The hot compression deformation behavior of Mg-6Zn-1Mn-0.5Ca(ZM61-0.5Ca)and Mg-6Zn-1Mn-2Sn-0.5Ca(ZMT612-0.5Ca)alloys was investigated at deformation temperatures ranging from 250℃to 400℃and strain rates varying from...The hot compression deformation behavior of Mg-6Zn-1Mn-0.5Ca(ZM61-0.5Ca)and Mg-6Zn-1Mn-2Sn-0.5Ca(ZMT612-0.5Ca)alloys was investigated at deformation temperatures ranging from 250℃to 400℃and strain rates varying from 0.001 s^(-1) to 1 s^(-1).The results show that the addition of Sn promotes dynamic recrystallization(DRX),and CaMgSn phases can act as nucleation sites during the compression deformation.Flow stress increases with increasing the strain rate and decreasing the temperature.Both the ZM61-0.5Ca and ZMT612-0.5Ca alloys exhibit obvious DRX characteristics.CaMgSn phases can effectively inhibit dislocation motion with the addition of Sn,thus increasing the peak fl ow stress of the alloy.The addition of Sn increases the hot deformation activation energy of the ZM61-0.5Ca alloy from 199.654 kJ/mol to 276.649 kJ/mol,thus improving the thermal stability of the alloy.For the ZMT612-0.5Ca alloy,the optimal hot deformation parameters are determined to be a deformation temperature range of 350–400℃and a strain rate range of 0.001–0.01 s^(-1).展开更多
Cast aluminum(Al)alloys,owing to their low density and high specific strength,offer significant advantages in the fabrication of complex,large-scale,or monolithic structural components across civilian,defense,and mili...Cast aluminum(Al)alloys,owing to their low density and high specific strength,offer significant advantages in the fabrication of complex,large-scale,or monolithic structural components across civilian,defense,and military sectors that are weight-sensitive,including transportation,aerospace,and underwater weaponry.However,a substantial portion of these alloys often exhibit pronounced hot tearing susceptibility(HTS)during casting,which not only detrimentally affects the quality and efficiency of industrial production but also limits their further development in high-tech applications.Therefore,a comprehensive and profound understanding of hot tearing behavior in cast Al alloys is essential.This review first analyzes the formation mechanisms of hot tearing,encompassing strength theory,liquid film theory,intergranular bridging theory,solidification shrinkage compensation theory,and relevant models,as well as the key factors governing its occurrence,including alloy composition,grain structure,casting parameters,and inclusions.It then introduces current research methods,ranging from simple evaluation and physical parameter-based approaches to in situ observation and numerical simulation,followed by a summary of newly proposed hot tearing criteria.Finally,it discusses the remaining scientific challenges and outlines future research directions.Particular emphasis is placed on recent advances in the hot tearing of cast Al alloys over the past decade.展开更多
Inconel 625 alloy components were fabricated using hot wire laser metal deposition(HW-LMD)through process optimization,achieving a wire deposition rate of 1.72 kg/h.The microstructure and mechanical properties of the ...Inconel 625 alloy components were fabricated using hot wire laser metal deposition(HW-LMD)through process optimization,achieving a wire deposition rate of 1.72 kg/h.The microstructure and mechanical properties of the HW-LMD Inconel 625 alloys were systematically investigated.The results revealed that the microstructure of the HWLMD Inconel 625 alloys consisted of columnar dendrites,characterized by an average grain size of 12.5μm and a strong{100}〈001〉texture.The main phase identified wasγ-Ni,with the precipitation of Laves phase,measuring less than 1μm,observed in the inter-columnar dendritic regions.The average microhardness of the HW-LMD Inconel 625 alloys was HV1.0258.The yield strength and ultimate tensile strength were 493.5 and 837.4 MPa,respectively,with elongation exceeding 50%.Impact absorbing energies at 25 and-78℃were 223.08 and 200.24 J,respectively.Both the tensile and impact fracture surfaces exhibited dimples,indicating a ductile fracture mechanism during the deformation process.展开更多
The widespread application of aluminum silicon coatings in hot-stamping steel can be attributed to their exceptional heat resistance and oxidation resilience.However,alterations in the diffusion behavior of aluminum s...The widespread application of aluminum silicon coatings in hot-stamping steel can be attributed to their exceptional heat resistance and oxidation resilience.However,alterations in the diffusion behavior of aluminum silicon coatings during the heating process,such as coating corrosion and welding,considerably affect the ultimate performance of components post hot stamping.This study scrutinized the distinctive behaviors exhibited by two typical coatings,namely 30/30 and 75/75 coatings,throughout the heat treatment process and their consequential effects on welding and other inherent properties of typical components.Our investigation unveiled the heightened susceptibility of the 30/30 coating to the development of pinhole leakage defects on the surface compared with the 75/75 coating.Moreover,the diffusion rate of the 30/30 coating surpassed that of the 75/75 coating.This discrepancy holds significance as it influences welding processes,coating corrosion resistance,and attainable heat treatment windows.展开更多
The western Los Angeles(LA)wildfires of early January 2025 caused catastrophic social and environmental impacts,drawing widespread attention.This study investigates the characteristics of these wildfires and quantifie...The western Los Angeles(LA)wildfires of early January 2025 caused catastrophic social and environmental impacts,drawing widespread attention.This study investigates the characteristics of these wildfires and quantifies the influence of heat and drought on their likelihood using a copula-based Bayesian probability framework.The wildfires were characterized by burned area(BA)and intensity(fire radiative power,FRP).The criteria establishing the presence of“hot drought”conditions were identified using the 5-day Standardized Temperature Index(STI)and 75-day Standardized Precipitation Index(SPI),respectively.The wildfire outbreak began on 7 January 2025 and burned for more than six days,with the total burned area exceeding 245 km^(2) and the cumulative FRP exceeding 41060 MW.Based on satellite-derived active fire observations from 2001 to 2025,we estimate that such large and intense wildfires during LA’s rainy season represent a once-in-a-67-year event.The wildfires were largely driven by the combination of hot and dry conditions,which dried out soils and vegetation that had proliferated due to above-average precipitation in previous winter seasons,thereby providing abundant fuel.Our seasonal analysis reveals that extreme drought increased the probability of wildfires matching the 2025 intensity and BA by 54%and 75%,respectively.Hot drought further amplified these probabilities by 149%(intensity)and 210%(BA).These findings suggest an elevated risk of large wildfires under hot drought conditions,contributing to their expansion into the non-traditional fire season.展开更多
