In the post-Moore era, as the energy consumption of micro-nano electronic devices rapidly increases, near-field radiative heat transfer(NFRHT) with super-Planckian phenomena has gradually shown great potential for app...In the post-Moore era, as the energy consumption of micro-nano electronic devices rapidly increases, near-field radiative heat transfer(NFRHT) with super-Planckian phenomena has gradually shown great potential for applications in efficient and ultrafast thermal modulation and energy conversion. Recently, hyperbolic materials, an important class of anisotropic materials with hyperbolic isofrequency contours, have been intensively investigated. As an exotic optical platform, hyperbolic materials bring tremendous new opportunities for NFRHT from theoretical advances to experimental designs. To date, there have been considerable achievements in NFRHT for hyperbolic materials, which range from the establishment of different unprecedented heat transport phenomena to various potential applications. This review concisely introduces the basic physics of NFRHT for hyperbolic materials, lays out the theoretical methods to address NFRHT for hyperbolic materials, and highlights unique behaviors as realized in different hyperbolic materials and the resulting applications. Finally, key challenges and opportunities of the NFRHT for hyperbolic materials in terms of fundamental physics, experimental validations, and potential applications are outlined and discussed.展开更多
Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic media.Due to the strong in-plane anisotropy,natural hyperbolic materials can be...Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic media.Due to the strong in-plane anisotropy,natural hyperbolic materials can be used to construct near-field radiative modulators with excellent modulation effects.However,in practical applications,natural hyperbolic materials need to be deposited on the substrate,and the influence of substrate on modulation effect has not been studied yet.In this work,we investigate the influence of substrate effect on near-field radiative modulator based onα-MoO_(3).The results show that compared to the situation without a substrate,the presence of both lossless and lossy substrate will reduce the modulation contrast(MC)for different film thicknesses.When the real or imaginary component of the substrate permittivity increases,the mismatch of hyperbolic phonon polaritons(HPPs)weakens,resulting in a reduction in MC.By reducing the real and imaginary components of substrate permittivity,the MC can be significantly improved,reaching 4.64 forε_(s)=3 at t=10 nm.This work indicates that choosing a substrate with a smaller permittivity helps to achieve a better modulation effect,and provides guidance for the application of natural hyperbolic materials in the near-field radiative modulator.展开更多
We investigated the spin splitting of vortex beam on the surface of biaxial natural hyperbolic materials(NHMs)rotated by an angle with respect to the incident plane. An obvious asymmetry of spatial shifts produced by ...We investigated the spin splitting of vortex beam on the surface of biaxial natural hyperbolic materials(NHMs)rotated by an angle with respect to the incident plane. An obvious asymmetry of spatial shifts produced by the left-handed circularly(LCP) component and right-handed circularly polarized(RCP) component is exhibited. We derived the analytical expression for in-and out-of-plane spatial shifts for each spin component of the vortex beam. The orientation angle of the optical axis plays a key role in the spin splitting between the two spin components, which can be reflected in the simple expressions for spatial shifts without the rotation angle. Based on an α-MoO_(3) biaxial NHM, the spatial shifts of the two spin components with the topological charge were investigated. As the topological charge increases, the spatial shifts also increase;in addition, a tiny spatial shift close to zero can be obtained if we control the incident frequency or the polarization of the reflected beams. It can also be concluded that the maximum of the spin splitting results from the LCP component at p-incidence and the RCP component at s-incidence in the RB-Ⅱ hyperbolic frequency band. The effect of the incident angle and the thickness of the α-MoO_(3) film on spin splitting is also considered. These results can be used for manipulating infrared radiation and optical detection.展开更多
Anisotropic hyperbolic phonon polaritons(PhPs)in natural biaxial hyperbolic materialα-MoO_(3) has opened up new avenues for mid-infrared nanophotonics,while active tunability ofα-MoO_(3) PhPs is still an urgent prob...Anisotropic hyperbolic phonon polaritons(PhPs)in natural biaxial hyperbolic materialα-MoO_(3) has opened up new avenues for mid-infrared nanophotonics,while active tunability ofα-MoO_(3) PhPs is still an urgent problem necessarily to be solved.In this study,we present a theoretical demonstration of actively tuningα-MoO_(3) PhPs using phase change material VO_(2) and graphene.It is observed thatα-MoO_(3) PhPs are greatly dependent on the propagation plane angle of PhPs.The insulator-to-metal phase transition of VO_(2) has a significant effect on the hybridization PhPs of theα-MoO_(3)/VO_(2) structure and allows to obtain actively tunableα-MoO_(3) PhPs,which is especially obvious when the propagation plane angle of PhPs is 900.Moreover,when graphene surface plasmon sources are placed at the top or bottom ofα-MoO_(3) inα-MoO_(3)/VO_(2)structure,tunable coupled hyperbolic plasmon-phonon polaritons inside its Reststrahlen bands(RB s)and surface plasmonphonon polaritons outside its RBs can be achieved.In addition,the above-mentionedα-MoO_(3)-based structures also lead to actively tunable anisotropic spontaneous emission(SE)enhancement.This study may be beneficial for realization of active tunability of both PhPs and SE ofα-MoO_(3),and facilitate a deeper understanding of the mechanisms of anisotropic light-matter interaction inα-MoO_(3) using functional materials.展开更多
