A series of CaMoO4：xTb3＋ （x=0.01, 0.03, 0.05, 0.07, 0.09, 0.15 and 0.20） phosphors in pure phase were prepared via high temperature solid-state reaction approach. The crystal structure of the phosphors was investi...A series of CaMoO4：xTb3＋ （x=0.01, 0.03, 0.05, 0.07, 0.09, 0.15 and 0.20） phosphors in pure phase were prepared via high temperature solid-state reaction approach. The crystal structure of the phosphors was investigated by X-ray diffraction （XRD）, and the optical properties were investigated by Fourier transform infrared spectroscopy （FT-IR）, ultraviolet-visible spectroscopy （UV-Vis） and photoluminescence （PL） spectroscopy. The PL spectra illustrated that these phosphors could be efficiently excited by the charge transfer band of the host and the energy transfer efficiency from the host to the doped activator reached 60% when the doping con- centration of the activator Th3＋ was 20 mol.%. The concentration quenching occurred at x= 10 mol.%, from which the critical distance of activator was calculated to be about 1.14 nm. The CIE coordinates were estimated to be close to the standard green value. The host sensitized samples had potential application as green phosphors.展开更多
In order to obtain a single-host-white-light phosphor, a series of Bal.8 -x-y-zSrwLi0.4xCexEuyMnzSi04 （BSLS：Ce3＋,Eu2＋, Mn2＋） powder samples were synthesized via high temperature solid-state reaction. The structu...In order to obtain a single-host-white-light phosphor, a series of Bal.8 -x-y-zSrwLi0.4xCexEuyMnzSi04 （BSLS：Ce3＋,Eu2＋, Mn2＋） powder samples were synthesized via high temperature solid-state reaction. The structure and photoluminescence properties were investigated. Under ultraviolet excitation, the emission spectra contained three bands： the 370-470 nm blue band, the 470-570 nm green band and the 570-700 nm red band, which arose from the 5d---4f transitions of Ce3＋ and Eu2＋, and the 4TI---6A1 transition of Mn2＋, respectively. The excitation spectra of the emissions of Ce3＋ and Mn2＋ ions showed the energy transfer from Ce3＋ to Mn2＋. White light emission was obtained from the tri-doped samples of appropriate doping concentration under 31 0-360 nm excitation.展开更多
The spectra of solutions, films and light emitting diodes of rare earth complexes were studied. It is shown that the absorption spectra of PVK dopping rare earth complexes can be red shifted to the visible region a...The spectra of solutions, films and light emitting diodes of rare earth complexes were studied. It is shown that the absorption spectra of PVK dopping rare earth complexes can be red shifted to the visible region and overlap with the emission spectrum of PVK, which makes the energy transfer possible from PVK to the rare earth ion.展开更多
This paper reports the synthesis of host-vip nanocomposite material [Fe(bpy)(3)]Y2+ (where bpy=2,2'-bipyridine) using the flexible ligand method. X-ray diffraction analysis. adsorption technique, and cyclic volt...This paper reports the synthesis of host-vip nanocomposite material [Fe(bpy)(3)]Y2+ (where bpy=2,2'-bipyridine) using the flexible ligand method. X-ray diffraction analysis. adsorption technique, and cyclic voltammetry were used to characterize the material. The results show that [Fe(bpy)(3)](2+) has been entrapped in the supercage of zeolite, its electron transfer is realized by electron hopping of [Fe(bpy)(3)](2+) within the supercage of zeolite.展开更多
基金Project supported by National Natural Science Foundation of China(20903123)Key Project of Chinese Ministry of Education(211154)Natural Science Foundation Project of Chongqing(KJ110532,CSTCjjA1425)
文摘A series of CaMoO4：xTb3＋ （x=0.01, 0.03, 0.05, 0.07, 0.09, 0.15 and 0.20） phosphors in pure phase were prepared via high temperature solid-state reaction approach. The crystal structure of the phosphors was investigated by X-ray diffraction （XRD）, and the optical properties were investigated by Fourier transform infrared spectroscopy （FT-IR）, ultraviolet-visible spectroscopy （UV-Vis） and photoluminescence （PL） spectroscopy. The PL spectra illustrated that these phosphors could be efficiently excited by the charge transfer band of the host and the energy transfer efficiency from the host to the doped activator reached 60% when the doping con- centration of the activator Th3＋ was 20 mol.%. The concentration quenching occurred at x= 10 mol.%, from which the critical distance of activator was calculated to be about 1.14 nm. The CIE coordinates were estimated to be close to the standard green value. The host sensitized samples had potential application as green phosphors.
基金Project supported by National Natural Science Foundation of China (11074245,10904139,11204292)
文摘In order to obtain a single-host-white-light phosphor, a series of Bal.8 -x-y-zSrwLi0.4xCexEuyMnzSi04 （BSLS：Ce3＋,Eu2＋, Mn2＋） powder samples were synthesized via high temperature solid-state reaction. The structure and photoluminescence properties were investigated. Under ultraviolet excitation, the emission spectra contained three bands： the 370-470 nm blue band, the 470-570 nm green band and the 570-700 nm red band, which arose from the 5d---4f transitions of Ce3＋ and Eu2＋, and the 4TI---6A1 transition of Mn2＋, respectively. The excitation spectra of the emissions of Ce3＋ and Mn2＋ ions showed the energy transfer from Ce3＋ to Mn2＋. White light emission was obtained from the tri-doped samples of appropriate doping concentration under 31 0-360 nm excitation.
文摘The spectra of solutions, films and light emitting diodes of rare earth complexes were studied. It is shown that the absorption spectra of PVK dopping rare earth complexes can be red shifted to the visible region and overlap with the emission spectrum of PVK, which makes the energy transfer possible from PVK to the rare earth ion.
文摘This paper reports the synthesis of host-vip nanocomposite material [Fe(bpy)(3)]Y2+ (where bpy=2,2'-bipyridine) using the flexible ligand method. X-ray diffraction analysis. adsorption technique, and cyclic voltammetry were used to characterize the material. The results show that [Fe(bpy)(3)](2+) has been entrapped in the supercage of zeolite, its electron transfer is realized by electron hopping of [Fe(bpy)(3)](2+) within the supercage of zeolite.
