In order to address environmental pollution and resource depletion caused by traditional power generation,this paper proposes an adaptive iterative dynamic-balance optimization algorithm that integrates the Improved D...In order to address environmental pollution and resource depletion caused by traditional power generation,this paper proposes an adaptive iterative dynamic-balance optimization algorithm that integrates the Improved Dung Beetle Optimizer(IDBO)with VariationalMode Decomposition(VMD).The IDBO-VMD method is designed to enhance the accuracy and efficiency of wind-speed time-series decomposition and to effectively smooth photovoltaic power fluctuations.This study innovatively improves the traditional variational mode decomposition(VMD)algorithm,and significantly improves the accuracy and adaptive ability of signal decomposition by IDBO selfoptimization of key parameters K and a.On this basis,Fourier transform technology is used to define the boundary point between high frequency and low frequency signals,and a targeted energy distribution strategy is proposed:high frequency fluctuations are allocated to supercapacitors to quickly respond to transient power fluctuations;Lowfrequency components are distributed to lead-carbon batteries,optimizing long-term energy storage and scheduling efficiency.This strategy effectively improves the response speed and stability of the energy storage system.The experimental results demonstrate that the IDBO-VMD algorithm markedly outperforms traditional methods in both decomposition accuracy and computational efficiency.Specifically,it effectively reduces the charge–discharge frequency of the battery,prolongs battery life,and optimizes the operating ranges of the state-of-charge(SOC)for both leadcarbon batteries and supercapacitors.In addition,the energy management strategy based on the algorithm not only improves the overall energy utilization efficiency of the system,but also shows excellent performance in the dynamic management and intelligent scheduling of renewable energy generation.展开更多
Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains...Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.展开更多
Multi-label feature selection(MFS)is a crucial dimensionality reduction technique aimed at identifying informative features associated with multiple labels.However,traditional centralized methods face significant chal...Multi-label feature selection(MFS)is a crucial dimensionality reduction technique aimed at identifying informative features associated with multiple labels.However,traditional centralized methods face significant challenges in privacy-sensitive and distributed settings,often neglecting label dependencies and suffering from low computational efficiency.To address these issues,we introduce a novel framework,Fed-MFSDHBCPSO—federated MFS via dual-layer hybrid breeding cooperative particle swarm optimization algorithm with manifold and sparsity regularization(DHBCPSO-MSR).Leveraging the federated learning paradigm,Fed-MFSDHBCPSO allows clients to perform local feature selection(FS)using DHBCPSO-MSR.Locally selected feature subsets are encrypted with differential privacy(DP)and transmitted to a central server,where they are securely aggregated and refined through secure multi-party computation(SMPC)until global convergence is achieved.Within each client,DHBCPSO-MSR employs a dual-layer FS strategy.The inner layer constructs sample and label similarity graphs,generates Laplacian matrices to capture the manifold structure between samples and labels,and applies L2,1-norm regularization to sparsify the feature subset,yielding an optimized feature weight matrix.The outer layer uses a hybrid breeding cooperative particle swarm optimization algorithm to further refine the feature weight matrix and identify the optimal feature subset.The updated weight matrix is then fed back to the inner layer for further optimization.Comprehensive experiments on multiple real-world multi-label datasets demonstrate that Fed-MFSDHBCPSO consistently outperforms both centralized and federated baseline methods across several key evaluation metrics.展开更多
The hybridization gap in strained-layer InAs/In_(x)Ga_(1−x) Sb quantum spin Hall insulators(QSHIs)is significantly enhanced compared to binary InAs/GaSb QSHI structures,where the typical indium composition,x,ranges be...The hybridization gap in strained-layer InAs/In_(x)Ga_(1−x) Sb quantum spin Hall insulators(QSHIs)is significantly enhanced compared to binary InAs/GaSb QSHI structures,where the typical indium composition,x,ranges between 0.2 and 0.4.This enhancement prompts a critical question:to what extent can quantum wells(QWs)be strained while still preserving the fundamental QSHI phase?In this study,we demonstrate the controlled molecular beam epitaxial growth of highly strained-layer QWs with an indium composition of x=0.5.These structures possess a substantial compressive strain within the In_(0.5)Ga_(0.5)Sb QW.Detailed crystal structure analyses confirm the exceptional quality of the resulting epitaxial films,indicating coherent lattice structures and the absence of visible dislocations.Transport measurements further reveal that the QSHI phase in InAs/In_(0.5)Ga_(0.5)Sb QWs is robust and protected by time-reversal symmetry.Notably,the edge states in these systems exhibit giant magnetoresistance when subjected to a modest perpendicular magnetic field.This behavior is in agreement with the𝑍2 topological property predicted by the Bernevig–Hughes–Zhang model,confirming the preservation of topologically protected edge transport in the presence of enhanced bulk strain.展开更多
