A simple and general method for the synthesis of bi(acyl)disulfides is reported.Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65℃ under PTC,which can react with acyl halides to afford b...A simple and general method for the synthesis of bi(acyl)disulfides is reported.Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65℃ under PTC,which can react with acyl halides to afford bi(acyl)disulfides in good to excellent isolated yields.The effects of solvents and phase transfer catalysts are discussed.展开更多
A clean method for preparing layered double hydroxides （LDHs） has been developed, featured by using the hydroxides of two different metals as starting materials by atom-economic reactions. The reactions were carried...A clean method for preparing layered double hydroxides （LDHs） has been developed, featured by using the hydroxides of two different metals as starting materials by atom-economic reactions. The reactions were carried out under hydrothermal conditions in either a high pressure autoclave or a microwave digester. The compositions, structural parameters and thermal behavior of the resulting LDHs are very similar to those of materials produced by using the separate nucleation and aging steps （SNAS） method. The major advantage of the new method is that no by-product is produced, so that filtration and washing processes are unnecessary. The consequent reduction in water consumption is beneficial to the environment.展开更多
Microtubes/rods of the layered metal hydroxide salt compound Cd2（OH）3（DS）·nH2O, where DS stands for dodecyl sulfate sandwiched between two adjacent inorganic sheets, have been synthesized for the first time t...Microtubes/rods of the layered metal hydroxide salt compound Cd2（OH）3（DS）·nH2O, where DS stands for dodecyl sulfate sandwiched between two adjacent inorganic sheets, have been synthesized for the first time through a mild hydrothermal reaction route. The microtubes/rods have a diameter of about 1 μm and a length ranging from several microns to 20μm. The growth process of microtubes/rods under the experimental conditions employed follows a dissolution-recrystallization route.展开更多
文摘A simple and general method for the synthesis of bi(acyl)disulfides is reported.Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65℃ under PTC,which can react with acyl halides to afford bi(acyl)disulfides in good to excellent isolated yields.The effects of solvents and phase transfer catalysts are discussed.
文摘A clean method for preparing layered double hydroxides （LDHs） has been developed, featured by using the hydroxides of two different metals as starting materials by atom-economic reactions. The reactions were carried out under hydrothermal conditions in either a high pressure autoclave or a microwave digester. The compositions, structural parameters and thermal behavior of the resulting LDHs are very similar to those of materials produced by using the separate nucleation and aging steps （SNAS） method. The major advantage of the new method is that no by-product is produced, so that filtration and washing processes are unnecessary. The consequent reduction in water consumption is beneficial to the environment.
基金the National Natural Science Foun-dation of China for financial support
文摘Microtubes/rods of the layered metal hydroxide salt compound Cd2（OH）3（DS）·nH2O, where DS stands for dodecyl sulfate sandwiched between two adjacent inorganic sheets, have been synthesized for the first time through a mild hydrothermal reaction route. The microtubes/rods have a diameter of about 1 μm and a length ranging from several microns to 20μm. The growth process of microtubes/rods under the experimental conditions employed follows a dissolution-recrystallization route.
