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Therapeutic effects of low-intensity transcranial focused ultrasound stimulation on ischemic stroke in rats:An in vivo evaluation using electrical impedance tomography
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作者 Jiecheng Guo Sixuan He +4 位作者 Li Yan Lei Wang Xuetao Shi Huijing Hu Le Li 《Neural Regeneration Research》 2026年第3期1183-1190,共8页
Although previous studies have demonstrated that transcranial focused ultrasound stimulation protects the ischemic brain,clear criteria for the stimulation time window and intensity are lacking.Electrical impedance to... Although previous studies have demonstrated that transcranial focused ultrasound stimulation protects the ischemic brain,clear criteria for the stimulation time window and intensity are lacking.Electrical impedance tomography enables real-time monitoring of changes in cerebral blood perfusion within the ischemic brain,but investigating the feasibility of using this method to assess post-stroke rehabilitation in vivo remains critical.In this study,ischemic stroke was induced in rats through middle cerebral artery occlusion surgery.Transcranial focused ultrasound stimulation was used to treat the rat model of ischemia,and electrical impedance tomography was used to measure impedance during both the acute stage of ischemia and the rehabilitation stage following the stimulation.Electrical impedance tomography results indicated that cerebral impedance increased after the onset of ischemia and decreased following transcranial focused ultrasound stimulation.Furthermore,the stimulation promoted motor function recovery,reduced cerebral infarction volume in the rat model of ischemic stroke,and induced the expression of brain-derived neurotrophic factor in the ischemic brain.Our results also revealed a significant correlation between the impedance of the ischemic brain post-intervention and improvements in behavioral scores and infarct volume.This study shows that daily administration of transcranial focused ultrasound stimulation for 20 minutes to the ischemic hemisphere 24 hours after cerebral ischemia enhanced motor recovery in a rat model of ischemia.Additionally,our findings indicate that electrical impedance tomography can serve as a valuable tool for quantitatively evaluating rehabilitation after ischemic stroke in vivo.These findings suggest the feasibility of using impedance data collected via electrical impedance tomography to clinically assess the effects of rehabilitatory interventions for patients with ischemic stroke. 展开更多
关键词 animal model brain stimulation electrical impedance tomography evaluation impedance noninvasive treatment real-time monitoring REHABILITATION STROKE transcranial focused ultrasound stimulation
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Intraoperative Impedance Gradient as a Physiological Indicator of Electrode-Neural Interface in Pediatric Cochlear Implantation
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作者 Richi Sinha Maruti Nandan +1 位作者 Amit Kumar Sharma Rakesh Kumar Singh 《Journal of Otology》 2026年第1期16-21,共6页
Objective:To investigate the spatial gradient of intraoperative impedance across the cochlear electrode array in pediatric cochlear implant recipients and assess its potential as a physiological indicator for the elec... Objective:To investigate the spatial gradient of intraoperative impedance across the cochlear electrode array in pediatric cochlear implant recipients and assess its potential as a physiological indicator for the electrode-neural interface.Methods:A prospective observational study involving 56 pediatric patients underwent cochlear implantation with Cochlear Nucleus devices.Intraoperative polarized impedance and electrically evoked compound action potential(ECAP)threshold were recorded across all 1232 electrodes using AutoNRT software.Eight electrodes with open-or short-circuit were excluded,leaving 1,224 for analysis.Impedance values were categorized by cochlear region(basal,middle,apical),and electrodes with elevated impedance(10-20 kΩ)were analyzed for regional distribution and clinical relevance.Data were analyzed for spatial patterns and correlation with the ECAP threshold profiles.Results:A consistent basal-to-apical increase in impedance was observed(7.7±1.9,9.2±1.4,10.8±1.5 kΩ;p<0.001).Impedance and ECAP threshold were weakly correlated(ρ=-0.20,p<0.001;β=-1.26,p<0.001),with a positive association in the apical region(ρ=0.12,p=0.048).Electrodes with higher impedance(1020 kΩ)were less likely to show elevated or absent TNRT(OR=0.175,p=0.02).The impedance gradient persisted across age groups and was significantly correlated with ECAP threshold patterns.Conclusion:Intraoperative impedance monitoring reveals a strong and physiologically consistent gradient,with higher values in apical electrodes.This gradient reflects anatomical and tissue interface variations,which may offer a valuable physiological indicator for intraoperative electrode positioning and neural interface integrity. 展开更多
关键词 Cochlear Implant IMPEDANCE ECAP Neural Response Telemetry Electrode Array Physiological Indicator
