The large-scale application of Zn-air battery requires the development of efficient,low-cost,and stable bifunctional electrocatalysts for the oxygen evolution reaction(OER)and oxygen reduction reaction(ORR).Herein,an ...The large-scale application of Zn-air battery requires the development of efficient,low-cost,and stable bifunctional electrocatalysts for the oxygen evolution reaction(OER)and oxygen reduction reaction(ORR).Herein,an electrocatalyst of a Co/Mo C-nanoparticles embedded N-doped carbon(Co/Mo C@N-C)was prepared via the in-situ encapsulation of Co_(2)(CO)_(8)and Mo(CO)6 in ZIF-8 using ball-milling,followed by pyrolysis under an Ar atmosphere.When used as a bifunctional electrocatalyst,the as-prepared Co/Mo C@N-C showed an ORR half-wave potential of 0.824 V in an alkaline medium and an overpotential of only 290 m V for the OER at 10 m A cm^(-2),which was 70 m V lower than Ru O_(2).The Co/Mo C@N-C was also evaluated as a cathode in a solid-state Zn-air battery and delivered a higher peak discharge power density and better cycling stability(over 1600 min)than Pt/C-Ru O_(2).Most importantly,our work provides a new strategy to prepare bifunctional catalysts and promotes their applications in the energy conversion field.展开更多
Three-dimensional supramolecular organic frameworks with precisely tunable pore sizes are highly demanded for a wide range of applications,e.g.,encapsulating enzymes to enhance their stability,activity,and reusability...Three-dimensional supramolecular organic frameworks with precisely tunable pore sizes are highly demanded for a wide range of applications,e.g.,encapsulating enzymes to enhance their stability,activity,and reusability.However,precise control and tune the pore size of such frameworks still remains a significant challenge to date.In this study,we constructed supramolecular polymer frameworks using rigid tetrahedral star polyisocyanides with tunable length and sufficiently narrow distribution as building block.First,a series of tetrahedral four-arm star polyisocyanides with controlled chain lengths and narrow molecular weight distributions was prepared via the Pd(Ⅱ)-catalyzed living isocyanide polymerization.Then 2-ureido-4[1H]-pyrimidinone(Upy) unit was installed onto each chain-end of polyisocyanide arms via post-polymerization functionalization.Leveraging the supramolecular hydrogen bonding interactions between the terminal Upy units,well-ordered supramolecular polymer frameworks were readily obtained.Notably,the pore size was dependent on the chain length of the polyisocyanide arms.Precisely control the chain length of polyisocyanide arms,supramolecular polymer frameworks with pore sizes ranging from 5.06 nm to 9.72 nm were achieved.These frameworks,with tunable and large pore apertures,demonstrated exceptional capabilities in encapsulating enzymes of different sizes,such as lipase(TL),horseradish peroxidase(HRP),and glucose oxidase(GOx).The encapsulated enzymes exhibited significantly enhanced catalytic activity and durability.Moreover,the frameworks' tunable and large pore apertures facilitated the co-encapsulation of multiple enzymes,enabling efficient dual-enzyme cascade reactions.展开更多
Mini light-emitting diodes(Mini-LEDs)show great application potential in high-end displays owing to their superior pixel density,brightness,responsiveness,and efficiency.However,current packaging materials for Mini-LE...Mini light-emitting diodes(Mini-LEDs)show great application potential in high-end displays owing to their superior pixel density,brightness,responsiveness,and efficiency.However,current packaging materials for Mini-LEDs are predominantly thermally cured,which is energy-and time-consuming and can adversely affect electronic components.In this study,a novel UV-curable silicone resin containing phenyl,disulfide,and acryloyl groups(SPASR)is developed from commercially available siloxanes.The resin exhibits a refractive index(n_(d))higher than 1.5,and it can be cured within 30 s under UV irradiation.After curing,it exhibits an optical transparency exceeding 92%,a lap adhesion strength of up to1.84 MPa,and good thermostability(T_(5%)>265℃).Notably,the volume shrinkage is less than 4.83%,attributed to the release of photopolymerization stress via UV-induced disulfide metathesis during UV curing.Mini-LEDs encapsulated with this resin show luminescence properties comparable to those of conventional thermally-cured sealants,and show excellent sealability wihtout visible penetration after being immersed in red ink for 12 h.Consequently,these excellent properties make the SPASR resin an ideal candidate for microelectronic encapsulation,offering a more reliable and efficient solution for the electronics industry.展开更多
Owing to the outstanding optoelectronic properties of perovskite materials,perovskite solar cells(PSCs)have been widely studied by academic organizations and industry corporations,with great potential to become the ne...Owing to the outstanding optoelectronic properties of perovskite materials,perovskite solar cells(PSCs)have been widely studied by academic organizations and industry corporations,with great potential to become the next-generation commercial solar cells.However,critical challenges remain in preserving high efficiency practical large-scale commercialized PSCs:a)the long-term stability of the cell materials and devices,b)lead leakage,and c)methods to scale the cells for larger area applications.This paper summarizes the prior-art strategies to address the above challenges,including the latest studies on the traditional glass-glass and thin-film encapsulation methods to better improve the reliability of PSCs,new technologies for preventing lead leakage,and geometric improvement strategies to enhance the reliability,efficiency,and performance of perovskite solar modules(PSMs).Through these strategies,the device achieved enhanced performance in long-term stability tests.The encapsulation resulted in a high lead leakage inhibition rate of up to 99%,and the PSMs possessed a geometric fill factor of 99.6%and a power conversion efficiency(PCE)of 20.7%.The dramatic improvement of efficiency and reliability of perovskite solar cells and modules indicate the great potential for mass production and commer-cialization of perovskite solar applications in the near future.展开更多
High-temperature phase change materials(PCMs)have attracted significant attention in the field of thermal energy storage due to their ability to store and release large amounts of heat within a small temperature fluct...High-temperature phase change materials(PCMs)have attracted significant attention in the field of thermal energy storage due to their ability to store and release large amounts of heat within a small temperature fluctuation range.However,their practical application is limited due to problems such as leakage,corrosion,and volume changes at high temperatures.Recent research has shown that macroencapsulation technology holds promise in addressing these issues.This paper focuses on the macroencapsulation technology of high-temperature PCMs,starting with a review of the classification and development history of high-temperature macroencapsulatd PCMs.Four major encapsulation strategies,including electroplating method,solid/liquid filling method,sacrificial material method,and powder compaction into sphere method,are then summarized.The methods for effectively addressing issues such as corrosion,leakage,supercooling,and phase separation in PCMs are analyzed,along with approaches for improving the heat transfer performance,mechanical strength,and thermal cycling stability of macrocapsules.Subsequently,the structure and packing arrangement optimization of macrocapsules in thermal storage systems is discussed in detail.Finally,after comparing the performance of various encapsulation strategies and summarizing existing issues,the current technical challenges,improvement methods,and future development directions are proposed.More attention should be given to utilizing AI technology and reinforcement learning to reveal the multiphysics-coupled heat and mass transfer mechanisms in macrocapsule applications,as well as to optimize material selection and encapsulation parameters,thereby enhancing the overall efficiency of thermal storage systems.展开更多