Under the background of achieving energy efficiency and carbon reduction,the use of Continuous Casting-Direct Hot Charging Rolling(CC-DHCR)technology was explored at the Hot Rolling Plant of Baosteel,China.As temperat...Under the background of achieving energy efficiency and carbon reduction,the use of Continuous Casting-Direct Hot Charging Rolling(CC-DHCR)technology was explored at the Hot Rolling Plant of Baosteel,China.As temperature variation and temperature uniformity directly affect the rolling quality of the billet,numerical simulations of the billet temperature profile changes in the CC-DHCR were conducted at the start of the industrial trial,and the billet temperature distribution and cross-section temperature difference during its transportation and throughout the heating process were analyzed.According to numerical simulation calculations,the average temperature of billet discharged from the heating furnace was 1150℃,which after subsequent controlled cooling met the final rolling temperature requirements of(880±30)℃for this kind of steel.The maximum temperature difference of the billet discharged from the furnace was within 35 K,which meets the billet heating uniformity requirements of the rolling process.The simulation results were compared with experimental results,and the rationality of the simulation was validated.In addition,the industrial trial billet was rolled,and the rolling quality was good during tracking.In this CC-DHCR industrial trial,the fuel consumption was 28.6 kgce/t(kilogram coal equivalent per ton),a reduction of 33.7%compared with the current traditional process,and CO 2 emissions were reduced by 38.09 kg/t.展开更多
The available heat content (stored heat energy) of hot dry rock (HDR) at a depth of 1–10 km in the global land crust is estimated to be 5.06×10~8 EJ,attracting considerable global attention.This paper presents a...The available heat content (stored heat energy) of hot dry rock (HDR) at a depth of 1–10 km in the global land crust is estimated to be 5.06×10~8 EJ,attracting considerable global attention.This paper presents a comprehensive analysis of the geological framework,HDR resource potential,exploration advancements,and the development of enhanced geothermal systems (EGSs) in China.HDR resources are extensively distributed across China.Within the depth range of 3–10 km,China’s estimated potential approximates2.29×10~7 EJ,with a theoretical power generation capacity of approximately 1.67×10^(16) k Wh.Replacing coal power with HDR can help to achieve a net emission reduction of 1.34×10^(16) kg CO_(2) (approximately1.34×10^(13) t),representing an emission reduction efficiency of 94.4%.Based on a development cycle of100 years,the average annual emission reduction reaches 1.34×10^(10) t CO_(2),equivalent to 117%of China’s annual carbon emissions in 2022.Furthermore,in the context of global warming,the development and utilization of HDR,which is feasible in virtually any region worldwide,offers significant potential to support global carbon reduction efforts.China has made substantial progress in HDR exploration in recent years.This paper systematically classifies China’s HDR resources into four genetic types—highly radioactive heat-producing,sedimentary basin,active volcanic,and intensely tectonic zones—and offers detailed exploration insights for each category.Each classification exhibits distinct geological and tectonic characteristics that influence heat source mechanisms and resource distribution.Furthermore,this paper documents significant advances in EGS construction,particularly in the Gonghe Basin on the northeastern margin of the Qianghai-Xizang Plateau and the Matouying uplift in the North China Basin,where successful reservoir stimulation,microseismic monitoring,and experimental power generation have been achieved.Despite these developments,challenges persist,including technical adaptability under complex geological conditions and the economic viability of large-scale HDR development.This paper suggests that future initiatives should emphasize resource exploration,technological research,and policy support to foster sustainable HDR resource development in China,thereby contributing to the global energy transition and environmental sustainability.展开更多
The microstructures and mechanical properties of Al-8.3Zn-3.3Cu-2.2Mg alloys prepared via hot extrusion and liquid forging methods were investigated.Results show that based on DEFORM simulation analysis,the optimal ho...The microstructures and mechanical properties of Al-8.3Zn-3.3Cu-2.2Mg alloys prepared via hot extrusion and liquid forging methods were investigated.Results show that based on DEFORM simulation analysis,the optimal hot extrusion parameters are determined as ingot initial temperature of 380°C and extrusion speed of 3 mm/s.The hot-extruded aluminum alloy after T6 heat treatment presents superior mechanical properties with yield strength of 519.6 MPa,ultimate tensile strength of 582.1 MPa,and elongation of 11.0%.Compared with the properties of gravity-cast and liquid-forged alloys,the yield strength of hot-extruded alloy increases by 30.8%and 4.9%,and the ultimate tensile strength improves by 43.5%and 10.2%,respectively.The significant improvement in tensile strength of the hot-extruded alloys is attributed to the elimination of casting defects and the refinement of matrix grain and eutectic phases.In addition,the hot-extruded alloy demonstrates superior plasticity compared with the liquid-forged alloy.This is because severe plastic deformation occurs during hot extrusion,which effectively breaks and disperses the eutectic phases,facilitating the dissolution and precipitation of the second phases and inhibiting the microcrack initiation.展开更多
To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0....To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0.27%to 0.22%,enabling the elements Mo and Ti to diffuse fully and to distribute more uniformly,and to forming a substantial number of low-angle grain boundaries.The tensile strength soars from 286±32 MPa to 598±22 MPa,while the elongation increases from 0.08%±0.02%to 0.18%±0.02%,without notable alterations in grain morphology during the tensile deformation.HIP treatment eliminates the molten pool boundaries,which are the primary source for premature failure in LPBFed Mo alloys.Consequently,HIP treatment emerges as a novel and effective approach for strengthening the mechanical properties of LPBFed Mo alloys,offering a fresh perspective on producing high-performance Mo-based alloys.展开更多