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A programmable frequency scan algorithm based on harmonic balance
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作者 Lu Miao Wenyan Jia +4 位作者 Jinchang Chen Yang Yi Shun Li Qirong Jiang Chongbin Zhao 《iEnergy》 2026年第1期2-6,共5页
This paper presents a programmable frequency scan algorithm based on harmonic balance.The core idea involves treating systems under perturbation as nonlinear time-periodic(NTP)systems.Steady-state harmonics are first ... This paper presents a programmable frequency scan algorithm based on harmonic balance.The core idea involves treating systems under perturbation as nonlinear time-periodic(NTP)systems.Steady-state harmonics are first solved via Newton-Raphson iteration through a set of nonlinear equations,and then input-output variables are selected to estimate the linear transfer function of the original NTP system without perturbations.The applications and insights of the proposed algorithm are discussed,particularly in guiding existing frequency scan algorithms,which are restricted by time-domain signal generation or measurement.This improvement is achieved through linear stability analysis of NTP systems with perturbations. 展开更多
关键词 Frequency scan Nonlinear time-periodic system Impedance model Harmonic balance Stability analysis
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Synthesis of Dynamic Virtual Impedance for Grid-forming Converters to Improve Self-stability and Stabilizing Ability
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作者 Hangyu Chen Verena Häberle +3 位作者 Ying Yang Kehao Zhuang Huanhai Xin Linbin Huang 《CSEE Journal of Power and Energy Systems》 2026年第1期44-55,共12页
In the future power-electronics-dominated power systems,grid-forming(GFM)converters have been regarded as important devices to actively establish frequency and voltage,so as to provide essential grid support.However,d... In the future power-electronics-dominated power systems,grid-forming(GFM)converters have been regarded as important devices to actively establish frequency and voltage,so as to provide essential grid support.However,due to their voltage source behavior and emulated swing dynamics,GFM converters may encounter low-frequency oscillations(LFOs)when connected to strong grids,which belongs to the self-stability problem of GFM converters.Moreover,GFM converters will also interact with grid-following(GFL)converters and thus impact the mid-frequency oscillations(MFOs)induced by phase-locked loops(PLLs).It has been preliminarily shown in the literature that GFM converters can help stabilize the PLL-induced MFOs,but currently,there is a lack of systematic design methods to coordinate the self-stability and stabilizing ability of GFM converters.This paper addresses this gap by revisiting the impedance model of a typical GFM converter and briefly analyze the oscillations caused by converters.Based on our analysis,we propose a frequency-partitioned synthesis design framework to enable dynamic virtual impedance(DVI)in GFM converters,aiming to enhance their self-stability and stabilizing ability simultaneously.Particularly,a self-stabilizing module is designed to ensure robust device-level damping,with control parameters auto-tuned using H∞methods.In parallel,a stabilizing module is introduced to stabilize GFL converters and enhance the system-level stability,which utilizes a perceive-and-optimize tuning strategy.Simulation results validate the effectiveness of the proposed synthesis DVI framework. 展开更多
关键词 Control synthesis dynamic virtual impedance grid-forming converters self-stability stabilizing ability
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Impedance of RF shield on ceramic chamber in the rapid cycling synchrotron of China Spallation Neutron Source
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作者 Liang‑Sheng Huang Bin Wu +6 位作者 Ming‑Yang Huang Ren‑Hong Liu Biao Tan Peng‑Cheng Wang Yong‑Chuan Xiao Li‑Rui Zeng Xiao Li 《Nuclear Science and Techniques》 2026年第1期130-140,共11页
In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of co... In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors. 展开更多
关键词 Beam coupling impedance Ceramic chamber RF shield RESONANCE High dynamic magnetic environment
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Multimodal deep learning with time-frequency health features for battery SOH and RUL prediction
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作者 Rongzheng Wang Le Chen +8 位作者 Jiahao Xu Fei Yuan Junjie Han Zongrun Li Zekun Li Yiwei Zhang Peiyan Li Lipeng Zhang Zhouguang Lu 《Journal of Energy Chemistry》 2026年第2期303-314,I0009,共13页