Many azo compounds and their intermediates are toxic and have been linked to various health issues,representing a growing global problem.Molecular engineering for selective encapsulation of azobenzene compounds is cri...Many azo compounds and their intermediates are toxic and have been linked to various health issues,representing a growing global problem.Molecular engineering for selective encapsulation of azobenzene compounds is critical,given their significant use in smart materials and prevalence as environmental micropollutants released from the food and dye industries.However,the current host molecules catering to azobenzene compounds are mainly limited to cyclodextrins,pillar[n]arenes and cucurbit[n]urils,demonstrating a moderate affinity.This report describes that a novel 3,3'-bipyridinium-based cyclophane was capable of encapsulating anionic azobenzene compounds in water with high binding affinity and pH stability through electrostatic attraction-enhanced mechanism,surpassing the extensively reported supramolecular systems.1D&2D NMR experiments,UV-vis spectrum,X-ray crystallography and computational modeling were carried out to understand the host-vip complexation.It's worth noting that the tetracationic cyclophane exhibited good selective and anti-interference encapsulation properties in binary,ternary and seawater systems.Furthermore,upon UV/white light irradiation,the reversible conversion between(E)-4,4'-azobisbenzoate and(Z)-4,4'-azobisbenzoate triggers the dissociation/recomplexation of the host-vip complex within 3 min.This reversible photo-switchable(E)-disodium 4,4'-azobisbenzoateBPy-Box^(4+)supramolecular system holds promise for designing novel materials for extraction/release of azo compounds and other small smart materials.展开更多
Guava(Psidium guajava L.),a plant belonging to the Myrtaceae family,holds significant medicinal and nutritional values.Leaves of the plant are described to be elliptical with a dark green color and are utilized in the...Guava(Psidium guajava L.),a plant belonging to the Myrtaceae family,holds significant medicinal and nutritional values.Leaves of the plant are described to be elliptical with a dark green color and are utilized in the treatment of gastrointestinal and respiratory issues along with increasing the platelet count in patients suffering from dengue.In this review paper,the nutritional composition and bioactive compounds of guava leaves,including proteins,vitamins,minerals,and polysaccharides,have been reviewed.The methods of extraction of bioactive compounds from guava leaves and their bioactivities,including antioxidant,anti-diabetic,and anti-cancer potential,have been explored.Further,encapsulation techniques for improving the transport of bioactive compounds and living cells into foods have been studied.The application of guava leaves in different food systems such as herbal tea,pork sausage,chocolates,jelly,meals for chickens,functional beverages,and as antibacterial agents in food preservatives has also been investigated.The findings of this review illustrated that the phytochemicals present in guava leaves showed excellent antimicrobial and antioxidant properties.Encapsulation appears to be a promising technique for improving the stability,bioavailability,and controlled release of bioactive chemicals extracted from guava leaves.Different methods for the encapsulation of bioactive compounds employed and applied in distinct food systems showed preservation of phytochemicals,improved bioactivities,and nutritional values.Overall,this review paper demonstrated how guava leaves,an abundant source of bioactive compounds,can be used as a multipurpose component to create functional foods,edible coatings,and active packaging to enhance the nutritional,antioxidant,and antimicrobial properties of various food systems that have qualities that promote health.展开更多
Encapsulation and protection of hesperidin(HES)in mung bean protein isolate(MPI)-dextran(DX)conjugatestabilized nanoemulsions(MDC NEs)were investigated in this study.The degree of grafting of MDC prepared by a dry-hea...Encapsulation and protection of hesperidin(HES)in mung bean protein isolate(MPI)-dextran(DX)conjugatestabilized nanoemulsions(MDC NEs)were investigated in this study.The degree of grafting of MDC prepared by a dry-heating method reached 39.70%±0.01% under the optimal conditions of MPI/DX mass ratio 1:2.3,reaction temperature 58.8℃,and reaction time 4 d.Moreover,the analyses of Fourier infrared spectroscopy,intrinsic fluorescence spectroscopy,surface hydrophobicity,and thermal stability further confirmed the covalent grafting of dextran onto MPI molecules.When encapsulated in MDC NEs at 80 MPa for three times by highpressure homogenization,the encapsulation efficiency and loading capacity of HES were 63.62%±0.01%and 0.40±0.00 g/g,respectively.The encapsulated HES exhibited higher antioxidant activity and stronger light and storage stability than the free HES.Additionally,the incorporation of HES inhibited the formation of lipid peroxides in the nanoemulsions.The findings suggest that glycosylation combined with high-pressure homogenization is an effective strategy for enhancing the stability of MPI-based emulsions and improving their encapsulation of HES.This study provides a promising approach for the development of innovative food and beverage products based on MPI emulsions or new materials for encapsulating fat-soluble bioactive compounds.展开更多
Cryopreservation is a fundamental technology in biomedical research,regenerative medicine,and tissue engineering,enabling the long-term storage of cells,tissues,and organs.However,its effectiveness is limited by chall...Cryopreservation is a fundamental technology in biomedical research,regenerative medicine,and tissue engineering,enabling the long-term storage of cells,tissues,and organs.However,its effectiveness is limited by challenges such as intracellular ice formation,cryoprotectant toxicity,and reduced post-thaw viability.This review explores the crucial role of encapsulation in enhancing cryopreservation efficiency,with a focus on recent advances in materials science,bioengineering,and cryobiology.Emerging technologies,such as nanotechnology and stimuli-responsive polymers,are transforming encapsulation strategies.Innovations such as microfluidic systems offer precise control over cooling rates and cryoprotectant distribution,thereby mitigating conventional limitations.The review also addresses current obstacles related to scaling up encapsulation processes and ensuring the long-term biocompatibility and stability of preserved specimens.By synthesizing recent findings,this work provides a comprehensive resource for researchers and clinicians seeking to enhance biopreservation techniques and their applications in contemporary medicine and biotechnology.Finally,the review identifies critical knowledge gaps that must be addressed to improve the efficacy of cryopreservation strategies and advance their clinical translation.展开更多