Theβsolidifiedγ-TiAl alloy holds important application value in the aerospace industry,while its com-plex phase compositions and geometric structures pose challenges to its microstructure control during the thermal-...Theβsolidifiedγ-TiAl alloy holds important application value in the aerospace industry,while its com-plex phase compositions and geometric structures pose challenges to its microstructure control during the thermal-mechanical process.The microstructure evolution of Ti-43Al-4Nb-1Mo-0.2B alloy at 1200℃/0.01 s−1 was investigated to clarify the coupling role of dynamic recrystallization(DRX)and phase transformation.The results revealed that the rate of DRX inα2+γlamellar colonies was comparatively slower than that inβo+γmixed structure,instead being accompanied by intense lamellar kinking and rotation.The initiation and development rates of DRX inα2,βo,andγphases decreased sequentially.The asynchronous DRX of the various geometric structures and phase compositions resulted in the un-even deformed microstructure,and the dynamic softening induced by lamellar kinking and rotation was replaced by strengthened DRX as strain increased.Additionally,the blockyα2 phase and the terminals ofα2 lamellae were the preferential DRX sites owing to the abundant activated slip systems.Theα2→βo transformation within lamellar colonies facilitated DRX and fragment ofα2 lamellae,while theα2→γtransformation promoted the decomposition ofα2 lamellae and DRX ofγlamellae.Moreover,the var-iedβo+γmixed structures underwent complicated evolution:(1)Theγ→βo transformation occurred at boundaries of lamellar colonies,followed by simultaneous DRX ofγlamellar terminals and neighboringβo phase;(2)DRX occurred earlier within the band-likeβo phase,with the delayed DRX in enclosedγphase;(3)DRX within theβo synapses and neighboringγphase was accelerated owing to generation of elastic stress field;(4)Dispersedβo particles triggered particle stimulated nucleation(PSN)ofγphase.Eventually,atomic diffusion along crystal defects inβo andγphases caused fracture of band-likeβo phase and formation of massiveβo particles,impeding grain boundary migration and hindering DRXed grain growth ofγphase.展开更多
Hot deformation with high strain rate has been paid more attention due to its high efficiency and low cost,however,the strain rate dependent dynamic recrystallization(DRX)and texture evolution in hot deformation proce...Hot deformation with high strain rate has been paid more attention due to its high efficiency and low cost,however,the strain rate dependent dynamic recrystallization(DRX)and texture evolution in hot deformation process,which affect the formability of metals,are lack of study.In this work,the DRX behavior and texture evolution of Mg-8Gd-1Er-0.5Zr alloy hot compressed with strain rates of 0.1 s^(−1),1 s^(−1),10 s^(−1) and 50 s^(−1) are studied,and the corresponding dominant mechanisms for DRX and texture weakening are discussed.Results indicated the DRX fraction was 20%and the whole texture intensity was 16.89 MRD when the strain rate was 0.1 s^(−1),but they were 76%and 6.55 MRD,respectively,when the strain rate increased to 50 s^(−1).The increment of DRX fraction is suggested to result from the reduced DRX critical strain and the increased dislocation density as well as velocity,while the weakened whole texture is attributed to the increased DRX grains.At the low strain rate of 0.1 s^(−1),discontinuous DRX(DDRX)was the dominant,but the whole texture was controlled by the deformed grains with the preferred orientation of{0001}⊥CD,because the number of DDRX grains was limited.At the high strain rate of 50 s^(−1),continuous DRX(CDRX)and twin-induced DRX(TDRX)were promoted,and more DRX grains resulted in orientation randomization.The whole texture was mainly weakened by CDRX and TDRX grains,in which CDRX plays a major role.The results of present work are significant for understanding the hot workability of Mg-RE alloys with a high strain rate.展开更多
Hot isostatic pressing (HIP) temperature has a significant impact on the service performance of powder metallurgy titanium alloys. In this study, a high-temperature titanium alloy, Ti-6.5Al-3.5Mo-1.5Zr-0.3Si, was prep...Hot isostatic pressing (HIP) temperature has a significant impact on the service performance of powder metallurgy titanium alloys. In this study, a high-temperature titanium alloy, Ti-6.5Al-3.5Mo-1.5Zr-0.3Si, was prepared under different HIP temperatures (880–1000℃), and the microstructural evolution and mechanical properties were systematically investigated. The results demonstrated that the HIPed alloys were predominantly composed of more than 80 vol.% α phase and a small amount of β phase, and their phase compositions were basically unaffected by the HIP temperatures. Under the typical single-temperature-maintained HIP (STM-HIP) regime, the microstructure of alloy significantly coarsened as the HIP temperature increased, and the alloy strength exhibited an obvious linear negative correlation with the HIP temperature. On the basis of Hall–Petch relation, the prediction model of grain size was established, and the mathematical equation between HIP temperature and grain size (d=M(T_(HIP-N)^(-2))) was deduced. Furthermore, a possible evolution mechanism of microstructure was proposed, which could be divided into the decomposition of initial α′ martensite for as-received powder, formation of the globular α grains in prior particle boundaries (PPBs) region, and precipitation of the platelet α grains in non-PPBs region. For these alloys prepared by the dual-temperature-maintained HIP (DTM-HIP) regime, although their tensile properties were comparable to that of alloy prepared by STM-HIP regime with same high-temperature holding stage, higher proportion of globular α grains occurred due to more recrystallization nucleation during the low-temperature holding stage, which probably provided a solution for improving the dynamic service performance of HIPed alloys.展开更多
An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of t...An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of the internal variables were considered in this ISV model,and the parameters were optimized by genetic algorithm.After validation,the ISV model was used to simulate the evolution of grain size(GS)and dynamic recrystallization(DRX)fraction during hot spinning via Abaqus and its subroutine Vumat.By comparing the simulated results with the experimental results,the application of the ISV model was proven to be reliable.Meanwhile,the strength of the thin-walled spun ZK61 tube increased from 303 to 334 MPa due to grain refinement by DRX and texture strengthening.Besides,some ultrafine grains(0.5μm)that played an important role in mechanical properties were formed due to the proliferation,movement,and entanglement of dislocations during the spinning process.展开更多
The microstructure,mechanical properties,and corrosion resistance of as-cast Zr–Sn–Co ternary alloys have been investigated in this experiment.The properties of as-cast Zr–1.5Sn–xCo(x=0,2.5,5,7.5,and 10 at.%)terna...The microstructure,mechanical properties,and corrosion resistance of as-cast Zr–Sn–Co ternary alloys have been investigated in this experiment.The properties of as-cast Zr–1.5Sn–xCo(x=0,2.5,5,7.5,and 10 at.%)ternary alloys were investigated,and the alloy composition exhibiting the best comprehensive performance was identified.Subsequently,the chosen alloys were subjected to hot rolling treatment.The microstructure of the alloys in the rolled state was analyzed using the optical microscope,X-ray diffractometer,and scanning electron microscope.The mechanical properties of the alloys were analyzed using room temperature compression tests and microhardness tests,while the corrosion properties of the alloy were investigated through electrochemical testing.The results show that the strength of as-cast Zr–1.5Sn–Co ternary alloy increases significantly with the increase in Co content.The incorporation of Co element makes the corrosion resistance of as-cast Zr–1.5Sn–Co alloy increase significantly.The hot rolling treatment has minimal effect on enhancing the corrosion resistance of Zr–1.5Sn–2.5Co alloy.However,the mechanical properties of Zr–1.5Sn–2.5Co alloy after rolling treatment are significantly enhanced.The alloy exhibits the highest strength and hardness at a rolling temperature of 600℃ and exhibits the best plasticity at a rolling temperature of 800℃.展开更多