This study proposes a multimodal deep learning framework for joint prediction of the state of health(SOH)and remaining useful life(RUL)of lithium-ion batteries.Twelve representative impedance features-covering charge-... This study proposes a multimodal deep learning framework for joint prediction of the state of health(SOH)and remaining useful life(RUL)of lithium-ion batteries.Twelve representative impedance features-covering charge-transfer resistance,solid electrolyte interface(SEI)layer impedance,and ion diffusion-are extracted from electrochemical impedance spectroscopy(EIS)and combined with short voltage/current segments to form a compact,interpretable feature set.A residual multi-layer perceptron(ResMLP)is employed for SOH regression,and a temporal convolutional network with attention(TCNAttention)is used for RUL estimation.Lifetime experiments on two battery types with different chemistries and form factors,evaluated through three rounds of paired cross-validation,validate the approach.Results show that the proposed features significantly reduce dimensionality and computational cost while substantially lowering SOH error,achieving an average normalized root mean square error of 2.3%.The RUL prediction reaches an average error of 14.8%.Overall,the framework balances interpretability,robustness,and feasibility,providing a practical solution for battery management systems(BMS)monitoring and life prediction. 展开更多
关键词 State of health Remaining useful life Feature selection Electrochemical impedance spectroscopy Machine learning
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Harnessing Carbon-Containing Materials for Next-Generation High-Temperature Electromagnetic Wave Absorbers
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作者 Yang Li Yuchang Qing +7 位作者 Wei Li Chao Ma Zhongyi Bai Gang Shao Hailong Wang Ming Huang Xianhu Liu Bingbing Fan 《Carbon Energy》 2026年第2期1-33,共33页
The demand for high-temperature electromagnetic wave absorption(EWA)materials has significantly increased alongside advancements in aerospace and communication technologies.Although traditional magnetic absorbers,such... The demand for high-temperature electromagnetic wave absorption(EWA)materials has significantly increased alongside advancements in aerospace and communication technologies.Although traditional magnetic absorbers,such as ferrites and metal powders,show excellent magnetic loss performance at room temperature,they have significant limitations in harsh environments due to their high density,low Curie temperature,and susceptibility to oxidation.In contrast,carbon-containing materials have emerged as promising candidates for high-temperature EWA applications,owing to their high melting point,low density,tunable dielectric loss mechanisms,and superior thermal stability.Unlike magnetic materials,carbon-based systems primarily dissipate electromagnetic energy through conductance loss,dipole polarization,and interfacial polarization,thereby avoiding performance degradation at elevated temperatures.However,several critical challenges remain,including insufficient oxidation resistance,mechanical reliability issues,and the need for stable impedance matching.To address these limitations,recent strategies such as defect engineering,heterointerface construction,and metamaterial design have been proposed to enhance thermal stability and functional performance.This review provides a systematic summary of recent advances in carbon-containing absorbers,with a focus on dielectric loss mechanisms,optimization strategies,and multiscale structural design principles.By elucidating the structure–property relationships of carbon materials,carbide ceramics,and novel carbon hybrids,this study aims to offer theoretical and technical guidance for the development of advanced high-temperature electromagnetic wave absorbers,thereby promoting their practical applications in aerospace and telecommunications. 展开更多
关键词 carbon‐containing materials dielectric loss electromagnetic wave absorption impedance matching thermal stability
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Operando characterization of the internal multi-fields of industrial-scale fuel cells and mechanistic insight
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作者 Weichen Ji Xin Cai +3 位作者 Yunyang Ma Xin Liu Andreas Friedrich Rui Lin 《Journal of Energy Chemistry》 2026年第3期667-675,共9页
Despite significant progress in fuel cell technology,its large-scale industrial application is still challenged by the frequently encountered performance failure during long-term operation.Clarifying the failure mecha... Despite significant progress in fuel cell technology,its large-scale industrial application is still challenged by the frequently encountered performance failure during long-term operation.Clarifying the failure mechanism is the key to extending the lifecycle and enhancing stability.Herein,we have developed a time and space resolved multi-field characterization,including electrochemical impedance spectroscopy,to unveil its underlying mechanism.With this operando and non-destructive characterization,the dynamic evolution of the internal mass transport,heat,and electricity field distribution is fully depicted within an industrial-scale fuel cell in operation.Thus,it is revealed that hydrogen starvation occurs in the outlet region due to the excessive hydrogen consumption during the loading-down process.This can induce local low current density and carbon corrosion,which may subsequently cause severe damage to the structure of the catalyst layer and membrane,ultimately leading to performance failure.With this understanding,we further identify a descriptor for early diagnosis to prevent any potential degradation.The methodology is of significance,which can bring fuel cell technology a step further towards industrial applications. 展开更多