Hydrogen-bonded framework(HOF) offers an attractive platform to encapsulate enzymes and stabilize their conformation,due to the advantages of mild synthesis conditions,tailorable pore structure,and backbone biocompati...Hydrogen-bonded framework(HOF) offers an attractive platform to encapsulate enzymes and stabilize their conformation,due to the advantages of mild synthesis conditions,tailorable pore structure,and backbone biocompatibility.However,the efficiency of this HOF approach relies on the interfacial interactions between enzyme vip and the ligand precursors,limiting its adaptability to enzymes with varying surface chemistry property.In this study,we report a site-specific surface modification strategy to positively tailor the enzyme surface charge,facilitating the biomimetic encapsulation of enzymes within HOF in situ.Both experimental results and computational simulation reveal that site-specific amination of enzyme surface's acidic residues contributes to the interfacial accumulation of carboxylic ligand precursors in aqueous solutions via synergistic electrostatic and hydrogen bonding interactions.This substantially facilitates the in situ growth of porous HOF surrounding the aminated enzyme biotemplates,with up to 100% enzyme loading efficiency.The resultant hydrogen-bonded biohybrid framework(HBF) retains high biocatalytic functions while exhibiting exceptional stability under harsh conditions.By leveraging the marked catalytic activity of GOx-NH_(2)@HBF-1 and a H_(2)O_(2)-sensitive QD,a highly sensitive glucose fluorescence sensor is fabricated with a wide linear range(5-2000 μmol/L) and a low quantification limit of 5 μmol/L.This work presents a simple yet effective enzyme surface engineering approach for integrating enzyme into HOF,opening new avenues for the construction of multifunctional HOF biocomposites.展开更多
Extreme environments challenge the structural health monitoring of advanced equipment.In-situ dynamic tracking temperature is of particular value due to its enormous impact on material properties.However,the realizati...Extreme environments challenge the structural health monitoring of advanced equipment.In-situ dynamic tracking temperature is of particular value due to its enormous impact on material properties.However,the realization of such integrated temperature sensors typically requires complicated layer-by-layer molding and sintering processes including additional thermal barrier coatings.Herein,we report a laser-induced in-situ conductive passivation strategy for the fabrication of a thin-film based wide-range temperature sensor.The instantaneous thermal effect of laser irradiation creates crystalline conductive traces in response to temperature variations.Synchronously,it also allows the formation of an amorphous antioxidative layer without necessitating extra protective coatings.Such configuration enables precise real-time sensing across-50℃to 950℃following the Steinhart-Hart equation.It also exhibits durable performance with only 1.2%drift over 20 hours during long-term high-temperature,instant thermal shock,frequent wearing,and severe vibration.This in-situ,facile laser manufacturing strategy holds great promise in structural health monitoring and fault diagnosis for advanced equipment working in extreme environments.展开更多
Despite the ongoing increase in the efficiency of perovskite solar cells(PSCs),residual lead iodide(PbI2and moisture sensitivity issues continue to constrain their further commercialization.Herein,we propose a thermal...Despite the ongoing increase in the efficiency of perovskite solar cells(PSCs),residual lead iodide(PbI2and moisture sensitivity issues continue to constrain their further commercialization.Herein,we propose a thermally mediated in situ repair and encapsulation strategy to construct high-performance PSCs by incorporating piperazine thioctic acid salt(TAPPZ)as a dopant into the perovskite precursor Thermally dissociated piperazine(PPZ)from TAPPZ integrates microcrystals to form larger grain(>2000 nm),while the carboxylic acid in thioctic acid(TA)and the amine salt in TAPPZ synergistically passivate and transform PbI_(2),significantly reducing its residual amount.Additionally,TAPPZ undergoe thermal self-crosslinking during perovskite annealing,enabling melt-polymerization to form in situ encapsulation for enhanced water resistance.The TAPPZ-incorporated device achieves a remarkable efficiency of 25.65% and exhibits excellent operational stability,retaining over 90% of its initial efficiency after 2000 h under ambient conditions(20-30℃,20%-30% relative humidity).This study provide new insights into the construction of high-performance perovskite solar cells by designing and synthe sizing multifunctional single molecules for in situ repair and encapsulation of perovskites.展开更多
Exploring cost-effective and efficient catalysts for oxygen reduction reaction(ORR)poses a significant challenge,espe-cially in the pursuit of alternatives to precious metals like platinum.Significant advancements hav...Exploring cost-effective and efficient catalysts for oxygen reduction reaction(ORR)poses a significant challenge,espe-cially in the pursuit of alternatives to precious metals like platinum.Significant advancements have driven electrochem-ists to develop efficient ORR catalysts using abundant materials,particularly iron(Fe)-based,known for their exceptional performance in ORR.While the crucial function of Fe in boosting ORR catalytic activity is recognized,the connection between material attributes and catalytic performance remains enigmatic.Understanding the dynamic processes involved in oxygen electrocatalysis is paramount for designing precious-metals-free ORR electrocatalysts.Mössbauer spectroscopy stands out as a powerful technique for deciphering the structural characteristics of Fe species in catalysis,facilitating the identification of active sites and the clarification of catalytic mechanisms.By showcasing noteworthy case studies within this review,we demonstrate the application of in-situ/operando 57Fe Mössbauer spectroscopy across diverse Fe-involved materials in ORR catalysis.This sheds light on various aspects of ORR catalysis,such as identifying active sites,assessing stability,and understanding the reaction mechanism.Our inquiry drives towards the opportunities and hurdles associ-ated with Mössbauer spectroscopy,unveiling potential breakthroughs and avenues for enhancement within this pivotal research realm.展开更多
To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,t...To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,the effects of carrier gas types,regeneration temperatures,and granular activated carbon(GAC)addition on iron-based catalyst regeneration were investigated.The Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regenerated at 550°C with additional GAC and 15%water vapor exhibited the optimal degradation efficiency towards polychlorinated biphenyls(PCBs),with an increase from 41.2%to 93.5%,compared with non-regenerated Fe_(3)O_(4)/𝛾-Al_(2)O_(3).In addition,the 60-hour stability test revealed a well-recovered catalytic activity.During the Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regeneration,the coke on the catalyst surface was oxidized and removed in the form of CO_(2),and meanwhile the oxidized Fe(III)was reduced into Fe(II)in the catalyst.This study provides a safe and efficient iron-based catalyst regeneration technology for PCB off-gas degradation and reveals the catalytic activity recovery mechanism during catalyst regeneration.展开更多
