topography impacts the basin’s response to ground motion,leading to barrier effects.This research provides a scientific foundation for seismic zoning,urban planning,and seismic design in nearfault mountain basin regions.
基金Project(52373065)supported by the National Natural Science Foundation of ChinaProject(2220004002898)supported by the Zhuhai Industry University Research Cooperation and Basic and Applied Research Projects,China。
文摘Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.
基金supported by the National Natural Science Foundation of China(Nos.52305401 and 52475391)National Key Research and Development Program of China(2024YFB3714301)+1 种基金the Fundamental Research Program of Shanxi Province(202303011211004,TZLH20230818001)Engineering Research Center of the Ministry of Education.
文摘Cold deformation treatment of Cu-bearing stainless steel through a cold rolling process combined with electric pulse treatment(EPT)can significantly improve the microstructure and formability of cold-rolled Cu-bearing stainless steel.The microstructure after EPT was characterized by scanning electron microscopy,transmission electron microscopy,and in-situ tensile testing.It is found that compared with conventional heat treatment,EPT process can significantly promote the nucleation rate and mobility at grain boundaries of the deformed samples,greatly accelerating the recovery and static recrystallization of Cu-bearing stainless steel samples at lower temperatures and contributing to the recovery of anisotropy and the re-molding of deformed samples.Microstructural characterization and theoretical analyses show that the rapid recrystallization during EPT process is caused not only by Joule heating effects but also by non-thermal effects that accelerate grain boundary migration and dislocation destruction and regeneration.In addition,EPT process significantly accelerated the nucleation and precipitation growth of Cu-rich phase.The coarsening of Cu-rich phase during EPT process is due to not only the high vacancy diffusion coefficient under the action of the electric pulse but also the increase in the vacancy diffusion flux induced by the electromigration in the process of the electric pulse.
基金Supported by Shanghai Agriculture Applied Technology Development Program (Grant No.T20220120).
文摘[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and puncture,the index data of the fruit were obtained by setting different trigger forces,deformation levels,test speeds,as well as puncture speeds and puncture depths.The data included TPA hardness,adhesiveness,springiness,cohesiveness,gumminess,chewiness,resilience,as well as skin hardness,skin toughness,flesh hardness,fracturability,and compactness.[Results]Different deformation levels had a significant impact on all parameters.Hardness,adhesiveness,gumminess and chewiness showed a trend of first increasing and then decreasing with the deformation level increasing.When the deformation level was 30%,the adhesiveness,gumminess and chewiness reached their maximum values.When the deformation level was 50%,TPA hardness reached its maximum.When the compression speed was 3 mm/s,the measured values of TPA hardness,adhesiveness,chewiness,and resilience were at their maximums.The skin hardness varied significantly under different trigger forces.When the trigger force was 15 g,the skin hardness reached a maximum value of 944.63 g,and the skin toughness,flesh hardness,fracturability,and compactness also reach their maximum values respectively.When the puncture depth was 12 mm,the flesh hardness and skin toughness reached their maximums of 682.51 g and 1.82 mm,respectively.In the TPA mode,the flesh hardness of chieh-qua showed an extremely significant negative correlation with springiness,cohesiveness,and resilience(P<0.01).The fruit fracturability detected by puncture had an extremely significant positive correlation with compactness(P<0.01).[Conclusions]The evaluation method for measuring chieh-qua texture by combining TPA and the puncture mode could accurately and quantitatively reflect the differences in the flesh texture quality of chieh-qua.The optimal parameters for texture measurement of chieh-qua fruit were determined as a 15 g trigger force with 50%deformation and a 3 mm/s compression speed in TPA mode,and a 15 g trigger force with a 12 mm puncture depth in puncture mode.Puncture speed was found to have no significant effect on the texture indices of chieh-qua.
基金Project supported by the National Natural Science Foundation of China(Nos.52405095,12272089,and 92360305)the Guangdong Basic and Applied Basic Research Foundation of China(No.2023A1515110557)+4 种基金the Natural Science Foundation of Liaoning Province of China(No.2023-BSBA-102)the Open Fund of National Key Laboratory of Particle Transport and Separation Technology of China(No.WZKF-2024-6)the Open Project of Guangxi Key Laboratory of Automobile Components and Vehicle Technology of China(Nos.2024GKLACVTKF07 and 2024GKLACVTKF06)the Basic Research Projects of Liaoning Provincial Department of Education of China(No.JYTQN2023162)the Fundamental Research Funds for the Central Universities of China(No.N2403022)。
文摘The testing of large structures is limited by high costs and long cycles, making scaling methods an attractive solution. However, the scaling process of elastic rings introduces complexities in multi-parameter geometric distortions, leading to a diminution in the predictive accuracy of the distorted similitude. To address this challenge, this study formulates a novel set of scaling laws, tailored to account for the intricate geometric distortions associated with elastic rings. The proposed scaling laws are formulated based on the intrinsic deformation characteristics of elastic rings, rather than the traditional systemic governing equations. Numerical and experimental cases are conducted to assess the efficacy and precision of the proposed scaling laws, and the obtained results are compared with those achieved by traditional methods. The outcomes demonstrate that the scaling laws put forth by this study significantly enhance the predictive capabilities for deformations of elastic rings.