关键词 Operando characterization Internal multi-fields Industrial-scale fuel cell Local Electrochemical impedance spectroscopy Stability mechanism
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Spatio-temporal resolutions of charge transfer reactions in the Li-ion battery studied by electrochemical impedance spectroscopy
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作者 Zijie Wu Qiu-An Huang +2 位作者 Yuxuan Bai Jiujun Zhang Kai Wu 《Journal of Energy Chemistry》 2026年第1期1026-1045,I0022,共21页
The pseudo-two-dimensional(P2D)model plays an important role in exploring physicochemical mechanisms,predicting the state of health,and improving the fast charge capability for Li-ion batteries(LIBs).However,the fast ... The pseudo-two-dimensional(P2D)model plays an important role in exploring physicochemical mechanisms,predicting the state of health,and improving the fast charge capability for Li-ion batteries(LIBs).However,the fast charge leads to the lithium concentration gradient in the solid and electrolyte phases and the non-uniform electrochemical reaction at the solid/electrolyte interface.In order to decouple charge transfer reactions in LIBs under dynamic conditions,understanding the spatio-temporal resolution of the P2D model is urgently required.Till now,the study of this aspect is still insufficient.This work studies the spatio-temporal resolution for dynamic/static electrochemical impedance spectroscopy(DEIS/SEIS)on multiple scales.In detail,DEIS and SEIS with spatio-temporal resolutions are used to decouple charge transfer reactions in LIBs based on the numerical solution of the P2D model in the frequency domain.The calculated results indicate that decoupling solid diffusion requires a high spatial resolution along the r-direction in particles,decoupling electrolyte diffusion and interfacial transfer reaction requires a high spatial resolution along the x-direction,and decoupling charge transfer reactions in LIBs at an extremely low state of charge(SOC)requires an extremely high temporal resolution along the t-direction.Finally,the optimal range of spatio-temporal resolutions for DEIS/SEIS is derived,and the method to decouple charge transfer reactions with spatio-temporal resolutions is developed. 展开更多
关键词 Spatio-temporal resolution Discretization grid Electrochemical impedance spectroscopy Pseudo-two-dimensional model Li-ion battery
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Impedance Modeling and Stability Analysis of LCC-HVDC Transmission System
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作者 Bo Zhang Xiong Du +3 位作者 Shangning Tan Junliang Liu Haijiao Wang Yiding Jin 《CSEE Journal of Power and Energy Systems》 2026年第1期366-376,共11页
Interaction between the converter and the grid may lead to harmonic oscillations.The impedance-based method is an effective way to deal with the stability issue.In this study,the impedance-based method is used to inve... Interaction between the converter and the grid may lead to harmonic oscillations.The impedance-based method is an effective way to deal with the stability issue.In this study,the impedance-based method is used to investigate the small-signal stability of a cascaded 12-pulse line-commutated converter-based high-voltage direct current(LCC-HVDC)transmission system.In the modeling part,the impedance models of the single rectifier and inverter are established respectively with consideration to the effect of frequency coupling,which has improved the accuracy of the models.Based on the models,the AC impedance models of the cascaded LCC-HVDC transmission system are established both on the rectifier and inverter side.In the stability analysis part,the stability of the system is analyzed under different working conditions.The simulation results reveal that the established impedance model can properly represent the stability of this system.The findings of this study can provide a theoretical reference for the stability design and oscillation suppression strategy of LCC-HVDC transmission systems and LCC interconnected systems. 展开更多
关键词 Frequency coupling LCC impedance modeling stability analysis
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Application of electrical impedance tomographyguided PEEP titration in acute respiratory distress syndrome patients with intra-abdominal hypertension
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作者 Hui Wen Maiying Fan +5 位作者 Junliang Xiao Zhiqun Liu Xiaohua Liu Shuzhen Mao Xiaotong Han Fengling Ning 《World Journal of Emergency Medicine》 2026年第1期70-75,共6页
