Systems hosting flat bands offer a powerful platform for exploring strong correlation physics.Theoretically,topological degeneracy arising in systems with non-trivial topological orders on periodic manifolds of non-ze...Systems hosting flat bands offer a powerful platform for exploring strong correlation physics.Theoretically,topological degeneracy arising in systems with non-trivial topological orders on periodic manifolds of non-zero genus can generate ideal flat bands.However,experimental realization of such geometrically engineered systems is very difficult.In this work,we demonstrate that flat planes with strategically patterned hole defects can engineer ideal flat bands.We construct two families of models:singular flat band systems where degeneracy is stabilized by non-contractible loop excitations tied to hole defects and perfectly nested van Hove systems where degeneracy arises from line excitations in momentum space.These models circumvent the need for exotic manifolds while retaining the essential features of topological flat bands.By directly linking defect engineering to degeneracy mechanisms,our results establish a scalable framework for experimentally accessible flat band design.展开更多
In this study,a patch removing based Isogeometric analysis(PR-IGA)method is proposed to conduct the holed structural analysis with only one parametric domain,in which there are also no trimmed elements.The theoretical...In this study,a patch removing based Isogeometric analysis(PR-IGA)method is proposed to conduct the holed structural analysis with only one parametric domain,in which there are also no trimmed elements.The theoretical foundation of this novel patch removing approach is that any holed structure can be obtained by removing sub-patches(i.e.,the holes)from an intact base patch.Since the parametric domains of these patches are all meshed by rectangular grids,the elements in the resulted holed structural parametric domain could all be untrimmed rectangles under certain mapping conditions.To achieve the special condition,a systematic technique consisting of T-spline local refinement and control points substitution/adjustment is provided.Due to the intactness of parametric elements,the analysis procedure of holed structures based on the proposed PRIGA is quite simplified and efficient compared to traditional multi-patch and trimming schemes.Moreover,after the deduction of analytical sensitivities related to structural mass and mechanical responses,the PR-IGA is directly employed in the holed structural shape optimization to successfully eliminate the need for model transformation during modeling,analysis and optimization processes.Numerical examples involving analysis and shape optimization of complex holed structures are presented to demonstrate the effectiveness of the proposed method.展开更多
We have studied the morphology evolution of holed nanostructures formed by aluminum droplet epitaxy on a GaAs surface.Unique outer rings with concentric inner holed rings were observed.Further,an empirical equation to...We have studied the morphology evolution of holed nanostructures formed by aluminum droplet epitaxy on a GaAs surface.Unique outer rings with concentric inner holed rings were observed.Further,an empirical equation to describe the size distribution of the outer rings in the holed nanostructures has been established.The contour line generated by the equation provides physical insights into quantum ring formation by droplets of groupⅢmaterials onⅢ-Ⅴsubstrates.展开更多
As demonstrated by former work,the holed casing treatment can be used to expand the stall margin of a centrifugal compressor with unshrouded impeller.In addition,the choked margin can also be expanded as experimental ...As demonstrated by former work,the holed casing treatment can be used to expand the stall margin of a centrifugal compressor with unshrouded impeller.In addition,the choked margin can also be expanded as experimental results indicated.Moreover,the compressor performance,especially the efficiency,on the whole working range is improved.As shown by experiments,the stall margin and choked margin of the compressor are extended,and the maximum efficiency improvement is 14%at the large flowrate of 1.386.Numerical simulations were carried out to analyze the flow in the impeller and in the holes in the case of large flowrate.The results indicate that in large flowrate conditions,there is a low-pressure region on the throat part of the impeller passage,leading to the bypass flows appearing in the holes,which means the flow area at the inlet of the impeller is increased.The bypass flow can also contribute to the decrease of the Mach number at the throat part near the shroud end-wall which implies that the choked margin is expanded.Besides,as the bypass flow would inhibit the development of the vertexes in the tip clearance and suppress the flow recirculation in the shroud end-wall region,both the pressure ratio and efficiency of the compressor are improved,which agrees well with the experiments.展开更多
The coupling of photoanode(Pho)and oxygen evolution catalyst(OEC)is an ideal approach to enhance the photoelectrochemical(PEC)activity.Nevertheless,the anticipated photocurrent density has not been reached due to slow...The coupling of photoanode(Pho)and oxygen evolution catalyst(OEC)is an ideal approach to enhance the photoelectrochemical(PEC)activity.Nevertheless,the anticipated photocurrent density has not been reached due to slow charge transfer dynamics and severe charge recombination at the interface.Herein,a novel“killing two birds with one stone”approach was discovered by employing CoPi as an interface mediator,which shifts its charge transfer behavior from conventional hole storage or passivation to hole transporter.The optimized BiVO_(4)/CoPi/FeOOH photoanode achieves a noteworthy photocurrent density of 5.4 mA/cm^(2) and exhibits long term stability(13 h).The dynamic analysis and electrochemical characterization reveal that CoPi can rapidly and directly transfer more photogenerated holes to the surface of OEC in comparison to traditional slow holes transfer behavior,resulting in highly efficient interface charge separation.Interestingly,the strong interfacial interactions can also be extended to OEC/electrolyte interface,specifically by promoting the surface reaction dynamics.Moreover,this innovative approach of altering behavior of CoPi can also be utilized to design other photoanodes,like BiVO_(4)/CoPi/NiOOH,aimed at efficient PEC water splitting.This finding affords a smart strategy to develop highly efficient and stable photoelectrodes for water splitting.展开更多
