A semi-empirical adsorption kinetic model was proposed with the time compensation method to describe the chemisorption of SO2 in flue gas by carbon adsorbents for flue gas purification.The change in adsorption capacit...A semi-empirical adsorption kinetic model was proposed with the time compensation method to describe the chemisorption of SO2 in flue gas by carbon adsorbents for flue gas purification.The change in adsorption capacity and adsorption rate with time at different water vapor concentrations and different SO2 concentrations was studied.The model was in good agreement with experimental data.The surface reaction was probably the rate controlling step in the early stage for SO2 adsorption by ZL50 activated carbon.The parameters m and n in the nth order adsorption kinetic model were related to the magnitude of the time compensation and adsorption driving force,respectively.The change of parameter n with water vapor concentrations and sulfur dioxide concentrations was studied and some physical implications were given.The sum of square errors was less than 1.0 and the average absolute percentage deviations ranged from 0.5 to 3.2.The kinetic model was compared with other models in the literature.展开更多
Experimental study is performed on the probabilistic models for the long fatigue crack growth rates （da/dN） of LZ50 axle steel. An equation for crack growth rate was derived to consider the trend of stress intensity...Experimental study is performed on the probabilistic models for the long fatigue crack growth rates （da/dN） of LZ50 axle steel. An equation for crack growth rate was derived to consider the trend of stress intensity factor range going down to the threshold and the average stress effect. The probabilistic models were presented on the equation. They consist of the probabilistic da/dN-△K relations, the confidence-based da/dN-△K relations, and the probabilistic- and confidence-based da/dN-△K relations. Efforts were made respectively to characterize the effects of probabilistic assessments due to the scattering regularity of test data, the number of sampling, and both of them. These relations can provide wide selections for practice. Analysis on the test data of LZ50 steel indicates that the present models are available and feasible.展开更多
In order to theoretically study the growth morphology of dihydroxylammonium 5,5’-bistetrazole-1,1’-dio late(TKX-50)crystal in different solvent systems,crystal–solvent models were established,and then molecular dyn...In order to theoretically study the growth morphology of dihydroxylammonium 5,5’-bistetrazole-1,1’-dio late(TKX-50)crystal in different solvent systems,crystal–solvent models were established,and then molecular dynamics(MD)methods were adopted as a means to simulate particle motion.Modified attachment energy(MAE)model was employed to calculate the growth morphology of TKX-50.The simulation results demonstrate that COMPASS force field and RESP charge are suitable for molecular dynamics simulation of TKX-50.The morphologically dominant growth surfaces of TKX-50 in vacuum are(020),(011),(11–1),(100)and(120),respectively.In water(H_(2)O)and N,N-dimethylformamide(DMF)solvents,the(11–1)face is the largest in the habit face,the growth rate of(020)face becomes faster.With the increase of temperature,the aspect ratios of TKX-50 crystal in DMF solvent increase,and the areas of the(120)faces decrease.In ethylene glycol/H_(2)O mixed solvent system with volume ratio of 1/1,aspect ratio of TKX-50 is relatively small.In formic acid/H_(2)O mixed solvents with different volume ratios(1/4,1/3,1/2,1/1 and 2/1),aspect ratio of TKX-50 is relatively small when volume ratio is 1/2.展开更多
Through-thickness heterogeneity in creep properties of 7B50-T7451 aluminum alloy Friction Stir Welding(FSW)joints was investigated.Creep tests for three slices of the FSW joint were conducted at the temperature of 150...Through-thickness heterogeneity in creep properties of 7B50-T7451 aluminum alloy Friction Stir Welding(FSW)joints was investigated.Creep tests for three slices of the FSW joint were conducted at the temperature of 150-200℃ and applied stress of 60-225 MPa.The theta projection method was used to predict creep curves and minimum creep rate.The results show that the minimum creep rate increases and creep rupture life decreases with the increase of creep temperature and applied stress.Creep properties of the FSW joint deteriorate along the thickness direction from the top to the bottom.The threshold stress of all three slices of the FSW joint decreases with the increase of creep temperature and even disappears at 200℃ for the bottom slice.Creep activation energy approaches the activation energy of the lattice self-diffusion of aluminum.The value of true stress exponent for different slices is approximately equal to three.The predominant creep mechanism of the FSW joint is dislocation viscous glide by lattice self-diffusion.What is more,a constitutive model is established based on the theta method to accurately describe creep behavior ofdifferent slices of the FSW joint.展开更多
This paper employs the PPO(Proximal Policy Optimization) algorithm to study the risk hedging problem of the Shanghai Stock Exchange(SSE) 50ETF options. First, the action and state spaces were designed based on the cha...This paper employs the PPO(Proximal Policy Optimization) algorithm to study the risk hedging problem of the Shanghai Stock Exchange(SSE) 50ETF options. First, the action and state spaces were designed based on the characteristics of the hedging task, and a reward function was developed according to the cost function of the options. Second, combining the concept of curriculum learning, the agent was guided to adopt a simulated-to-real learning approach for dynamic hedging tasks, reducing the learning difficulty and addressing the issue of insufficient option data. A dynamic hedging strategy for 50ETF options was constructed. Finally, numerical experiments demonstrate the superiority of the designed algorithm over traditional hedging strategies in terms of hedging effectiveness.展开更多
文摘A semi-empirical adsorption kinetic model was proposed with the time compensation method to describe the chemisorption of SO2 in flue gas by carbon adsorbents for flue gas purification.The change in adsorption capacity and adsorption rate with time at different water vapor concentrations and different SO2 concentrations was studied.The model was in good agreement with experimental data.The surface reaction was probably the rate controlling step in the early stage for SO2 adsorption by ZL50 activated carbon.The parameters m and n in the nth order adsorption kinetic model were related to the magnitude of the time compensation and adsorption driving force,respectively.The change of parameter n with water vapor concentrations and sulfur dioxide concentrations was studied and some physical implications were given.The sum of square errors was less than 1.0 and the average absolute percentage deviations ranged from 0.5 to 3.2.The kinetic model was compared with other models in the literature.
