Objective The distribution characteristics and formation mechanism of rearranged hopanes in hydrocarbon source rocks are affected by various geological conditions.Among these geological conditions,thermal action has a...Objective The distribution characteristics and formation mechanism of rearranged hopanes in hydrocarbon source rocks are affected by various geological conditions.Among these geological conditions,thermal action has an important influence on the formation of rearranged hopanes,which has been however little documented previously.展开更多
The Songliao Basin, one of the biggest continental petroliferous basins in eastern China, is a Mesozoic- Cenozoic fault-depressed and fault-subsided basin developed on the Hercynian fold basement. Generally, rearrange...The Songliao Basin, one of the biggest continental petroliferous basins in eastern China, is a Mesozoic- Cenozoic fault-depressed and fault-subsided basin developed on the Hercynian fold basement. Generally, rearranged hopanes are considered to be formed by clay- mediated acidic catalysis under oxic or suboxic environment, whereas high abundance of rearranged hopanes were found in hydrocarbon source rocks and crude oils that are derived from salty environment in the Songliao Basin. This phenomenon rarely happens all over the world.展开更多
Based on the data of 44 samples of hydrocarbon source rocks in Nanpu No.3 buffed-hill region, the kerogen type is judged through the pyrolysis and microscopic identification. At the same time, organic matter maturity ...Based on the data of 44 samples of hydrocarbon source rocks in Nanpu No.3 buffed-hill region, the kerogen type is judged through the pyrolysis and microscopic identification. At the same time, organic matter maturity and hydrocarbon generation threshold are studied by using vitrinite reflectance, pyrolysis yield and hydrocarbon abundance. Meanwhile the hydrocarbon expulsion threshold is calculated. And the characteristics of organic hydrocarbon generation and expulsion are preliminarily revealed and evaluated. The result shows that the No.3 buffed-hill region has abundant hydrocarbon source rocks with high content of organic carbon. And the primary types of kerogen are II, and lI 2. The hydrocarbon source rocks which passed biochemistry, thermolysis and thermal cracking have developed into the mature-postmature phase of different extents. And plenty of oil and gas were expelled out. It is believed the depth of oil-generating window is 3 600 m and the depth of hydro- carbon-expulsion threshold is 4 100 m. The comprehensive analysis indicates that Nanpu No.3 burried-hill region has a certain condition to generate hydrocarbon which is very promising in oil exploration and thus can become an important exploration and development target next.展开更多
The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Pa...The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.展开更多
Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas ge...Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter （solid bitumen and heavy oil）, and kerogen. order of crude oil （light oil and condensate）, dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln（CffC3） can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln（CJC2）-（δ13C1-δ13C2） can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.展开更多
In the hinterland of the Junggar Basin, there are multiple depressions with multiple sets of source rocks. Therefore, the conditions of hydrocarbon sources are complex, and the geochemical characteristics and sources ...In the hinterland of the Junggar Basin, there are multiple depressions with multiple sets of source rocks. Therefore, the conditions of hydrocarbon sources are complex, and the geochemical characteristics and sources of hydrocarbon vary in different structural belts. The evolution of the Che- Mo palaeohigh affected the formation of hydrocarbon source kitchens and hydrocarbon migration. We studied the combination and superimposition of hydrocarbon source kitchens, using as an example the hinterland of the Junggar Basin （including the Yongjin, Zhengshacun, Moxizhuang and Luliang uplift areas）. The study was based on geochemical analyses of crude oil and fluid inclusions, and the histories of tectonic evolution and hydrocarbon generation. The results indicated that before the Paleogene there were two hydrocarbon-generating depressions： the Western Well Penl depression and the Changji depression on the south and north sides of the Che-Mo palaeohigh, respectively. The Permian source kitchen had been generating hydrocarbon continuously since Triassic and reached high maturity stage in the Cretaceous period. After Paleogene, the adjustment of the Che-Mo palaeohigh led to the subsidence of the Changji depression and the Jurassic source rocks reached mature stage and became the main source kitchens. However, the Jurassic source rocks in the Western Well Penl depression were still in a low maturity stage and did not generate oil because of the adjustment of tectonic movements. As a result, in the central and southern parts of the Junggar Basin, Jurassic source rocks generated oil, but in the Luliang uplift, the crude oil was from the Permian source rocks in the Western Well Penl depression and the Jurassic source rocks did not contribute. The crude oil in the central Zhengshacun-Moxizhuang belt was from the Permian source rocks in two depressions, and partially from the Jurassic source rocks. The crude oil in the Luliang uplift was from the source rocks of the lower Permian Fengcheng Formation and middle Permian Wuerhe Formation, which is characterized by superimposition of two sets of source kitchens and three accumulation stages. The crude oil in the Yongjin tectonic belt was from the lower Permian, middle Permian and Jurassic source rocks, which is characterized by superimposition of three sets of source kitchens and two accumulation stages. The crude oil in the Zhengshacun tectonic belt was from a combination of source kitchens of lower Permian and middle Permian in the Western Well Penl depression in the early stage and from the superimposition of Jurassic source rocks in the Changji depression in the late stage.展开更多
Hydrocarbon source rocks, as a main geologic factor of petroliferous systems in a sedimentary basin, play a key role in the accumulation of oil and gas and the formation of hydrocarbon accumulations. This study, which...Hydrocarbon source rocks, as a main geologic factor of petroliferous systems in a sedimentary basin, play a key role in the accumulation of oil and gas and the formation of hydrocarbon accumulations. This study, which focuses on difficulties in prediction of hydrocarbon source rocks in basins or sags with low exploration degree and insufficient hydrocarbon source rock indicators, taking the Wenchang Formation of northern Zhu I Depression, Pearl River Mouth Basin as an example, proposed a hypothesis of “finding lakes and hydrocarbon source rocks”. Detailed steps include, first, determination of the lacustrine basin boundary according to analysis of seismic foreset facies, determination of the depositional area based on the compilation of strata residual thickness maps, determination of the lacustrine basin shape according to deciphering slope break belt system, determination of the fluctuation of paleo-water depth according to biogeochemical indicators of mature exploration areas, determination of the lacustrine basin scale based on analyses of tectonics intensity and accommodation space, which prove the existence of the lacustrine basin and identify the range of semi deep-deep lake;second, further analyses of tectonopalaeogeomorphology, paleo-provenance,palaeoclimate and paleo-water depth to reconstruct the geologic background of the original basin and semideep-deep lacustrine facies, to determine the distribution of semi-deep/deep lacustrine sediments in combination with studies