China has abundant resources of hot dry rocks.However,due to the fact that the evaluation methods for favorable areas are mainly qualitative,and the evaluation indicators and standards are inconsistent,which restrict ...China has abundant resources of hot dry rocks.However,due to the fact that the evaluation methods for favorable areas are mainly qualitative,and the evaluation indicators and standards are inconsistent,which restrict the evaluation efficiency and exploration process of dry hot rocks.This paper is based on the understanding of the geologic features and genesis mechanisms of hot dry rocks in China and abroad.By integrating the main controlling factors of hot dry rock formation,and using index grading and quantification,the fuzzy hierarchical comprehensive method is applied to establish an evaluation system and standards for favorable areas of hot dry rocks.The evaluation system is based on four indicators:heat source,thermal channel,thermal reservoir and cap rock.It includes 11 evaluation parameters,including time of magmatic/volcanic activity,depth of molten mass or magma chamber,distribution of discordogenic faults,burial depth of thermal reservoir,cap rock type and thickness,surface thermal anomaly,heat flow,geothermal gradient,Moho depth,Curie depth,Earthquake magnitude and focal depth.Each parameter is divided into 3 levels.Applying this evaluation system to assess hot dry rock in central Inner Mongolia revealed that Class I favorable zones cover approximately 494 km^(2),while Class II favorable zones span about 5.7×10^(4) km^(2).The Jirgalangtu Sag and Honghaershute Sag in the Erlian Basin,along with Reshuitang Town in Keshiketeng Banner,Reshui Town in Ningcheng County,and Reshuitang Town in Aohan Banner of Chifeng City,are identified as Class I favorable zones for hot dry rock resources.These areas are characterized by high-temperature subsurface molten bodies or magma chambers serving as high-quality heat sources,shallow thermal reservoir depths,and overlying thick sedimentary rock layers acting as caprock.The establishment and application of the evaluation system for favorable areas of hot dry rock are expected to provide new approaches and scientific basis for guiding the practice of selecting hot dry rock areas in China.展开更多
The effects of varying strain rates and deformation temperatures on the microstructure evolution of the FGH4113A alloy were investigated through hot compression experiments.During hot deformation,grain evolution is pr...The effects of varying strain rates and deformation temperatures on the microstructure evolution of the FGH4113A alloy were investigated through hot compression experiments.During hot deformation,grain evolution is primarily governed by dynamic recrystallization(DRX)and twinning primarily.Furthermore,the pinning effect of the primaryγ'phase(γ'p phase)plays a crucial role in grain refinement.Lower strain rates or higher temperatures facilitate DRX,twinning,and the dissolution of theγ'p phase.At 1140℃,significant dissolution of theγ'p phase and the subsequent loss of its pinning effect reduce twinning activity.A unique twinning mechanism,termed“pinning twinning”,is identified,occurring exclusively under the influence of the pinning effect.When grain boundary migration fails to accommodate dislocations due to the pinning effect,grains preferentially eliminate dislocations via twinning,thereby reducing local strain energy.The grain size prediction model is improved by considering the pinning effect.展开更多
The influence of Nb-V microalloying on the hot deformation behavior and microstructures of medium Mn steel(MMS)was investigated by uniaxial hot compression tests.By establishing the constitutive equations for simulati...The influence of Nb-V microalloying on the hot deformation behavior and microstructures of medium Mn steel(MMS)was investigated by uniaxial hot compression tests.By establishing the constitutive equations for simulating the measured flow curves,we successfully constructed deformation activation energy(Q)maps and processing maps for identifying the region of flow instability.We concluded the following consequences of Nb-V alloying for MMS.(i)The critical strain increases and the increment diminishes with the increasing deformation temperature,suggesting that NbC precipitates more efficiently retard dynamic recrystallization(DRX)in MMS compared with solute Nb.(ii)The deformation activation energy of MMS is significantly increased and even higher than that of some reported high Mn steels,suggesting that its ability to retard DRX is greater than that of the high Mn content.(iii)The hot workability of MMS is improved by narrowing the hot processing window for the unstable flow stress,in which fine recrystallized and coarse unrecrystallized grains are present.展开更多
The overall heat transfer coefficient(OHTC)of rock fractures is a fundamental parameter for characterizing the heat transfer behavior of rock fractures in hot dry rock(HDR)geothermal mining.Although a number of practi...The overall heat transfer coefficient(OHTC)of rock fractures is a fundamental parameter for characterizing the heat transfer behavior of rock fractures in hot dry rock(HDR)geothermal mining.Although a number of practical formulae for heat transfer coefficients have been developed in the literature,there is still no widely accepted analytical solution.This paper constructs highly accurate analytical solutions for the temperatures of the inner fracture wall and the fluid.Then they are employed to develop new definition-based formulae(formula A and its simplification formula B)of the OHTC,which are well validated by the experimental and numerical simulation results.An empirical correlation formula of heat transfer coefficient is proposed based on the definition-based formulae which can be directly used in the numerical simulations of heat transfer in rock fractures.A site-scale application example of numerical simulation also demonstrates the effectiveness of the empirical correlation formula.展开更多
基金Sichuan Science and Technology Program(2025ZNSFSC1341)Fundamental Research Funds for the Central Universities(J2022-090,25CAFUC04087)。
文摘The hot compression deformation behavior of Mg-6Zn-1Mn-0.5Ca(ZM61-0.5Ca)and Mg-6Zn-1Mn-2Sn-0.5Ca(ZMT612-0.5Ca)alloys was investigated at deformation temperatures ranging from 250℃to 400℃and strain rates varying from 0.001 s^(-1) to 1 s^(-1).The results show that the addition of Sn promotes dynamic recrystallization(DRX),and CaMgSn phases can act as nucleation sites during the compression deformation.Flow stress increases with increasing the strain rate and decreasing the temperature.Both the ZM61-0.5Ca and ZMT612-0.5Ca alloys exhibit obvious DRX characteristics.CaMgSn phases can effectively inhibit dislocation motion with the addition of Sn,thus increasing the peak fl ow stress of the alloy.The addition of Sn increases the hot deformation activation energy of the ZM61-0.5Ca alloy from 199.654 kJ/mol to 276.649 kJ/mol,thus improving the thermal stability of the alloy.For the ZMT612-0.5Ca alloy,the optimal hot deformation parameters are determined to be a deformation temperature range of 350–400℃and a strain rate range of 0.001–0.01 s^(-1).