In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of roc...In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of rocks after stress relief introduces errors.To improve accuracy,this study proposes an in-situ stress solution theory that incorporates time-dependent stress relief effects.Triaxial stepwise loadingunloading rheological tests on granite and siltstone established quantitative relationships between instantaneous elastic recovery and viscoelastic recovery under different stress levels,confirming their impact on measurement accuracy.By integrating a dual-class elastic deformation recovery model,an improved in-situ stress solution theory was derived.Additionally,accounting for the nonlinear characteristics of rock masses,a determination method for time-dependent nonlinear mechanical parameters was proposed.Based on the CSIRO hollow inclusion strain cell,time-dependent strain correction equations and long-term confining pressure calibration equations were formulated.Finally,the proposed theory was successfully applied at one iron mine(736 m depth)in Xinjiang,China,and one coal mine(510 m depth)in Ningxia,China.Compared to classical theory,the calculated mean stress values showed accuracy improvements of 6.0%and 9.4%,respectively,validating the applicability and reliability of the proposed theory.展开更多
The Ru-based catalysts with different preparation methods or supports were achieved and applied in efficientlycatalytic elimination of 1,2-dichloroethane(1,2-DCE).It wasfirstly found that the redox ability and chlorine...The Ru-based catalysts with different preparation methods or supports were achieved and applied in efficientlycatalytic elimination of 1,2-dichloroethane(1,2-DCE).It wasfirstly found that the redox ability and chlorine re-sistance of the catalyst could be improved by regulating the interaction between Ru and supports.Compared withother supports and conventionally impregnated methods,the Ru@ZSM-5 catalyst synthesized by the in-situ en-capsulation strategy exhibited an excellent low-temperature catalytic performance(T50=262°C,T90=327℃),superior stability in long-term test as well as ideal target products.The acidity,specific surface area,and in-teraction with precious metals of the supports have significant influences on the catalytic activity,and the Ruclusters inside the pore structures are more closely bound to the framework Al species,which promotes theoxidation behavior.The encapsulation strategy also significantly improves the Ru dispersion thereby facilitatesoxygen activation as well as Cl-containing volatile organic compounds(CVOCs)deep oxidation,and preserveslarge amounts of Brønsted acid sites to optimize the hydrolysis mechanism for purification of CVOCs.Subse-quently,the synergistic effect between metal redox and acidity is greatly optimized,thus extremely promotingthe catalytic efficiency of 1,2-DCE oxidation.展开更多
Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating p...Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating packed bed(RPB)in premixing and crystallization on crystallinity and RE utilization rate was further investigated.The results indicate that lanthanide(La)cations are successfully introduced into the sodalite cage of Y-type zeolite.The optimized conditions are that the molar ratio of Si/La is 150,premixing for 5 h,crystallization at 90℃ for 18 h,and calcination at 550℃ for 3.5 h.At this stage,the RE utilization rate reaches 74.5%.Compared with the conventional stirred tank reactor(STR),RPB can effectively shorten the premixing time and crystallization time by 4.3 h and 6 h,improve the crystallinity by 23%and RE utilization rate by 7.5%.The RE utilization rate is more than 80%by RPB,surpassing the effectiveness of using the one-exchange one-calcination process in the traditional liquid ion exchange process.It is expected to provide a reference for the in-situ efficient and green synthesis of RE zeolite.展开更多
The main purpose of using geothermal energy piles(GEPs)is to enable the exploitation of geothermal energy for meeting the heating/cooling demands of buildings efficiently.However,the installation process of convention...The main purpose of using geothermal energy piles(GEPs)is to enable the exploitation of geothermal energy for meeting the heating/cooling demands of buildings efficiently.However,the installation process of conventional GEPs is inconvenient compared with that of traditional foundation piles.The pre-bored grouted planted geothermal energy pile(PGP GEP)is an innovative technology to simplify the installation process.Most investigations of in-situ experiments for conventional GEPs have focused on summer conditions.An in-situ test for a PGP GEP was conducted to analyze the temperature changes and thermo-mechanical characteristics under winter conditions.The results show that the average temperature of the pile decreased by 5.1℃,and the pile exhibited a general trend of high temperatures at both ends and low temperatures in the middle.In mechanics,strong pile end restraints resulted in smaller observed axial strain and higher axial thermal-induced force in the pile ends than at the middle of the pile.展开更多
In the present work,the porous Ti particle reinforced Mg-based bulk metallic glass matrix composites(BMGCs)have been successfully fabricated via a novel in-situ dealloying method in metallic melt.A dual reinforcing st...In the present work,the porous Ti particle reinforced Mg-based bulk metallic glass matrix composites(BMGCs)have been successfully fabricated via a novel in-situ dealloying method in metallic melt.A dual reinforcing structure,including large-scale between porous particles and fine-scale inside one particle,was induced to further overcome the strength-plasticity tradeoff.The microstructure and mechanical properties of such dual-scale structure-reinforced BMGCs with various volume fractions and diameters of porous Ti particles were investigated in detail.It is found that with more and finer porous Ti particles,the BMGC showed both high fracture strength(1131.9±39.1 MPa)and good plastic deformability(1.48±0.38%).The characteristic of the reinforcing structure(0.48μm)inside the porous particles was close to the plastic processing zone size of the matrix(0.1~0.2μm),which generated a locally ideal reinforcing structure.Such dual-scale reinforcing structures with more interfaces can effectively promote the multiplication of shear bands at the interfaces.Due to the size effect,the refined submicron matrix between the Ti ligaments inside the porous particles should exhibit homogeneous shearing events.Such delocalization behavior from the dual-scale reinforcing structures should help to enhance the role of the interactions between shear bands,thus improving the yield strength of the composites.Based on the in-situ dealloying method,the dual-scale structure design provides a novel approach to fabricate various BMGCs with both high strength and good plasticity.展开更多
Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrate...Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.展开更多
基金the Program of Introducing Talents of Discipline to Universities(B18030)the National Natural Science Foundation of China(21421001 and 21531005)+2 种基金the Natural Science Foundation of Tianjin City(19JCZDJC37200)the National Postdoctoral Program for Innovative Talents(BX20190157)the China Postdoctoral Science Foundation(2019 M660979)。
文摘The large-scale application of Zn-air battery requires the development of efficient,low-cost,and stable bifunctional electrocatalysts for the oxygen evolution reaction(OER)and oxygen reduction reaction(ORR).Herein,an electrocatalyst of a Co/Mo C-nanoparticles embedded N-doped carbon(Co/Mo C@N-C)was prepared via the in-situ encapsulation of Co_(2)(CO)_(8)and Mo(CO)6 in ZIF-8 using ball-milling,followed by pyrolysis under an Ar atmosphere.When used as a bifunctional electrocatalyst,the as-prepared Co/Mo C@N-C showed an ORR half-wave potential of 0.824 V in an alkaline medium and an overpotential of only 290 m V for the OER at 10 m A cm^(-2),which was 70 m V lower than Ru O_(2).The Co/Mo C@N-C was also evaluated as a cathode in a solid-state Zn-air battery and delivered a higher peak discharge power density and better cycling stability(over 1600 min)than Pt/C-Ru O_(2).Most importantly,our work provides a new strategy to prepare bifunctional catalysts and promotes their applications in the energy conversion field.