of logging facies, core facies, seismic facies and sedimentary facies, and to rank the sags’ potential of developing hydrocarbon source rocks from controlling factors of source-to-sink system development;third, on the basis of regional sedimentary facies analysis, through identification and assessment of seismic facies types of semi-deep/deep lacustrine basins in mature areas, establishing “hydrocarbon source rock facies” in mature areas to instruct the identification and depicting of hydrocarbon source rocks in semideep/deep lacustrine basins with low exploration degree;fourth, through systematical summary of hydrocarbon-rich geological factors and lower limit index of hydrocarbon formation of the sags already revealed by drilling wells(e.g., sag area, tectonic subsidence amount, accommodation space, provenance characteristic, mudstone thickness, water body environment, sedimentary facies types of hydrocarbon source rocks), in correlation with corresponding indexes of sags with low exploration degree, then the evaluation and sorting of high-quality source rocks in areas with sparsely distributed or no drilling wells can be conducted with multi-factors and multiple dimensions. It is concluded that LF22 sag, HZ10 sag and HZ8 sag are II-order hydrocarbon rich sags;whereas HZS, HZ11 and HZ24 are the III-order hydrocarbon-generating sags.展开更多
Continental shale strata in China are rich in petroleum resources and are an important area to strengthen domestic oil exploration and development.Based on the latest progress in geological research and exploration an...Continental shale strata in China are rich in petroleum resources and are an important area to strengthen domestic oil exploration and development.Based on the latest progress in geological research and exploration and development of petroleum inside continental source kitchens of China National Petroleum Corporation exploration areas in recent two years,we have achieved the following results:(1)The geological connotations of continental hydrocarbon accumulation inside source kitchen and"sweet spot"have been proposed.The intra-source petroleum accumulation refers to the accumulation of liquid-rich hydrocarbons retained or captured in the continental organic-rich shale strata,and"sweet spot"refers to the favorable reservoir with higher oil content,better physical properties,easier to stimulate and higher in commercial development value in the overall oil-bearing continental source rock series,they can be divided into three types,interlayer,hybrid sediment and shale.(2)High-quality shale formations in both salt water and freshwater lacustrine basins can generate hydrocarbons on a large scale,shale strata have multiple types of favorable reservoirs with large-scale storage capacity,the intra-source shale strata are overall oil-bearing and large in resource scale,and there are multiple favorable shale series for development.The exploration and development practice is propelling the formation of a series of exploration and development key technologies with"sweet spot exploration"and"volume development"as the core.Some pilot tests of these technologies have provided an important scientific basis for the economic and effective development of hydrocarbon accumulation inside source kitchen,and popularization of these technologies have achieved encouraging results preliminarily.(3)Two types of continental intra-source petroleum resources in China have great potential,including medium-high maturity with liquid-rich hydrocarbons and medium-low maturity with organic-rich matter.The Ordos,Songliao,Bohai Bay and Junggar basins are the main areas of these resources.By addressing the theoretical and technical challenges in the exploration and development,the two types of resources inside continental source kitchens will become the realistic and major strategic replacement oil resources respectively in the future.展开更多
The discovery of the Bozhong 19-6 gas field,the largest integrated condensate gas field in the eastern China in 2018,opened up a new field for the natural gas exploration deep strata in the Bohai Bay Basin,demonstrati...The discovery of the Bozhong 19-6 gas field,the largest integrated condensate gas field in the eastern China in 2018,opened up a new field for the natural gas exploration deep strata in the Bohai Bay Basin,demonstrating there is a great potential for natural gas exploration in oil-type basins.The ethane isotope of the Bozhong 19-6 condensate gas is heavy,showing the characteristics of partial humic gas.In this paper,aimed at the source rocks of the Bozhong 19-6 gas field in the Bohai Bay Basin,the characteristics of the source rocks in the Bozhong 19-6 structural belt were clarified and the reason are explained from impact of microorganism degradation on hydrocarbon generation of source rocks why the condensate oil and gas had heavy carbon isotope and why it showed partial humic characteristics was explored based on the research of parent materials.The following conclusions were obtained:The paleontology of the Bozhong 19-6 structural belt and its surrounding sub-sags is dominated by higher plants,such as angiosperm and gymnosperm.During the formation of source rocks,under the intensive transformation of microorganism,the original sedimentary organic matter such as higher plants was degraded and transformed by defunctionalization.Especially,the transformation of anaerobic microorganisms on source rocks causes the degradation and defunctionalization of a large number of humic products such as higher plants and the increase of hydrogen content.The degradation and transformation of microorganism don't transform the terrestrial humic organic matter into newly formed“sapropel”hydrocarbons,the source rocks are mixed partial humic source rocks.As a result,hydrogen content incrased and the quality of source rocks was improved,forming the partial humic source rocks dominated by humic amorphous bodies.The partial humic source rocks are the main source rocks in the Bozhong 19-6 gas field,and it is also the internal reason why the isotope of natural gas is heavy.展开更多
In a thermal simulation experiment of gold tubes of closed-system, calculating with the KINETICS and GOR-ISOTOPE KINETICS software, kinetic parameters of gas generation and methane carbon isotopic fractionation from T...In a thermal simulation experiment of gold tubes of closed-system, calculating with the KINETICS and GOR-ISOTOPE KINETICS software, kinetic parameters of gas generation and methane carbon isotopic fractionation from Triassic-Jurassic hydrocarbon source rocks in the Kuqa depression of Tarim Basin are obtained. The activation energies of methane generated from Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Depression are 197-268 kJ/mol, 180-260 kJ/mol and 214-289 kJ/mol, respectively, and their frequency factors are 5.265×10^13 s^-1, 9.761×10^11 s^-1 and 2.270×10^14 s^-1. This reflects their differences of hydrocarbon generation behaviors. The kinetic parameters of methane carbon isotopic fractionation are also different in Jurassic coal, Jurassic mudstone and Triassic mudstone, whose average activation energies are 228 kJ/mol, 205 kJ/mol and 231 kJ/mol, respectively. Combined with the geological background, the origin of natural gas in the Yinan-2 gas pool is discussed, and an accumulation model of natural gas is thus established. The Yinan- 2 gas is primarily derived from Jurassic coal-bearing source rocks in the Yangxia Sag. Main gas accumulation time is 5-0 Ma and the corresponding Ro is in the range from 1.25 %-1.95 %. The loss rate of natural gas is 25 %-30 %.展开更多
According to the study on the oil-gas source rocks in China for ten years,in connection with the microscopic, submicroscopic levels, the authors used the microscope photometry together with transmission electronic mic...According to the study on the oil-gas source rocks in China for ten years,in connection with the microscopic, submicroscopic levels, the authors used the microscope photometry together with transmission electronic microscopy, scanning electronic microscopy and proposed a new classification for sedimentary organic matters.展开更多