基金financially supported by the National Natural Science Foundation of China(No.52475380)the inaugural Young Elite Scientists Sponsorship Program(Doctoral Student Special Plan)of the China Association for Science and Technology(CAST)。
文摘Cast aluminum(Al)alloys,owing to their low density and high specific strength,offer significant advantages in the fabrication of complex,large-scale,or monolithic structural components across civilian,defense,and military sectors that are weight-sensitive,including transportation,aerospace,and underwater weaponry.However,a substantial portion of these alloys often exhibit pronounced hot tearing susceptibility(HTS)during casting,which not only detrimentally affects the quality and efficiency of industrial production but also limits their further development in high-tech applications.Therefore,a comprehensive and profound understanding of hot tearing behavior in cast Al alloys is essential.This review first analyzes the formation mechanisms of hot tearing,encompassing strength theory,liquid film theory,intergranular bridging theory,solidification shrinkage compensation theory,and relevant models,as well as the key factors governing its occurrence,including alloy composition,grain structure,casting parameters,and inclusions.It then introduces current research methods,ranging from simple evaluation and physical parameter-based approaches to in situ observation and numerical simulation,followed by a summary of newly proposed hot tearing criteria.Finally,it discusses the remaining scientific challenges and outlines future research directions.Particular emphasis is placed on recent advances in the hot tearing of cast Al alloys over the past decade.
基金supported by the Special Project of Gansu Province,China(Nos.23ZDGA010,22ZD6GA008)the Central Guiding Fund for Local Science and Technology Development Project,China(Nos.24ZYQA054,23ZYQA308)the Key Project of Research and Innovation in Universities,China(No.2024CXPT-06)。
文摘Inconel 625 alloy components were fabricated using hot wire laser metal deposition(HW-LMD)through process optimization,achieving a wire deposition rate of 1.72 kg/h.The microstructure and mechanical properties of the HW-LMD Inconel 625 alloys were systematically investigated.The results revealed that the microstructure of the HWLMD Inconel 625 alloys consisted of columnar dendrites,characterized by an average grain size of 12.5μm and a strong{100}〈001〉texture.The main phase identified wasγ-Ni,with the precipitation of Laves phase,measuring less than 1μm,observed in the inter-columnar dendritic regions.The average microhardness of the HW-LMD Inconel 625 alloys was HV1.0258.The yield strength and ultimate tensile strength were 493.5 and 837.4 MPa,respectively,with elongation exceeding 50%.Impact absorbing energies at 25 and-78℃were 223.08 and 200.24 J,respectively.Both the tensile and impact fracture surfaces exhibited dimples,indicating a ductile fracture mechanism during the deformation process.
基金supported by Research Institute(R&D Center)of Baosteel.The flat model test received support from Shanghai University and Baosteel High-tech Parts Company.
文摘The widespread application of aluminum silicon coatings in hot-stamping steel can be attributed to their exceptional heat resistance and oxidation resilience.However,alterations in the diffusion behavior of aluminum silicon coatings during the heating process,such as coating corrosion and welding,considerably affect the ultimate performance of components post hot stamping.This study scrutinized the distinctive behaviors exhibited by two typical coatings,namely 30/30 and 75/75 coatings,throughout the heat treatment process and their consequential effects on welding and other inherent properties of typical components.Our investigation unveiled the heightened susceptibility of the 30/30 coating to the development of pinhole leakage defects on the surface compared with the 75/75 coating.Moreover,the diffusion rate of the 30/30 coating surpassed that of the 75/75 coating.This discrepancy holds significance as it influences welding processes,coating corrosion resistance,and attainable heat treatment windows.
基金supported by the National Natural Science Foundation of China(Grant Nos.42471034,42330604)the Qing Lan Projectsupport from the National Key Scientific and Technological Infrastructure project“Earth System Numerical Simulation Facility”(EarthLab).
文摘The western Los Angeles(LA)wildfires of early January 2025 caused catastrophic social and environmental impacts,drawing widespread attention.This study investigates the characteristics of these wildfires and quantifies the influence of heat and drought on their likelihood using a copula-based Bayesian probability framework.The wildfires were characterized by burned area(BA)and intensity(fire radiative power,FRP).The criteria establishing the presence of“hot drought”conditions were identified using the 5-day Standardized Temperature Index(STI)and 75-day Standardized Precipitation Index(SPI),respectively.The wildfire outbreak began on 7 January 2025 and burned for more than six days,with the total burned area exceeding 245 km^(2) and the cumulative FRP exceeding 41060 MW.Based on satellite-derived active fire observations from 2001 to 2025,we estimate that such large and intense wildfires during LA’s rainy season represent a once-in-a-67-year event.The wildfires were largely driven by the combination of hot and dry conditions,which dried out soils and vegetation that had proliferated due to above-average precipitation in previous winter seasons,thereby providing abundant fuel.Our seasonal analysis reveals that extreme drought increased the probability of wildfires matching the 2025 intensity and BA by 54%and 75%,respectively.Hot drought further amplified these probabilities by 149%(intensity)and 210%(BA).These findings suggest an elevated risk of large wildfires under hot drought conditions,contributing to their expansion into the non-traditional fire season.