基金The National Natural Science Foundation of China (NSFC,Nos.92256201,52273006,22071041,92356302,and 21971052)Natural Science Foundation of Jilin Province (No.20240101181JC) are gratefully appreciated for financial the supportssupported by the User Experiment Assist System of Shanghai Synchrotron Radiation Facility (SSRF)。
文摘Three-dimensional supramolecular organic frameworks with precisely tunable pore sizes are highly demanded for a wide range of applications,e.g.,encapsulating enzymes to enhance their stability,activity,and reusability.However,precise control and tune the pore size of such frameworks still remains a significant challenge to date.In this study,we constructed supramolecular polymer frameworks using rigid tetrahedral star polyisocyanides with tunable length and sufficiently narrow distribution as building block.First,a series of tetrahedral four-arm star polyisocyanides with controlled chain lengths and narrow molecular weight distributions was prepared via the Pd(Ⅱ)-catalyzed living isocyanide polymerization.Then 2-ureido-4[1H]-pyrimidinone(Upy) unit was installed onto each chain-end of polyisocyanide arms via post-polymerization functionalization.Leveraging the supramolecular hydrogen bonding interactions between the terminal Upy units,well-ordered supramolecular polymer frameworks were readily obtained.Notably,the pore size was dependent on the chain length of the polyisocyanide arms.Precisely control the chain length of polyisocyanide arms,supramolecular polymer frameworks with pore sizes ranging from 5.06 nm to 9.72 nm were achieved.These frameworks,with tunable and large pore apertures,demonstrated exceptional capabilities in encapsulating enzymes of different sizes,such as lipase(TL),horseradish peroxidase(HRP),and glucose oxidase(GOx).The encapsulated enzymes exhibited significantly enhanced catalytic activity and durability.Moreover,the frameworks' tunable and large pore apertures facilitated the co-encapsulation of multiple enzymes,enabling efficient dual-enzyme cascade reactions.
基金financially supported by the National Natural Science Foundation of China(No.52273104)。
文摘Mini light-emitting diodes(Mini-LEDs)show great application potential in high-end displays owing to their superior pixel density,brightness,responsiveness,and efficiency.However,current packaging materials for Mini-LEDs are predominantly thermally cured,which is energy-and time-consuming and can adversely affect electronic components.In this study,a novel UV-curable silicone resin containing phenyl,disulfide,and acryloyl groups(SPASR)is developed from commercially available siloxanes.The resin exhibits a refractive index(n_(d))higher than 1.5,and it can be cured within 30 s under UV irradiation.After curing,it exhibits an optical transparency exceeding 92%,a lap adhesion strength of up to1.84 MPa,and good thermostability(T_(5%)>265℃).Notably,the volume shrinkage is less than 4.83%,attributed to the release of photopolymerization stress via UV-induced disulfide metathesis during UV curing.Mini-LEDs encapsulated with this resin show luminescence properties comparable to those of conventional thermally-cured sealants,and show excellent sealability wihtout visible penetration after being immersed in red ink for 12 h.Consequently,these excellent properties make the SPASR resin an ideal candidate for microelectronic encapsulation,offering a more reliable and efficient solution for the electronics industry.
基金supported by the National Natural Science Foundation of China(No.62404041)the Natural Science Foundation of Jiangsu Province of China(No.BK20230830).
文摘Owing to the outstanding optoelectronic properties of perovskite materials,perovskite solar cells(PSCs)have been widely studied by academic organizations and industry corporations,with great potential to become the next-generation commercial solar cells.However,critical challenges remain in preserving high efficiency practical large-scale commercialized PSCs:a)the long-term stability of the cell materials and devices,b)lead leakage,and c)methods to scale the cells for larger area applications.This paper summarizes the prior-art strategies to address the above challenges,including the latest studies on the traditional glass-glass and thin-film encapsulation methods to better improve the reliability of PSCs,new technologies for preventing lead leakage,and geometric improvement strategies to enhance the reliability,efficiency,and performance of perovskite solar modules(PSMs).Through these strategies,the device achieved enhanced performance in long-term stability tests.The encapsulation resulted in a high lead leakage inhibition rate of up to 99%,and the PSMs possessed a geometric fill factor of 99.6%and a power conversion efficiency(PCE)of 20.7%.The dramatic improvement of efficiency and reliability of perovskite solar cells and modules indicate the great potential for mass production and commer-cialization of perovskite solar applications in the near future.
基金supported by the National Natural Science Foundation of China(Grant No.51976092)。
文摘High-temperature phase change materials(PCMs)have attracted significant attention in the field of thermal energy storage due to their ability to store and release large amounts of heat within a small temperature fluctuation range.However,their practical application is limited due to problems such as leakage,corrosion,and volume changes at high temperatures.Recent research has shown that macroencapsulation technology holds promise in addressing these issues.This paper focuses on the macroencapsulation technology of high-temperature PCMs,starting with a review of the classification and development history of high-temperature macroencapsulatd PCMs.Four major encapsulation strategies,including electroplating method,solid/liquid filling method,sacrificial material method,and powder compaction into sphere method,are then summarized.The methods for effectively addressing issues such as corrosion,leakage,supercooling,and phase separation in PCMs are analyzed,along with approaches for improving the heat transfer performance,mechanical strength,and thermal cycling stability of macrocapsules.Subsequently,the structure and packing arrangement optimization of macrocapsules in thermal storage systems is discussed in detail.Finally,after comparing the performance of various encapsulation strategies and summarizing existing issues,the current technical challenges,improvement methods,and future development directions are proposed.More attention should be given to utilizing AI technology and reinforcement learning to reveal the multiphysics-coupled heat and mass transfer mechanisms in macrocapsule applications,as well as to optimize material selection and encapsulation parameters,thereby enhancing the overall efficiency of thermal storage systems.
基金support by the National Natural Science Foundation of China(No.52473225)the Guangdong Basic and Applied Basic Research Foundation(No.2023A1515110262)。
文摘Many azo compounds and their intermediates are toxic and have been linked to various health issues,representing a growing global problem.Molecular engineering for selective encapsulation of azobenzene compounds is critical,given their significant use in smart materials and prevalence as environmental micropollutants released from the food and dye industries.However,the current host molecules catering to azobenzene compounds are mainly limited to cyclodextrins,pillar[n]arenes and cucurbit[n]urils,demonstrating a moderate affinity.This report describes that a novel 3,3'-bipyridinium-based cyclophane was capable of encapsulating anionic azobenzene compounds in water with high binding affinity and pH stability through electrostatic attraction-enhanced mechanism,surpassing the extensively reported supramolecular systems.1D&2D NMR experiments,UV-vis spectrum,X-ray crystallography and computational modeling were carried out to understand the host-vip complexation.It's worth noting that the tetracationic cyclophane exhibited good selective and anti-interference encapsulation properties in binary,ternary and seawater systems.Furthermore,upon UV/white light irradiation,the reversible conversion between(E)-4,4'-azobisbenzoate and(Z)-4,4'-azobisbenzoate triggers the dissociation/recomplexation of the host-vip complex within 3 min.This reversible photo-switchable(E)-disodium 4,4'-azobisbenzoateBPy-Box^(4+)supramolecular system holds promise for designing novel materials for extraction/release of azo compounds and other small smart materials.