The ancient structure characteristic,correlation of the oil and the hydrocarbon source rock characteristics,hydrocarbon migration trace,types and conditions of traps,migration passages and characteristic of hydrocarbo...The ancient structure characteristic,correlation of the oil and the hydrocarbon source rock characteristics,hydrocarbon migration trace,types and conditions of traps,migration passages and characteristic of hydrocarbon accumulation are researched in this paper.It is shown through the analysis that two main large tectonic activities after the Early Hercynian orogeny resulted in different tectonic patterns in the study area.Two main hydrocarbon infills occurred in the Donghetang Formation,the first occurred in the Early Hercynian resulting in the ancient hydrocarbon accumulation in the northern Tahe,the second infill was a large amount that occurred in places beneficial for hydrocarbon accumulation,such as structural traps and structural-stratigraphic traps formed in the Early Himalayan orogeny after migration along the faults through source rocks and other passages.Before the earlier period of the Himalayan orogeny,the petroleum mainly migrated to the north,whereas petroleum migrated to the south and southeast because of the structural reverse in the Himalayan orogeny,so the middle and later period of the Himalayan orogeny is the key period for hydrocarbon accumulation.The model of＂oil generation formed early,hydrocarbon accumulation controlled by the faults through source rocks and structures formed late＂is proposed.It is pointed out that the south of the research area is currently the beneficial district for hydrocarbon accumulation, which provides the basis for future petroleum exploration.展开更多
Taking a hydrocarbon zone or a basin group as a unit,this paper analyzed the vertical hydrocarbon generation regularity of onshore and offshore oil and gasfields in China,based on the theory of co-control of source an...Taking a hydrocarbon zone or a basin group as a unit,this paper analyzed the vertical hydrocarbon generation regularity of onshore and offshore oil and gasfields in China,based on the theory of co-control of source and heat.The results demonstrated that the hydrocarbon generation modes of oil and gasfields in China are orderly.First,the hydrocarbon zones in southeastern China offshore area,including the East and South China Sea basins,are dominated by single hydrocarbon generation mode,which displays as either single oil generation in the near shore or single gas generation in the offshore controlled by both source and heat.Second,the eastern hydrocarbon zones,including the Bohai Bay,Songliao and Jianghan basins and the North and South Yellow Sea basins,are dominated by a two-layer hydrocarbon generation mode,which performs as“upper oil and lower gas”.Third,the central hydrocarbon zones,including the Ordos,Sichuan and Chuxiong basins,are also dominated by the“upper oil and lower gas”two-layer hydrocarbon generation mode.In the Ordos Basin,gas is mainly generated in the Triassic,and oil is predominantly generated in the Paleozoic.In the Sichuan Basin,oil was discovered in the Jurassic,and gas was mostly discovered in the Sinian and Triassic.Fourth,the western hydrocarbon zones are dominated by a“sandwich”multi-layer mode,such as the Junggar,Tarim,Qaidam basins.In summary,the theory of co-control of source and heat will be widely applied to oil and gas exploration all over China.Oil targets should be focused on the near shore areas in the southeastern China sea,the upper strata in the eastern and middle hydrocarbon zones,and the Ordovician,Permian and Paleogene strata in the western hydrocarbon zone,while gas targets should be focused on the off-shore areas in the southeastern China sea,the Cambrian,Carboniferous,Jurassic,and Quaternary strata in the western hydrocarbon zone.A pattern of exploring gasfields under or outside oilfields and oilfields under or outside gasfields is presented.Therefore,there is still a great prospect for oil and gas exploration in China.展开更多
The effects of different carbon sources(sugars) on the production and molecular properties of exopolysaccharides(EPS) were evaluated in the mycelial liquid culture of a medicinal fungus Cordyceps sinensis Cs-HK1. Gala...The effects of different carbon sources(sugars) on the production and molecular properties of exopolysaccharides(EPS) were evaluated in the mycelial liquid culture of a medicinal fungus Cordyceps sinensis Cs-HK1. Galactose or mannose was used(at 5 g·L^(-1)) as a secondary carbon source with glucose(35 g·L^(-1)) at the mass ratio of 1:7. Mannose was consumed notably since the first day of culture, but galactose was not even after glucose was exhausted.The volumetric yield of EPS in culture was increased slightly with the addition of galactose and decreased with mannose. The monosaccharide composition of EPS was also different, e.g., on day 8, the glucose contents of EPS were 76%with the addition of mannose, 59% with galactose, compared with 62% with glucose only. The molecular weight distribution of EPS was also affected by the secondary carbon source, being generally lower compared with that with glucose only. The results suggested that the addition of galactose improved the total yield of EPS in culture while mannose can improve the yield of glucan constituent of EPS.展开更多
To investigate the levels of exposure to particulate-bound polycyclic aromatic hydrocarbon （PAH） and to estimate the risk these levels pose to traffic assistants （TAs） in Tianjin （a rnegacity in North China）, a ...To investigate the levels of exposure to particulate-bound polycyclic aromatic hydrocarbon （PAH） and to estimate the risk these levels pose to traffic assistants （TAs） in Tianjin （a rnegacity in North China）, a measurement campaign （33 all-day exposure samples, 25 occupational-exposure samples and 10 indoor samples） was conducted to characterize the TAs＇ exposure to PAHs, assess the cancer risk and identify the potential sources of exposure. The average total exposure concentration of 14 PAHs was approximately 2871 ＋ 928 ng/rn3 （on-duty）, and 1622 ＋ 457 ng/m3 （all-day）. The indoor PAHs level was 1257 ＋ 107 ng/m3. After 8000 Monte Carlo simulations, the cancer risk resulting from exposure to PAHs was found to be approximately 1.05 x 10-4. A multivariate analysis was applied to identify the potential sources, and the results showed that, in addition to vehicle exhaust, coal combustion and cooking fumes were also another two important contributors to personal PAH exposure. The diagnostic ratios of PAH compounds agree with the source apportionment results derived from principal component analysis.展开更多
0 INTRODUTION The Kuqa Depression,situated along the northern margin of the Tarim Basin,holds substantial geological significance due to its intricate sedimentary burial history,tectonic history,and the evolution of h...0 INTRODUTION The Kuqa Depression,situated along the northern margin of the Tarim Basin,holds substantial geological significance due to its intricate sedimentary burial history,tectonic history,and the evolution of hydrocarbon source rocks(Jiang et al.,2024;Zhang et al.,2023;Huang et al.,2019;Yang et al.,2017;Jia et al.,2003;Hendrix,2000).展开更多
