Social interaction with peer pressure is widely studied in social network analysis.Game theory can be utilized to model dynamic social interaction,and one class of game network models assumes that people’s decision p...Social interaction with peer pressure is widely studied in social network analysis.Game theory can be utilized to model dynamic social interaction,and one class of game network models assumes that people’s decision payoff functions hinge on individual covariates and the choices of their friends.However,peer pressure would be misidentified and induce a non-negligible bias when incomplete covariates are involved in the game model.For this reason,we develop a generalized constant peer effects model based on homogeneity structure in dynamic social networks.The new model can effectively avoid bias through homogeneity pursuit and can be applied to a wider range of scenarios.To estimate peer pressure in the model,we first present two algorithms based on the initialize expand merge method and the polynomial-time twostage method to estimate homogeneity parameters.Then we apply the nested pseudo-likelihood method and obtain consistent estimators of peer pressure.Simulation evaluations show that our proposed methodology can achieve desirable and effective results in terms of the community misclassification rate and parameter estimation error.We also illustrate the advantages of our model in the empirical analysis when compared with a benchmark model.展开更多
The photoinduced ligand-to-metal charge transfer(LMCT)process has been extensively investigated,however,the recovery of photocatalysts has remained a persistent challenge in the field.In light of this issue,a novel ap...The photoinduced ligand-to-metal charge transfer(LMCT)process has been extensively investigated,however,the recovery of photocatalysts has remained a persistent challenge in the field.In light of this issue,a novel approach involving the development of iron-based ionic liquids as photocatalysts has been pursued for the first time,with the goal of simultaneously facilitating the LMCT process and addressing the issue of photocatalyst recovery.Remarkably,the iron-based ionic liquid 1-butyl-3-methylimidazolium tetrachloroferrate(C_(4)mim-Fe Cl_(4))demonstrates exceptional recyclability and stability for the photocatalytic hydroacylation of olefins.This study will pave the way for new approaches to photocatalytic organic synthesis using ionic liquids as recyclable photocatalysts.展开更多
Currently,perovskite solar cells have achieved commendable progresses in power conversion efficiency(PCE)and operational stability.However,some conventional laboratory-scale fabrication methods become challenging when...Currently,perovskite solar cells have achieved commendable progresses in power conversion efficiency(PCE)and operational stability.However,some conventional laboratory-scale fabrication methods become challenging when scaling up material syntheses or device production.Particularly,the prolonged high-temperature annealing process for the crystallization of perovskites requires a substantial amount of energy consumption and impact the modules’throughput.Here,we report a modified near-infrared annealing(NIRA)process,which involves the excess PbI_(2)engineered crystallization,efficiently reduces the preparation time for perovskite active layer to within 20 s compared to dozens of min in conventional hot plate annealing(HPA)process.The study showed that the incorporated PbI_(2)promoted the consistent nucleation of the perovskite film,leading to the subsequent rapid and homogeneous crystallization at the NIRA stage.Thus,highly crystalized perovskite film was realized with even better crystallization performance than conventional HPA-based film.Ultimately,efficient perovskite solar modules of 36 and 100 cm^(2)were readily fabricated with the optimal PCEs of 22.03%and 20.18%,respectively.This study demonstrates,for the first time,the successful achievement of homogeneous and high-quality crystallization in large-area perovskite films through rapid NIRA processing.This approach not only significantly reduces energy consumption during production,but also substantially shortens the manufacturing cycle,paving a new path toward the commercial-scale application of perovskite solar modules.展开更多
In this paper,the class of starlike functions of complex order γ(γ∈ℂ−{0})is extended from the case on unit disk U=(z∈C:|z|<1)to the case on the unit ball B in a complex Banach space or the unit polydisk U^(n) i...In this paper,the class of starlike functions of complex order γ(γ∈ℂ−{0})is extended from the case on unit disk U=(z∈C:|z|<1)to the case on the unit ball B in a complex Banach space or the unit polydisk U^(n) in C^(n).Let g be a convex function in U. We mainly establish the sharp bounds of all terms of homogeneous polynomial expansions for a subclass of g-parametric starlike mappings of complex order γ on B (resp.U^(n))when the mappings f are k-fold symmetric, k ∈ N. Our results partly solve the Bieberbach conjecture in several complex variables and generalize some prior works.展开更多