BACKGROUND:Individualized positive end-expiratory pressure(PEEP)titration is a crucial technique in mechanical ventilation therapy for acute respiratory distress syndrome(ARDS)patients with intra-abdominal hypertensio... BACKGROUND:Individualized positive end-expiratory pressure(PEEP)titration is a crucial technique in mechanical ventilation therapy for acute respiratory distress syndrome(ARDS)patients with intra-abdominal hypertension(IAH).This study aimed to evaluate the eff ectiveness of electrical impedance tomography(EIT)-guided PEEP titration in this population.METHODS:This prospective study enrolled 36 ARDS patients,including 22 patients with IAH and 14 without IAH.All the patients underwent EIT-guided PEEP titration at the intersection point between alveolar overdistension and collapse during a decremental PEEP trial.The changes in pulmonary ventilation distribution,respiratory mechanics and hemodynamics during the titration process were observed.RESULTS:After EIT-guided PEEP titration was performed,the PEEP,peak inspiratory pressure and plateau pressure increased significantly(P<0.05).Furthermore,no significant differences were observed in respiratory system compliance,tidal volume,driving pressure,or the 4*DP+RR index between the two groups(P>0.05).The mechanical power increased in the non-IAH(NIAH)group after PEEP titration(P<0.05).Ventilation in gravity-dependent lung regions significantly increased(P<0.05),and the oxygenation index(PaO2/FiO2)improved signifi cantly(P<0.05)in both groups.However,blood pressure,heart rate,respiratory rate,central venous pressure,and lactate levels did not signifi cantly change.In the IAH group,the PaO2/FiO2 ratio improved less than that in the NIAH group did(P<0.05).CONCLUSION:In our study,individualized PEEP titration guided by EIT improved oxygenation in ARDS patients with concomitant IAH without signifi cantly aff ecting hemodynamics.The presence of IAH may limit the improvement of oxygenation during EIT-guided PEEP titration. 展开更多
关键词 Acute respiratory distress syndrome Positive end-expiratory pressure Electrical impedance tomography Intra-abdominal pressure
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Broadband performance of multi-degree-of-freedom septum liners under high-velocity grazing flows
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作者 Yujie WANG Xianghai QIU +5 位作者 Xiaodong JING Lin DU Shuangying JI Yiang LYU Yao XU Xiaofeng SUN 《Chinese Journal of Aeronautics》 2026年第2期151-161,共11页
Developing advanced acoustic treatments,such as the Multi-Degree-of-Freedom(MDOF)septum liner,to realize the broadband noise reduction is critical for silent aeroengines.This study investigates experimentally the MDOF... Developing advanced acoustic treatments,such as the Multi-Degree-of-Freedom(MDOF)septum liner,to realize the broadband noise reduction is critical for silent aeroengines.This study investigates experimentally the MDOF septum liner and its impedance model on the Beihang Grazing Flow Duct(BGFD)setup,over a wide frequency range under grazing flows up to 0.5 Mach number and Sound Pressure Level(SPL)up to 150 dB,typically encountered in aeroengine nacelles.Several specimens varying in the numbers,types,and depths of septa among units are designed,fabricated,and measured.Their impedances and Transmission Losses(TL)are obtained using the mirror-based multimodal straightforward method and the mode decomposition technique,respectively.Generally,the model predictions show good agreement with the educed impedances in all cases,and such liners with a large-porosity facesheet exhibit low acoustic nonlinearities in the presence of high SPL,especially under high-velocity grazing flows.Moreover,a MDOF liner we delicately designed,compared with a conventional broadband three-layer perforated liner as the reference,is close to the resonant state at more frequencies and thus has higher and wider measured TL spectra almost from 1 kHz up to 10 kHz at studied Mach numbers,under the premise of saving 22.7 mm in the thickness.These show that,the MDOF septum liner,if well designed,can achieve an ultra-broadband efficient sound attenuation using more limited spaces in complex aeroacoustic environments. 展开更多
关键词 Broadband performance High-velocity grazing flow Impedance prediction model Low acoustic nonlinearity Multi-degree-of-freedom septum liner
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Obvious corrosion resistance of 2Cr13 martensitic stainless steel subjected to thermo-mechanical laser shock peening and subsequent slight polishing
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作者 Changyu WANG Qianwei ZHANG +7 位作者 Lujie XU Liangliang LI Weiwei DENG Tianyi ZHANG Yang LIU Gang XU Liping LIU Pengfei LI 《Chinese Journal of Aeronautics》 2026年第2期564-581,共18页