In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperat...In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperature(T_(c))of 1D superconductors is low.In this work,we theoretically investigate the possible high T_(c) superconductivity of(5,5)carbon nanotube(CNT).The pristine(5,5)CNT is a Dirac semimetal and can be modulated into a semiconductor by full hydrogenation.Interestingly,by further hole doping,it can be regulated into a metallic state with the sp3-hybridized𝜎electrons metalized,and a giant Kohn anomaly appears in the optical phonons.The two factors together enhance the electron–phonon coupling,and lead to high-T_(c) superconductivity.When the hole doping concentration of hydrogenated-(5,5)CNT is 2.5 hole/cell,the calculated T_(c) is 82.3 K,exceeding the boiling point of liquid nitrogen.Therefore,the predicted hole-doped hydrogenated-(5,5)CNT provides a new platform for 1D high-T_(c) superconductivity and may have potential applications in 1D nanodevices.展开更多
LOKIBASE is a non-linear isolator/dissipator device to protect pallet racking systems against the earthquake.LOKIBASE consists of the following main components:(1)two slider devices on which a rubber membrane is set u...LOKIBASE is a non-linear isolator/dissipator device to protect pallet racking systems against the earthquake.LOKIBASE consists of the following main components:(1)two slider devices on which a rubber membrane is set up(LOKI devices).LOKI devices are linear displacement dependent ones;(2)a cylindrical beam damper(“CANDLE”device).The“CANDLE”device is a non-linear displacement dependent one;(3)two anti-lifting devices(“UP-LIFT”devices);(4)a fuse plug(see www.lokibasedevice.com).The main work which is the purpose of the paper,is the optimization of the behavior of an isolator/dissipator device to mitigate the seismic action on special structures,where the stiffness values are very different in the main cross-aisle and down-aisle directions.Under seismic action,in these structures it is very important to reduce the value of the forces at the Limit state for the safeguard of human life(SLV)in the down-aisle direction as much as possible and simultaneously to use the highest damping value allowed by the building rules to reduce the LOKIBASE displacement at the Limit state for collapse prevention(SLC)in the cross-aisle direction.The goal was achieved through a cylindrical device made of stainless steel(AISI304)with an optimized shape,under large displacement during seismic action.展开更多
SiC_(f)/SiC ceramic matrix composites(SiC_(f)/SiC composites)are difficult to drill small holes due to their heterogeneity,high hardness,and low electrical conductivity.In order to solve the difficulties of poor quali...SiC_(f)/SiC ceramic matrix composites(SiC_(f)/SiC composites)are difficult to drill small holes due to their heterogeneity,high hardness,and low electrical conductivity.In order to solve the difficulties of poor quality and low efficiency when drilling small holes,a novel femtosecond laser rotary drilling(FLRD)technique is proposed.Beam kinematic paths and experimental studies were carried out to analyze the effects of processing parameters on the drilling results in the two-step drilling process.In the through-hole drilling stage,the material removal rate increases with increasing laser power,decreasing feed speed and decreasing pitch.As for the finishing stage of drilling,the exit diameter increased with increasing laser power and decreasing feed speed.The drilling parameters were selected by taking the processing efficiency of through-hole and the quality of finished hole as the constraint criteria.Holes with a diameter of 500μm were drilled using FLRD in 3 mm thick SiC_(f)/SiC composites with a drilling time<150 s.The hole aspect ratio was 6,the taper<0.2°,and there was no significant thermal damage at the orifice or the wall of the hole.The FLRD provides a solution for precision machining of small holes in difficult-to-machine materials by offering the advantages of high processing quality and short drilling times.展开更多
In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were invest...In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were investigated by using a single factor variable method.The surface morphologies of the shell molds produced by different temperatures of the surface(first)layer slurries were observed via electron microscopy.Furthermore,the microscopic composition of these shell molds was obtained by EDS,and the osmotic effect of the slurry on the wax patterns at different temperatures was also assessed by the PZ-200 Contact Angle detector.The forming reasons for the surface cracks and holes of thick and large ZTC4 titanium alloy by investment casting were analyzed.The experimental results show that the surface of the shell molds prepared by the surface layer slurry with a low temperature exhibits noticeable damage,which is mainly due to the poor coating performance and the serious expansion and contraction of wax pattern at low temperatures.The second layer shell material(SiO_(2),Al_(2)O_(3))immerses into the crack area of the surface layer,contacts and reacts with the molten titanium to form