In this paper,the authors prove that the parameterized area integralμ_(Ω,S)^(ρ)and the parameterized Littlewood-Paley g_(δ)^(*)-functionμ_(Ω,δ)^(*,ρ)are bounded on two-weight grand homogeneous variable Herz-Mo...In this paper,the authors prove that the parameterized area integralμ_(Ω,S)^(ρ)and the parameterized Littlewood-Paley g_(δ)^(*)-functionμ_(Ω,δ)^(*,ρ)are bounded on two-weight grand homogeneous variable Herz-Morrey spaces MK_(p),θ,q(·))^(α(·),λ)(ω_(1),ω_(2)),where θ>0,λ∈(2,∞),q(·)∈B(R^(n)),α(·)∈L^(∞)(R^(n)),ω_(1)∈A_(p_(ω_(1)))for p_(ω_(1))∈[1,∞]and ω_(2) is a weight.Furthermore,the authors prove that the commutators[b,μ_(Ω,S)^(ρ)]which is formed by b∈BMO(R^(n))and the μ_(Ω,S)^(ρ),and the[b,μ_(Ω,δ)^(*,ρ)]generated by b∈BMO(R^(n))and theμ_(Ω,δ)^(*,ρ)are bounded on MK_(p),θ,q(·))^(α(·),λ)(ω_(1),ω_(2)),respectively.展开更多
Degradation of cellulose to chemicals is one of major routes for biomass conversion. Here, a new simple and two-step method has been developed to convert cellulose in its homogeneously alkaline solution to organic aci...Degradation of cellulose to chemicals is one of major routes for biomass conversion. Here, a new simple and two-step method has been developed to convert cellulose in its homogeneously alkaline solution to organic acids under atmospheric pressure at mild temperature. At first, cellulose was degraded to smM1 molecular intermediates at 110 ℃ for 3 h under atmospheric pressure, and then it was oxidized with H202 at 50 ℃ for 4 h. Under the optimal condition, 73.5% conversion of cellulose could be achieved, and the yield of organic acids was 32.8% （formic acid）, 11.6% （lactic acid）, and 2.3% （oxalic acid）, respectively. It is noteworthy that the new strategy reduces energy consumption in the process of reaction, unlike the hydrothermal reaction under high temperature and high pressure.展开更多
Ultra-fine Ce:YAG phosphors were prepared by homogeneous precipitation under microwave irradiation method . The formation of Ce: YAG was investigated by means of XRD and DTA/TG. The purified YAG crystallized phase was...Ultra-fine Ce:YAG phosphors were prepared by homogeneous precipitation under microwave irradiation method . The formation of Ce: YAG was investigated by means of XRD and DTA/TG. The purified YAG crystallized phase was obtained at a lower temperature (1100℃). Basically spherical Ce:YAG powders were indicated from TEM images, and the size of the particles is about 80 nm. Two peaks of 436 and 473 nm can be seen from the excitation spectrum in the range of 402 -510 nm. A broad emission band located at 480 ~ 630 nm shows the phosphors prepared by this method have good emission properties.展开更多
Using A1(NO3)3·9H2O, NH4Al(SO4)2·12H2O, Y(NO3)3as mother salts, and urea as precipitant, YAG nano-powders were synthesized by microwave homogeneous precipitation. The composition, morphology, and phase trans...Using A1(NO3)3·9H2O, NH4Al(SO4)2·12H2O, Y(NO3)3as mother salts, and urea as precipitant, YAG nano-powders were synthesized by microwave homogeneous precipitation. The composition, morphology, and phase transformation of precursor were analyzed by IR, XRD and TEM. The size distribution of YAG powders was characterized using laser diffraction method. The results show that sulfate ions influence the dispersion, composition and morphology of the YAG precursors. The addition of moderate sulfate ions can produce YAG powders with nano size and excellent dispersion at 1100℃.展开更多
In this article,the authors obtain an inequality of homogeneous expansion for f,where f is a quasi-convex mapping(including quasi-convex mapping of type A and quasi-convex mapping of type B)defined on the open unit po...In this article,the authors obtain an inequality of homogeneous expansion for f,where f is a quasi-convex mapping(including quasi-convex mapping of type A and quasi-convex mapping of type B)defined on the open unit polydisk in C n .Meanwhile,the authors also investigate its application.展开更多
In this article, first, a sufficient condition for a starlike mapping of order a f（x） defined on the unit ball in a complex Banach space is given. Second, the sharp estimate of the third homogeneous expansion for f ...In this article, first, a sufficient condition for a starlike mapping of order a f（x） defined on the unit ball in a complex Banach space is given. Second, the sharp estimate of the third homogeneous expansion for f is established as well, where f（z） = （f1（z）, f2（z）,..., fn（z））＇ is a starlike mapping of order a or a normalized biholomorphic starlike mapping defined on the unit polydisk in Cn, and D2fk（0）（z2） /2i= zk（∑l=1^b akzzl）, k = 2t l=1 k = 1, 2,..., n. Our result states that the Bieberbaeh conjecture in several complex variables （the case of the third homogeneous expansion for starlike mappings of order α and biholomorphic starlike mappings） is partly proved.展开更多