文摘Under the background of achieving energy efficiency and carbon reduction,the use of Continuous Casting-Direct Hot Charging Rolling(CC-DHCR)technology was explored at the Hot Rolling Plant of Baosteel,China.As temperature variation and temperature uniformity directly affect the rolling quality of the billet,numerical simulations of the billet temperature profile changes in the CC-DHCR were conducted at the start of the industrial trial,and the billet temperature distribution and cross-section temperature difference during its transportation and throughout the heating process were analyzed.According to numerical simulation calculations,the average temperature of billet discharged from the heating furnace was 1150℃,which after subsequent controlled cooling met the final rolling temperature requirements of(880±30)℃for this kind of steel.The maximum temperature difference of the billet discharged from the furnace was within 35 K,which meets the billet heating uniformity requirements of the rolling process.The simulation results were compared with experimental results,and the rationality of the simulation was validated.In addition,the industrial trial billet was rolled,and the rolling quality was good during tracking.In this CC-DHCR industrial trial,the fuel consumption was 28.6 kgce/t(kilogram coal equivalent per ton),a reduction of 33.7%compared with the current traditional process,and CO 2 emissions were reduced by 38.09 kg/t.
基金supported by the National Key Research and Development Program of China (2021YFB1507401)Qinghai Province Clean Energy Minerals Special Project(2022013004qj004)Geological Survey Project of China Geological Survey (DD20221676, DD20230019)。
文摘The available heat content (stored heat energy) of hot dry rock (HDR) at a depth of 1–10 km in the global land crust is estimated to be 5.06×10~8 EJ,attracting considerable global attention.This paper presents a comprehensive analysis of the geological framework,HDR resource potential,exploration advancements,and the development of enhanced geothermal systems (EGSs) in China.HDR resources are extensively distributed across China.Within the depth range of 3–10 km,China’s estimated potential approximates2.29×10~7 EJ,with a theoretical power generation capacity of approximately 1.67×10^(16) k Wh.Replacing coal power with HDR can help to achieve a net emission reduction of 1.34×10^(16) kg CO_(2) (approximately1.34×10^(13) t),representing an emission reduction efficiency of 94.4%.Based on a development cycle of100 years,the average annual emission reduction reaches 1.34×10^(10) t CO_(2),equivalent to 117%of China’s annual carbon emissions in 2022.Furthermore,in the context of global warming,the development and utilization of HDR,which is feasible in virtually any region worldwide,offers significant potential to support global carbon reduction efforts.China has made substantial progress in HDR exploration in recent years.This paper systematically classifies China’s HDR resources into four genetic types—highly radioactive heat-producing,sedimentary basin,active volcanic,and intensely tectonic zones—and offers detailed exploration insights for each category.Each classification exhibits distinct geological and tectonic characteristics that influence heat source mechanisms and resource distribution.Furthermore,this paper documents significant advances in EGS construction,particularly in the Gonghe Basin on the northeastern margin of the Qianghai-Xizang Plateau and the Matouying uplift in the North China Basin,where successful reservoir stimulation,microseismic monitoring,and experimental power generation have been achieved.Despite these developments,challenges persist,including technical adaptability under complex geological conditions and the economic viability of large-scale HDR development.This paper suggests that future initiatives should emphasize resource exploration,technological research,and policy support to foster sustainable HDR resource development in China,thereby contributing to the global energy transition and environmental sustainability.
基金Natural Science Foundation of Shandong Province of China(ZR2023QE193)。
文摘The microstructures and mechanical properties of Al-8.3Zn-3.3Cu-2.2Mg alloys prepared via hot extrusion and liquid forging methods were investigated.Results show that based on DEFORM simulation analysis,the optimal hot extrusion parameters are determined as ingot initial temperature of 380°C and extrusion speed of 3 mm/s.The hot-extruded aluminum alloy after T6 heat treatment presents superior mechanical properties with yield strength of 519.6 MPa,ultimate tensile strength of 582.1 MPa,and elongation of 11.0%.Compared with the properties of gravity-cast and liquid-forged alloys,the yield strength of hot-extruded alloy increases by 30.8%and 4.9%,and the ultimate tensile strength improves by 43.5%and 10.2%,respectively.The significant improvement in tensile strength of the hot-extruded alloys is attributed to the elimination of casting defects and the refinement of matrix grain and eutectic phases.In addition,the hot-extruded alloy demonstrates superior plasticity compared with the liquid-forged alloy.This is because severe plastic deformation occurs during hot extrusion,which effectively breaks and disperses the eutectic phases,facilitating the dissolution and precipitation of the second phases and inhibiting the microcrack initiation.
基金National Natural Science Foundation of China(52105385)Stable Support Plan Program of Shenzhen Natural Science Fund(20220810132537001)+2 种基金Guangdong Basic and Applied Basic Research Foundation(2022A1515010781)Joint Fund of Henan Province Science and Technology R&D Program(225200810002)Fundamental Research Funds of Henan Academy of Sciences(240621041)。
文摘To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0.27%to 0.22%,enabling the elements Mo and Ti to diffuse fully and to distribute more uniformly,and to forming a substantial number of low-angle grain boundaries.The tensile strength soars from 286±32 MPa to 598±22 MPa,while the elongation increases from 0.08%±0.02%to 0.18%±0.02%,without notable alterations in grain morphology during the tensile deformation.HIP treatment eliminates the molten pool boundaries,which are the primary source for premature failure in LPBFed Mo alloys.Consequently,HIP treatment emerges as a novel and effective approach for strengthening the mechanical properties of LPBFed Mo alloys,offering a fresh perspective on producing high-performance Mo-based alloys.
基金financially supported by the National Key Re-search and Development Program of China(No.2021YFB3702604)the National Natural Science Foundation of China(No.52174377)+1 种基金the Chongqing Natural Science Foundation Project(No.CSTB2023NSCQ-MSX0824)This work was also supported by the Shaanxi Materials Analysis&Research Center and the Analytical&Testing Center of NPU.