Hyperbolic materials are highly anisotropic optical media that provide valuable assistance in emission engineering,nanoscale light focusing,and scattering enhancement.Recently discovered organic hyperbolic materials(O...Hyperbolic materials are highly anisotropic optical media that provide valuable assistance in emission engineering,nanoscale light focusing,and scattering enhancement.Recently discovered organic hyperbolic materials(OHMs)with exceptional biocompatibility and tunability offer promising prospects as next-generation optical media for nanoscopy,enabling superresolution bioimaging capabilities.Nonetheless,an OHM is still less accessible to many researchers because of its rarity and narrow operating wavelength range.Here,we employ first-principles calculations to expand the number of known OHMs,including conjugated polymers with multiple assembly units.Through the systematic investigation of structural and optical properties of the target copolymers,we discover extraordinary multiband hyperbolic dispersions from candidate OHMs.This approach provides a new perspective on the molecular-scale design of broadband,low-loss OHMs.It aids in identifying potential hyperbolic material candidates applicable to optical engineering and super-resolution bioimaging,offering new insights into nanoscale light–matter interactions.展开更多
Polaritons in two-dimensional(2D)materials continues to garner significant attention due to their favorable ability of field-confinement and intriguing potential for low-loss and ultrafast optical and photonic devices...Polaritons in two-dimensional(2D)materials continues to garner significant attention due to their favorable ability of field-confinement and intriguing potential for low-loss and ultrafast optical and photonic devices.The recent experimental observation of in-plane anisotropic dispersion in natural van der Waals materials has revealed much richer physics as compared to isotropic plasmonic materials,which provides new insight to manipulate the polaritons and manufacture flat optical devices with unprecedented controls.Herein,we give an overview of the recent progress in in-plane anisotropic polaritons launched and visualized in the near-field range in 2D layered van der Waals materials.Furthermore,future prospects in this promising but emerging field are featured on the basis of its peculiar applications.This review article will stimulate the scientific community to explore other hyperbolic materials and structures in order to develop optical technologies with novel functionalities and further improve the understanding of the exotic photonic phenomena.展开更多
Thin films exhibit substantial potential in energy management and utilization as the development of micro-and nanofabrication technologies.It is well known that thermal radiation is one of the fundamental ways of ener...Thin films exhibit substantial potential in energy management and utilization as the development of micro-and nanofabrication technologies.It is well known that thermal radiation is one of the fundamental ways of energy transfer.However,the potential of hyperbolic films for radiative heat transfer is always ignored.Whether the radiative heat flux between hyperbolic films surpasses that of the bulk materials remains insufficiently explored.In this work,we theoretically investigate the radiative heat transfer between hexagonal boron nitride(hBN)at a separation from 20nm to 2μm.The results show that when the optical axis of hBN is oriented in-plane,the near-field radiative heat flux of hBN with a thickness of 10nm exceeds that of hBN bulk by 47%and exceeds the blackbody limit by two orders of magnitude at a gap distance of 20nm.The physical mechanism is attributed to the volume-confined hyperbolic polaritons can be excited in a higher wavevector space.Conversely,when the gap distance is 600nm,the heat flux between films is considerably lower than that of bulk material.This work opens up potential avenues for developing hyperbolic film-dependent thermal devices and strategies for thermal management.展开更多
基金supported by the Natural Science Foundation of Shandong Province (ZR2020LLZ004)the National Natural Science Foundation of China (Grant No.52106099),the National Natural Science Foundation of China (Grant No.52076056)the Fundamental Research Funds for the Central Universities (Grant No.AUGA5710094020)。
文摘In the post-Moore era, as the energy consumption of micro-nano electronic devices rapidly increases, near-field radiative heat transfer(NFRHT) with super-Planckian phenomena has gradually shown great potential for applications in efficient and ultrafast thermal modulation and energy conversion. Recently, hyperbolic materials, an important class of anisotropic materials with hyperbolic isofrequency contours, have been intensively investigated. As an exotic optical platform, hyperbolic materials bring tremendous new opportunities for NFRHT from theoretical advances to experimental designs. To date, there have been considerable achievements in NFRHT for hyperbolic materials, which range from the establishment of different unprecedented heat transport phenomena to various potential applications. This review concisely introduces the basic physics of NFRHT for hyperbolic materials, lays out the theoretical methods to address NFRHT for hyperbolic materials, and highlights unique behaviors as realized in different hyperbolic materials and the resulting applications. Finally, key challenges and opportunities of the NFRHT for hyperbolic materials in terms of fundamental physics, experimental validations, and potential applications are outlined and discussed.
