Through cation exchanging of montmorillonite, mixed hydroxy Fe Al pillared montmorillonites with large basal spacing were synthesized. The application of these mixed hydroxy Fe Al pillared montmorillonites as adsorben...Through cation exchanging of montmorillonite, mixed hydroxy Fe Al pillared montmorillonites with large basal spacing were synthesized. The application of these mixed hydroxy Fe Al pillared montmorillonites as adsorbents in the areas of environmental protection and pollution control was investigated. Adsorption of Direct Green B, an organic dye, on OH—Fe—, OH—Al—, OH—Fe—Al— pillared montmorillonites was studied. Results showed that these pillared montmorillonites had much better adsorption properties than traditional Na organo montmorillonite. It was also found that pH of the solutions had great effect on the performance of these hydroxy metal pillared montmorillonites in treating the wastewater containing Direct Green B.展开更多
Hydroxy Fe ions react slowly with montmorillonite by intercalation into their interlayer space and adsorption on their surface to form various hydroxyiron montmorillonite complexes. Hydroxyiron montmorillonite comp...Hydroxy Fe ions react slowly with montmorillonite by intercalation into their interlayer space and adsorption on their surface to form various hydroxyiron montmorillonite complexes. Hydroxyiron montmorillonite complexes are assumed to have the ability to adsorb anions such as H 2PO - 4, HPO 2- 4, CrO 2- 4, CrO - 2, H 2AsO - 4, HAsO 2- 4 , AsO 3- 4 and F -, which may come from weathered rocks or waste industrial water, and result in concentration of P, Cr, As and F in soil. In this paper, hydroxy Fe ions including Fe(OH) 2+ , Fe(OH) + 2 and Fe 2(OH) 2+ 2 are prepared through hydrolysis of iron in acid solutions with different pH values. Corresponding hydroxyiron montmorillonite complexes are obtained by intercalation and adsorption of these hydroxy Fe ions into the interlayer space and on the surface of montmorillonite. The obtained hydroxyiron montmorillonite complexes are characterized with XRD and DTA, showing that they have similar basal space and thermal stability with Fe montmorillonite.展开更多
文摘Through cation exchanging of montmorillonite, mixed hydroxy Fe Al pillared montmorillonites with large basal spacing were synthesized. The application of these mixed hydroxy Fe Al pillared montmorillonites as adsorbents in the areas of environmental protection and pollution control was investigated. Adsorption of Direct Green B, an organic dye, on OH—Fe—, OH—Al—, OH—Fe—Al— pillared montmorillonites was studied. Results showed that these pillared montmorillonites had much better adsorption properties than traditional Na organo montmorillonite. It was also found that pH of the solutions had great effect on the performance of these hydroxy metal pillared montmorillonites in treating the wastewater containing Direct Green B.
基金The study is supported by the National Natural Science Foundation of China( No.49973 0 2 8)
文摘Hydroxy Fe ions react slowly with montmorillonite by intercalation into their interlayer space and adsorption on their surface to form various hydroxyiron montmorillonite complexes. Hydroxyiron montmorillonite complexes are assumed to have the ability to adsorb anions such as H 2PO - 4, HPO 2- 4, CrO 2- 4, CrO - 2, H 2AsO - 4, HAsO 2- 4 , AsO 3- 4 and F -, which may come from weathered rocks or waste industrial water, and result in concentration of P, Cr, As and F in soil. In this paper, hydroxy Fe ions including Fe(OH) 2+ , Fe(OH) + 2 and Fe 2(OH) 2+ 2 are prepared through hydrolysis of iron in acid solutions with different pH values. Corresponding hydroxyiron montmorillonite complexes are obtained by intercalation and adsorption of these hydroxy Fe ions into the interlayer space and on the surface of montmorillonite. The obtained hydroxyiron montmorillonite complexes are characterized with XRD and DTA, showing that they have similar basal space and thermal stability with Fe montmorillonite.