To enhance power flow regulation in scenarios involving large-scale renewable energy transmission via high-voltage direct current(HVDC)links and multi-infeed DC systems in load-center regions,this paper proposes a hyb...To enhance power flow regulation in scenarios involving large-scale renewable energy transmission via high-voltage direct current(HVDC)links and multi-infeed DC systems in load-center regions,this paper proposes a hybrid modular multilevel converter–capacitor-commutated line-commutated converter(MMC-CLCC)HVDC transmission system and its corresponding control strategy.First,the system topology is constructed,and a submodule configuration method for the MMC—combining full-bridge submodules(FBSMs)and half-bridge submodules(HBSMs)—is proposed to enable direct power flow reversal.Second,a hierarchical control strategy is introduced,includingMMCvoltage control,CLCC current control,and a coordinationmechanism,along with the derivation of the hybrid system’s power flow reversal characteristics.Third,leveraging the CLCC’s fast current regulation and theMMC’s negative voltage control capability,a coordinated power flow reversal control strategy is developed.Finally,an 800 kV MMC-CLCC hybrid HVDC system is modeled in PSCAD/EMTDC to validate the power flow reversal performance under a high proportion of full-bridge submodule configuration.Results demonstrate that the proposed control strategy enables rapid(1-s transition)and smooth switching of bidirectional power flow without modifying the structure of primary equipment:the transient fluctuation ofDC voltage from the rated value(UdcN)to themaximumreverse voltage(-kUdcN)is less than 5%;the DC current strictly follows the preset characteristic curve with a deviation of≤3%;the active power reverses continuously,and the system maintains stable operation throughout the reversal process.展开更多
Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effecti...Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.展开更多
Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longe...Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.展开更多
The new energy power generation is becoming increasingly important in the power system.Such as photovoltaic power generation has become a research hotspot,however,due to the characteristics of light radiation changes,...The new energy power generation is becoming increasingly important in the power system.Such as photovoltaic power generation has become a research hotspot,however,due to the characteristics of light radiation changes,photovoltaic power generation is unstable and random,resulting in a low utilization rate and directly affecting the stability of the power grid.To solve this problem,this paper proposes a coordinated control strategy for a newenergy power generation system with a hybrid energy storage unit based on the lithium iron phosphate-supercapacitor hybrid energy storage unit.Firstly,the variational mode decomposition algorithm is used to separate the high and low frequencies of the power signal,which is conducive to the rapid and accurate suppression of the power fluctuation of the energy storage system.Secondly,the fuzzy control algorithm is introduced to balance the power between energy storage.In this paper,the actual data is used for simulation,and the simulation results show that the strategy realizes the effective suppression of the bus voltage fluctuation and the accurate control of the internal state of the energy storage unit,effectively avoiding problems such as overshoot and over-discharge,and can significantly improve the stability of the photovoltaic power generation systemand the stability of the Direct Current bus.It is of great significance to promote the development of collaborative control technology for photovoltaic hybrid energy storage units.展开更多