Effects of thermo-mechanical Laser Shock Peening without Absorbing Coating(LSPwC)on the dual-phase structural evolution and the potential of LSPwC in the corrosion resistance of2Cr13 martensitic stainless steel were i... Effects of thermo-mechanical Laser Shock Peening without Absorbing Coating(LSPwC)on the dual-phase structural evolution and the potential of LSPwC in the corrosion resistance of2Cr13 martensitic stainless steel were investigated.A Neodymium-doped Yttrium Aluminium Garnet(Nd:YAG)laser with a pulse energy of 7.6 J was used for the LSPwC treatment.Microstructural changes were characterized using X-Ray Diffraction(XRD),Transmission Electron Microscopy(TEM)and X-ray Photoelectron Spectroscopy(XPS).Corrosion behavior was evaluated via Electrochemical Impedance Spectroscopy(EIS)and Potentiodynamic Polarization(PDP)measurements,and the morphology of corrosion pits was observed using Scanning Electron Microscopy(SEM).Results show that the LSPwC treatment led to an obvious reduction in the corrosion resistance owing to the precipitation of numerous Cr_(8)O_(21),surface roughening and tensile residual stress generated by laser ablation.However,LSPwC with subsequent treatment of slight ablation layer removal brought about 13.5 fold increase in charge transfer resistance and about 83.6% reduction of passive current density,and the significant improvement in the corrosion resistance is attributed to the Cr2O3-rich surface passive film resulting from Cr_(15.58)Fe_(7.42)C_(6)decomposition caused by LSPwC-induced mechanical effects. 展开更多
关键词 Electrochemical Impedance Spectroscopy(EIS) Martensitic stainless steel Pitting corrosion Polarization Transmission Electron Microscopy(TEM)
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Tailoringα-MnO_(2) gas diffusion electrodes for enhanced oxygen reduction in aluminum-air batteries
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作者 Alexander Rampf Robert Leiter +2 位作者 Simon Fleischmann Giuseppe Antonio Elia Roswitha Zeis 《Journal of Energy Chemistry》 2026年第3期473-484,共12页
α-MnO_(2) is a promising,inexpensive,and readily producible catalyst for the oxygen reduction reaction(ORR)in alkaline media,but its application is limited by low electronic conductivity.In this study,we enhance the ... α-MnO_(2) is a promising,inexpensive,and readily producible catalyst for the oxygen reduction reaction(ORR)in alkaline media,but its application is limited by low electronic conductivity.In this study,we enhance the performance ofα-MnO_(2) electrodes by systematically varying theα-MnO_(2)-to-Vulcan ratio within the catalyst layer.Electrodes are evaluated in a gas diffusion electrode(GDE)half-cell,where an optimized catalyst layer composition leads to significantly improved ORR performance.By finetuning both theα-MnO_(2)-to-Vulcan ratio and theα-MnO_(2) loading,the electrode outperforms a commercial MnO_(2)-based electrode and approaches the performance of the Pt/C benchmark.The improvement is attributed to the presence of a three-dimensional(3D)Vulcan network electronically connecting catalytically activeα-MnO_(2) sites with the substrate.Additionally,the optimized electrodes are employed in a prototype Al-O_(2) flow cell.Under constant oxygen flow,power densities exceed 250 mW cm^(-2),which is significantly higher than that of conventional Al-air batteries.Electrochemical impedance spectroscopy combined with distribution of relaxation times(DRT)analysis enables the separation of anode and cathode charge transfer impedances without the need for an additional reference electrode.The analysis reveals that the anode contributes more than twice as much impedance as the cathode,highlighting the need for further anode optimization.This work demonstrates a transferable approach for catalyst layer screening under technically relevant conditions in the GDE half-cell.Subsequent measurements in an Al-O_(2) flow cell validate the approach.The methodology is widely applicable to the development of advanced electrodes for a variety of metal-air battery technologies. 展开更多
关键词 Manganese dioxide Oxygen reduction reaction(ORR) Aluminum-air battery Gas diffusion electrode half-cell Electrochemical impedance spectroscopy(EIS) Distribution of relaxation times(DRT)
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Integration of Electrical Properties and Polarization Loss Modulation on Atomic Fe–N‑RGO for Boosting Electromagnetic Wave Absorption 被引量:1
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作者 Kaili Zhang Yuefeng Yan +4 位作者 Zhen Wang Guansheng Ma Dechang Jia Xiaoxiao Huang Yu Zhou 《Nano-Micro Letters》 SCIE EI CAS 2025年第2期517-532,共16页
Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band ... Developing effective strategies to regulate graphene’s conduction loss and polarization has become a key to expanding its application in the electromagnetic wave absorption(EMWA)field.Based on the unique energy band structure of graphene,regulating its bandgap and electrical properties by introducing heteroatoms is considered a feasible solution.Herein,metal-nitrogen doping reduced graphene oxide(M–N-RGO)was prepared by embedding a series of single metal atoms M–N_(4) sites(M=Mn,Fe,Co,Ni,Cu,Zn,Nb,Cd,and Sn)in RGO using an N-coordination atom-assisted strategy.These composites had adjustable conductivity and polarization to optimize dielectric loss and impedance matching for efficient EMWA performance.The results showed that the minimum reflection loss(RL_(min))of Fe–N-RGO reaches−74.05 dB(2.0 mm)and the maximum effective absorption bandwidth(EAB_(max))is 7.05 GHz(1.89 mm)even with a low filler loading of only 1 wt%.Combined with X-ray absorption spectra(XAFS),atomic force microscopy,and density functional theory calculation analysis,the Fe–N_(4) can be used as the polarization center to increase dipole polarization,interface polarization and defect-induced polarization due to d-p orbital hybridization and structural distortion.Moreover,electron migration within the Fe further leads to conduction loss,thereby synergistically promoting energy attenuation.This study demonstrates the effectiveness of metal-nitrogen doping in regulating the graphene′s dielectric properties,which provides an important basis for further investigation of the loss mechanism. 展开更多