文摘Theβsolidifiedγ-TiAl alloy holds important application value in the aerospace industry,while its com-plex phase compositions and geometric structures pose challenges to its microstructure control during the thermal-mechanical process.The microstructure evolution of Ti-43Al-4Nb-1Mo-0.2B alloy at 1200℃/0.01 s−1 was investigated to clarify the coupling role of dynamic recrystallization(DRX)and phase transformation.The results revealed that the rate of DRX inα2+γlamellar colonies was comparatively slower than that inβo+γmixed structure,instead being accompanied by intense lamellar kinking and rotation.The initiation and development rates of DRX inα2,βo,andγphases decreased sequentially.The asynchronous DRX of the various geometric structures and phase compositions resulted in the un-even deformed microstructure,and the dynamic softening induced by lamellar kinking and rotation was replaced by strengthened DRX as strain increased.Additionally,the blockyα2 phase and the terminals ofα2 lamellae were the preferential DRX sites owing to the abundant activated slip systems.Theα2→βo transformation within lamellar colonies facilitated DRX and fragment ofα2 lamellae,while theα2→γtransformation promoted the decomposition ofα2 lamellae and DRX ofγlamellae.Moreover,the var-iedβo+γmixed structures underwent complicated evolution:(1)Theγ→βo transformation occurred at boundaries of lamellar colonies,followed by simultaneous DRX ofγlamellar terminals and neighboringβo phase;(2)DRX occurred earlier within the band-likeβo phase,with the delayed DRX in enclosedγphase;(3)DRX within theβo synapses and neighboringγphase was accelerated owing to generation of elastic stress field;(4)Dispersedβo particles triggered particle stimulated nucleation(PSN)ofγphase.Eventually,atomic diffusion along crystal defects inβo andγphases caused fracture of band-likeβo phase and formation of massiveβo particles,impeding grain boundary migration and hindering DRXed grain growth ofγphase.
基金supported by the Nation Key Research and Development Program of China(No.2021YFB3701100).
文摘Hot deformation with high strain rate has been paid more attention due to its high efficiency and low cost,however,the strain rate dependent dynamic recrystallization(DRX)and texture evolution in hot deformation process,which affect the formability of metals,are lack of study.In this work,the DRX behavior and texture evolution of Mg-8Gd-1Er-0.5Zr alloy hot compressed with strain rates of 0.1 s^(−1),1 s^(−1),10 s^(−1) and 50 s^(−1) are studied,and the corresponding dominant mechanisms for DRX and texture weakening are discussed.Results indicated the DRX fraction was 20%and the whole texture intensity was 16.89 MRD when the strain rate was 0.1 s^(−1),but they were 76%and 6.55 MRD,respectively,when the strain rate increased to 50 s^(−1).The increment of DRX fraction is suggested to result from the reduced DRX critical strain and the increased dislocation density as well as velocity,while the weakened whole texture is attributed to the increased DRX grains.At the low strain rate of 0.1 s^(−1),discontinuous DRX(DDRX)was the dominant,but the whole texture was controlled by the deformed grains with the preferred orientation of{0001}⊥CD,because the number of DDRX grains was limited.At the high strain rate of 50 s^(−1),continuous DRX(CDRX)and twin-induced DRX(TDRX)were promoted,and more DRX grains resulted in orientation randomization.The whole texture was mainly weakened by CDRX and TDRX grains,in which CDRX plays a major role.The results of present work are significant for understanding the hot workability of Mg-RE alloys with a high strain rate.
基金support from CAS Project for Young Scientists in Basic Research(YSBR-025)and the Technology Innovation(RCJJ-145-24-39)R.P.Guo acknowledges the financial support from the National Natural Science Foundation of China(No.52401104)+1 种基金the Fundamental Research Program of Shanxi Province(No.202203021221072)the China Postdoctoral Science Foundation(No.2024M753298).
文摘Hot isostatic pressing (HIP) temperature has a significant impact on the service performance of powder metallurgy titanium alloys. In this study, a high-temperature titanium alloy, Ti-6.5Al-3.5Mo-1.5Zr-0.3Si, was prepared under different HIP temperatures (880–1000℃), and the microstructural evolution and mechanical properties were systematically investigated. The results demonstrated that the HIPed alloys were predominantly composed of more than 80 vol.% α phase and a small amount of β phase, and their phase compositions were basically unaffected by the HIP temperatures. Under the typical single-temperature-maintained HIP (STM-HIP) regime, the microstructure of alloy significantly coarsened as the HIP temperature increased, and the alloy strength exhibited an obvious linear negative correlation with the HIP temperature. On the basis of Hall–Petch relation, the prediction model of grain size was established, and the mathematical equation between HIP temperature and grain size (d=M(T_(HIP-N)^(-2))) was deduced. Furthermore, a possible evolution mechanism of microstructure was proposed, which could be divided into the decomposition of initial α′ martensite for as-received powder, formation of the globular α grains in prior particle boundaries (PPBs) region, and precipitation of the platelet α grains in non-PPBs region. For these alloys prepared by the dual-temperature-maintained HIP (DTM-HIP) regime, although their tensile properties were comparable to that of alloy prepared by STM-HIP regime with same high-temperature holding stage, higher proportion of globular α grains occurred due to more recrystallization nucleation during the low-temperature holding stage, which probably provided a solution for improving the dynamic service performance of HIPed alloys.
基金supported by the National Natural Science Foundation of China(No.51905123)Major Scientific and Technological Innovation Program of Shandong Province,China(Nos.2020CXGC010303,2022ZLGX04)Key R&D Programme of Shandong Province,China(No.2022JMRH0308).
文摘An internal state variable(ISV)model was established according to the experimental results of hot plane strain compression(PSC)to predict the microstructure evolution during hot spinning of ZK61 alloy.The effects of the internal variables were considered in this ISV model,and the parameters were optimized by genetic algorithm.After validation,the ISV model was used to simulate the evolution of grain size(GS)and dynamic recrystallization(DRX)fraction during hot spinning via Abaqus and its subroutine Vumat.By comparing the simulated results with the experimental results,the application of the ISV model was proven to be reliable.Meanwhile,the strength of the thin-walled spun ZK61 tube increased from 303 to 334 MPa due to grain refinement by DRX and texture strengthening.Besides,some ultrafine grains(0.5μm)that played an important role in mechanical properties were formed due to the proliferation,movement,and entanglement of dislocations during the spinning process.
基金supported by the National Natural Science Foundation of China(Grant No.52071126)the Natural Science Foundation of Tianjin City China(Grant No.22JCQNJC01240)+1 种基金the Central Guidance on Local Science and Technology Development Fund of Hebei Province(226Z1009G)the special funds for science and technology innovation in Hebei(2022X19).