基金国家自然科学基金，Special Foundation of National Excellent Ph.D.Thesis，Outstanding Young Teachers of Ministry of Education of China
文摘Experimental study is performed on the probabilistic models for the long fatigue crack growth rates （da/dN） of LZ50 axle steel. An equation for crack growth rate was derived to consider the trend of stress intensity factor range going down to the threshold and the average stress effect. The probabilistic models were presented on the equation. They consist of the probabilistic da/dN-△K relations, the confidence-based da/dN-△K relations, and the probabilistic- and confidence-based da/dN-△K relations. Efforts were made respectively to characterize the effects of probabilistic assessments due to the scattering regularity of test data, the number of sampling, and both of them. These relations can provide wide selections for practice. Analysis on the test data of LZ50 steel indicates that the present models are available and feasible.
基金supported by Fundamental Research Program of Shanxi Province(20210302123055)and(201801D221035).
文摘In order to theoretically study the growth morphology of dihydroxylammonium 5,5’-bistetrazole-1,1’-dio late(TKX-50)crystal in different solvent systems,crystal–solvent models were established,and then molecular dynamics(MD)methods were adopted as a means to simulate particle motion.Modified attachment energy(MAE)model was employed to calculate the growth morphology of TKX-50.The simulation results demonstrate that COMPASS force field and RESP charge are suitable for molecular dynamics simulation of TKX-50.The morphologically dominant growth surfaces of TKX-50 in vacuum are(020),(011),(11–1),(100)and(120),respectively.In water(H_(2)O)and N,N-dimethylformamide(DMF)solvents,the(11–1)face is the largest in the habit face,the growth rate of(020)face becomes faster.With the increase of temperature,the aspect ratios of TKX-50 crystal in DMF solvent increase,and the areas of the(120)faces decrease.In ethylene glycol/H_(2)O mixed solvent system with volume ratio of 1/1,aspect ratio of TKX-50 is relatively small.In formic acid/H_(2)O mixed solvents with different volume ratios(1/4,1/3,1/2,1/1 and 2/1),aspect ratio of TKX-50 is relatively small when volume ratio is 1/2.
基金financially supported by the National Natural Science Foundation of China(No.52075450)the Fundamental Research Funds for the Central Universities,China(No.D5000220503).
文摘Through-thickness heterogeneity in creep properties of 7B50-T7451 aluminum alloy Friction Stir Welding(FSW)joints was investigated.Creep tests for three slices of the FSW joint were conducted at the temperature of 150-200℃ and applied stress of 60-225 MPa.The theta projection method was used to predict creep curves and minimum creep rate.The results show that the minimum creep rate increases and creep rupture life decreases with the increase of creep temperature and applied stress.Creep properties of the FSW joint deteriorate along the thickness direction from the top to the bottom.The threshold stress of all three slices of the FSW joint decreases with the increase of creep temperature and even disappears at 200℃ for the bottom slice.Creep activation energy approaches the activation energy of the lattice self-diffusion of aluminum.The value of true stress exponent for different slices is approximately equal to three.The predominant creep mechanism of the FSW joint is dislocation viscous glide by lattice self-diffusion.What is more,a constitutive model is established based on the theta method to accurately describe creep behavior ofdifferent slices of the FSW joint.
基金supported by the Foundation of Key Laboratory of System Control and Information Processing,Ministry of Education,China,Scip20240111Aeronautical Science Foundation of China,Grant 2024Z071108001the Foundation of Key Laboratory of Traffic Information and Safety of Anhui Higher Education Institutes,Anhui Sanlian University,KLAHEI18018.
文摘This paper employs the PPO(Proximal Policy Optimization) algorithm to study the risk hedging problem of the Shanghai Stock Exchange(SSE) 50ETF options. First, the action and state spaces were designed based on the characteristics of the hedging task, and a reward function was developed according to the cost function of the options. Second, combining the concept of curriculum learning, the agent was guided to adopt a simulated-to-real learning approach for dynamic hedging tasks, reducing the learning difficulty and addressing the issue of insufficient option data. A dynamic hedging strategy for 50ETF options was constructed. Finally, numerical experiments demonstrate the superiority of the designed algorithm over traditional hedging strategies in terms of hedging effectiveness.