基金Project supported by the National Natural Science Foundation of China (Grant No.52106099)the Natural Science Foundation of Shandong Province of China (Grant No.ZR2022YQ57)the Taishan Scholars Program。
文摘Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic media.Due to the strong in-plane anisotropy,natural hyperbolic materials can be used to construct near-field radiative modulators with excellent modulation effects.However,in practical applications,natural hyperbolic materials need to be deposited on the substrate,and the influence of substrate on modulation effect has not been studied yet.In this work,we investigate the influence of substrate effect on near-field radiative modulator based onα-MoO_(3).The results show that compared to the situation without a substrate,the presence of both lossless and lossy substrate will reduce the modulation contrast(MC)for different film thicknesses.When the real or imaginary component of the substrate permittivity increases,the mismatch of hyperbolic phonon polaritons(HPPs)weakens,resulting in a reduction in MC.By reducing the real and imaginary components of substrate permittivity,the MC can be significantly improved,reaching 4.64 forε_(s)=3 at t=10 nm.This work indicates that choosing a substrate with a smaller permittivity helps to achieve a better modulation effect,and provides guidance for the application of natural hyperbolic materials in the near-field radiative modulator.
基金Project supported by the Natural Science Foundation of Heilongjiang Province of China (Grant No. LH2022F041)。
文摘We investigated the spin splitting of vortex beam on the surface of biaxial natural hyperbolic materials(NHMs)rotated by an angle with respect to the incident plane. An obvious asymmetry of spatial shifts produced by the left-handed circularly(LCP) component and right-handed circularly polarized(RCP) component is exhibited. We derived the analytical expression for in-and out-of-plane spatial shifts for each spin component of the vortex beam. The orientation angle of the optical axis plays a key role in the spin splitting between the two spin components, which can be reflected in the simple expressions for spatial shifts without the rotation angle. Based on an α-MoO_(3) biaxial NHM, the spatial shifts of the two spin components with the topological charge were investigated. As the topological charge increases, the spatial shifts also increase;in addition, a tiny spatial shift close to zero can be obtained if we control the incident frequency or the polarization of the reflected beams. It can also be concluded that the maximum of the spin splitting results from the LCP component at p-incidence and the RCP component at s-incidence in the RB-Ⅱ hyperbolic frequency band. The effect of the incident angle and the thickness of the α-MoO_(3) film on spin splitting is also considered. These results can be used for manipulating infrared radiation and optical detection.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.52204258 and 52106099)the Postdoctoral Research Foundation of China (Grant No.2023M743779)+2 种基金the Fundamental Research Funds for the Central Universities (Grant No.2022QN1017)the Key Research Development Projects in Xinjiang Uygur Autonomous Region (Grant No.2022B03003-3)the Shandong Provincial Natural Science Foundation (Grant No.ZR2020LLZ004)。
文摘Anisotropic hyperbolic phonon polaritons(PhPs)in natural biaxial hyperbolic materialα-MoO_(3) has opened up new avenues for mid-infrared nanophotonics,while active tunability ofα-MoO_(3) PhPs is still an urgent problem necessarily to be solved.In this study,we present a theoretical demonstration of actively tuningα-MoO_(3) PhPs using phase change material VO_(2) and graphene.It is observed thatα-MoO_(3) PhPs are greatly dependent on the propagation plane angle of PhPs.The insulator-to-metal phase transition of VO_(2) has a significant effect on the hybridization PhPs of theα-MoO_(3)/VO_(2) structure and allows to obtain actively tunableα-MoO_(3) PhPs,which is especially obvious when the propagation plane angle of PhPs is 900.Moreover,when graphene surface plasmon sources are placed at the top or bottom ofα-MoO_(3) inα-MoO_(3)/VO_(2)structure,tunable coupled hyperbolic plasmon-phonon polaritons inside its Reststrahlen bands(RB s)and surface plasmonphonon polaritons outside its RBs can be achieved.In addition,the above-mentionedα-MoO_(3)-based structures also lead to actively tunable anisotropic spontaneous emission(SE)enhancement.This study may be beneficial for realization of active tunability of both PhPs and SE ofα-MoO_(3),and facilitate a deeper understanding of the mechanisms of anisotropic light-matter interaction inα-MoO_(3) using functional materials.