文摘Guava(Psidium guajava L.),a plant belonging to the Myrtaceae family,holds significant medicinal and nutritional values.Leaves of the plant are described to be elliptical with a dark green color and are utilized in the treatment of gastrointestinal and respiratory issues along with increasing the platelet count in patients suffering from dengue.In this review paper,the nutritional composition and bioactive compounds of guava leaves,including proteins,vitamins,minerals,and polysaccharides,have been reviewed.The methods of extraction of bioactive compounds from guava leaves and their bioactivities,including antioxidant,anti-diabetic,and anti-cancer potential,have been explored.Further,encapsulation techniques for improving the transport of bioactive compounds and living cells into foods have been studied.The application of guava leaves in different food systems such as herbal tea,pork sausage,chocolates,jelly,meals for chickens,functional beverages,and as antibacterial agents in food preservatives has also been investigated.The findings of this review illustrated that the phytochemicals present in guava leaves showed excellent antimicrobial and antioxidant properties.Encapsulation appears to be a promising technique for improving the stability,bioavailability,and controlled release of bioactive chemicals extracted from guava leaves.Different methods for the encapsulation of bioactive compounds employed and applied in distinct food systems showed preservation of phytochemicals,improved bioactivities,and nutritional values.Overall,this review paper demonstrated how guava leaves,an abundant source of bioactive compounds,can be used as a multipurpose component to create functional foods,edible coatings,and active packaging to enhance the nutritional,antioxidant,and antimicrobial properties of various food systems that have qualities that promote health.
基金financially supported by the National Natural Science Foundation of China(Grant No.32101981)the cooperation project between Ya’an city and Sichuan Agricultural University(23ZDF0003)。
文摘Encapsulation and protection of hesperidin(HES)in mung bean protein isolate(MPI)-dextran(DX)conjugatestabilized nanoemulsions(MDC NEs)were investigated in this study.The degree of grafting of MDC prepared by a dry-heating method reached 39.70%±0.01% under the optimal conditions of MPI/DX mass ratio 1:2.3,reaction temperature 58.8℃,and reaction time 4 d.Moreover,the analyses of Fourier infrared spectroscopy,intrinsic fluorescence spectroscopy,surface hydrophobicity,and thermal stability further confirmed the covalent grafting of dextran onto MPI molecules.When encapsulated in MDC NEs at 80 MPa for three times by highpressure homogenization,the encapsulation efficiency and loading capacity of HES were 63.62%±0.01%and 0.40±0.00 g/g,respectively.The encapsulated HES exhibited higher antioxidant activity and stronger light and storage stability than the free HES.Additionally,the incorporation of HES inhibited the formation of lipid peroxides in the nanoemulsions.The findings suggest that glycosylation combined with high-pressure homogenization is an effective strategy for enhancing the stability of MPI-based emulsions and improving their encapsulation of HES.This study provides a promising approach for the development of innovative food and beverage products based on MPI emulsions or new materials for encapsulating fat-soluble bioactive compounds.
基金supported by the National Natural Science Foundation of China(82172114)the"Challenge and Response"project for key and common technology research of Hefei(GJ2022SH08).
文摘Cryopreservation is a fundamental technology in biomedical research,regenerative medicine,and tissue engineering,enabling the long-term storage of cells,tissues,and organs.However,its effectiveness is limited by challenges such as intracellular ice formation,cryoprotectant toxicity,and reduced post-thaw viability.This review explores the crucial role of encapsulation in enhancing cryopreservation efficiency,with a focus on recent advances in materials science,bioengineering,and cryobiology.Emerging technologies,such as nanotechnology and stimuli-responsive polymers,are transforming encapsulation strategies.Innovations such as microfluidic systems offer precise control over cooling rates and cryoprotectant distribution,thereby mitigating conventional limitations.The review also addresses current obstacles related to scaling up encapsulation processes and ensuring the long-term biocompatibility and stability of preserved specimens.By synthesizing recent findings,this work provides a comprehensive resource for researchers and clinicians seeking to enhance biopreservation techniques and their applications in contemporary medicine and biotechnology.Finally,the review identifies critical knowledge gaps that must be addressed to improve the efficacy of cryopreservation strategies and advance their clinical translation.
基金financial support from projects of the National Natural Science Foundation of China(Nos.22104159,22174164)Guangdong Basic and Applied Basic Research Foundation(Nos.2023A1515011632,2024B1515020070)。
文摘Hydrogen-bonded framework(HOF) offers an attractive platform to encapsulate enzymes and stabilize their conformation,due to the advantages of mild synthesis conditions,tailorable pore structure,and backbone biocompatibility.However,the efficiency of this HOF approach relies on the interfacial interactions between enzyme vip and the ligand precursors,limiting its adaptability to enzymes with varying surface chemistry property.In this study,we report a site-specific surface modification strategy to positively tailor the enzyme surface charge,facilitating the biomimetic encapsulation of enzymes within HOF in situ.Both experimental results and computational simulation reveal that site-specific amination of enzyme surface's acidic residues contributes to the interfacial accumulation of carboxylic ligand precursors in aqueous solutions via synergistic electrostatic and hydrogen bonding interactions.This substantially facilitates the in situ growth of porous HOF surrounding the aminated enzyme biotemplates,with up to 100% enzyme loading efficiency.The resultant hydrogen-bonded biohybrid framework(HBF) retains high biocatalytic functions while exhibiting exceptional stability under harsh conditions.By leveraging the marked catalytic activity of GOx-NH_(2)@HBF-1 and a H_(2)O_(2)-sensitive QD,a highly sensitive glucose fluorescence sensor is fabricated with a wide linear range(5-2000 μmol/L) and a low quantification limit of 5 μmol/L.This work presents a simple yet effective enzyme surface engineering approach for integrating enzyme into HOF,opening new avenues for the construction of multifunctional HOF biocomposites.