关键词 Electromagnetic wave absorption Fe-N-RGO Dipole polarization Conduction loss Impedance matching
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Improve Strategy for Transient Power Angle Stability Control of VSG Combining Frequency Difference Feedback and Virtual Impedance 被引量:2
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作者 Dianlang Wang Qi Yin +3 位作者 Haifeng Wang Jing Chen Hong Miao Yihan Chen 《Energy Engineering》 2025年第2期651-666,共16页
As the penetration rate of distributed energy increases,the transient power angle stability problem of the virtual synchronous generator(VSG)has gradually become prominent.In view of the situation that the grid impeda... As the penetration rate of distributed energy increases,the transient power angle stability problem of the virtual synchronous generator(VSG)has gradually become prominent.In view of the situation that the grid impedance ratio(R/X)is high and affects the transient power angle stability of VSG,this paper proposes a VSG transient power angle stability control strategy based on the combination of frequency difference feedback and virtual impedance.To improve the transient power angle stability of the VSG,a virtual impedance is adopted in the voltage loop to adjust the impedance ratio R/X;and the PI control feedback of the VSG frequency difference is introduced in the reactive powervoltage link of theVSGto enhance the damping effect.Thesecond-orderVSGdynamic nonlinearmodel considering the reactive power-voltage loop is established and the influence of different proportional integral(PI)control parameters on the system balance stability is analyzed.Moreover,the impact of the impedance ratio R/X on the transient power angle stability is presented using the equal area criterion.In the simulations,during the voltage dips with the reduction of R/X from 1.6 to 0.8,Δδ_(1)is reduced from 0.194 rad to 0.072 rad,Δf_(1)is reduced from 0.170 to 0.093 Hz,which shows better transient power angle stability.Simulation results verify that compared with traditional VSG,the proposedmethod can effectively improve the transient power angle stability of the system. 展开更多
关键词 Transient synchronous stability virtual synchronous generator impedance ratio
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Flash-PEO of magnesium:Phosphate precursor driven functionalization 被引量:2
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作者 M.H.Guerra-Mutis J.M.Vega +2 位作者 M.I.Barrena E.Matykina R.Arrabal 《Journal of Magnesium and Alloys》 2025年第2期592-612,共21页
In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings ... In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings on AZ31B magnesium alloy.The main novelty is the successful incorporation of calcium,zinc,manganese and phosphate species into the Flash-PEO coatings via a precursor layer rather than using the electrolyte.The precursor also led to longer lasting and more intense discharges during the PEO process,resulting in increased pore size.Corrosion studies revealed similar short-term performance for all coatings,with impedance modulus at low frequencies above 10^(7)Ωcm^(2),and slightly better performance for the SiPF-based coating.Nonetheless,the enlarged pores in the PEO coatings functionalized with the PCC precursor compromised the effectiveness of self-healing mechanisms by creating diffusion pathways for corrosive species,leading to earlier failure.These phenomena were effectively monitored by recording the open circuit potential during immersion in 0.5 wt.%NaCl solution.In summary,this study demonstrates that conversion coatings are a viable option for the functionalization of PEO coatings on magnesium alloys,as they allow for the incorporation of cationic and other species.However,it is crucial to maintain a small pore size to facilitate effective blockage through self-healing mechanisms. 展开更多
关键词 AZ31B magnesium alloy PHOSPHATES Chemical conversion coating Flash plasma electrolytic oxidation Electrochemical impedance spectroscopy Transmission electron microscopy
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Constructing Ti_(3)C_(2)T_(x)-MXene-based gradient woodpile structure by direct ink writing 3D printing for efficient microwave absorption 被引量:2
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作者 Changtian Zhu Pei Liu +8 位作者 Jin Chen Zixuan Ding Guohui Tang Qingqing Gao Yinxu Ni Kai Xu Zhilei Hao Gaojie Xu Fenghua Liu 《International Journal of Minerals,Metallurgy and Materials》 2025年第3期657-667,共11页