Power quality is a crucial area of research in contemporary power systems,particularly given the rapid proliferation of intermittent renewable energy sources such as wind power.This study investigated the relationship...Power quality is a crucial area of research in contemporary power systems,particularly given the rapid proliferation of intermittent renewable energy sources such as wind power.This study investigated the relationships between power quality indices of system output and PSD by utilizing theories related to spectra,PSD,and random signal power spectra.The relationship was derived,validated through experiments and simulations,and subsequently applied to multi-objective optimization.Various optimization algorithms were compared to achieve optimal system power quality.The findings revealed that the relationships between power quality indices and PSD were influenced by variations in the order of the power spectral estimation model.An increase in the order of the AR model resulted in a 36%improvement in the number of optimal solutions.Regarding optimal solution distribution,NSGA-II demonstrated superior diversity,while MOEA/D exhibited better convergence.However,practical applications showed that while MOEA/D had higher convergence,NSGA-II produced superior optimal solutions,achieving the best power quality indices(THDi at 4.62%,d%at 3.51%,and cosφat 96%).These results suggest that the proposed method holds significant potential for optimizing power quality in practical applications.展开更多
3D printing technology enhances the combustion characteristics of hybrid rocket fuels by enabling complex geometries. However, improvements in regression rates and energy properties of monotonous 3D printed fuels have...3D printing technology enhances the combustion characteristics of hybrid rocket fuels by enabling complex geometries. However, improvements in regression rates and energy properties of monotonous 3D printed fuels have been limited. This study explores the impact of poly(vinylidene fluoride) and polydopamine-coated aluminum particles on the thermal and combustion properties of 3D printed hybrid rocket fuels. Physical self-assembly and anti-solvent methods were employed for constructing composite μAl particles. Characterization using SEM, XRD, XPS, FTIR, and μCT revealed a core-shell structure and homogeneous elemental distribution. Thermal analysis showed that PVDF coatings significantly increased the heat of combustion for aluminum particles, with maximum enhancement observed in μAl@PDA@PVDF(denoted as μAl@PF) at 6.20 k J/g. Subsequently, 3D printed fuels with varying pure and composite μAl particle contents were prepared using 3D printing. Combustion tests indicated higher regression rates for Al@PF/Resin composites compared to pure resin, positively correlating with particle content. The fluorocarbon-alumina reaction during the combustion stage intensified Al particle combustion, reducing residue size. A comprehensive model based on experiments provides insights into the combustion process of PDA and PVDF-coated droplets. This study advances the design of 3D-printed hybrid rocket fuels, offering strategies to improve regression rates and energy release, crucial for enhancing solid fuel performance for hybrid propulsion.展开更多
Graphite-silicon species(Gr-Si)hybrid anodes have merged as potential candidates for high-energy lithium-ion batteries(LIBs),yet long been plagued by rapid capacity fading due to their unstable mechano-electrochemistr...Graphite-silicon species(Gr-Si)hybrid anodes have merged as potential candidates for high-energy lithium-ion batteries(LIBs),yet long been plagued by rapid capacity fading due to their unstable mechano-electrochemistry.The dominant approach to enhance electrochemical stability of the Gr-Si hybrid anodes typically involves the optimization of the electrode material structures and the employment of low active Si species content in electrode(<10 wt%in most instances).However,the electrode structure design,a factor of equal importance in determining the electrochemical performance of Gr-Si hybrid anodes,has received scant attention.In this study,three Gr-Si hybrid anodes with the identical material composition but distinct electrode structures are designed to investigate the mechanoelectrochemistry of the electrodes.It is revealed that the substantial volume change of Si species particles in Gr-Si hybrid anodes led to the local lattice stress of Gr at their contact interface during the charge/discharge processes,thereby increasing thermodynamic and kinetic barrier of Li-ion migration.Furthermore,the huge disparity in volume change of Si species and Gr particles trigger the separate agglomeration of these two materials,resulting in a considerable electrode volume change and increased electrochemical resistance.An advanced Gr/Si hybrid anode with upper Gr and lower Si species layer structure design addresses the above challenges using photovoltaic waste silicon sources under high Si species content(17 wt%)and areal capacity(2.0 mA h cm^(-2))in Ah-level full pouch cells with a low negative/positive(N/P)ratio of 1.09.The cell shows stable cycling for 100 cycles at 0.3 C with an impressively low capacity decay rate of 0.0546%per cycle,outperforming most reported Gr-Si hybrid anodes.展开更多
Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic de-vices.Neve...Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic de-vices.Nevertheless,employing PEDOT:PSS in supercapacitors(SC)in its pristine state presents challenges due to its suboptimal electrochemical performance and operational instability.To surmount these limita-tions,PEDOT:PSS has been integrated with carbon-based materials to form flexible electrodes,which ex-hibit physical and chemical stability during SC operation.We developed a streamlined fabrication process for high-performance SC electrodes composed of PEDOT:PSS and carbon quantum dots(CQDs).The CQDs were synthesized under microwave irradiation,yielding green-and red-light emissions.Through optimiz-ing the ratios of CQDs to PEDOT:PSS,the SC electrodes were prepared using a spray-coating technique,marking a significant improvement in device performance with a high volumetric capacitance(104.10 F cm-3),impressive energy density(19.68 Wh cm^(-3)),and excellent cyclic stability,retaining~85% of its original volumetric capacitance after 15,000 repeated GCD cycles.Moreover,the SCs,when utilized as a flexible substrate,demonstrated the ability to maintain up to~85% of their electrochemical performance even after 3,000 bending cycles(at a bending angle of 60°).These attributes render this hybrid composite an ideal candidate for a lightweight smart energy storage component in portable and wearable electronic technologies.展开更多
Laser twin-arc GTAW(LTA-GTAW)process has been developed by using the synergic interaction effects of laser and a coupled arc in a weld pool to achieve higher energy efficiency.In this study,bead-on-plate welding was c...Laser twin-arc GTAW(LTA-GTAW)process has been developed by using the synergic interaction effects of laser and a coupled arc in a weld pool to achieve higher energy efficiency.In this study,bead-on-plate welding was conducted on 8-mm-thick Q235B work-pieces to investigate the variation of hybrid arc profile,the influence of hybrid arc profile on weld forming,microstructure and mech-anical properties of the joint during the LTA-GTAW process.The influence of Laser-GTAW and LTA-GTAW methods on weld surface appearance,heat input per unit length,and weld metal microstructure were also demonstrated systematically.The LTA-GTAW can make the distribution of arc energy more reasonable in welding depth and width.When defocus is 0,I_(f)is 330 A,I_(b)is 240 A,laser power is 2.4 kW,and spacing between heat sources of tungsten electrode is 10 mm,the weld shape is better.Compared with Laser-GTAW,LTA-GTAW can achieve lower heat input at the same penetration depth,and the microstructure of the weld is refined.The tensile strength of the welded joint is 121.8%of the base material,and the fracture mode of the welded joint is ductile fracture,the comprehensive mechanical properties are better.展开更多
基金funded by the Institute of Smart Energy,Huaiyin Institute of Technology,under Grant No.HIT-ISE-2024-07.
文摘In order to address environmental pollution and resource depletion caused by traditional power generation,this paper proposes an adaptive iterative dynamic-balance optimization algorithm that integrates the Improved Dung Beetle Optimizer(IDBO)with VariationalMode Decomposition(VMD).The IDBO-VMD method is designed to enhance the accuracy and efficiency of wind-speed time-series decomposition and to effectively smooth photovoltaic power fluctuations.This study innovatively improves the traditional variational mode decomposition(VMD)algorithm,and significantly improves the accuracy and adaptive ability of signal decomposition by IDBO selfoptimization of key parameters K and a.On this basis,Fourier transform technology is used to define the boundary point between high frequency and low frequency signals,and a targeted energy distribution strategy is proposed:high frequency fluctuations are allocated to supercapacitors to quickly respond to transient power fluctuations;Lowfrequency components are distributed to lead-carbon batteries,optimizing long-term energy storage and scheduling efficiency.This strategy effectively improves the response speed and stability of the energy storage system.The experimental results demonstrate that the IDBO-VMD algorithm markedly outperforms traditional methods in both decomposition accuracy and computational efficiency.Specifically,it effectively reduces the charge–discharge frequency of the battery,prolongs battery life,and optimizes the operating ranges of the state-of-charge(SOC)for both leadcarbon batteries and supercapacitors.In addition,the energy management strategy based on the algorithm not only improves the overall energy utilization efficiency of the system,but also shows excellent performance in the dynamic management and intelligent scheduling of renewable energy generation.
基金financially supported by the National Natural Science Foundation of China(Nos.22272118,22172111,and 22309134)the Science and Technology Commission of Shanghai Municipality,China(Nos.22ZR1464100,20ZR1460300,and 19DZ2271500)+2 种基金the China Postdoctoral Science Foundation(2022M712402),the Shanghai Rising-Star Program(23YF1449200)the Zhejiang Provincial Science and Technology Project(2022C01182)the Fundamental Research Funds for the Central Universities(2023-3-YB-07)。
文摘Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.