As the abundant biopolymer, cellulose can be used as a feedstock for chemicals and materials. Effective conversion of cellulose by simple processes is a key point. Degradation of cellulose in its homogeneous solution ...As the abundant biopolymer, cellulose can be used as a feedstock for chemicals and materials. Effective conversion of cellulose by simple processes is a key point. Degradation of cellulose in its homogeneous solution is attractive for the molecular chains are free and spread. Here,microcrystalline cellulose was first dissolved in aqueous solution of Na OH and urea, and then hydrothermal reaction was carried out at various temperature and time. Fluorescence carbon dots(CDs) were generated accompanied with six organic acids: oxalic acid, formic acid, malonic acid, lactic acid, acetic acid, and fumaric acid. The yields of all organic acids and CDs, and the fluorescence quantum yield(QY) of CDs were studied at different reaction conditions. It was found that the maximum yield of organic acids and CDs are 80.1% and 6.03%, respectively, and the highest QY of the CDs is 10.9%. Fluorescence studies reveal that the as-prepared CDs has efficient selectivity and sensitivity toward iron ions in acidic condition, indicating it is a potential fluorescent sensor to the detection of Fe3+. Importantly, it provides a panorama to summary the degradation routes of cellulose in its homogeneous aqueous solution with both organic molecules and CDs as products.展开更多
The lowly-agglomerated single-phase YAG nanopowders were synthesized for the first time by the microwave homogeneous precipitation in the presence of urea. The composition and transformations during calcination of YAG...The lowly-agglomerated single-phase YAG nanopowders were synthesized for the first time by the microwave homogeneous precipitation in the presence of urea. The composition and transformations during calcination of YAG precursor were analyzed by IR, DTA/TG and XRD. The size and morphology of YAG powders were characterized by LD and TEM methods. Results show that amorphous precursor synthesized under [urea]/[metal ions] molar ratio of 15 crystallizes directly to single-phase YAG at 900degreesC. The size distribution and sinterability of YAG powders are obviously improved by adding (NH4)(2)SO4 into the reaction solution. YAG powders obtained from precursor with the (NH4)(2)SO4 content of 8% have good sinterability and are highly densified at a temperature of 1500degreesC展开更多
Y2O3： Er^3＋, Yb^3＋ nanoparticles were synthesized by a homogeneous precipitation method without and with different concentrations of EDTA 2Na. Upconversion luminescence spectra of the samples were studied under 980...Y2O3： Er^3＋, Yb^3＋ nanoparticles were synthesized by a homogeneous precipitation method without and with different concentrations of EDTA 2Na. Upconversion luminescence spectra of the samples were studied under 980 nm laser excitation. The results of XRD showed that the obtained Y2O3：Er^3＋,Yb^3＋ nanoparticles were of a cubic structure. The average crystallite sizes calculated were in the range of 28-40 nm. Green and red upconversion emission were observed, and attributed to ^2H11/2,^4S3/2→^4I15/2 and ^4F9/2→^4I15/2 transitions of the ion, respectively. The ratio of the intensity of green emission to that of red emission drastically changed with a change in the EDTA 2Na concentration. In the sample synthesized without EDTA, the relative intensity of the green emission was weaker than that of the red emission. The relative intensities of green emission increased with the increased amount of EDTA 2Na used. The possible upconversion luminescence mechanisms were discussed.展开更多
Direct numerical simulations （DNS） were performed for the forced homogeneous isotropic turbulence （FHIT） with/without polymer additives in order to elaborate the characteristics of the turbulent energy cascading i...Direct numerical simulations （DNS） were performed for the forced homogeneous isotropic turbulence （FHIT） with/without polymer additives in order to elaborate the characteristics of the turbulent energy cascading influenced by drag-reducing effects. The finite elastic non-linear extensibility-Peterlin model （FENE-P） was used as the conformation tensor equation for the viscoelastic polymer solution. Detailed analyses of DNS data were carried out in this paper for the turbulence scaling law and the topological dynamics of FHIT as well as the important turbulent parameters, including turbulent kinetic energy spectra, enstrophy and strain, velocity structure function, small-scale intermittency, etc. A natural and straightforward definition for the drag reduction rate was also proposed for the drag-reducing FHIT based on the decrease degree of the turbulent kinetic energy. It was found that the turbulent energy cascading in the FHIT was greatly modified by the drag-reducing polymer additives. The enstrophy and the strain fields in the FH1T of the polymer solution were remarkably weakened as compared with their Newtonian counterparts. The small-scale vortices and the small-scale intermittency were all inhibited by the viscoelastic effects in the FHIT of the polymer solution. However, the scaling law in a fashion of extended self-similarity for the FHIT of the polymer solution, within the presently simulated range of Weissenberg numbers, had no distinct differences compared with that of the Newtonian fluid case.展开更多