Paleofluid-rock interaction results in the modification of the ultra-deep reservoir quality,but the coupling effects of the paleofluid evolution on reservoir quality modification are still underestimated.Here,the mult...Paleofluid-rock interaction results in the modification of the ultra-deep reservoir quality,but the coupling effects of the paleofluid evolution on reservoir quality modification are still underestimated.Here,the multi-stage dolomite cements have been studied by means of core observations,thin section identification,fluid inclusions,and in situ elements and isotopic analyses in order to reaveal the paleofluid evolution processes and their effects on the reservoir quality.The fibrous dolomite cement(FDC)and bladed dolomite cement(BDC)both have similar geochemical properties and homogenization temperature(Th)to the matrix dolostone.Subsequent early silicification occurs(QZ1).However,silt-to fine-sized crystalline dolomite cement(CD2)has higher concentration of Fe and medium rare earth element,more negativeδ^(18)O than for FDC and BDC,and 103.4-150.2℃in Th.The first petroleum charge episode solid bitumen 1(SB1)followed the CD2.The medium to coarse sized crystalline dolomite cement(CD3)is characterized by the higher Mn and lower Sr concentration than CD2,positiveδEu anomaly,negativeδ^(13)C andδ^(18)O,high^(87)Sr/^(86)Sr ratio and 138.9℃-184.3℃in Th.The solid bitumen 2(SB2)occurs after CD3.Subsequently,the saddle dolomite(SD)has higher Fe and Mn concentration and lower Na and Sr than others cement,δEu positive anomaly,negativeδ^(13)C andδ^(18)O,high ^(87)Sr/^(86)Sr ratio and 177.5℃-243.6℃in Th.Eventually massive silicification(QZ2)took place.The FDC,BDC,QZ1 and SB1 formed in the early diagenetic stage and have little negative effect on the reservoir quality.But the CD2 and CD3 dramatically decreased the reservoir quality related to a quantity of hydrothermal fluids entrance in the mesodiagenetic stage along the strike-slip faults and the unconformity surface at top of the Deng-2 Member during the late stage of the Caledonian orogeny.The reservoir spaces were retained and enlarged during the late diagenetic stage when the peak petroleum charge occurred,massive silicification and thermochemical sulfate reduction took place with SB2,SD and QZ2 being formed.The research outcome may update our understanding on the retention mechanism and the insights for further hydrocarbon exploration of Precambrian ultra-deep microbial reservoirs.展开更多
The marine primary producers assimilate the atmospheric CO2 to form the organic carbon in surface water. The organic carbon then settles down through the water column and is removed from the oceans by final preservati...The marine primary producers assimilate the atmospheric CO2 to form the organic carbon in surface water. The organic carbon then settles down through the water column and is removed from the oceans by final preservation in sediments in the form of petroleum or nature gases. The reconstruction of paleoproductivity will thus improve our understanding of the biological processes in the formation of fossil energy resource and help to locate new sites for future exploration. In this study, biorelated elements P, Cd, Al, Ba, as well as redox sensitive element Mo, were analyzed in the 448 rock samples collected from Permian strata at the Shangsi （上寺） Section, Guangyuan （广元）, Northeast Sichuan （四川） in China. On the basis of the Ti content, the nondetrital contents of P, Ca, and Al, denoted as Pxs, Cdxs, and Alxs, were calculated and found to coincide with the TOC content throughout the whole section, with some enrichment intervals being found in the middle part of Chihsia Formation, topmost Maokou （茅口） Formation, and Dalong （大隆） Formation. This suggests that the biorelated elements could he used as proxies for the paleoproductivity here in this section. Baxs, a paleoproductivity indicator widely used in the paleoceanography, shows insignificant correlation with TOC, Pxs, Cdxs, and Alxs, probably arising from the loss of biological barium in anoxic conditions. Compiled with the data of TOC content and Pxs, Cdxs, and Alxs, three episodes of enhanced paleoproductivity were identified in Permian strata including the middle part of Chihsia Formation, topmost Maokou Formation, and Dalong Formation.展开更多
The present paper mainly studies the petroleum system of the Sufyan Depression in the Muglad Basin of central Africa and analyzes its control of hydrocarbon accumulation. On the basis of comprehensive analysis of effe...The present paper mainly studies the petroleum system of the Sufyan Depression in the Muglad Basin of central Africa and analyzes its control of hydrocarbon accumulation. On the basis of comprehensive analysis of effective source rock, reservoir bed types and source-reservoir-seal assemblages, petroleum system theory has been used to classify the petroleum system of the Sufyan Depression. Vertically, the Sufyan Depression consists of two subsystems. One is an Abu Gabra subsystem as a self generating, accumulating and sealing assemblage. The other subsystem is composed of an Abu Gabra source rock, Bentiu channel sandstone reservoir and Darfur group shale seal, which is a prolific assemblage in this area. Laterally, the Sufyan Depression is divided into eastern and western parts with separate hydrocarbon generation centers more than 10 000 m deep. The potential of the petroleum system is tremendous. Recently, there has been a great breakthrough in exploration. The Sufyan C-1 well drilled in the central structural belt obtained high-yielding oil flow exceeding 100 tons per day and controlled geologic reserves of tens of millions of tons. The total resource potential of the Sufyan Depression is considerable. The central structural belt is most favorable as an exploration and development prospect.展开更多
Petroleum system theory has been used to study characteristics of the Fula depression in the Central African fault zone.In this system,deep lacustrine facies mudstone in the Abu Gabra For-mation of the Lower Cretaceou...Petroleum system theory has been used to study characteristics of the Fula depression in the Central African fault zone.In this system,deep lacustrine facies mudstone in the Abu Gabra For-mation of the Lower Cretaceous is a very good source rock,thick deltaic facies sandstone of the Abu Gabra Formation and fluvial facies sandstone of the Bentiu Formation are good reservoir beds,and the mudstone in the Upper Cretaceous Darfur Group is the regional cap rock.The oil search mode and fault block trap seal-off conditions are considered here for passive rift basins.Particularly with respect to oil source rock distribution,successive development of reverse fault block and faulted anticlinal traps on low relief structures could have accumulated hydrocarbons because of lateral sealing by down-thrown mudstone along the up-dipping reservoir beds.At present,discoveries in this system are all large-duty oil fields.In 2009,proved reserves exceeded 2×108 t,and about 3×106 t annual throughput of crude oil was obtained.Risk exploration of the Fula depression is of short cycle and high benefit,which will be of great help for exploration in the Muglad basin.展开更多
基金supported by the National Natural Science Foundation of China (grant No.41272170)the National Oil and Gas Major Project (grant No.2016ZX05007-001)
文摘Objective The distribution characteristics and formation mechanism of rearranged hopanes in hydrocarbon source rocks are affected by various geological conditions.Among these geological conditions,thermal action has an important influence on the formation of rearranged hopanes,which has been however little documented previously.
基金supported by the National Natural Science Foundation of China(grant No.41272170)
文摘The Songliao Basin, one of the biggest continental petroliferous basins in eastern China, is a Mesozoic- Cenozoic fault-depressed and fault-subsided basin developed on the Hercynian fold basement. Generally, rearranged hopanes are considered to be formed by clay- mediated acidic catalysis under oxic or suboxic environment, whereas high abundance of rearranged hopanes were found in hydrocarbon source rocks and crude oils that are derived from salty environment in the Songliao Basin. This phenomenon rarely happens all over the world.