文摘Multi-label feature selection(MFS)is a crucial dimensionality reduction technique aimed at identifying informative features associated with multiple labels.However,traditional centralized methods face significant challenges in privacy-sensitive and distributed settings,often neglecting label dependencies and suffering from low computational efficiency.To address these issues,we introduce a novel framework,Fed-MFSDHBCPSO—federated MFS via dual-layer hybrid breeding cooperative particle swarm optimization algorithm with manifold and sparsity regularization(DHBCPSO-MSR).Leveraging the federated learning paradigm,Fed-MFSDHBCPSO allows clients to perform local feature selection(FS)using DHBCPSO-MSR.Locally selected feature subsets are encrypted with differential privacy(DP)and transmitted to a central server,where they are securely aggregated and refined through secure multi-party computation(SMPC)until global convergence is achieved.Within each client,DHBCPSO-MSR employs a dual-layer FS strategy.The inner layer constructs sample and label similarity graphs,generates Laplacian matrices to capture the manifold structure between samples and labels,and applies L2,1-norm regularization to sparsify the feature subset,yielding an optimized feature weight matrix.The outer layer uses a hybrid breeding cooperative particle swarm optimization algorithm to further refine the feature weight matrix and identify the optimal feature subset.The updated weight matrix is then fed back to the inner layer for further optimization.Comprehensive experiments on multiple real-world multi-label datasets demonstrate that Fed-MFSDHBCPSO consistently outperforms both centralized and federated baseline methods across several key evaluation metrics.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences (Grant Nos.XDB28000000 and XDB0460000)the Quantum Science and Technology-National Science and Technology Major Project (Grant No.2021ZD0302600)the National Key Research and Development Program of China(Grant No.2024YFA1409002)。
文摘The hybridization gap in strained-layer InAs/In_(x)Ga_(1−x) Sb quantum spin Hall insulators(QSHIs)is significantly enhanced compared to binary InAs/GaSb QSHI structures,where the typical indium composition,x,ranges between 0.2 and 0.4.This enhancement prompts a critical question:to what extent can quantum wells(QWs)be strained while still preserving the fundamental QSHI phase?In this study,we demonstrate the controlled molecular beam epitaxial growth of highly strained-layer QWs with an indium composition of x=0.5.These structures possess a substantial compressive strain within the In_(0.5)Ga_(0.5)Sb QW.Detailed crystal structure analyses confirm the exceptional quality of the resulting epitaxial films,indicating coherent lattice structures and the absence of visible dislocations.Transport measurements further reveal that the QSHI phase in InAs/In_(0.5)Ga_(0.5)Sb QWs is robust and protected by time-reversal symmetry.Notably,the edge states in these systems exhibit giant magnetoresistance when subjected to a modest perpendicular magnetic field.This behavior is in agreement with the𝑍2 topological property predicted by the Bernevig–Hughes–Zhang model,confirming the preservation of topologically protected edge transport in the presence of enhanced bulk strain.
基金supported by Science and Technology Project of the headquarters of the State Grid Corporation of China(No.5500-202324492A-3-2-ZN).
文摘To enhance power flow regulation in scenarios involving large-scale renewable energy transmission via high-voltage direct current(HVDC)links and multi-infeed DC systems in load-center regions,this paper proposes a hybrid modular multilevel converter–capacitor-commutated line-commutated converter(MMC-CLCC)HVDC transmission system and its corresponding control strategy.First,the system topology is constructed,and a submodule configuration method for the MMC—combining full-bridge submodules(FBSMs)and half-bridge submodules(HBSMs)—is proposed to enable direct power flow reversal.Second,a hierarchical control strategy is introduced,includingMMCvoltage control,CLCC current control,and a coordinationmechanism,along with the derivation of the hybrid system’s power flow reversal characteristics.Third,leveraging the CLCC’s fast current regulation and theMMC’s negative voltage control capability,a coordinated power flow reversal control strategy is developed.Finally,an 800 kV MMC-CLCC hybrid HVDC system is modeled in PSCAD/EMTDC to validate the power flow reversal performance under a high proportion of full-bridge submodule configuration.Results demonstrate that the proposed control strategy enables rapid(1-s transition)and smooth switching of bidirectional power flow without modifying the structure of primary equipment:the transient fluctuation ofDC voltage from the rated value(UdcN)to themaximumreverse voltage(-kUdcN)is less than 5%;the DC current strictly follows the preset characteristic curve with a deviation of≤3%;the active power reverses continuously,and the system maintains stable operation throughout the reversal process.
文摘Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.