As a novel 2D material,Ti_(3)C_(2)T_(x)-MXene has become a major area of interest in the field of microwave absorption(MA).However,the MA effect of common Ti_(3)C_(2)T_(x)-MXene is not prominent and often requires com... As a novel 2D material,Ti_(3)C_(2)T_(x)-MXene has become a major area of interest in the field of microwave absorption(MA).However,the MA effect of common Ti_(3)C_(2)T_(x)-MXene is not prominent and often requires complex processes or combinations of other ma-terials to achieve enhanced performance.In this context,a kind of gradient woodpile structure using common Ti_(3)C_(2)T_(x)-MXene as MA ma-terial was designed and manufactured through direct ink writing(DIW)3D printing.The minimum reflection loss(RL_(min))of the Ti_(3)C_(2)T_(x)-MXene-based gradient woodpile structures with a thickness of less than 3 mm can reach-70 dB,showing considerable improve-ment compared with that of a completely filled structure.In addition,the effective absorption bandwidth(EAB)reaches 7.73 GHz.This study demonstrates that a Ti_(3)C_(2)T_(x)-MXene material with excellent MA performance and tunable frequency band can be successfully fab-ricated with a macroscopic structural design and through DIW 3D printing without complex material hybridization and modification,of-fering broad application prospects by reducing electromagnetic wave radiation and interference. 展开更多
关键词 Ti_(3)C_(2)T_(x)-MXene electromagnetic wave absorption macro-design impedance matching 3D printing ink
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Sensorless battery expansion estimation using electromechanical coupled models and machine learning 被引量:1
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作者 Xue Cai Caiping Zhang +4 位作者 Jue Chen Zeping Chen Linjing Zhang Dirk Uwe Sauer Weihan Li 《Journal of Energy Chemistry》 2025年第6期142-157,I0004,共17页
Developing sensorless techniques for estimating battery expansion is essential for effective mechanical state monitoring,improving the accuracy of digital twin simulation and abnormality detection.Therefore,this paper... Developing sensorless techniques for estimating battery expansion is essential for effective mechanical state monitoring,improving the accuracy of digital twin simulation and abnormality detection.Therefore,this paper presents a data-driven approach to expansion estimation using electromechanical coupled models with machine learning.The proposed method integrates reduced-order impedance models with data-driven mechanical models,coupling the electrochemical and mechanical states through the state of charge(SOC)and mechanical pressure within a state estimation framework.The coupling relationship was established through experimental insights into pressure-related impedance parameters and the nonlinear mechanical behavior with SOC and pressure.The data-driven model was interpreted by introducing a novel swelling coefficient defined by component stiffnesses to capture the nonlinear mechanical behavior across various mechanical constraints.Sensitivity analysis of the impedance model shows that updating model parameters with pressure can reduce the mean absolute error of simulated voltage by 20 mV and SOC estimation error by 2%.The results demonstrate the model's estimation capabilities,achieving a root mean square error of less than 1 kPa when the maximum expansion force is from 30 kPa to 120 kPa,outperforming calibrated stiffness models and other machine learning techniques.The model's robustness and generalizability are further supported by its effective handling of SOC estimation and pressure measurement errors.This work highlights the importance of the proposed framework in enhancing state estimation and fault diagnosis for lithium-ion batteries. 展开更多
关键词 Sensorless estimation Electromechanical coupling Impedance model Data-driven model Mechanical pressure
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Semi-Active Sound Absorption Method with Acoustic Impedance Matching 被引量:1
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作者 ZHU Congyun ZHANG Shaoqi DING Guofang 《Journal of Donghua University(English Edition)》 2025年第1期64-70,共7页
The active sound absorption technique excels in mitigating low-frequency sound waves,yet it falls short when dealing with medium and high-frequency sound waves.To enhance the sound-absorbing effect of medium and high-... The active sound absorption technique excels in mitigating low-frequency sound waves,yet it falls short when dealing with medium and high-frequency sound waves.To enhance the sound-absorbing effect of medium and high-frequency sound waves,a novel semi-active sound absorption method has been introduced.This method modulates the surface impedance of a loudspeaker positioned behind the sound-absorbing material,thereby altering the sound absorption coefficient.The theoretical sound absorption coefficient is calculated using MATLAB and compared with the experimental one.Results show that the method can effectively modulates the absorption coefficient in response to varying incident sound wave frequencies,ensuring that it remains at its peak value. 展开更多
关键词 acoustic impedance semi-active sound absorption rigid wall cavity depth sound absorption coefficient
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