基金the financial support from the National Natural Science Foundation of China(52475610,52105593)the Zhejiang Provincial Natural Science Foundation of China(LDQ24E050001)+1 种基金the"Pioneer"and"Leading Goose"R&D Program of Zhejiang(2023C03007,2024C01173)the Fundamental Research Funds for the Central Universities(226-2024-00085)。
文摘Extreme environments challenge the structural health monitoring of advanced equipment.In-situ dynamic tracking temperature is of particular value due to its enormous impact on material properties.However,the realization of such integrated temperature sensors typically requires complicated layer-by-layer molding and sintering processes including additional thermal barrier coatings.Herein,we report a laser-induced in-situ conductive passivation strategy for the fabrication of a thin-film based wide-range temperature sensor.The instantaneous thermal effect of laser irradiation creates crystalline conductive traces in response to temperature variations.Synchronously,it also allows the formation of an amorphous antioxidative layer without necessitating extra protective coatings.Such configuration enables precise real-time sensing across-50℃to 950℃following the Steinhart-Hart equation.It also exhibits durable performance with only 1.2%drift over 20 hours during long-term high-temperature,instant thermal shock,frequent wearing,and severe vibration.This in-situ,facile laser manufacturing strategy holds great promise in structural health monitoring and fault diagnosis for advanced equipment working in extreme environments.
基金supported by the National Natural Science Foundation of China(22238002 and 22208047)the China Postdoctoral Science Foundation(2024T170086 and 2022M720639)+1 种基金the Research and Innovation Team Project of Dalian University of Technology(DUT2022TB10)the Fundamental Research Funds for the Central Universities(DUT22LAB610)。
文摘Despite the ongoing increase in the efficiency of perovskite solar cells(PSCs),residual lead iodide(PbI2and moisture sensitivity issues continue to constrain their further commercialization.Herein,we propose a thermally mediated in situ repair and encapsulation strategy to construct high-performance PSCs by incorporating piperazine thioctic acid salt(TAPPZ)as a dopant into the perovskite precursor Thermally dissociated piperazine(PPZ)from TAPPZ integrates microcrystals to form larger grain(>2000 nm),while the carboxylic acid in thioctic acid(TA)and the amine salt in TAPPZ synergistically passivate and transform PbI_(2),significantly reducing its residual amount.Additionally,TAPPZ undergoe thermal self-crosslinking during perovskite annealing,enabling melt-polymerization to form in situ encapsulation for enhanced water resistance.The TAPPZ-incorporated device achieves a remarkable efficiency of 25.65% and exhibits excellent operational stability,retaining over 90% of its initial efficiency after 2000 h under ambient conditions(20-30℃,20%-30% relative humidity).This study provide new insights into the construction of high-performance perovskite solar cells by designing and synthe sizing multifunctional single molecules for in situ repair and encapsulation of perovskites.
基金financially supported by the National Natural Science Foundation of China (22350410386,W2412116,22375200,U22A202175,21961142006)。
文摘Exploring cost-effective and efficient catalysts for oxygen reduction reaction(ORR)poses a significant challenge,espe-cially in the pursuit of alternatives to precious metals like platinum.Significant advancements have driven electrochem-ists to develop efficient ORR catalysts using abundant materials,particularly iron(Fe)-based,known for their exceptional performance in ORR.While the crucial function of Fe in boosting ORR catalytic activity is recognized,the connection between material attributes and catalytic performance remains enigmatic.Understanding the dynamic processes involved in oxygen electrocatalysis is paramount for designing precious-metals-free ORR electrocatalysts.Mössbauer spectroscopy stands out as a powerful technique for deciphering the structural characteristics of Fe species in catalysis,facilitating the identification of active sites and the clarification of catalytic mechanisms.By showcasing noteworthy case studies within this review,we demonstrate the application of in-situ/operando 57Fe Mössbauer spectroscopy across diverse Fe-involved materials in ORR catalysis.This sheds light on various aspects of ORR catalysis,such as identifying active sites,assessing stability,and understanding the reaction mechanism.Our inquiry drives towards the opportunities and hurdles associ-ated with Mössbauer spectroscopy,unveiling potential breakthroughs and avenues for enhancement within this pivotal research realm.
基金supported by the Fundamental Research Funds for the Central Publicinterest Scientific Institution(No.2024YSKY-44)the National Key R&D Program of China(No.2023YFC3708003).
文摘To address the problems with catalytic degradation,such as poisoning and inactivation,a simple and efficient gas purging regeneration technique was developed for iron-based catalyst in-situ regeneration.Specifically,the effects of carrier gas types,regeneration temperatures,and granular activated carbon(GAC)addition on iron-based catalyst regeneration were investigated.The Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regenerated at 550°C with additional GAC and 15%water vapor exhibited the optimal degradation efficiency towards polychlorinated biphenyls(PCBs),with an increase from 41.2%to 93.5%,compared with non-regenerated Fe_(3)O_(4)/𝛾-Al_(2)O_(3).In addition,the 60-hour stability test revealed a well-recovered catalytic activity.During the Fe_(3)O_(4)/𝛾-Al_(2)O_(3) regeneration,the coke on the catalyst surface was oxidized and removed in the form of CO_(2),and meanwhile the oxidized Fe(III)was reduced into Fe(II)in the catalyst.This study provides a safe and efficient iron-based catalyst regeneration technology for PCB off-gas degradation and reveals the catalytic activity recovery mechanism during catalyst regeneration.
基金supported by the National Science and Technology Major Project of the Ministry of Science and Technology of China(No.2024ZD1700201)the National Natural Science Foundation of China(Nos.U2034206,51974014 and 51574014)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2024A1515011631)the National Key Research and Development Project of China(No.2022YFC3004601)。
文摘In-situ stress is a key parameter for underground mine design and rock stability analysis.The borehole overcoring technique is widely used for in-situ stress measurement,but the rheological recovery deformation of rocks after stress relief introduces errors.To improve accuracy,this study proposes an in-situ stress solution theory that incorporates time-dependent stress relief effects.Triaxial stepwise loadingunloading rheological tests on granite and siltstone established quantitative relationships between instantaneous elastic recovery and viscoelastic recovery under different stress levels,confirming their impact on measurement accuracy.By integrating a dual-class elastic deformation recovery model,an improved in-situ stress solution theory was derived.Additionally,accounting for the nonlinear characteristics of rock masses,a determination method for time-dependent nonlinear mechanical parameters was proposed.Based on the CSIRO hollow inclusion strain cell,time-dependent strain correction equations and long-term confining pressure calibration equations were formulated.Finally,the proposed theory was successfully applied at one iron mine(736 m depth)in Xinjiang,China,and one coal mine(510 m depth)in Ningxia,China.Compared to classical theory,the calculated mean stress values showed accuracy improvements of 6.0%and 9.4%,respectively,validating the applicability and reliability of the proposed theory.
基金supported by the National Key Research and Development Program of China(No.2023YFC3905400)the National Natural Science Foundation of China(No.22176010).