surface cracks and holes in the castings.With the increase of the temperature of surface layer slurry,the damage to the shell surface tends to weaken,and the composition of the shell molds'surface becomes more uniform with less impurities.The results show that the surface layer slurry at 22℃is evenly coated on the surface of the wax patterns with appropriate thickness,and there is no surface shell mold rupture caused by sliding slurry after sand leaching.The surface layer slurry temperature is consistent with the wax pattern temperature and the workshop temperature,so there is no damage of the surface layer shell caused by expansion and contraction.Therefore,the shell mold prepared by the surface layer slurry at this temperature has good integrity,isolating the contact between the low inert shell material and the titanium liquid effectively,and the ZTC4 titanium alloy cylinder casting prepared by this shell mold is smooth,without cracks and holes.展开更多
Traditional p-type colloidal quantum dot(CQD)hole transport layers(HTLs)used in CQD solar cells(CQDSCs)are commonly based on organic ligands exchange and the layer-by-layer(LbL)technique.Nonetheless,the ligand detachm...Traditional p-type colloidal quantum dot(CQD)hole transport layers(HTLs)used in CQD solar cells(CQDSCs)are commonly based on organic ligands exchange and the layer-by-layer(LbL)technique.Nonetheless,the ligand detachment and complex fabrication process introduce surface defects,compromising device stability and efficiency.In this work,we propose a solution-phase ligand exchange(SPLE)method utilizing inorganic ligands to develop stable p-type lead sulfide(PbS)CQD inks for the first time.Various amounts of tin(Ⅱ)iodide(SnI_(2))were mixed with lead halide(PbX_(2);X=I,Br)in the ligand solution.By precisely controlling the SnI_(2)concentration,we regulate the transition of PbS QDs from n-type to p-type.PbS CQDSCs were fabricated using two different HTL approaches:one with 1,2-ethanedithiol(EDT)-passivated QDs via the LbL method(control)and another with inorganic ligand-passivated QD ink(target).The target devices achieved a higher power conversion efficiency(PCE)of 10.93%,compared to 9.83%for the control devices.This improvement is attributed to reduced interfacial defects and enhanced carrier mobility.The proposed technique offers an efficient pathway for producing stable p-type PbS CQD inks using inorganic ligands,paving the way for high-performance and flexible CQD-based optoelectronic devices.展开更多
The hole transport layer(HTL)-free carbon-based perovskite solar cells(C-PSCs)are promising for commercialization owing to their excellent operational stability and simple fabrication process.However,the power convers...The hole transport layer(HTL)-free carbon-based perovskite solar cells(C-PSCs)are promising for commercialization owing to their excellent operational stability and simple fabrication process.However,the power conversion efficiencies(PCE)of C-PSCs are inferior to the metal electrode-based devices due to their open-circuit voltage(V_(oc))loss.Herein,time-resolved confocal photoluminescence microscopy reveals that grain boundary defects at the perovskite/carbon interface are very likely to function as nonradiative recombination centers in HTL-free C-PSCs.A versatile additive Li_(2)CO_(3)is used to modify the conformal tin oxide electron transport layer for HTL-free C-PSCs.Li_(2)CO_(3)modification can result in enhanced charge extraction and optimized energy alignment at electron transport layer/perovskite interface,as well as suppressed defects at perovskite top surface due to Li_(2)CO_(3)-induced formation of PbI_(2)crystallites.Such dual interfacial passivation ultimately leads to significantly improved Voc up to 1.142 V,which is comparable to the metal electrode-based devices with HTL.Moreover,a record-high PCE of 33.2%is achieved for Li_(2)CO_(3)-modified C-PSCs under weak light illumination conditions,demonstrating excellent indoor photovoltaic performance.This work provides a practical approach to fabricate low-cost,highly efficient carbon-based perovskite solar cells.展开更多
Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numeri...Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numerical parameter analysis is conducted on the key influencing factors of the vibration isolation hole(VIH),which include hole diameter,hole net spacing,hole depth,hole number,hole arrangement,and soil parameters.The results indicate that a smaller ratio of net spacing to hole diameter,the deeper the hole,the multi-row hole,the hole adoption of staggered arrangements,and better site soil conditions can enhance the efficiency of the VIH barrier.The average maximum vibration reduction efficiency within the vibration isolation area can reach 42.2%.The vibration safety of adjacent oil pipelines during a dynamic compaction projection was evaluated according to existing standards,and the measurement of the VIH was recommended to reduce excessive vibration.The single-row vibration isolation scheme and three-row staggered arrangement with the same hole parameters are suggested according to different cases.The research findings can serve as a reference for the vibration safety analysis,assessment,and control of adjacent underground facilities under the influence of strong surface impact loads.展开更多