文摘Based on the data of 44 samples of hydrocarbon source rocks in Nanpu No.3 buffed-hill region, the kerogen type is judged through the pyrolysis and microscopic identification. At the same time, organic matter maturity and hydrocarbon generation threshold are studied by using vitrinite reflectance, pyrolysis yield and hydrocarbon abundance. Meanwhile the hydrocarbon expulsion threshold is calculated. And the characteristics of organic hydrocarbon generation and expulsion are preliminarily revealed and evaluated. The result shows that the No.3 buffed-hill region has abundant hydrocarbon source rocks with high content of organic carbon. And the primary types of kerogen are II, and lI 2. The hydrocarbon source rocks which passed biochemistry, thermolysis and thermal cracking have developed into the mature-postmature phase of different extents. And plenty of oil and gas were expelled out. It is believed the depth of oil-generating window is 3 600 m and the depth of hydro- carbon-expulsion threshold is 4 100 m. The comprehensive analysis indicates that Nanpu No.3 burried-hill region has a certain condition to generate hydrocarbon which is very promising in oil exploration and thus can become an important exploration and development target next.
基金supported by the CNPC Science and Technology Major Project of the Fourteenth Five-Year Plan(2021DJ0101)the National Natural Science Foundation of China(U19B600302,41872148)。
文摘The Early Cambrian Yuertusi Formation(Є_(1)y)in the Tarim Basin of China deposits a continuously developed suite of organic-rich black mudstones,which constitute an important source of oil and gas reservoirs in the Paleozoic.However,its hydrocarbon generation and evolution characteristics and resource potential have long been constrained by deeply buried strata and previous research.In this paper,based on the newly obtained ultra-deep well drilling data,the hydrocarbon generation and expulsion model ofЄ_(1)y shale was established by using data-driven Monte Carlo simulation,upon which the hydrocarbon generation,expulsion,and retention amounts were calculated by using the diagenetic method.The research indicates that theЄ_(1)y shale reaches the hydrocarbon generation and expulsion threshold at equivalent vitrinite reflectances of 0.46%and 0.72%,respectively.The cumulative hydrocarbon generation is 68.88×10^(10)t,the cumulative hydrocarbon expulsion is 35.59×10^(10)t,and the cumulative residual hydrocarbon is 33.29×10^(10)t.This paper systematically and quantitatively calculates the hydrocarbon expulsion at various key geological periods for theЄ_(1)y source rocks in the study area for the first time,more precisely confirming that the black shale of theЄ_(1)y is the most significant source rock contributing to the marine oil and gas resources in the Tarim Basin,filling the gap in hydrocarbon expulsion calculation in the study area,and providing an important basis for the formation and distribution of Paleozoic hydrocarbon reservoirs.The prospect of deep ultra-deep oil and gas exploration in the Tarim Basin is promising.Especially,the large area of dolomite reservoirs under the Cambrian salt and source rock interiors are the key breakthrough targets for the next exploration in the Tarim Basin.
基金supported by Petroleum & Chemical United Fund Project(Grant No. 40739902)
文摘Using high pressure and geological condition simulation vessels, we conducted hydrous pyrolysis experiments of kerogen, solid bitumen and liquid hydrocarbons in southern China in order to study the processes of gas generation and derive geo- chemical indicators of gas genesis under approximate pressure and temperature. The results indicate that gas generation productivity of different marine material decreased in the ganic matter （solid bitumen and heavy oil）, and kerogen. order of crude oil （light oil and condensate）, dispersed soluble or- Under identical temperature-pressure regimes, pyrolysates derived from kerogen and dispersed soluble organic matter display drastically different geochemical characteristics. For example, the δ13Cc02-δ13C1 values of gaseous products from dispersed soluble organic matter are greater than 20%o, whereas those from kerogen are less than 20%~. The 813C1 values of pyrolysates from different marine hydrocarbon sources generally increase with pyrolysis temperature, but are always lower than those of the source precursors. The δ13C values of ethane and propane in the pyrolysates also increase with increasing pyrolysis temperature, eventually approaching that of their sources, at peak hydro- carbon generation. At high-over mature stages, the δ13C values of ethane and propane are often greater than those of their sources but close to those of coal gases, and thus become ineffective as gas genetic indicators. Ln（CffC3） can clearly distin- guish kerogen degradation gas from oil cracking gas and Ln（CJC2）-（δ13C1-δ13C2） can be an effective indicator for distinguishing oil cracking gas from dispersed soluble organic matter cracking gas.
基金supported by the National Basic Research Program in China (2006CB202300)
文摘In the hinterland of the Junggar Basin, there are multiple depressions with multiple sets of source rocks. Therefore, the conditions of hydrocarbon sources are complex, and the geochemical characteristics and sources of hydrocarbon vary in different structural belts. The evolution of the Che- Mo palaeohigh affected the formation of hydrocarbon source kitchens and hydrocarbon migration. We studied the combination and superimposition of hydrocarbon source kitchens, using as an example the hinterland of the Junggar Basin （including the Yongjin, Zhengshacun, Moxizhuang and Luliang uplift areas）. The study was based on geochemical analyses of crude oil and fluid inclusions, and the histories of tectonic evolution and hydrocarbon generation. The results indicated that before the Paleogene there were two hydrocarbon-generating depressions： the Western Well Penl depression and the Changji depression on the south and north sides of the Che-Mo palaeohigh, respectively. The Permian source kitchen had been generating hydrocarbon continuously since Triassic and reached high maturity stage in the Cretaceous period. After Paleogene, the adjustment of the Che-Mo palaeohigh led to the subsidence of the Changji depression and the Jurassic source rocks reached mature stage and became the main source kitchens. However, the Jurassic source rocks in the Western Well Penl depression were still in a low maturity stage and did not generate oil because of the adjustment of tectonic movements. As a result, in the central and southern parts of the Junggar Basin, Jurassic source rocks generated oil, but in the Luliang uplift, the crude oil was from the Permian source rocks in the Western Well Penl depression and the Jurassic source rocks did not contribute. The crude oil in the central Zhengshacun-Moxizhuang belt was from the Permian source rocks in two depressions, and partially from the Jurassic source rocks. The crude oil in the Luliang uplift was from the source rocks of the lower Permian Fengcheng Formation and middle Permian Wuerhe Formation, which is characterized by superimposition of two sets of source kitchens and three accumulation stages. The crude oil in the Yongjin tectonic belt was from the lower Permian, middle Permian and Jurassic source rocks, which is characterized by superimposition of three sets of source kitchens and two accumulation stages. The crude oil in the Zhengshacun tectonic belt was from a combination of source kitchens of lower Permian and middle Permian in the Western Well Penl depression in the early stage and from the superimposition of Jurassic source rocks in the Changji depression in the late stage.
