Heavy metal pollution poses serious risks to the human health and the natural environment,and there is an urgent need to develop efficient heavy metal removal technologies.The adsorption strategy is one of the most fa...Heavy metal pollution poses serious risks to the human health and the natural environment,and there is an urgent need to develop efficient heavy metal removal technologies.The adsorption strategy is one of the most famous strategies for the capture of heavy metal ions.In recent years,hyper crosslinked polymers(HCPs),a kind of hyper crosslinked porous material prepared by Friedel-Crafts alkylation reaction,have attracted more and more attention because of their advantages of ultra-light framework,wide range of building monomers,easy modification and functionalization.This review focuses on the advances of HCPs in the efficient applications to the removal of heavy metal ions.The fundamentals are presented including physicochemical properties,adsorption mechanism,and preparation strategies.Subsequently,the application and influencing factors of HCPs toward heavy metal ion adsorption are discussed in detail.Furthermore,the opportunities and challenges of HCPs in this promising research field are summarized and anticipated.We are convinced that the advanced HCP-based materials will make further contributions to heavy metal removal in wastewater treatment,further paving the way of advancing researches in this field.展开更多
0 INTRODUCTION The Yichun Li-Cs-Ta deposit in SE China has received significant attention for several decades,and it represents one of the most typical granitic examples that resemble typical LCT-type mineralization i...0 INTRODUCTION The Yichun Li-Cs-Ta deposit in SE China has received significant attention for several decades,and it represents one of the most typical granitic examples that resemble typical LCT-type mineralization in peraluminous pegmatites.展开更多
Whipple shields as sacrificial bumpers,safeguard the satellites against extremely fast,different-sized projectiles traveling through space in the low earth orbit.Typical Whipple shields comprise a front and rear plate...Whipple shields as sacrificial bumpers,safeguard the satellites against extremely fast,different-sized projectiles traveling through space in the low earth orbit.Typical Whipple shields comprise a front and rear plate,separated by a gap or space.Recent advancements have explored the use of foam,cellular cores,and alternative materials such as ceramics instead of aluminium for the plates.In the current work,the effect of including fluid cores(air/water)sandwiched between the front and rear plates,on the response to hypervelocity impact was explored through a numerical approach.The numerical simulation consisted of hypervelocity impact by a 2 mm diameter,stainless steel projectile,launched at speeds of 3 e9 km/s with a normal impact trajectory towards the Whipple shield.The front and rear bumpers,made of AA6061-T6,were each 1 mm thick.A space of 10 mm was taken between the plates(occupied by fluid).The key metrics analyzed were the perforation characteristics,stages of the debris cloud generation and propagation,energy variations(internal,kinetic and plastic work),temperature variations,and the fragmentation summary.From the computational analysis,employing water-core in Whipple shields could prevent the rear bumper perforation till 6 km/s,lower the peak temperatures at the front bumper perforation zones and debris tip,and generate fewer,larger fragments.展开更多
Super duplex stainless steels(SDSSs)and hyper duplex stainless steels(HDSSs),with more alloying elements content,are more corrosion resistant than the standard grades.Progresses of research works on weldability of SDS...Super duplex stainless steels(SDSSs)and hyper duplex stainless steels(HDSSs),with more alloying elements content,are more corrosion resistant than the standard grades.Progresses of research works on weldability of SDSSs and HDSSs in recent years are reviewed in this paper.If proper heat input is provided,SDSSs and HDSSs can be welded with most fusion welding processes,while tungsten inert gas welding is the most popular process.SDSSs and HDSSs are more prone to secondary phases precipitation than the standard and lean grades,and heat input for SDSSs and HDSSs welding is restricted to a smaller range.Matching filler materials are usually recommended for SDSSs and HDSSs welding,rather than Ni-riched ones for standard and lean grades.Nitrogen addition in shielding gas is always beneficial.Post weld heat treatment with slow cooling rate will be harmful.Hot cracking tendency of SDSSs and HDSSs joints is not high,but sometimes they can suffer from hydrogen induced stress cracking.展开更多
The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress ...The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress curves reveal a balance between work hardening and dynamic recovery at the beginning of the deformation and subsequently demonstrate various softening mechanisms with the increase of strain.At high strain rates,dynamic recovery is the prevailing mechanism,whereas,at medium and low strain rates,dynamic recrystallization becomes dominant.The constitutive equation was constructed,and the deformation activation energy was calculated to be 645.46 kJ·mol^(-1).The hot processing map was drawn based on the dynamic material model at a strain of 0.8.The results indicate that the hot workability of 2707 HDSS decreases due to its high alloying content.The microstructure evolution of 2707 HDSS at 1,050℃ was identified by means of electron backscatter diffraction and transmission electron microscopy.The results demonstrate that the ferrite completes dynamic recrystallization at the strain rate of 1 s^(-1).The softening process of austenite is influenced by ferrite and mainly experiences dynamic recovery.The austenite located at the α/γ phase boundaries tends to undergo dynamic recrystallization.展开更多
The controller design and digital simulation for the hyper velocity kinetic energy missile is investigated. A mathematical model of the trajectory deviation from the line of sight was established, the guidance closed ...The controller design and digital simulation for the hyper velocity kinetic energy missile is investigated. A mathematical model of the trajectory deviation from the line of sight was established, the guidance closed loop was compensated with a phase advance lag corrective network, a selecting algorithm of the attitude control motors used to steer the missile's attitude was presented. In the presence of a wide variety of disturbances the results of digital simulation are satisfactory to circular error probability(CEP) being less than 0 5?m. The steering scheme utilizing attitude control motors as actuators to control the attitude of the missile is feasible.展开更多
基金supported by Innovation Platform(Base)and Talent Special Project,Jilin Provincial Science&Technology Department,China(No.20230508033RC)。
文摘Heavy metal pollution poses serious risks to the human health and the natural environment,and there is an urgent need to develop efficient heavy metal removal technologies.The adsorption strategy is one of the most famous strategies for the capture of heavy metal ions.In recent years,hyper crosslinked polymers(HCPs),a kind of hyper crosslinked porous material prepared by Friedel-Crafts alkylation reaction,have attracted more and more attention because of their advantages of ultra-light framework,wide range of building monomers,easy modification and functionalization.This review focuses on the advances of HCPs in the efficient applications to the removal of heavy metal ions.The fundamentals are presented including physicochemical properties,adsorption mechanism,and preparation strategies.Subsequently,the application and influencing factors of HCPs toward heavy metal ion adsorption are discussed in detail.Furthermore,the opportunities and challenges of HCPs in this promising research field are summarized and anticipated.We are convinced that the advanced HCP-based materials will make further contributions to heavy metal removal in wastewater treatment,further paving the way of advancing researches in this field.