Understanding the dynamic responses of hard rocks is crucial during deep mining and tunneling activities and when constructing nuclear waste repositories. However, the response of deep massive rocks with openings of d...Understanding the dynamic responses of hard rocks is crucial during deep mining and tunneling activities and when constructing nuclear waste repositories. However, the response of deep massive rocks with openings of different shapes and orientations to dynamic loading is not well understood. Therefore, this study investigates the dynamic responses of hard rocks of deep underground excavation activities. Split Hopkins Pressure Bar (SHPB) tests on granite with holes of different shapes (rectangle, circle, vertical ellipse (elliptical short (ES) axis parallel to the impact load direction), and horizontal ellipse (elliptical long (EL) axis parallel to the impact load direction)) were carried out. The influence of hole shape and location on the dynamic responses was analyzed to reveal the rocks' dynamic strengths and cracking characteristics. We used the ResNet18 (convolutional neural network-based) network to recognize crack types using high-speed photographs. Moreover, a prediction model for the stress-strain response of rocks with different openings was established using Deep Neural Network (DNN). The results show that the dynamic strengths of the granite with EL and ES holes are the highest and lowest, respectively. The strength-weakening coefficient decreases first and then increases with an increase of thickness-span ratio (h/L). The weakening of the granite with ES holes is the most obvious. The ResNet18 network can improve the analyzing efficiency of the cracking mechanism, and the trained model's recognition accuracy reaches 99%. Finally, the dynamic stress-strain prediction model can predict the complete stress-strain curve well, with an accuracy above 85%.展开更多
Owing to the low p-type doping efficiency in the hole injection layers(HILs)of GaN-based ultra-violet(UV)vertical-cavity surface-emitting laser(VCSEL),effective hole injection in multi-quantum wells(MQW)is not achieve...Owing to the low p-type doping efficiency in the hole injection layers(HILs)of GaN-based ultra-violet(UV)vertical-cavity surface-emitting laser(VCSEL),effective hole injection in multi-quantum wells(MQW)is not achieved,significantly limiting the photoelectric performance of UV VCSELs.We developed a slope-shaped HIL and an EBL structure in AlGaN-based UV VCSELs.In this study,by improving hole in-jection efficiency,the hole concentration in the HIL is increased,and the hole barrier at the electron barrier layer(EBL)/HIL interface is decreased.This minimises the hindering effect of hole injection.A mathematic-al model of this structure was established using a commercial software,photonic integrated circuit simulator in three-dimension(PICS3D).We conducted simulations and theoretical analyses of the band structure and carrier concentration.Introducing polarisation doping through the Al composition gradient in the HIL en-hanced the hole concentration,thereby improving the hole injection efficiency.Furthermore,modifying the EBL eliminated the abrupt potential barrier for holes at the HIL/EBL interface,smoothing the valence band.This improved the stimulated radiative recombination rate in the MQW,increasing the laser power.There-fore,the sloped p-type layer can enhance the optoelectronic performance of UV VCSELs.展开更多
A series of solid solutions with high content of Tb_(2)O_(3)-(Tb_(x)Ti_(1−x))4O_(8−2x)(x=0.667-0.830)are synthesized in the Tb_(2)O_(3)-TiO_(2)system via co-precipitation and/or mechanical activation.This is followed ...A series of solid solutions with high content of Tb_(2)O_(3)-(Tb_(x)Ti_(1−x))4O_(8−2x)(x=0.667-0.830)are synthesized in the Tb_(2)O_(3)-TiO_(2)system via co-precipitation and/or mechanical activation.This is followed by high-temperature annealing for 4-22 h.The X-ray diffrac-tion method showed that the fluorite structure was realized for(Tb_(x)Ti_(1−x))4O_(8−2x)(x=0.75-0.817).The solid solution Tb_(3.12)Ti_(0.88)O_(6.44)(64mol%Tb_(2)O_(3)(x=0.78))with a fluorite structure exhibited a maximum hole conductivity of~22 S/cm at 600℃.To separate the ionic component of the conductivity in the electronic conductor Tb_(3.12)Ti_(0.88)O_(6.44),its high entropy analogue,(La_(0.2)Gd_(0.2)Tm_(0.2)Lu_(0.2)Y_(0.2))_(3.12)Ti_(0.88)O_(6.44),was synthesized in which all rare-earth elements(REE)cations exhibited valency of+3.Consequently,the contribution of ionic(proton)conductivity(~7×10^(−6)S/cm at 600℃)was revealed with respect to the background of dominant hole conductivity.The proton conduct-ivity of high-entropy oxide(HEО)(La_(0.2)Gd_(0.2)Tm_(0.2)Lu_(0.2)Y_(0.2))_(3.12)Ti_(0.88)O_(6.44)was confirmed by the detection of the isotope effect,where the mobility of the heavier O-D ions was lower than that of the O-H hydroxyls,resulting in lower conductivity in D_(2)O vapors when com-pared to H_(2)O.展开更多
Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway s...Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway stability and relief effectiveness.In this study,a mechanical model for optimal matching between the large-diameter drilling hole and anchoring hole was established following the principle of synergistic control.The influence of large-diameter drilling hole diameter on the optimal spacing under the synergistic relief effect was investigated by integrating theoretical analysis,numerical simulation,and field practice.The results suggest that the hole spacing achieved a synergistic effect in a certain range when the optimal hole spacing increased linearly with the hole diameter.For instance,when the anchoring hole diameter was 20 mm,an increase in the aperture ratio from 5 to 10 brought about an increase in the optimal spacing from 0.25 m to 0.45 m.Additionally,the vertical stress between the large-diameter drilling hole and anchor hole increased nonlinearly under the condition of constant pore ratio but varying hole spacing.Both excessively small and excessively large hole spacings were detrimental to the pressure relief effect.In the engineering practice,optimizing the hole spacing from 0.55 m to 0.45 m in the 1208 working face contributed to reducing coal body drilling cuttings and the roadway moving quantity by 33%and 19.2%,respectively.This demonstrates that the pressure relief-support reinforcement synergistic effect should be fully considered in optimization design.展开更多