基金supported in part by the Mining Hydraulic Technology and Equipment Engineering Research Center,Liaoning Technical University,Fuxin,China(Grant No.MHTE23-R04)the Fundamental Research Funds for the Central Universities(ID N25BSS068).
文摘This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.
基金support provided by the National Natural Science Foundation of China(No.22273043).
文摘As a novel class of purely organic fluores-cent materials,multiple resonance thermal-ly activated delayed fluorescence(MR-TADF)compounds hold significant promise for next-generation display technologies.The efficiency of exciton utilization and the overall performance of organic light-emit-ting devices are closely linked to the singlet-triplet energy gap(ΔE_(ST))of MR-TADF emitters.Identifying an economic and accu-rate theoretical approach to predictΔE_(ST)would be beneficial for high-throughput screening and facilitate the inverse design of MR-TADF molecules.In this study,we evaluated the S_(1)state energy(E(S_(1))),T_(1)state ener-gy(E(T_(1))),andΔE_(ST)using three different physical interpretations:adiabatic excitation ener-gy,vertical absorption energy,and vertical emission energy.We employed the time-depen-dent density functional theory(TDDFT)and delta self-consistent field(ΔSCF)methods to calculate E(S_(1)),E(T_(1)),andΔE_(ST)for 20 MR-TADF molecules reported in the literature.We compared these calculated values with experimental data obtained from fluorescence spec-troscopy at room-temperature(or 77 K)and phosphorescence spectroscopy conducted at 77 K.Our findings indicate that the vertical absorption energy at the S0 state minimum,deter-mined by theΔSCF method,accurately predicts the S_(1)state energy.Similarly,the vertical absorption energy at the S0 state minimum,calculated using the TDDFT method,effectively predicts the T_(1)state energy.TheΔE_(ST)derived from the difference between these two excita-tion energies exhibited the smallest mean absolute error of only 0.039 eV compared to the ex-perimental values.This combination represents the most accurate and cost-effective method reported to date for predicting theΔE_(ST)of MR-TADF molecules,and can be integrated into AI-driven inverse design workflows for new emitters.
基金supported by the National Natural Science Foundation of China(Grant Nos.12272393 and 52130905).
文摘As binary geological media,soil-rock mixtures(SRMs)exhibit a distinct gradational composition,leading to their unique mechanical behaviors.To appraise the stability of SRM slopes,it is essential to determine equivalent parameters of SRMs,which are typically obtained through experimental and numerical methods.In contrasted to other numerical methods,the numerical manifold method(NMM)is more effective in addressing SRM problems.This is because the high-precision regular mathematical meshes in NMM can be used without aligning with the soil-rock interfaces and boundaries of SRMs.In the current research,the equivalent strength parameters of SRMs,i.e.the equivalent cohesion ce and internal friction angleϕ_(e),are determined using NMM.Initially,an NMM triaxial numerical model is established and validated based on triaxial experiments.Subsequently,the soil and rock parameters are derived through parameter inversion.Moreover,the impacts of rock content,size,shape and rock blocks'major-axis orientation on ce andϕ_(e) of SRMs are thoroughly examined using the NMM triaxial numerical model.Additionally,a fitting function is proposed to linkϕ_(e) to the rock content and size of SRMs.When other influencing factors are fixed,the above fitting model leads to the following conclusions:(1)the predictedϕ_(e) of SRMs increase with the increase of rock content;and(2)SRM samples with smaller rocks display a higher predictedϕ_(e).
基金support from the National Natural Science Foundation of China(Grant No.42407256)the State Key Laboratory of Hydraulics and Mountain River Engineering,China(Grant No.SKHL2113)the Sichuan Science and Technology Program(Grant No.2024YFHZ0341).
文摘This paper develops a semi-analytical solution for pile penetration in natural soft clays using the strain path method(SPM).The stress-strain behavior of soils is characterized by the S-CLAY1S model,which can capture the anisotropic evolution and destructuring nature of soft clays.By integrating the S-CLAY1S model into the theoretical framework of the SPM,a set of ordinary differential equations is formulated with respect to the vertical coordinate of soil particles.The distribution of excess pore water pressure(EPWP)following pile installation is approximated through one-dimensional(1D)radial integration around the pile shaft.The distribution of stresses and EPWP,along with the evolution of fabric anisotropy within the soil surrounding the pile,is presented to illustrate the response of pile penetration in natural soft clays.The proposed solution is validated against existing theoretical solutions using the SPM and cavity expansion method(CEM),along with experimental data.The findings demonstrate that the SPM reveals lower radial effective stresses and EPWP at the pile shaft than that of CEM.Pile penetration alters the soil's anisotropic properties,inducing rotational hardening and affecting post-installation stress distribution.Soil destructuration eliminates bonding among particles near the pile,resulting in a complete disruption of soil structure at the pile surface,which is particularly pronounced for higher initial soil structure ratios.Minimal variation was observed in the three principal stresses and shear stress on the cone side surface as the angle increased from 18°to 60°,except for a slight reduction in EPWP.