文摘The Ru-based catalysts with different preparation methods or supports were achieved and applied in efficientlycatalytic elimination of 1,2-dichloroethane(1,2-DCE).It wasfirstly found that the redox ability and chlorine re-sistance of the catalyst could be improved by regulating the interaction between Ru and supports.Compared withother supports and conventionally impregnated methods,the Ru@ZSM-5 catalyst synthesized by the in-situ en-capsulation strategy exhibited an excellent low-temperature catalytic performance(T50=262°C,T90=327℃),superior stability in long-term test as well as ideal target products.The acidity,specific surface area,and in-teraction with precious metals of the supports have significant influences on the catalytic activity,and the Ruclusters inside the pore structures are more closely bound to the framework Al species,which promotes theoxidation behavior.The encapsulation strategy also significantly improves the Ru dispersion thereby facilitatesoxygen activation as well as Cl-containing volatile organic compounds(CVOCs)deep oxidation,and preserveslarge amounts of Brønsted acid sites to optimize the hydrolysis mechanism for purification of CVOCs.Subse-quently,the synergistic effect between metal redox and acidity is greatly optimized,thus extremely promotingthe catalytic efficiency of 1,2-DCE oxidation.
基金supported by the NationalKey Research and Development Program of China(2023YFA1507701)National Natural Science Foundation of China(U22B6011,22288102)“Announcement and Challenge”Science and Technology Project of Xinjiang Uygur Autonomous Region(XJKJTJBGS-2023).
文摘Rare earth(RE)Y-type zeolite was synthesized in situ by acidic co-hydrolysis route and hydrothermal method.The key process parameters were optimized based on the RE utilization rate.The effect of inducing a rotating packed bed(RPB)in premixing and crystallization on crystallinity and RE utilization rate was further investigated.The results indicate that lanthanide(La)cations are successfully introduced into the sodalite cage of Y-type zeolite.The optimized conditions are that the molar ratio of Si/La is 150,premixing for 5 h,crystallization at 90℃ for 18 h,and calcination at 550℃ for 3.5 h.At this stage,the RE utilization rate reaches 74.5%.Compared with the conventional stirred tank reactor(STR),RPB can effectively shorten the premixing time and crystallization time by 4.3 h and 6 h,improve the crystallinity by 23%and RE utilization rate by 7.5%.The RE utilization rate is more than 80%by RPB,surpassing the effectiveness of using the one-exchange one-calcination process in the traditional liquid ion exchange process.It is expected to provide a reference for the in-situ efficient and green synthesis of RE zeolite.
文摘The main purpose of using geothermal energy piles(GEPs)is to enable the exploitation of geothermal energy for meeting the heating/cooling demands of buildings efficiently.However,the installation process of conventional GEPs is inconvenient compared with that of traditional foundation piles.The pre-bored grouted planted geothermal energy pile(PGP GEP)is an innovative technology to simplify the installation process.Most investigations of in-situ experiments for conventional GEPs have focused on summer conditions.An in-situ test for a PGP GEP was conducted to analyze the temperature changes and thermo-mechanical characteristics under winter conditions.The results show that the average temperature of the pile decreased by 5.1℃,and the pile exhibited a general trend of high temperatures at both ends and low temperatures in the middle.In mechanics,strong pile end restraints resulted in smaller observed axial strain and higher axial thermal-induced force in the pile ends than at the middle of the pile.
基金supported by National Natural Science Foundation of China(No.52101138)Natural Science Foundation of Hubei Province(No.2023AFB798)+1 种基金Shenzhen Science and Technology Program(No.JCYJ20220530160813032)State Key Laboratory of Solidification Processing in NWPU(No.SKLSP202309).
文摘In the present work,the porous Ti particle reinforced Mg-based bulk metallic glass matrix composites(BMGCs)have been successfully fabricated via a novel in-situ dealloying method in metallic melt.A dual reinforcing structure,including large-scale between porous particles and fine-scale inside one particle,was induced to further overcome the strength-plasticity tradeoff.The microstructure and mechanical properties of such dual-scale structure-reinforced BMGCs with various volume fractions and diameters of porous Ti particles were investigated in detail.It is found that with more and finer porous Ti particles,the BMGC showed both high fracture strength(1131.9±39.1 MPa)and good plastic deformability(1.48±0.38%).The characteristic of the reinforcing structure(0.48μm)inside the porous particles was close to the plastic processing zone size of the matrix(0.1~0.2μm),which generated a locally ideal reinforcing structure.Such dual-scale reinforcing structures with more interfaces can effectively promote the multiplication of shear bands at the interfaces.Due to the size effect,the refined submicron matrix between the Ti ligaments inside the porous particles should exhibit homogeneous shearing events.Such delocalization behavior from the dual-scale reinforcing structures should help to enhance the role of the interactions between shear bands,thus improving the yield strength of the composites.Based on the in-situ dealloying method,the dual-scale structure design provides a novel approach to fabricate various BMGCs with both high strength and good plasticity.
基金Project(52373065)supported by the National Natural Science Foundation of ChinaProject(2220004002898)supported by the Zhuhai Industry University Research Cooperation and Basic and Applied Research Projects,China。
文摘Waterborne acrylic coatings are widely utilized due to their cost-effectiveness,high transparency,strong resistance to weather and chemicals,impressive mechanical properties,and excellent adhesion to various substrates.In these coatings,a reactive emulsifier containing phosphate groups can be integrated into the molecular chain during polymerization,which enhances the coating's compactness and corrosion resistance.This work focuses on the synthesis of styrene-butyl acrylate(St-BA)latex and methyl methacrylate-butyl acrylate(MMA-BA)latex using the reactive phosphate emulsifier ANPEO_(10)-P_(1) through seed emulsion polymerization,achieving a conversion rate of approximately 99%and a solid content close to 50%.The resulting coatings from St-BA and MMA-BA latexes demonstrated long-term corrosion protection for carbon steel and aluminum alloy due to in-situ phosphatization,effectively preventing flash rust.Notably,the MMA-BA coating exhibited remarkable durability,enduring immersion for up to 1224 h(51 d)on Q 235 carbon steel before reaching the failure threshold(|Z|0.01 Hz£106Ω·cm^(2))on Q 235 carbon steel.On 5052 aluminum alloy,the St-BA coating maintained|Z|0.01 Hz>10^(8)Ω·cm^(2) for 480 h(20 d).Furthermore,the corrosion resistance of St-BA and MMA BA coatings on Q 235 steel sheet and 5052 aluminum alloy surpassed that of commercially available MMA-BA and St BA coatings after immersion in a 3.5 wt%NaCl aqueous solution.This work also delves into the anticorrosion mechanism of MMA-BA and St-BA coatings.