Primordial black holes(PBHs) offer a compelling candidate for dark matter. The production of PBHs through well-tested and accepted physical processes is highly worthy of investigation. This work highlights the role of...Primordial black holes(PBHs) offer a compelling candidate for dark matter. The production of PBHs through well-tested and accepted physical processes is highly worthy of investigation. This work highlights the role of turbulences in the very early universe in sustaining intense and persistent fluctuations in energy or mass density,which could provide a natural mechanism for PBH formation in the primordial universe. We analyze the mass range and abundance of PBHs produced in the magnetohydrodynamic turbulence induced by the electroweak phase transition. Remarkably, we find that the mass range of the produced PBHs falls within the most viable“asteroid mass” window from the present-day observations, and within natural parameter regions their abundance can be sufficiently large. These findings suggest that PBHs produced during magnetohydrodynamic turbulence in the very early universe may comprise a dominant part of dark matter.展开更多
Although lots of efforts have been devoted on new less hygroscopic dopants to address problems in hole transport materials(HTM),the long-time post-oxidation and the volatilization of 4-tert-butylpyridine(tBP)are still...Although lots of efforts have been devoted on new less hygroscopic dopants to address problems in hole transport materials(HTM),the long-time post-oxidation and the volatilization of 4-tert-butylpyridine(tBP)are still issues.A new doping mechanism for spiro-OMeTAD by disulfiram(TETD)is revealed in this work.Owing to its disulfide bond,TETD can be activated easily to produce reactive sulfur for the rapid oxidation of spiro-OMeTAD in the absence of oxygen with formation of[spiro-OMeTAD•]+[SC(S)N(C_(2)H_(5))_(2)]^(-).Thus,in this situation,the Li+ion has the opportunity to coordinate tBP and fix each other in HTM film.DFT calculations suggest that the resulting favorable energy(with a△E of−1.29 eV)must come from the mutual interactions among Li^(+),TFSI^(−),and tBP,which is different from the well-known doping process that tBP would not participate in the doping reaction.As a result,the introduction of a new radical into the HTM greatly reduce device performance fluctuations due to the environmental dependence and inhibit tBP volatilizing for enhanced long-term stability.展开更多
2,2',7,7'-Tetrakis(N,N-di(4-methoxyphenyl)amino)-9,9'-spirobifluorene(Spiro)is an essential hole-transport material used in perovskite solar cells(PSCs).However,the redox reaction of Spiro and its impact a...2,2',7,7'-Tetrakis(N,N-di(4-methoxyphenyl)amino)-9,9'-spirobifluorene(Spiro)is an essential hole-transport material used in perovskite solar cells(PSCs).However,the redox reaction of Spiro and its impact at the interface with the metal electrode are not yet fully understood.In this study,we introduced a crystalline additive(CA)to regulate the redox process of Spiro and its interface with an Ag electrode.Our findings indicate that CA functions as a molecular scaffold,improving the crystallinity and stability of radicals in Spiro throughout the entire redox reaction.This enhancement increases the hole mobility of Spiro and strengthens the internal electric field,thereby improving hole extraction and transport efficiency at both interfaces.Moreover,the optimized redox reaction of Spiro reduces energy loss at the Ag electrode,significantly boosting the power conversion efficiency to 25.21%.Furthermore,CA mitigates the aggregation of lithium salt and enhances the stability of the device.Our findings contribute to a deeper understanding of hole-transport mechanisms of Spiro and emphasize the importance of reducing energy loss at the Spiro/Ag electrode interface in PSCs.展开更多
We assume exponential corrections to the entropy of 5D charged Ad S black hole solutions,which are derived within the framework of Einstein-Gauss-Bonnet gravity and nonlinear electrodynamics.Additionally,we consider t...We assume exponential corrections to the entropy of 5D charged Ad S black hole solutions,which are derived within the framework of Einstein-Gauss-Bonnet gravity and nonlinear electrodynamics.Additionally,we consider two distinct versions of 5D charged Ad S black holes by setting the parameters q→0 and k→0(where q represents the charge,and k is the non-linear parameter).We investigate these black holes in the extended phase space,where the cosmological constant is interpreted as pressure,demonstrating the first law of black hole thermodynamics.The focus extends to understanding the thermal stability or instability,as well as identifying first and second-order phase transitions.This exploration is carried out through the analysis of various thermodynamic quantities,including heat capacity at constant pressure,Gibbs free energy(GFE),Helmholtz free energy(HFE),and the trace of the Hessian matrix.In order to visualize phase transitions,identify critical points,analyze stability and provide comprehensive analysis,we have made the contour plot of the mentioned thermodynamic quantities and observed that our results are very consistent.These investigations are conducted within the context of exponentially corrected entropies,providing valuable insights into the intricate thermodynamic behavior of these 5D charged Ad S black holes under different parameter limits.展开更多
基金supported by the Ministry of Science and Technology(Grant No.2022YFA1403901)the National Natural Science Foundation of China(Grant Nos.12494594,11888101,12174428,and 12504192)+2 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB28000000)the New Cornerstone Investigator Program,the Chinese Academy of Sciences through the Youth Innovation Promotion Association(Grant No.2022YSBR-048)the Shanghai Science and Technology Innovation Action Plan(Grant No.24LZ1400800).