基金supported by a Horizontal Project on the Development of a Hybrid Energy Storage Simulation Model for Wind Power Based on an RT-LAB Simulation System(PH2023000190)the Inner Mongolia Natural Science Foundation Project and the Optimization of Exergy Efficiency of a Hybrid Energy Storage System with Crossover Control for Wind Power(2023JQ04).
文摘Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.
基金supported by the State Grid Corporation of China Science and Technology Project,grant number 52270723000900K.
文摘The new energy power generation is becoming increasingly important in the power system.Such as photovoltaic power generation has become a research hotspot,however,due to the characteristics of light radiation changes,photovoltaic power generation is unstable and random,resulting in a low utilization rate and directly affecting the stability of the power grid.To solve this problem,this paper proposes a coordinated control strategy for a newenergy power generation system with a hybrid energy storage unit based on the lithium iron phosphate-supercapacitor hybrid energy storage unit.Firstly,the variational mode decomposition algorithm is used to separate the high and low frequencies of the power signal,which is conducive to the rapid and accurate suppression of the power fluctuation of the energy storage system.Secondly,the fuzzy control algorithm is introduced to balance the power between energy storage.In this paper,the actual data is used for simulation,and the simulation results show that the strategy realizes the effective suppression of the bus voltage fluctuation and the accurate control of the internal state of the energy storage unit,effectively avoiding problems such as overshoot and over-discharge,and can significantly improve the stability of the photovoltaic power generation systemand the stability of the Direct Current bus.It is of great significance to promote the development of collaborative control technology for photovoltaic hybrid energy storage units.
基金funded by the Inner Mongolia Nature Foundation Project,Project number:2023JQ04.
文摘Power quality is a crucial area of research in contemporary power systems,particularly given the rapid proliferation of intermittent renewable energy sources such as wind power.This study investigated the relationships between power quality indices of system output and PSD by utilizing theories related to spectra,PSD,and random signal power spectra.The relationship was derived,validated through experiments and simulations,and subsequently applied to multi-objective optimization.Various optimization algorithms were compared to achieve optimal system power quality.The findings revealed that the relationships between power quality indices and PSD were influenced by variations in the order of the power spectral estimation model.An increase in the order of the AR model resulted in a 36%improvement in the number of optimal solutions.Regarding optimal solution distribution,NSGA-II demonstrated superior diversity,while MOEA/D exhibited better convergence.However,practical applications showed that while MOEA/D had higher convergence,NSGA-II produced superior optimal solutions,achieving the best power quality indices(THDi at 4.62%,d%at 3.51%,and cosφat 96%).These results suggest that the proposed method holds significant potential for optimizing power quality in practical applications.
基金funded by the National Natural Science Foundation of China(Grant No.06101213)the National Natural Science Foundation of China(Grant No.22105160).
文摘3D printing technology enhances the combustion characteristics of hybrid rocket fuels by enabling complex geometries. However, improvements in regression rates and energy properties of monotonous 3D printed fuels have been limited. This study explores the impact of poly(vinylidene fluoride) and polydopamine-coated aluminum particles on the thermal and combustion properties of 3D printed hybrid rocket fuels. Physical self-assembly and anti-solvent methods were employed for constructing composite μAl particles. Characterization using SEM, XRD, XPS, FTIR, and μCT revealed a core-shell structure and homogeneous elemental distribution. Thermal analysis showed that PVDF coatings significantly increased the heat of combustion for aluminum particles, with maximum enhancement observed in μAl@PDA@PVDF(denoted as μAl@PF) at 6.20 k J/g. Subsequently, 3D printed fuels with varying pure and composite μAl particle contents were prepared using 3D printing. Combustion tests indicated higher regression rates for Al@PF/Resin composites compared to pure resin, positively correlating with particle content. The fluorocarbon-alumina reaction during the combustion stage intensified Al particle combustion, reducing residue size. A comprehensive model based on experiments provides insights into the combustion process of PDA and PVDF-coated droplets. This study advances the design of 3D-printed hybrid rocket fuels, offering strategies to improve regression rates and energy release, crucial for enhancing solid fuel performance for hybrid propulsion.