基金supported by the National Science Foundation of China (Grant No. 41676050)。
文摘Hydrocarbon source rocks, as a main geologic factor of petroliferous systems in a sedimentary basin, play a key role in the accumulation of oil and gas and the formation of hydrocarbon accumulations. This study, which focuses on difficulties in prediction of hydrocarbon source rocks in basins or sags with low exploration degree and insufficient hydrocarbon source rock indicators, taking the Wenchang Formation of northern Zhu I Depression, Pearl River Mouth Basin as an example, proposed a hypothesis of “finding lakes and hydrocarbon source rocks”. Detailed steps include, first, determination of the lacustrine basin boundary according to analysis of seismic foreset facies, determination of the depositional area based on the compilation of strata residual thickness maps, determination of the lacustrine basin shape according to deciphering slope break belt system, determination of the fluctuation of paleo-water depth according to biogeochemical indicators of mature exploration areas, determination of the lacustrine basin scale based on analyses of tectonics intensity and accommodation space, which prove the existence of the lacustrine basin and identify the range of semi deep-deep lake;second, further analyses of tectonopalaeogeomorphology, paleo-provenance,palaeoclimate and paleo-water depth to reconstruct the geologic background of the original basin and semideep-deep lacustrine facies, to determine the distribution of semi-deep/deep lacustrine sediments in combination with studies of logging facies, core facies, seismic facies and sedimentary facies, and to rank the sags’ potential of developing hydrocarbon source rocks from controlling factors of source-to-sink system development;third, on the basis of regional sedimentary facies analysis, through identification and assessment of seismic facies types of semi-deep/deep lacustrine basins in mature areas, establishing “hydrocarbon source rock facies” in mature areas to instruct the identification and depicting of hydrocarbon source rocks in semideep/deep lacustrine basins with low exploration degree;fourth, through systematical summary of hydrocarbon-rich geological factors and lower limit index of hydrocarbon formation of the sags already revealed by drilling wells(e.g., sag area, tectonic subsidence amount, accommodation space, provenance characteristic, mudstone thickness, water body environment, sedimentary facies types of hydrocarbon source rocks), in correlation with corresponding indexes of sags with low exploration degree, then the evaluation and sorting of high-quality source rocks in areas with sparsely distributed or no drilling wells can be conducted with multi-factors and multiple dimensions. It is concluded that LF22 sag, HZ10 sag and HZ8 sag are II-order hydrocarbon rich sags;whereas HZS, HZ11 and HZ24 are the III-order hydrocarbon-generating sags.
基金Supported by the National Key Basic Research and Development Program(973 Program),China(2014CB239000)China National Science and Technology Major Project(2016ZX05046)
文摘Continental shale strata in China are rich in petroleum resources and are an important area to strengthen domestic oil exploration and development.Based on the latest progress in geological research and exploration and development of petroleum inside continental source kitchens of China National Petroleum Corporation exploration areas in recent two years,we have achieved the following results:(1)The geological connotations of continental hydrocarbon accumulation inside source kitchen and"sweet spot"have been proposed.The intra-source petroleum accumulation refers to the accumulation of liquid-rich hydrocarbons retained or captured in the continental organic-rich shale strata,and"sweet spot"refers to the favorable reservoir with higher oil content,better physical properties,easier to stimulate and higher in commercial development value in the overall oil-bearing continental source rock series,they can be divided into three types,interlayer,hybrid sediment and shale.(2)High-quality shale formations in both salt water and freshwater lacustrine basins can generate hydrocarbons on a large scale,shale strata have multiple types of favorable reservoirs with large-scale storage capacity,the intra-source shale strata are overall oil-bearing and large in resource scale,and there are multiple favorable shale series for development.The exploration and development practice is propelling the formation of a series of exploration and development key technologies with"sweet spot exploration"and"volume development"as the core.Some pilot tests of these technologies have provided an important scientific basis for the economic and effective development of hydrocarbon accumulation inside source kitchen,and popularization of these technologies have achieved encouraging results preliminarily.(3)Two types of continental intra-source petroleum resources in China have great potential,including medium-high maturity with liquid-rich hydrocarbons and medium-low maturity with organic-rich matter.The Ordos,Songliao,Bohai Bay and Junggar basins are the main areas of these resources.By addressing the theoretical and technical challenges in the exploration and development,the two types of resources inside continental source kitchens will become the realistic and major strategic replacement oil resources respectively in the future.
文摘The discovery of the Bozhong 19-6 gas field,the largest integrated condensate gas field in the eastern China in 2018,opened up a new field for the natural gas exploration deep strata in the Bohai Bay Basin,demonstrating there is a great potential for natural gas exploration in oil-type basins.The ethane isotope of the Bozhong 19-6 condensate gas is heavy,showing the characteristics of partial humic gas.In this paper,aimed at the source rocks of the Bozhong 19-6 gas field in the Bohai Bay Basin,the characteristics of the source rocks in the Bozhong 19-6 structural belt were clarified and the reason are explained from impact of microorganism degradation on hydrocarbon generation of source rocks why the condensate oil and gas had heavy carbon isotope and why it showed partial humic characteristics was explored based on the research of parent materials.The following conclusions were obtained:The paleontology of the Bozhong 19-6 structural belt and its surrounding sub-sags is dominated by higher plants,such as angiosperm and gymnosperm.During the formation of source rocks,under the intensive transformation of microorganism,the original sedimentary organic matter such as higher plants was degraded and transformed by defunctionalization.Especially,the transformation of anaerobic microorganisms on source rocks causes the degradation and defunctionalization of a large number of humic products such as higher plants and the increase of hydrogen content.The degradation and transformation of microorganism don't transform the terrestrial humic organic matter into newly formed“sapropel”hydrocarbons,the source rocks are mixed partial humic source rocks.As a result,hydrogen content incrased and the quality of source rocks was improved,forming the partial humic source rocks dominated by humic amorphous bodies.The partial humic source rocks are the main source rocks in the Bozhong 19-6 gas field,and it is also the internal reason why the isotope of natural gas is heavy.
基金supported by the National Natural Science Foundation of China(No.40572085)Open Fund of State Key Laboratory of Organic Geochemistry,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences(No.OGL-200403)+2 种基金State Key Technologies R&D Program during the 10th Five-Year Plan Period(No.2001BA605A02-03-01 and 2004BA616A02-01-01)New-century Excellent Talent Program of Ministry of Education(No.NCET-06-0204)China Postdoctoral Science Foundation(No.2002031282).