文摘The microstructure,mechanical properties,and corrosion resistance of as-cast Zr–Sn–Co ternary alloys have been investigated in this experiment.The properties of as-cast Zr–1.5Sn–xCo(x=0,2.5,5,7.5,and 10 at.%)ternary alloys were investigated,and the alloy composition exhibiting the best comprehensive performance was identified.Subsequently,the chosen alloys were subjected to hot rolling treatment.The microstructure of the alloys in the rolled state was analyzed using the optical microscope,X-ray diffractometer,and scanning electron microscope.The mechanical properties of the alloys were analyzed using room temperature compression tests and microhardness tests,while the corrosion properties of the alloy were investigated through electrochemical testing.The results show that the strength of as-cast Zr–1.5Sn–Co ternary alloy increases significantly with the increase in Co content.The incorporation of Co element makes the corrosion resistance of as-cast Zr–1.5Sn–Co alloy increase significantly.The hot rolling treatment has minimal effect on enhancing the corrosion resistance of Zr–1.5Sn–2.5Co alloy.However,the mechanical properties of Zr–1.5Sn–2.5Co alloy after rolling treatment are significantly enhanced.The alloy exhibits the highest strength and hardness at a rolling temperature of 600℃ and exhibits the best plasticity at a rolling temperature of 800℃.
基金Supported by PetroChina Prospective and Basic Technological Project(2022DJ5503).
文摘China has abundant resources of hot dry rocks.However,due to the fact that the evaluation methods for favorable areas are mainly qualitative,and the evaluation indicators and standards are inconsistent,which restrict the evaluation efficiency and exploration process of dry hot rocks.This paper is based on the understanding of the geologic features and genesis mechanisms of hot dry rocks in China and abroad.By integrating the main controlling factors of hot dry rock formation,and using index grading and quantification,the fuzzy hierarchical comprehensive method is applied to establish an evaluation system and standards for favorable areas of hot dry rocks.The evaluation system is based on four indicators:heat source,thermal channel,thermal reservoir and cap rock.It includes 11 evaluation parameters,including time of magmatic/volcanic activity,depth of molten mass or magma chamber,distribution of discordogenic faults,burial depth of thermal reservoir,cap rock type and thickness,surface thermal anomaly,heat flow,geothermal gradient,Moho depth,Curie depth,Earthquake magnitude and focal depth.Each parameter is divided into 3 levels.Applying this evaluation system to assess hot dry rock in central Inner Mongolia revealed that Class I favorable zones cover approximately 494 km^(2),while Class II favorable zones span about 5.7×10^(4) km^(2).The Jirgalangtu Sag and Honghaershute Sag in the Erlian Basin,along with Reshuitang Town in Keshiketeng Banner,Reshui Town in Ningcheng County,and Reshuitang Town in Aohan Banner of Chifeng City,are identified as Class I favorable zones for hot dry rock resources.These areas are characterized by high-temperature subsurface molten bodies or magma chambers serving as high-quality heat sources,shallow thermal reservoir depths,and overlying thick sedimentary rock layers acting as caprock.The establishment and application of the evaluation system for favorable areas of hot dry rock are expected to provide new approaches and scientific basis for guiding the practice of selecting hot dry rock areas in China.
基金supported by the National Key Research and Development Program of China(No.2022YFB3706902)Innovation Project for Graduate Students of Hunan Province+1 种基金China(No.1053320212786)supported in part by the High Performance Computing Center of Central South University,China。
文摘The effects of varying strain rates and deformation temperatures on the microstructure evolution of the FGH4113A alloy were investigated through hot compression experiments.During hot deformation,grain evolution is primarily governed by dynamic recrystallization(DRX)and twinning primarily.Furthermore,the pinning effect of the primaryγ'phase(γ'p phase)plays a crucial role in grain refinement.Lower strain rates or higher temperatures facilitate DRX,twinning,and the dissolution of theγ'p phase.At 1140℃,significant dissolution of theγ'p phase and the subsequent loss of its pinning effect reduce twinning activity.A unique twinning mechanism,termed“pinning twinning”,is identified,occurring exclusively under the influence of the pinning effect.When grain boundary migration fails to accommodate dislocations due to the pinning effect,grains preferentially eliminate dislocations via twinning,thereby reducing local strain energy.The grain size prediction model is improved by considering the pinning effect.
基金financial support from the National Natural Science Foundation of China(Nos.52233018 and 51831002)the China Baowu Low Carbon Metallurgy Innovation Foudation(No.BWLCF202213)。
文摘The influence of Nb-V microalloying on the hot deformation behavior and microstructures of medium Mn steel(MMS)was investigated by uniaxial hot compression tests.By establishing the constitutive equations for simulating the measured flow curves,we successfully constructed deformation activation energy(Q)maps and processing maps for identifying the region of flow instability.We concluded the following consequences of Nb-V alloying for MMS.(i)The critical strain increases and the increment diminishes with the increasing deformation temperature,suggesting that NbC precipitates more efficiently retard dynamic recrystallization(DRX)in MMS compared with solute Nb.(ii)The deformation activation energy of MMS is significantly increased and even higher than that of some reported high Mn steels,suggesting that its ability to retard DRX is greater than that of the high Mn content.(iii)The hot workability of MMS is improved by narrowing the hot processing window for the unstable flow stress,in which fine recrystallized and coarse unrecrystallized grains are present.
基金support of this work by the National Natural Science Foundation of China (Grant Nos.41972316 and 41672252).
文摘The overall heat transfer coefficient(OHTC)of rock fractures is a fundamental parameter for characterizing the heat transfer behavior of rock fractures in hot dry rock(HDR)geothermal mining.Although a number of practical formulae for heat transfer coefficients have been developed in the literature,there is still no widely accepted analytical solution.This paper constructs highly accurate analytical solutions for the temperatures of the inner fracture wall and the fluid.Then they are employed to develop new definition-based formulae(formula A and its simplification formula B)of the OHTC,which are well validated by the experimental and numerical simulation results.An empirical correlation formula of heat transfer coefficient is proposed based on the definition-based formulae which can be directly used in the numerical simulations of heat transfer in rock fractures.A site-scale application example of numerical simulation also demonstrates the effectiveness of the empirical correlation formula.