文摘Systems hosting flat bands offer a powerful platform for exploring strong correlation physics.Theoretically,topological degeneracy arising in systems with non-trivial topological orders on periodic manifolds of non-zero genus can generate ideal flat bands.However,experimental realization of such geometrically engineered systems is very difficult.In this work,we demonstrate that flat planes with strategically patterned hole defects can engineer ideal flat bands.We construct two families of models:singular flat band systems where degeneracy is stabilized by non-contractible loop excitations tied to hole defects and perfectly nested van Hove systems where degeneracy arises from line excitations in momentum space.These models circumvent the need for exotic manifolds while retaining the essential features of topological flat bands.By directly linking defect engineering to degeneracy mechanisms,our results establish a scalable framework for experimentally accessible flat band design.
基金This work is supported by National Natural Science Foundation of China(Project No.11702254,SC,www.nsfc.gov.cn)Postdoctoral Science Foundation of China(Project No.2016M592306,SC,www.chinapostdoctor.org.cn)Key Scientific Research Project in Higher Education Institutions of Henan Province(Project No.17A130001,SC,www.haedu.gov.cn).
文摘In this study,a patch removing based Isogeometric analysis(PR-IGA)method is proposed to conduct the holed structural analysis with only one parametric domain,in which there are also no trimmed elements.The theoretical foundation of this novel patch removing approach is that any holed structure can be obtained by removing sub-patches(i.e.,the holes)from an intact base patch.Since the parametric domains of these patches are all meshed by rectangular grids,the elements in the resulted holed structural parametric domain could all be untrimmed rectangles under certain mapping conditions.To achieve the special condition,a systematic technique consisting of T-spline local refinement and control points substitution/adjustment is provided.Due to the intactness of parametric elements,the analysis procedure of holed structures based on the proposed PRIGA is quite simplified and efficient compared to traditional multi-patch and trimming schemes.Moreover,after the deduction of analytical sensitivities related to structural mass and mechanical responses,the PR-IGA is directly employed in the holed structural shape optimization to successfully eliminate the need for model transformation during modeling,analysis and optimization processes.Numerical examples involving analysis and shape optimization of complex holed structures are presented to demonstrate the effectiveness of the proposed method.
基金The authors gratefully acknowledge the financial support by the MRSEC Program of NSF Grant(DMR-0520550).
文摘We have studied the morphology evolution of holed nanostructures formed by aluminum droplet epitaxy on a GaAs surface.Unique outer rings with concentric inner holed rings were observed.Further,an empirical equation to describe the size distribution of the outer rings in the holed nanostructures has been established.The contour line generated by the equation provides physical insights into quantum ring formation by droplets of groupⅢmaterials onⅢ-Ⅴsubstrates.
基金supported by the National Natural Science Foundation of China(Grant No.50776056)the High Technology Research and Development Program of China("863"Program)(Grant No. 2009AA05Z201)
文摘As demonstrated by former work,the holed casing treatment can be used to expand the stall margin of a centrifugal compressor with unshrouded impeller.In addition,the choked margin can also be expanded as experimental results indicated.Moreover,the compressor performance,especially the efficiency,on the whole working range is improved.As shown by experiments,the stall margin and choked margin of the compressor are extended,and the maximum efficiency improvement is 14%at the large flowrate of 1.386.Numerical simulations were carried out to analyze the flow in the impeller and in the holes in the case of large flowrate.The results indicate that in large flowrate conditions,there is a low-pressure region on the throat part of the impeller passage,leading to the bypass flows appearing in the holes,which means the flow area at the inlet of the impeller is increased.The bypass flow can also contribute to the decrease of the Mach number at the throat part near the shroud end-wall which implies that the choked margin is expanded.Besides,as the bypass flow would inhibit the development of the vertexes in the tip clearance and suppress the flow recirculation in the shroud end-wall region,both the pressure ratio and efficiency of the compressor are improved,which agrees well with the experiments.
基金the National Natural Science Foundation of China(Nos.22202126,52273186,51873100,and 62105194)San Qin Scholars Innovation Teams in Shaanxi Province,China,International Joint Research Center of Shaanxi Province for Photoelectric Materials Science,and International Science and Technology Cooperation Project of Shaanxi Province,China(No.2021KW-20).
文摘The coupling of photoanode(Pho)and oxygen evolution catalyst(OEC)is an ideal approach to enhance the photoelectrochemical(PEC)activity.Nevertheless,the anticipated photocurrent density has not been reached due to slow charge transfer dynamics and severe charge recombination at the interface.Herein,a novel“killing two birds with one stone”approach was discovered by employing CoPi as an interface mediator,which shifts its charge transfer behavior from conventional hole storage or passivation to hole transporter.The optimized BiVO_(4)/CoPi/FeOOH photoanode achieves a noteworthy photocurrent density of 5.4 mA/cm^(2) and exhibits long term stability(13 h).The dynamic analysis and electrochemical characterization reveal that CoPi can rapidly and directly transfer more photogenerated holes to the surface of OEC in comparison to traditional slow holes transfer behavior,resulting in highly efficient interface charge separation.Interestingly,the strong interfacial interactions can also be extended to OEC/electrolyte interface,specifically by promoting the surface reaction dynamics.Moreover,this innovative approach of altering behavior of CoPi can also be utilized to design other photoanodes,like BiVO_(4)/CoPi/NiOOH,aimed at efficient PEC water splitting.This finding affords a smart strategy to develop highly efficient and stable photoelectrodes for water splitting.