文摘In a thermal simulation experiment of gold tubes of closed-system, calculating with the KINETICS and GOR-ISOTOPE KINETICS software, kinetic parameters of gas generation and methane carbon isotopic fractionation from Triassic-Jurassic hydrocarbon source rocks in the Kuqa depression of Tarim Basin are obtained. The activation energies of methane generated from Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Depression are 197-268 kJ/mol, 180-260 kJ/mol and 214-289 kJ/mol, respectively, and their frequency factors are 5.265×10^13 s^-1, 9.761×10^11 s^-1 and 2.270×10^14 s^-1. This reflects their differences of hydrocarbon generation behaviors. The kinetic parameters of methane carbon isotopic fractionation are also different in Jurassic coal, Jurassic mudstone and Triassic mudstone, whose average activation energies are 228 kJ/mol, 205 kJ/mol and 231 kJ/mol, respectively. Combined with the geological background, the origin of natural gas in the Yinan-2 gas pool is discussed, and an accumulation model of natural gas is thus established. The Yinan- 2 gas is primarily derived from Jurassic coal-bearing source rocks in the Yangxia Sag. Main gas accumulation time is 5-0 Ma and the corresponding Ro is in the range from 1.25 %-1.95 %. The loss rate of natural gas is 25 %-30 %.
文摘According to the study on the oil-gas source rocks in China for ten years,in connection with the microscopic, submicroscopic levels, the authors used the microscope photometry together with transmission electronic microscopy, scanning electronic microscopy and proposed a new classification for sedimentary organic matters.
基金supported by State Key Laboratory of Petroleum Reservoir Geology and Reservoir Engineering and partly by Northwest Bureau of Petroleum of SINOPEC
文摘The ancient structure characteristic,correlation of the oil and the hydrocarbon source rock characteristics,hydrocarbon migration trace,types and conditions of traps,migration passages and characteristic of hydrocarbon accumulation are researched in this paper.It is shown through the analysis that two main large tectonic activities after the Early Hercynian orogeny resulted in different tectonic patterns in the study area.Two main hydrocarbon infills occurred in the Donghetang Formation,the first occurred in the Early Hercynian resulting in the ancient hydrocarbon accumulation in the northern Tahe,the second infill was a large amount that occurred in places beneficial for hydrocarbon accumulation,such as structural traps and structural-stratigraphic traps formed in the Early Himalayan orogeny after migration along the faults through source rocks and other passages.Before the earlier period of the Himalayan orogeny,the petroleum mainly migrated to the north,whereas petroleum migrated to the south and southeast because of the structural reverse in the Himalayan orogeny,so the middle and later period of the Himalayan orogeny is the key period for hydrocarbon accumulation.The model of＂oil generation formed early,hydrocarbon accumulation controlled by the faults through source rocks and structures formed late＂is proposed.It is pointed out that the south of the research area is currently the beneficial district for hydrocarbon accumulation, which provides the basis for future petroleum exploration.
基金National Basic Research Program of China(973 Program)“Fundamental research on petroleum resources generation and distribution in deep basins in the South China Sea”(No.2009CB219400)National Science and Technology Major Project“Key technologies of deep sea petroleum exploration”(No.2008ZX05025,2011ZX05025).
文摘Taking a hydrocarbon zone or a basin group as a unit,this paper analyzed the vertical hydrocarbon generation regularity of onshore and offshore oil and gasfields in China,based on the theory of co-control of source and heat.The results demonstrated that the hydrocarbon generation modes of oil and gasfields in China are orderly.First,the hydrocarbon zones in southeastern China offshore area,including the East and South China Sea basins,are dominated by single hydrocarbon generation mode,which displays as either single oil generation in the near shore or single gas generation in the offshore controlled by both source and heat.Second,the eastern hydrocarbon zones,including the Bohai Bay,Songliao and Jianghan basins and the North and South Yellow Sea basins,are dominated by a two-layer hydrocarbon generation mode,which performs as“upper oil and lower gas”.Third,the central hydrocarbon zones,including the Ordos,Sichuan and Chuxiong basins,are also dominated by the“upper oil and lower gas”two-layer hydrocarbon generation mode.In the Ordos Basin,gas is mainly generated in the Triassic,and oil is predominantly generated in the Paleozoic.In the Sichuan Basin,oil was discovered in the Jurassic,and gas was mostly discovered in the Sinian and Triassic.Fourth,the western hydrocarbon zones are dominated by a“sandwich”multi-layer mode,such as the Junggar,Tarim,Qaidam basins.In summary,the theory of co-control of source and heat will be widely applied to oil and gas exploration all over China.Oil targets should be focused on the near shore areas in the southeastern China sea,the upper strata in the eastern and middle hydrocarbon zones,and the Ordovician,Permian and Paleogene strata in the western hydrocarbon zone,while gas targets should be focused on the off-shore areas in the southeastern China sea,the Cambrian,Carboniferous,Jurassic,and Quaternary strata in the western hydrocarbon zone.A pattern of exploring gasfields under or outside oilfields and oilfields under or outside gasfields is presented.Therefore,there is still a great prospect for oil and gas exploration in China.
基金Supported by The Hong Kong Polytechnic University internal grants(G-UC14 and G-YBB4)
文摘The effects of different carbon sources(sugars) on the production and molecular properties of exopolysaccharides(EPS) were evaluated in the mycelial liquid culture of a medicinal fungus Cordyceps sinensis Cs-HK1. Galactose or mannose was used(at 5 g·L^(-1)) as a secondary carbon source with glucose(35 g·L^(-1)) at the mass ratio of 1:7. Mannose was consumed notably since the first day of culture, but galactose was not even after glucose was exhausted.The volumetric yield of EPS in culture was increased slightly with the addition of galactose and decreased with mannose. The monosaccharide composition of EPS was also different, e.g., on day 8, the glucose contents of EPS were 76%with the addition of mannose, 59% with galactose, compared with 62% with glucose only. The molecular weight distribution of EPS was also affected by the secondary carbon source, being generally lower compared with that with glucose only. The results suggested that the addition of galactose improved the total yield of EPS in culture while mannose can improve the yield of glucan constituent of EPS.
基金supported by the Chinese National Science Funding Council (No. 20807002, 20307006)the National Basic Research Program of China (No. 2011CB503801)
文摘To investigate the levels of exposure to particulate-bound polycyclic aromatic hydrocarbon （PAH） and to estimate the risk these levels pose to traffic assistants （TAs） in Tianjin （a rnegacity in North China）, a measurement campaign （33 all-day exposure samples, 25 occupational-exposure samples and 10 indoor samples） was conducted to characterize the TAs＇ exposure to PAHs, assess the cancer risk and identify the potential sources of exposure. The average total exposure concentration of 14 PAHs was approximately 2871 ＋ 928 ng/rn3 （on-duty）, and 1622 ＋ 457 ng/m3 （all-day）. The indoor PAHs level was 1257 ＋ 107 ng/m3. After 8000 Monte Carlo simulations, the cancer risk resulting from exposure to PAHs was found to be approximately 1.05 x 10-4. A multivariate analysis was applied to identify the potential sources, and the results showed that, in addition to vehicle exhaust, coal combustion and cooking fumes were also another two important contributors to personal PAH exposure. The diagnostic ratios of PAH compounds agree with the source apportionment results derived from principal component analysis.