基金funded by the National Natural Science Foundation of China(Nos.42403065 and 92462302)the Frontiers Science Center for Deep-time Digital Earth(No.2652023001)the Open Research Project from the State Key Laboratory of Critical Earth Material Cycling and Mineral Deposits,Nanjing University(No.2025-K16).
文摘0 INTRODUCTION The Yichun Li-Cs-Ta deposit in SE China has received significant attention for several decades,and it represents one of the most typical granitic examples that resemble typical LCT-type mineralization in peraluminous pegmatites.
文摘Whipple shields as sacrificial bumpers,safeguard the satellites against extremely fast,different-sized projectiles traveling through space in the low earth orbit.Typical Whipple shields comprise a front and rear plate,separated by a gap or space.Recent advancements have explored the use of foam,cellular cores,and alternative materials such as ceramics instead of aluminium for the plates.In the current work,the effect of including fluid cores(air/water)sandwiched between the front and rear plates,on the response to hypervelocity impact was explored through a numerical approach.The numerical simulation consisted of hypervelocity impact by a 2 mm diameter,stainless steel projectile,launched at speeds of 3 e9 km/s with a normal impact trajectory towards the Whipple shield.The front and rear bumpers,made of AA6061-T6,were each 1 mm thick.A space of 10 mm was taken between the plates(occupied by fluid).The key metrics analyzed were the perforation characteristics,stages of the debris cloud generation and propagation,energy variations(internal,kinetic and plastic work),temperature variations,and the fragmentation summary.From the computational analysis,employing water-core in Whipple shields could prevent the rear bumper perforation till 6 km/s,lower the peak temperatures at the front bumper perforation zones and debris tip,and generate fewer,larger fragments.
文摘Super duplex stainless steels(SDSSs)and hyper duplex stainless steels(HDSSs),with more alloying elements content,are more corrosion resistant than the standard grades.Progresses of research works on weldability of SDSSs and HDSSs in recent years are reviewed in this paper.If proper heat input is provided,SDSSs and HDSSs can be welded with most fusion welding processes,while tungsten inert gas welding is the most popular process.SDSSs and HDSSs are more prone to secondary phases precipitation than the standard and lean grades,and heat input for SDSSs and HDSSs welding is restricted to a smaller range.Matching filler materials are usually recommended for SDSSs and HDSSs welding,rather than Ni-riched ones for standard and lean grades.Nitrogen addition in shielding gas is always beneficial.Post weld heat treatment with slow cooling rate will be harmful.Hot cracking tendency of SDSSs and HDSSs joints is not high,but sometimes they can suffer from hydrogen induced stress cracking.
基金funded by the Major Science and Technology Program of Luoyang,China(Grant No.2101005A)Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-ferrous Metal New Materials and Advanced Processing Technology.
文摘The hot deformation behavior of 2707 hyper duplex stainless steel(HDSS)was investigated through a hot compression test at 950℃ to 1,250℃ at strain rates of 0.01 s^(-1) to 10 s^(-1).Observations from the flow stress curves reveal a balance between work hardening and dynamic recovery at the beginning of the deformation and subsequently demonstrate various softening mechanisms with the increase of strain.At high strain rates,dynamic recovery is the prevailing mechanism,whereas,at medium and low strain rates,dynamic recrystallization becomes dominant.The constitutive equation was constructed,and the deformation activation energy was calculated to be 645.46 kJ·mol^(-1).The hot processing map was drawn based on the dynamic material model at a strain of 0.8.The results indicate that the hot workability of 2707 HDSS decreases due to its high alloying content.The microstructure evolution of 2707 HDSS at 1,050℃ was identified by means of electron backscatter diffraction and transmission electron microscopy.The results demonstrate that the ferrite completes dynamic recrystallization at the strain rate of 1 s^(-1).The softening process of austenite is influenced by ferrite and mainly experiences dynamic recovery.The austenite located at the α/γ phase boundaries tends to undergo dynamic recrystallization.
文摘The controller design and digital simulation for the hyper velocity kinetic energy missile is investigated. A mathematical model of the trajectory deviation from the line of sight was established, the guidance closed loop was compensated with a phase advance lag corrective network, a selecting algorithm of the attitude control motors used to steer the missile's attitude was presented. In the presence of a wide variety of disturbances the results of digital simulation are satisfactory to circular error probability(CEP) being less than 0 5?m. The steering scheme utilizing attitude control motors as actuators to control the attitude of the missile is feasible.