In order to prevent and control the spread of rumors, the implementation of immunization strategies for ignorant individuals is very necessary, where the immunization usually means letting them learn the truth of rumo...In order to prevent and control the spread of rumors, the implementation of immunization strategies for ignorant individuals is very necessary, where the immunization usually means letting them learn the truth of rumors.Considering the facts that there is always a delay time between rumor spreading and implementing immunization, and that the truth of rumors can also be spread out, this paper constructs a novel susceptible-infected-removed(SIR) model.The propagation dynamical behaviors of the SIR model on homogeneous networks are investigated by using the meanfield theory and the Monte Carlo method. Research shows that the greater the delay time, the worse the immune effect of the immunization strategy. It is also found that the spread of the truth can inhibit to some extent the propagation of rumors, and the trend will become more obvious with the increase of reliability of the truth. Moreover, under the influence of delay time, the existence of nodes' identification force still slightly reduces the propagation degree of rumors.展开更多
In order to accommodate the variety of algorithms with different performance in specific application and improve power efficiency,reconfigurable architecture has become an effective methodology in academia and industr...In order to accommodate the variety of algorithms with different performance in specific application and improve power efficiency,reconfigurable architecture has become an effective methodology in academia and industry.However,existing architectures suffer from performance bottleneck due to slow updating of contexts and inadequate flexibility.This paper presents an H-tree based reconfiguration mechanism(HRM)with Huffman-coding-like and mask addressing method in a homogeneous processing element(PE)array,which supports both programmable and data-driven modes.The proposed HRM can transfer reconfiguration instructions/contexts to a particular PE or associated PEs simultaneously in one clock cycle in unicast,multicast and broadcast mode,and shut down the unnecessary PE/PEs according to the current configuration.To verify the correctness and efficiency,we implement it in RTL synthesis and FPGA prototype.Compared to prior works,the experiment results show that the HRM has improved the work frequency by an average of 23.4%,increased the updating speed by 2×,and reduced the area by 36.9%;HRM can also power off the unnecessary PEs which reduced 51%of dynamic power dissipation in certain application configuration.Furthermore,in the data-driven mode,the system frequency can reach 214 MHz,which is 1.68×higher compared with the programmable mode.展开更多
This paper studies some boundedness results of commutators on a class of new spaces MKp,q^αλ （G） named as homogenous Morrey-Herz spaces over locally compact Vilenkin groups
Robust and easy-to-use kits specific for a particular DNA sequence are desirable for early detection of diseases. However, the major challenge with these tests is often the background fluorescence artifacts arising fr...Robust and easy-to-use kits specific for a particular DNA sequence are desirable for early detection of diseases. However, the major challenge with these tests is often the background fluorescence artifacts arising from biological species due to employing UV and visible range of light. Here, we have reported a near-infrared (NIR) fluorescence "turn-on" kit based on rare earth ions doped nanoparticles, upconversion nanoparticles (UCNPs), and gold nanoparticles (AuNPs), which forms a fluorescence-quencher pair,brought together by a hairpin structure through the formation of double-stranded DNA (dsDNA), with quenched upconversion luminescence. In the presence of analytes, the molecular beacon opens to push AuNPs away from UCNPs, with a distance longer than the efficient quenching distance, so that the inhibited upconversion emission will be restored. We demonstrated that this assay provides a homogeneous, facile, simple and highly selective HIV-1 based DNA detection system with restore efficiency up to 85%, and the detection limit of 5 nm.展开更多
Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectrosc...Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric and differential thermal analysis (TG-DTA) and photoluminescence spectra were used to characterize the samples. The effects of the initial solution pH value and urea content on the structure of the sample were studied. The XRD results show that pure phase Gd3Ga5O12 can be obtained at pH =6 and pH =8 of the initial solution. The average crystallite size can be calculated as in the range of 24~33 nm. The average crystallite size decreases with increasing molar ratio of urea to metal ion. The results of excitation spectra and emission spectra show that the emission peaks are ascribed to 5D0→7FJ transitions of Eu3+, and the magnetic dipole transition originated from 5D0 →7F1 of Eu3+ is the strongest; the broad excitation bands belong to change transfer band of Eu?O and the host absorption of Gd3Ga5O12. An efficient energy transfer occurs from Gd3+ to Eu3+.展开更多
基金supported by the National Nature Science Foundation of China(71771201,72531009,71973001)the USTC Research Funds of the Double First-Class Initiative(FSSF-A-240202).