基金supported by the National Natural Science Foundation of China (Grant Nos.12074213 and 11574108)the Major Basic Program of Natural Science Foundation of Shandong Province (Grant No.ZR2021ZD01)the Natural Science Foundation of Shandong Province (Grant No.ZR2023MA082)。
文摘In recent years,the research on superconductivity in one-dimensional(1D)materials has been attracting increasing attention due to its potential applications in low-dimensional nanodevices.However,the critical temperature(T_(c))of 1D superconductors is low.In this work,we theoretically investigate the possible high T_(c) superconductivity of(5,5)carbon nanotube(CNT).The pristine(5,5)CNT is a Dirac semimetal and can be modulated into a semiconductor by full hydrogenation.Interestingly,by further hole doping,it can be regulated into a metallic state with the sp3-hybridized𝜎electrons metalized,and a giant Kohn anomaly appears in the optical phonons.The two factors together enhance the electron–phonon coupling,and lead to high-T_(c) superconductivity.When the hole doping concentration of hydrogenated-(5,5)CNT is 2.5 hole/cell,the calculated T_(c) is 82.3 K,exceeding the boiling point of liquid nitrogen.Therefore,the predicted hole-doped hydrogenated-(5,5)CNT provides a new platform for 1D high-T_(c) superconductivity and may have potential applications in 1D nanodevices.
文摘LOKIBASE is a non-linear isolator/dissipator device to protect pallet racking systems against the earthquake.LOKIBASE consists of the following main components:(1)two slider devices on which a rubber membrane is set up(LOKI devices).LOKI devices are linear displacement dependent ones;(2)a cylindrical beam damper(“CANDLE”device).The“CANDLE”device is a non-linear displacement dependent one;(3)two anti-lifting devices(“UP-LIFT”devices);(4)a fuse plug(see www.lokibasedevice.com).The main work which is the purpose of the paper,is the optimization of the behavior of an isolator/dissipator device to mitigate the seismic action on special structures,where the stiffness values are very different in the main cross-aisle and down-aisle directions.Under seismic action,in these structures it is very important to reduce the value of the forces at the Limit state for the safeguard of human life(SLV)in the down-aisle direction as much as possible and simultaneously to use the highest damping value allowed by the building rules to reduce the LOKIBASE displacement at the Limit state for collapse prevention(SLC)in the cross-aisle direction.The goal was achieved through a cylindrical device made of stainless steel(AISI304)with an optimized shape,under large displacement during seismic action.
基金the support of the Xingliao Talent Program of Liaoning Province(No.XLYC2001004)the High Level Talents Innovation Plan of Dalian(No.2020RD02)the Fundamental Research Funds for the Central Universities(No.DUT22LAB501).
文摘SiC_(f)/SiC ceramic matrix composites(SiC_(f)/SiC composites)are difficult to drill small holes due to their heterogeneity,high hardness,and low electrical conductivity.In order to solve the difficulties of poor quality and low efficiency when drilling small holes,a novel femtosecond laser rotary drilling(FLRD)technique is proposed.Beam kinematic paths and experimental studies were carried out to analyze the effects of processing parameters on the drilling results in the two-step drilling process.In the through-hole drilling stage,the material removal rate increases with increasing laser power,decreasing feed speed and decreasing pitch.As for the finishing stage of drilling,the exit diameter increased with increasing laser power and decreasing feed speed.The drilling parameters were selected by taking the processing efficiency of through-hole and the quality of finished hole as the constraint criteria.Holes with a diameter of 500μm were drilled using FLRD in 3 mm thick SiC_(f)/SiC composites with a drilling time<150 s.The hole aspect ratio was 6,the taper<0.2°,and there was no significant thermal damage at the orifice or the wall of the hole.The FLRD provides a solution for precision machining of small holes in difficult-to-machine materials by offering the advantages of high processing quality and short drilling times.
文摘In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were investigated by using a single factor variable method.The surface morphologies of the shell molds produced by different temperatures of the surface(first)layer slurries were observed via electron microscopy.Furthermore,the microscopic composition of these shell molds was obtained by EDS,and the osmotic effect of the slurry on the wax patterns at different temperatures was also assessed by the PZ-200 Contact Angle detector.The forming reasons for the surface cracks and holes of thick and large ZTC4 titanium alloy by investment casting were analyzed.The experimental results show that the surface of the shell molds prepared by the surface layer slurry with a low temperature exhibits noticeable damage,which is mainly due to the poor coating performance and the serious expansion and contraction of wax pattern at low temperatures.The second layer shell material(SiO_(2),Al_(2)O_(3))immerses into the crack area of the surface layer,contacts and reacts with the molten titanium to form surface cracks and holes in the castings.With the increase of the temperature of surface layer slurry,the damage to the shell surface tends to weaken,and the composition of the shell molds'surface becomes more uniform with less impurities.The results show that the surface layer slurry at 22℃is evenly coated on the surface of the wax patterns with appropriate thickness,and there is no surface shell mold rupture caused by sliding slurry after sand leaching.The surface layer slurry temperature is consistent with the wax pattern temperature and the workshop temperature,so there is no damage of the surface layer shell caused by expansion and contraction.Therefore,the shell mold prepared by the surface layer slurry at this temperature has good integrity,isolating the contact between the low inert shell material and the titanium liquid effectively,and the ZTC4 titanium alloy cylinder casting prepared by this shell mold is smooth,without cracks and holes.
