Water management within the membrane electrode assemblies(MEAs)of electrochemical hydrogen compressors(EHCs)plays a crucial role in optimizing overall performance,particularly under low relative humidity(RH),where the...Water management within the membrane electrode assemblies(MEAs)of electrochemical hydrogen compressors(EHCs)plays a crucial role in optimizing overall performance,particularly under low relative humidity(RH),where the anode side tends to dry out.Hollow mesoporous silica nanoparticles functionalized with amino groups(HMSNs-NH_(2))were integrated into the anode catalyst layers of EHCs to establish humidity-independent proton pathways through acid-base interactions with Nafion ionomers.These acid-base pairs between grafted–NH_(2)and sulfonic acid groups create continuous“proton highways”,enabling efficient conduction via the Grotthuss mechanism even at 50%RH.With only 2.5 wt%HMSNs-NH_(2)in the anode catalyst layer,hydrogen was compressed to 0.9 MPa in 60±3 s at 50%RH,representing a 55%reduction in compression time compared to MEAs with conventional Pt/C catalyst layers under the same conditions.This work overcomes the critical water-management bottleneck in EHCs,advancing the deployment of hydrogen energy technologies in arid environments.展开更多
Ti-Cr- and Ti-Mn-based alloys were prepared to be low- and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen stora...Ti-Cr- and Ti-Mn-based alloys were prepared to be low- and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen storage properties were investigated. The alloy pair Ti0.9Zr0.1Mn1.4- Cr0.35V0.2Fe0.05/TiCr1.55Mn0.2Fe0.2 was optimized based on the comprehensive performance of the studied alloys. The product hydrogen with a pressure of 100 MPa could be produced from 4 MPa feed gas when hot oil was used as a heat reservoir.展开更多
基金supported by the National Natural Science Foundation of China(No.22208376,No.UA22A20429)the Fundamental Research Funds for the Central Universities(buctrc202118,No.25CX07002A)+1 种基金the Qingdao New Energy Shandong Laboratory Open Project(QNESL OP 202303)the Shandong Provincial Natural Science Foundation(ZR2024QB175 and ZR2023LFG005)。
文摘Water management within the membrane electrode assemblies(MEAs)of electrochemical hydrogen compressors(EHCs)plays a crucial role in optimizing overall performance,particularly under low relative humidity(RH),where the anode side tends to dry out.Hollow mesoporous silica nanoparticles functionalized with amino groups(HMSNs-NH_(2))were integrated into the anode catalyst layers of EHCs to establish humidity-independent proton pathways through acid-base interactions with Nafion ionomers.These acid-base pairs between grafted–NH_(2)and sulfonic acid groups create continuous“proton highways”,enabling efficient conduction via the Grotthuss mechanism even at 50%RH.With only 2.5 wt%HMSNs-NH_(2)in the anode catalyst layer,hydrogen was compressed to 0.9 MPa in 60±3 s at 50%RH,representing a 55%reduction in compression time compared to MEAs with conventional Pt/C catalyst layers under the same conditions.This work overcomes the critical water-management bottleneck in EHCs,advancing the deployment of hydrogen energy technologies in arid environments.
文摘Ti-Cr- and Ti-Mn-based alloys were prepared to be low- and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen storage properties were investigated. The alloy pair Ti0.9Zr0.1Mn1.4- Cr0.35V0.2Fe0.05/TiCr1.55Mn0.2Fe0.2 was optimized based on the comprehensive performance of the studied alloys. The product hydrogen with a pressure of 100 MPa could be produced from 4 MPa feed gas when hot oil was used as a heat reservoir.
文摘危险与可操作性(HAZO P)分析作为化工领域广泛采用的风险评估工具,其系统化和结构化的分析方法在识别工艺系统潜在危险方面具有显著优势。以加氢站氢气压缩机为研究对象,基于HAZO P分析方法,结合具体设计案例,对压缩机系统进行全面的风险辨识与评估。通过构建偏差分析矩阵,识别出高压氢气泄漏、机械密封失效等关键风险因素,进而提出多参数协同监测机制和分级联锁保护策略。研究结果表明:该方法可有效降低关键风险的发生概率,为加氢站核心设备的本质安全设计提供了技术参考,对推动氢能产业安全发展具有重要意义。同时,还探讨了HAZ O P分析方法在特殊工况下的适用性改进方案,为类似高压气体处理设备的安全评估提供了新的思路。
文摘针对高压氢能加注场景下90 MPa隔膜式氢气压缩机面临的设备振动、氢腐蚀、膜片疲劳及密封失效等核心难题,通过气-固-液多物理场耦合仿真、抗氢脆结构创新、油气协同调控技术及复合膜腔型线设计,构建“设计-材料-工艺-安全-产业化”一体化解决方案。研究优化两列对称平衡型主机结构,采用配气盘内嵌式组合缸盖、一体化硬密封膜片与抛物线-圆弧复合膜腔型线,研发高低压一体化油泵驱动机构、波形弹簧气阀及高可靠性连杆衬套。性能测试结果表明,整机振动≤8 mm s、膜片寿命提升至8000 h以上、连杆衬套寿命突破50000 h、排气压力稳定达90 MPa(排气量500 m 3 h),国产化率达95%。该研究为高压氢能装备国产化与规模化应用提供关键技术支撑,设备性能达国际先进水平。