文摘Social interaction with peer pressure is widely studied in social network analysis.Game theory can be utilized to model dynamic social interaction,and one class of game network models assumes that people’s decision payoff functions hinge on individual covariates and the choices of their friends.However,peer pressure would be misidentified and induce a non-negligible bias when incomplete covariates are involved in the game model.For this reason,we develop a generalized constant peer effects model based on homogeneity structure in dynamic social networks.The new model can effectively avoid bias through homogeneity pursuit and can be applied to a wider range of scenarios.To estimate peer pressure in the model,we first present two algorithms based on the initialize expand merge method and the polynomial-time twostage method to estimate homogeneity parameters.Then we apply the nested pseudo-likelihood method and obtain consistent estimators of peer pressure.Simulation evaluations show that our proposed methodology can achieve desirable and effective results in terms of the community misclassification rate and parameter estimation error.We also illustrate the advantages of our model in the empirical analysis when compared with a benchmark model.
基金financial support from the National Natural Science Foundation of China(Nos.22071222,22171249)the Natural Science Foundation of Henan Province(Nos.232300421363,242300420526)+2 种基金Key Research Projects of Universities in Henan Province(No.23A180010)Science&Technology Innovation Talents in Universities of Henan Province(No.23HASTIT003)Science and Technology Research and Development Plan Joint Fund of Henan Province(No.242301420006)。
文摘The photoinduced ligand-to-metal charge transfer(LMCT)process has been extensively investigated,however,the recovery of photocatalysts has remained a persistent challenge in the field.In light of this issue,a novel approach involving the development of iron-based ionic liquids as photocatalysts has been pursued for the first time,with the goal of simultaneously facilitating the LMCT process and addressing the issue of photocatalyst recovery.Remarkably,the iron-based ionic liquid 1-butyl-3-methylimidazolium tetrachloroferrate(C_(4)mim-Fe Cl_(4))demonstrates exceptional recyclability and stability for the photocatalytic hydroacylation of olefins.This study will pave the way for new approaches to photocatalytic organic synthesis using ionic liquids as recyclable photocatalysts.
基金supported by China Huaneng Group Key R&D Program(HNKJ22-H104)the Science and Technology Programs of Fujian Province(2022H0005)+1 种基金the Fundamental Research Funds for the Central Universities(20720240067)Technology Projects of Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province(RD2020020101 and RD2022040601).
文摘Currently,perovskite solar cells have achieved commendable progresses in power conversion efficiency(PCE)and operational stability.However,some conventional laboratory-scale fabrication methods become challenging when scaling up material syntheses or device production.Particularly,the prolonged high-temperature annealing process for the crystallization of perovskites requires a substantial amount of energy consumption and impact the modules’throughput.Here,we report a modified near-infrared annealing(NIRA)process,which involves the excess PbI_(2)engineered crystallization,efficiently reduces the preparation time for perovskite active layer to within 20 s compared to dozens of min in conventional hot plate annealing(HPA)process.The study showed that the incorporated PbI_(2)promoted the consistent nucleation of the perovskite film,leading to the subsequent rapid and homogeneous crystallization at the NIRA stage.Thus,highly crystalized perovskite film was realized with even better crystallization performance than conventional HPA-based film.Ultimately,efficient perovskite solar modules of 36 and 100 cm^(2)were readily fabricated with the optimal PCEs of 22.03%and 20.18%,respectively.This study demonstrates,for the first time,the successful achievement of homogeneous and high-quality crystallization in large-area perovskite films through rapid NIRA processing.This approach not only significantly reduces energy consumption during production,but also substantially shortens the manufacturing cycle,paving a new path toward the commercial-scale application of perovskite solar modules.
基金supported by the National Natural Science Foundation of China(12061035)the Research Foundation of Jiangxi Science and Technology Normal University of China(2021QNBJRC003)supported by the Graduate Innovation Fund of Jiangxi Science and Technology Normal University(YC2024-X10).
文摘In this paper,the class of starlike functions of complex order γ(γ∈ℂ−{0})is extended from the case on unit disk U=(z∈C:|z|<1)to the case on the unit ball B in a complex Banach space or the unit polydisk U^(n) in C^(n).Let g be a convex function in U. We mainly establish the sharp bounds of all terms of homogeneous polynomial expansions for a subclass of g-parametric starlike mappings of complex order γ on B (resp.U^(n))when the mappings f are k-fold symmetric, k ∈ N. Our results partly solve the Bieberbach conjecture in several complex variables and generalize some prior works.