基金the financial support by the National Natural Science Foundation of China(52072137)the National Natural Science Foundation of China(22205068)the"CUG Scholar"Scientific Research Funds at China University of Geosciences(Wuhan)(2022118)。
文摘Graphite-silicon species(Gr-Si)hybrid anodes have merged as potential candidates for high-energy lithium-ion batteries(LIBs),yet long been plagued by rapid capacity fading due to their unstable mechano-electrochemistry.The dominant approach to enhance electrochemical stability of the Gr-Si hybrid anodes typically involves the optimization of the electrode material structures and the employment of low active Si species content in electrode(<10 wt%in most instances).However,the electrode structure design,a factor of equal importance in determining the electrochemical performance of Gr-Si hybrid anodes,has received scant attention.In this study,three Gr-Si hybrid anodes with the identical material composition but distinct electrode structures are designed to investigate the mechanoelectrochemistry of the electrodes.It is revealed that the substantial volume change of Si species particles in Gr-Si hybrid anodes led to the local lattice stress of Gr at their contact interface during the charge/discharge processes,thereby increasing thermodynamic and kinetic barrier of Li-ion migration.Furthermore,the huge disparity in volume change of Si species and Gr particles trigger the separate agglomeration of these two materials,resulting in a considerable electrode volume change and increased electrochemical resistance.An advanced Gr/Si hybrid anode with upper Gr and lower Si species layer structure design addresses the above challenges using photovoltaic waste silicon sources under high Si species content(17 wt%)and areal capacity(2.0 mA h cm^(-2))in Ah-level full pouch cells with a low negative/positive(N/P)ratio of 1.09.The cell shows stable cycling for 100 cycles at 0.3 C with an impressively low capacity decay rate of 0.0546%per cycle,outperforming most reported Gr-Si hybrid anodes.
基金supported by the National Research Foundation of Korea(NRF)through a grant provided by the Korean government(No.NRF-2021R1F1A1063451).
文摘Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)is a highly successful conductive polymer utilized as an electrode material in energy storage units for portable and wearable electronic de-vices.Nevertheless,employing PEDOT:PSS in supercapacitors(SC)in its pristine state presents challenges due to its suboptimal electrochemical performance and operational instability.To surmount these limita-tions,PEDOT:PSS has been integrated with carbon-based materials to form flexible electrodes,which ex-hibit physical and chemical stability during SC operation.We developed a streamlined fabrication process for high-performance SC electrodes composed of PEDOT:PSS and carbon quantum dots(CQDs).The CQDs were synthesized under microwave irradiation,yielding green-and red-light emissions.Through optimiz-ing the ratios of CQDs to PEDOT:PSS,the SC electrodes were prepared using a spray-coating technique,marking a significant improvement in device performance with a high volumetric capacitance(104.10 F cm-3),impressive energy density(19.68 Wh cm^(-3)),and excellent cyclic stability,retaining~85% of its original volumetric capacitance after 15,000 repeated GCD cycles.Moreover,the SCs,when utilized as a flexible substrate,demonstrated the ability to maintain up to~85% of their electrochemical performance even after 3,000 bending cycles(at a bending angle of 60°).These attributes render this hybrid composite an ideal candidate for a lightweight smart energy storage component in portable and wearable electronic technologies.
基金supported by the Industrial Innovation Major Technology Global Unveiling Project of Jining City(2022JBZP004)Taishan Scholars Project.
文摘Laser twin-arc GTAW(LTA-GTAW)process has been developed by using the synergic interaction effects of laser and a coupled arc in a weld pool to achieve higher energy efficiency.In this study,bead-on-plate welding was conducted on 8-mm-thick Q235B work-pieces to investigate the variation of hybrid arc profile,the influence of hybrid arc profile on weld forming,microstructure and mech-anical properties of the joint during the LTA-GTAW process.The influence of Laser-GTAW and LTA-GTAW methods on weld surface appearance,heat input per unit length,and weld metal microstructure were also demonstrated systematically.The LTA-GTAW can make the distribution of arc energy more reasonable in welding depth and width.When defocus is 0,I_(f)is 330 A,I_(b)is 240 A,laser power is 2.4 kW,and spacing between heat sources of tungsten electrode is 10 mm,the weld shape is better.Compared with Laser-GTAW,LTA-GTAW can achieve lower heat input at the same penetration depth,and the microstructure of the weld is refined.The tensile strength of the welded joint is 121.8%of the base material,and the fracture mode of the welded joint is ductile fracture,the comprehensive mechanical properties are better.