基金supported by the National Key Research and Development Project(No.2019YFA0708601)the National Natural Science Foundation of China(No.4231101056)the Chinese Academy of Geological Sciences Basic Research Fund(No.JKYZD202402)。
文摘0 INTRODUTION The Kuqa Depression,situated along the northern margin of the Tarim Basin,holds substantial geological significance due to its intricate sedimentary burial history,tectonic history,and the evolution of hydrocarbon source rocks(Jiang et al.,2024;Zhang et al.,2023;Huang et al.,2019;Yang et al.,2017;Jia et al.,2003;Hendrix,2000).
基金supported by the National Natural Science Foundation of China(Nos.41872150,42230310)the Joint Funds of National Natural Science Foundation of China(Grant No.U19B6003)。
文摘Paleofluid-rock interaction results in the modification of the ultra-deep reservoir quality,but the coupling effects of the paleofluid evolution on reservoir quality modification are still underestimated.Here,the multi-stage dolomite cements have been studied by means of core observations,thin section identification,fluid inclusions,and in situ elements and isotopic analyses in order to reaveal the paleofluid evolution processes and their effects on the reservoir quality.The fibrous dolomite cement(FDC)and bladed dolomite cement(BDC)both have similar geochemical properties and homogenization temperature(Th)to the matrix dolostone.Subsequent early silicification occurs(QZ1).However,silt-to fine-sized crystalline dolomite cement(CD2)has higher concentration of Fe and medium rare earth element,more negativeδ^(18)O than for FDC and BDC,and 103.4-150.2℃in Th.The first petroleum charge episode solid bitumen 1(SB1)followed the CD2.The medium to coarse sized crystalline dolomite cement(CD3)is characterized by the higher Mn and lower Sr concentration than CD2,positiveδEu anomaly,negativeδ^(13)C andδ^(18)O,high^(87)Sr/^(86)Sr ratio and 138.9℃-184.3℃in Th.The solid bitumen 2(SB2)occurs after CD3.Subsequently,the saddle dolomite(SD)has higher Fe and Mn concentration and lower Na and Sr than others cement,δEu positive anomaly,negativeδ^(13)C andδ^(18)O,high ^(87)Sr/^(86)Sr ratio and 177.5℃-243.6℃in Th.Eventually massive silicification(QZ2)took place.The FDC,BDC,QZ1 and SB1 formed in the early diagenetic stage and have little negative effect on the reservoir quality.But the CD2 and CD3 dramatically decreased the reservoir quality related to a quantity of hydrothermal fluids entrance in the mesodiagenetic stage along the strike-slip faults and the unconformity surface at top of the Deng-2 Member during the late stage of the Caledonian orogeny.The reservoir spaces were retained and enlarged during the late diagenetic stage when the peak petroleum charge occurred,massive silicification and thermochemical sulfate reduction took place with SB2,SD and QZ2 being formed.The research outcome may update our understanding on the retention mechanism and the insights for further hydrocarbon exploration of Precambrian ultra-deep microbial reservoirs.
基金supported by the SINOPEC project (G0800-06-ZS-319)the National Natural Science Foundation of China (No. 40531004)
文摘The marine primary producers assimilate the atmospheric CO2 to form the organic carbon in surface water. The organic carbon then settles down through the water column and is removed from the oceans by final preservation in sediments in the form of petroleum or nature gases. The reconstruction of paleoproductivity will thus improve our understanding of the biological processes in the formation of fossil energy resource and help to locate new sites for future exploration. In this study, biorelated elements P, Cd, Al, Ba, as well as redox sensitive element Mo, were analyzed in the 448 rock samples collected from Permian strata at the Shangsi （上寺） Section, Guangyuan （广元）, Northeast Sichuan （四川） in China. On the basis of the Ti content, the nondetrital contents of P, Ca, and Al, denoted as Pxs, Cdxs, and Alxs, were calculated and found to coincide with the TOC content throughout the whole section, with some enrichment intervals being found in the middle part of Chihsia Formation, topmost Maokou （茅口） Formation, and Dalong （大隆） Formation. This suggests that the biorelated elements could he used as proxies for the paleoproductivity here in this section. Baxs, a paleoproductivity indicator widely used in the paleoceanography, shows insignificant correlation with TOC, Pxs, Cdxs, and Alxs, probably arising from the loss of biological barium in anoxic conditions. Compiled with the data of TOC content and Pxs, Cdxs, and Alxs, three episodes of enhanced paleoproductivity were identified in Permian strata including the middle part of Chihsia Formation, topmost Maokou Formation, and Dalong Formation.
基金supported by the CNPC Science and Technology Study Financing Project (EDR/CN-01-102)
文摘The present paper mainly studies the petroleum system of the Sufyan Depression in the Muglad Basin of central Africa and analyzes its control of hydrocarbon accumulation. On the basis of comprehensive analysis of effective source rock, reservoir bed types and source-reservoir-seal assemblages, petroleum system theory has been used to classify the petroleum system of the Sufyan Depression. Vertically, the Sufyan Depression consists of two subsystems. One is an Abu Gabra subsystem as a self generating, accumulating and sealing assemblage. The other subsystem is composed of an Abu Gabra source rock, Bentiu channel sandstone reservoir and Darfur group shale seal, which is a prolific assemblage in this area. Laterally, the Sufyan Depression is divided into eastern and western parts with separate hydrocarbon generation centers more than 10 000 m deep. The potential of the petroleum system is tremendous. Recently, there has been a great breakthrough in exploration. The Sufyan C-1 well drilled in the central structural belt obtained high-yielding oil flow exceeding 100 tons per day and controlled geologic reserves of tens of millions of tons. The total resource potential of the Sufyan Depression is considerable. The central structural belt is most favorable as an exploration and development prospect.
基金supported by the CNPC Science and Technology Study Financing Project (No. EDR/CN-01-102)
文摘Petroleum system theory has been used to study characteristics of the Fula depression in the Central African fault zone.In this system,deep lacustrine facies mudstone in the Abu Gabra For-mation of the Lower Cretaceous is a very good source rock,thick deltaic facies sandstone of the Abu Gabra Formation and fluvial facies sandstone of the Bentiu Formation are good reservoir beds,and the mudstone in the Upper Cretaceous Darfur Group is the regional cap rock.The oil search mode and fault block trap seal-off conditions are considered here for passive rift basins.Particularly with respect to oil source rock distribution,successive development of reverse fault block and faulted anticlinal traps on low relief structures could have accumulated hydrocarbons because of lateral sealing by down-thrown mudstone along the up-dipping reservoir beds.At present,discoveries in this system are all large-duty oil fields.In 2009,proved reserves exceeded 2×108 t,and about 3×106 t annual throughput of crude oil was obtained.Risk exploration of the Fula depression is of short cycle and high benefit,which will be of great help for exploration in the Muglad basin.