基金Supported by the National Natural Science Foundation of China(Grant No.12201500)。
文摘In this paper,the authors prove that the parameterized area integralμ_(Ω,S)^(ρ)and the parameterized Littlewood-Paley g_(δ)^(*)-functionμ_(Ω,δ)^(*,ρ)are bounded on two-weight grand homogeneous variable Herz-Morrey spaces MK_(p),θ,q(·))^(α(·),λ)(ω_(1),ω_(2)),where θ>0,λ∈(2,∞),q(·)∈B(R^(n)),α(·)∈L^(∞)(R^(n)),ω_(1)∈A_(p_(ω_(1)))for p_(ω_(1))∈[1,∞]and ω_(2) is a weight.Furthermore,the authors prove that the commutators[b,μ_(Ω,S)^(ρ)]which is formed by b∈BMO(R^(n))and the μ_(Ω,S)^(ρ),and the[b,μ_(Ω,δ)^(*,ρ)]generated by b∈BMO(R^(n))and theμ_(Ω,δ)^(*,ρ)are bounded on MK_(p),θ,q(·))^(α(·),λ)(ω_(1),ω_(2)),respectively.
基金This work was supported by the National Natural Science Foundation of China （No.51373162）, and the Natural Science Foundation of Anhui Province （No.1408085MKL03）.
文摘Degradation of cellulose to chemicals is one of major routes for biomass conversion. Here, a new simple and two-step method has been developed to convert cellulose in its homogeneously alkaline solution to organic acids under atmospheric pressure at mild temperature. At first, cellulose was degraded to smM1 molecular intermediates at 110 ℃ for 3 h under atmospheric pressure, and then it was oxidized with H202 at 50 ℃ for 4 h. Under the optimal condition, 73.5% conversion of cellulose could be achieved, and the yield of organic acids was 32.8% （formic acid）, 11.6% （lactic acid）, and 2.3% （oxalic acid）, respectively. It is noteworthy that the new strategy reduces energy consumption in the process of reaction, unlike the hydrothermal reaction under high temperature and high pressure.
基金Project supported by Foundation for the Excellent Middle-Aged or Young Scientists of Shandong Province (02BS049)
文摘Ultra-fine Ce:YAG phosphors were prepared by homogeneous precipitation under microwave irradiation method . The formation of Ce: YAG was investigated by means of XRD and DTA/TG. The purified YAG crystallized phase was obtained at a lower temperature (1100℃). Basically spherical Ce:YAG powders were indicated from TEM images, and the size of the particles is about 80 nm. Two peaks of 436 and 473 nm can be seen from the excitation spectrum in the range of 402 -510 nm. A broad emission band located at 480 ~ 630 nm shows the phosphors prepared by this method have good emission properties.
基金Project supported by the Excellent Middle-aged or Young Scientists from Shandong Province (02BS049)
文摘Using A1(NO3)3·9H2O, NH4Al(SO4)2·12H2O, Y(NO3)3as mother salts, and urea as precipitant, YAG nano-powders were synthesized by microwave homogeneous precipitation. The composition, morphology, and phase transformation of precursor were analyzed by IR, XRD and TEM. The size distribution of YAG powders was characterized using laser diffraction method. The results show that sulfate ions influence the dispersion, composition and morphology of the YAG precursors. The addition of moderate sulfate ions can produce YAG powders with nano size and excellent dispersion at 1100℃.
基金Sponsored by National Natural Science Foundation of China under grant No.10571164Specialized Research Fund for the Doctoral Program of Higher Education under grant No.20050358052Guangdong Natural Science Foundation under grant No.06301315
文摘In this article,the authors obtain an inequality of homogeneous expansion for f,where f is a quasi-convex mapping(including quasi-convex mapping of type A and quasi-convex mapping of type B)defined on the open unit polydisk in C n .Meanwhile,the authors also investigate its application.
基金Project supported by National Natural Science Foundation of China(10971063,11061015)Major Program of Zhejiang Provincial Natural Science Foundation of China(D7080080)Guangdong Natural Science Foundation(06301315)
文摘In this article, first, a sufficient condition for a starlike mapping of order a f（x） defined on the unit ball in a complex Banach space is given. Second, the sharp estimate of the third homogeneous expansion for f is established as well, where f（z） = （f1（z）, f2（z）,..., fn（z））＇ is a starlike mapping of order a or a normalized biholomorphic starlike mapping defined on the unit polydisk in Cn, and D2fk（0）（z2） /2i= zk（∑l=1^b akzzl）, k = 2t l=1 k = 1, 2,..., n. Our result states that the Bieberbaeh conjecture in several complex variables （the case of the third homogeneous expansion for starlike mappings of order α and biholomorphic starlike mappings） is partly proved.
