A chiral metal-organic framework(CMOF)with accessible binding pockets and multiple recognition sites is constructed from a tricarboxylate ligand derived from phenylalanine.The CMOF features a rare structure with cavit...A chiral metal-organic framework(CMOF)with accessible binding pockets and multiple recognition sites is constructed from a tricarboxylate ligand derived from phenylalanine.The CMOF features a rare structure with cavities encapsulated by a non-coordinated amino-acid moiety.It has been proven to be an efficient and recyclable chiral host,enabling adsorbing and separating racemic alcohols,diols,and epoxides with excellent enantioselectivity.展开更多
基金supported by the Fundamental Research Funds for the Central Universities of China(no.PA2021GDPK0067 and PA2020GDKC0011)the support of the Postdoctoral Scientific Research Station of Materials Science and Engineering at Hefei University of Technologythe assistance of the staff from the BL17B beamline of NFPS at the Shanghai Synchrotron Radiation Facility during crystal data collection.
文摘A chiral metal-organic framework(CMOF)with accessible binding pockets and multiple recognition sites is constructed from a tricarboxylate ligand derived from phenylalanine.The CMOF features a rare structure with cavities encapsulated by a non-coordinated amino-acid moiety.It has been proven to be an efficient and recyclable chiral host,enabling adsorbing and separating racemic alcohols,diols,and epoxides with excellent enantioselectivity.