基金support of the research and development program of the Korea Institute of Energy Research (Grant No. C4-2450)support by the National Research Foundation of Korea for funding (Grant No. 2022R1C1C1006040)the Institute of Information & Communications Technology Planning & Evaluation (IITP)ITRC (Information Technology Research Center) grant funded by the Korea government (MSIT) (Grant No. IITP-RS-202400437284)
文摘Hyperbolic materials are highly anisotropic optical media that provide valuable assistance in emission engineering,nanoscale light focusing,and scattering enhancement.Recently discovered organic hyperbolic materials(OHMs)with exceptional biocompatibility and tunability offer promising prospects as next-generation optical media for nanoscopy,enabling superresolution bioimaging capabilities.Nonetheless,an OHM is still less accessible to many researchers because of its rarity and narrow operating wavelength range.Here,we employ first-principles calculations to expand the number of known OHMs,including conjugated polymers with multiple assembly units.Through the systematic investigation of structural and optical properties of the target copolymers,we discover extraordinary multiband hyperbolic dispersions from candidate OHMs.This approach provides a new perspective on the molecular-scale design of broadband,low-loss OHMs.It aids in identifying potential hyperbolic material candidates applicable to optical engineering and super-resolution bioimaging,offering new insights into nanoscale light–matter interactions.
基金Australian Research Council,Grant/Award Numbers:IH150100006,CE170100039China Postdoctoral Science Foundation,Grant/Award Number:2017M622758,LHTD20170006+1 种基金support from the China Postdoctoral Science Foundation Grant(No.2017 M622758)Q.Bao acknowledges the support from the Australian Research Council(ARC,IH150100006,FT150100450,and CE170100039).
文摘Polaritons in two-dimensional(2D)materials continues to garner significant attention due to their favorable ability of field-confinement and intriguing potential for low-loss and ultrafast optical and photonic devices.The recent experimental observation of in-plane anisotropic dispersion in natural van der Waals materials has revealed much richer physics as compared to isotropic plasmonic materials,which provides new insight to manipulate the polaritons and manufacture flat optical devices with unprecedented controls.Herein,we give an overview of the recent progress in in-plane anisotropic polaritons launched and visualized in the near-field range in 2D layered van der Waals materials.Furthermore,future prospects in this promising but emerging field are featured on the basis of its peculiar applications.This review article will stimulate the scientific community to explore other hyperbolic materials and structures in order to develop optical technologies with novel functionalities and further improve the understanding of the exotic photonic phenomena.
基金supported by the National Natural Science Foundation of China(52106099)the Natural Science Foundation of Shandong Province(ZR2022YQ57)the Taishan Scholars Program.
文摘Thin films exhibit substantial potential in energy management and utilization as the development of micro-and nanofabrication technologies.It is well known that thermal radiation is one of the fundamental ways of energy transfer.However,the potential of hyperbolic films for radiative heat transfer is always ignored.Whether the radiative heat flux between hyperbolic films surpasses that of the bulk materials remains insufficiently explored.In this work,we theoretically investigate the radiative heat transfer between hexagonal boron nitride(hBN)at a separation from 20nm to 2μm.The results show that when the optical axis of hBN is oriented in-plane,the near-field radiative heat flux of hBN with a thickness of 10nm exceeds that of hBN bulk by 47%and exceeds the blackbody limit by two orders of magnitude at a gap distance of 20nm.The physical mechanism is attributed to the volume-confined hyperbolic polaritons can be excited in a higher wavevector space.Conversely,when the gap distance is 600nm,the heat flux between films is considerably lower than that of bulk material.This work opens up potential avenues for developing hyperbolic film-dependent thermal devices and strategies for thermal management.