基金supported by the National Natural Science Foundation of China (No. 51373162 and 51673180)
文摘As the abundant biopolymer, cellulose can be used as a feedstock for chemicals and materials. Effective conversion of cellulose by simple processes is a key point. Degradation of cellulose in its homogeneous solution is attractive for the molecular chains are free and spread. Here,microcrystalline cellulose was first dissolved in aqueous solution of Na OH and urea, and then hydrothermal reaction was carried out at various temperature and time. Fluorescence carbon dots(CDs) were generated accompanied with six organic acids: oxalic acid, formic acid, malonic acid, lactic acid, acetic acid, and fumaric acid. The yields of all organic acids and CDs, and the fluorescence quantum yield(QY) of CDs were studied at different reaction conditions. It was found that the maximum yield of organic acids and CDs are 80.1% and 6.03%, respectively, and the highest QY of the CDs is 10.9%. Fluorescence studies reveal that the as-prepared CDs has efficient selectivity and sensitivity toward iron ions in acidic condition, indicating it is a potential fluorescent sensor to the detection of Fe3+. Importantly, it provides a panorama to summary the degradation routes of cellulose in its homogeneous aqueous solution with both organic molecules and CDs as products.
文摘The lowly-agglomerated single-phase YAG nanopowders were synthesized for the first time by the microwave homogeneous precipitation in the presence of urea. The composition and transformations during calcination of YAG precursor were analyzed by IR, DTA/TG and XRD. The size and morphology of YAG powders were characterized by LD and TEM methods. Results show that amorphous precursor synthesized under [urea]/[metal ions] molar ratio of 15 crystallizes directly to single-phase YAG at 900degreesC. The size distribution and sinterability of YAG powders are obviously improved by adding (NH4)(2)SO4 into the reaction solution. YAG powders obtained from precursor with the (NH4)(2)SO4 content of 8% have good sinterability and are highly densified at a temperature of 1500degreesC
基金the Foundation for the University by Educational Department of Liaoning (05L337)Key Laboratory of Rare Earth Chemistry and Physics, Chinese Academy of Sciences
文摘Y2O3： Er^3＋, Yb^3＋ nanoparticles were synthesized by a homogeneous precipitation method without and with different concentrations of EDTA 2Na. Upconversion luminescence spectra of the samples were studied under 980 nm laser excitation. The results of XRD showed that the obtained Y2O3：Er^3＋,Yb^3＋ nanoparticles were of a cubic structure. The average crystallite sizes calculated were in the range of 28-40 nm. Green and red upconversion emission were observed, and attributed to ^2H11/2,^4S3/2→^4I15/2 and ^4F9/2→^4I15/2 transitions of the ion, respectively. The ratio of the intensity of green emission to that of red emission drastically changed with a change in the EDTA 2Na concentration. In the sample synthesized without EDTA, the relative intensity of the green emission was weaker than that of the red emission. The relative intensities of green emission increased with the increased amount of EDTA 2Na used. The possible upconversion luminescence mechanisms were discussed.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 51076036 and 51206033)the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (Grant No.51121004)+2 种基金the Fundamental Research Funds for the Central Universities,China (Grant No. HIT.BRET2.2010008)the Doctoral Fund of Ministry of Education of China (Grant No. 20112302110020)the China Postdoctoral Science Foundation (Grant No. 2011M500652)
文摘Direct numerical simulations （DNS） were performed for the forced homogeneous isotropic turbulence （FHIT） with/without polymer additives in order to elaborate the characteristics of the turbulent energy cascading influenced by drag-reducing effects. The finite elastic non-linear extensibility-Peterlin model （FENE-P） was used as the conformation tensor equation for the viscoelastic polymer solution. Detailed analyses of DNS data were carried out in this paper for the turbulence scaling law and the topological dynamics of FHIT as well as the important turbulent parameters, including turbulent kinetic energy spectra, enstrophy and strain, velocity structure function, small-scale intermittency, etc. A natural and straightforward definition for the drag reduction rate was also proposed for the drag-reducing FHIT based on the decrease degree of the turbulent kinetic energy. It was found that the turbulent energy cascading in the FHIT was greatly modified by the drag-reducing polymer additives. The enstrophy and the strain fields in the FH1T of the polymer solution were remarkably weakened as compared with their Newtonian counterparts. The small-scale vortices and the small-scale intermittency were all inhibited by the viscoelastic effects in the FHIT of the polymer solution. However, the scaling law in a fashion of extended self-similarity for the FHIT of the polymer solution, within the presently simulated range of Weissenberg numbers, had no distinct differences compared with that of the Newtonian fluid case.
基金Supported by the National Natural Science Foundation of China under Grant No.61402531the Natural Science Basic Research Plan in Shaanxi Province of China under Grant Nos.2014JQ8358,2015JQ6231,and 2014JQ8307+1 种基金the China Postdoctoral Science Foundation under Grant No.2015M582910the Basic Research Foundation of Engineering University of the Chinese People’s Armed Police Force under Grant Nos.WJY201419,WJY201605 and JLX201686
文摘In order to prevent and control the spread of rumors, the implementation of immunization strategies for ignorant individuals is very necessary, where the immunization usually means letting them learn the truth of rumors.Considering the facts that there is always a delay time between rumor spreading and implementing immunization, and that the truth of rumors can also be spread out, this paper constructs a novel susceptible-infected-removed(SIR) model.The propagation dynamical behaviors of the SIR model on homogeneous networks are investigated by using the meanfield theory and the Monte Carlo method. Research shows that the greater the delay time, the worse the immune effect of the immunization strategy. It is also found that the spread of the truth can inhibit to some extent the propagation of rumors, and the trend will become more obvious with the increase of reliability of the truth. Moreover, under the influence of delay time, the existence of nodes' identification force still slightly reduces the propagation degree of rumors.
基金supported by the National Natural Science Foundation of China (Nos. 61834005, 61602377, 61772417, 61802304, 61874087)the Shaanxi International Science and Technology Cooperation Program No. 2018KW-006+1 种基金Shaanxi Provincial Key R&D Plan under Grant No. 2017GY-060Shaanxi Province Co-ordination Innovation Project of Science and Technology under Grant No. 2016KTZDGY02-04-02
文摘In order to accommodate the variety of algorithms with different performance in specific application and improve power efficiency,reconfigurable architecture has become an effective methodology in academia and industry.However,existing architectures suffer from performance bottleneck due to slow updating of contexts and inadequate flexibility.This paper presents an H-tree based reconfiguration mechanism(HRM)with Huffman-coding-like and mask addressing method in a homogeneous processing element(PE)array,which supports both programmable and data-driven modes.The proposed HRM can transfer reconfiguration instructions/contexts to a particular PE or associated PEs simultaneously in one clock cycle in unicast,multicast and broadcast mode,and shut down the unnecessary PE/PEs according to the current configuration.To verify the correctness and efficiency,we implement it in RTL synthesis and FPGA prototype.Compared to prior works,the experiment results show that the HRM has improved the work frequency by an average of 23.4%,increased the updating speed by 2×,and reduced the area by 36.9%;HRM can also power off the unnecessary PEs which reduced 51%of dynamic power dissipation in certain application configuration.Furthermore,in the data-driven mode,the system frequency can reach 214 MHz,which is 1.68×higher compared with the programmable mode.
基金Supported by Mudanjiang Teachers College (KZ2008001)by Scientific Research Fund of Heilongjiang Provincial Education Department(No.11541378)
文摘This paper studies some boundedness results of commutators on a class of new spaces MKp,q^αλ （G） named as homogenous Morrey-Herz spaces over locally compact Vilenkin groups
基金supported by the Australian Research Council(ARC)Future Fellowship Scheme(D.J.,FT130100517)ARC Industry Transformational Research Hub Scheme(IH150100028)
文摘Robust and easy-to-use kits specific for a particular DNA sequence are desirable for early detection of diseases. However, the major challenge with these tests is often the background fluorescence artifacts arising from biological species due to employing UV and visible range of light. Here, we have reported a near-infrared (NIR) fluorescence "turn-on" kit based on rare earth ions doped nanoparticles, upconversion nanoparticles (UCNPs), and gold nanoparticles (AuNPs), which forms a fluorescence-quencher pair,brought together by a hairpin structure through the formation of double-stranded DNA (dsDNA), with quenched upconversion luminescence. In the presence of analytes, the molecular beacon opens to push AuNPs away from UCNPs, with a distance longer than the efficient quenching distance, so that the inhibited upconversion emission will be restored. We demonstrated that this assay provides a homogeneous, facile, simple and highly selective HIV-1 based DNA detection system with restore efficiency up to 85%, and the detection limit of 5 nm.
基金financially supported by the Science and Technology Research Project of Department of Education of Liaoning Province,China(No.L2011063)
文摘Nanocrystalline Gd3Ga5O12:Eu3+ with cubic phase was prepared by a urea homogeneous precipitation method. X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric and differential thermal analysis (TG-DTA) and photoluminescence spectra were used to characterize the samples. The effects of the initial solution pH value and urea content on the structure of the sample were studied. The XRD results show that pure phase Gd3Ga5O12 can be obtained at pH =6 and pH =8 of the initial solution. The average crystallite size can be calculated as in the range of 24~33 nm. The average crystallite size decreases with increasing molar ratio of urea to metal ion. The results of excitation spectra and emission spectra show that the emission peaks are ascribed to 5D0→7FJ transitions of Eu3+, and the magnetic dipole transition originated from 5D0 →7F1 of Eu3+ is the strongest; the broad excitation bands belong to change transfer band of Eu?O and the host absorption of Gd3Ga5O12. An efficient energy transfer occurs from Gd3+ to Eu3+.