基金supported by MEXT KAKENHI Grant(24K01295,26286013).
文摘Traditional p-type colloidal quantum dot(CQD)hole transport layers(HTLs)used in CQD solar cells(CQDSCs)are commonly based on organic ligands exchange and the layer-by-layer(LbL)technique.Nonetheless,the ligand detachment and complex fabrication process introduce surface defects,compromising device stability and efficiency.In this work,we propose a solution-phase ligand exchange(SPLE)method utilizing inorganic ligands to develop stable p-type lead sulfide(PbS)CQD inks for the first time.Various amounts of tin(Ⅱ)iodide(SnI_(2))were mixed with lead halide(PbX_(2);X=I,Br)in the ligand solution.By precisely controlling the SnI_(2)concentration,we regulate the transition of PbS QDs from n-type to p-type.PbS CQDSCs were fabricated using two different HTL approaches:one with 1,2-ethanedithiol(EDT)-passivated QDs via the LbL method(control)and another with inorganic ligand-passivated QD ink(target).The target devices achieved a higher power conversion efficiency(PCE)of 10.93%,compared to 9.83%for the control devices.This improvement is attributed to reduced interfacial defects and enhanced carrier mobility.The proposed technique offers an efficient pathway for producing stable p-type PbS CQD inks using inorganic ligands,paving the way for high-performance and flexible CQD-based optoelectronic devices.
基金supported by the National Natural Science Foundation of China(62104059,12104126,61935016,52173153)Nature Science Foundation of Hebei Province(F2021202044)the Science Research Project of Hebei Education Department(ZD2021031)。
文摘The hole transport layer(HTL)-free carbon-based perovskite solar cells(C-PSCs)are promising for commercialization owing to their excellent operational stability and simple fabrication process.However,the power conversion efficiencies(PCE)of C-PSCs are inferior to the metal electrode-based devices due to their open-circuit voltage(V_(oc))loss.Herein,time-resolved confocal photoluminescence microscopy reveals that grain boundary defects at the perovskite/carbon interface are very likely to function as nonradiative recombination centers in HTL-free C-PSCs.A versatile additive Li_(2)CO_(3)is used to modify the conformal tin oxide electron transport layer for HTL-free C-PSCs.Li_(2)CO_(3)modification can result in enhanced charge extraction and optimized energy alignment at electron transport layer/perovskite interface,as well as suppressed defects at perovskite top surface due to Li_(2)CO_(3)-induced formation of PbI_(2)crystallites.Such dual interfacial passivation ultimately leads to significantly improved Voc up to 1.142 V,which is comparable to the metal electrode-based devices with HTL.Moreover,a record-high PCE of 33.2%is achieved for Li_(2)CO_(3)-modified C-PSCs under weak light illumination conditions,demonstrating excellent indoor photovoltaic performance.This work provides a practical approach to fabricate low-cost,highly efficient carbon-based perovskite solar cells.
基金National Natural Science Foundation of China under Grant Nos.52078386 and 52308496SINOMACH Youth Science and Technology Fund under Grant No.QNJJ-PY-2022-02+2 种基金Young Elite Scientists Sponsorship Program under Grant No.BYESS2023432Fund of State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,Jianghan University under Grant No.PBSKL2023A9Fund of China Railway Construction Group Co.,Ltd.under Grant No.LX19-04b。
文摘Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numerical parameter analysis is conducted on the key influencing factors of the vibration isolation hole(VIH),which include hole diameter,hole net spacing,hole depth,hole number,hole arrangement,and soil parameters.The results indicate that a smaller ratio of net spacing to hole diameter,the deeper the hole,the multi-row hole,the hole adoption of staggered arrangements,and better site soil conditions can enhance the efficiency of the VIH barrier.The average maximum vibration reduction efficiency within the vibration isolation area can reach 42.2%.The vibration safety of adjacent oil pipelines during a dynamic compaction projection was evaluated according to existing standards,and the measurement of the VIH was recommended to reduce excessive vibration.The single-row vibration isolation scheme and three-row staggered arrangement with the same hole parameters are suggested according to different cases.The research findings can serve as a reference for the vibration safety analysis,assessment,and control of adjacent underground facilities under the influence of strong surface impact loads.
基金funding support from the National Natural Science Foundation of China(Grant No.52374119)the opening fund of State Key Laboratory of Coal Mine Disaster Dynamics and Control(Grant No.2011DA105827-FW202209)the opening fund of State Key Laboratory of Performance Monitoring and Protecting of Rail Transit Infrastructure,East China Jiaotong University(Grant No.HJGZ2023103).
文摘Understanding the dynamic responses of hard rocks is crucial during deep mining and tunneling activities and when constructing nuclear waste repositories. However, the response of deep massive rocks with openings of different shapes and orientations to dynamic loading is not well understood. Therefore, this study investigates the dynamic responses of hard rocks of deep underground excavation activities. Split Hopkins Pressure Bar (SHPB) tests on granite with holes of different shapes (rectangle, circle, vertical ellipse (elliptical short (ES) axis parallel to the impact load direction), and horizontal ellipse (elliptical long (EL) axis parallel to the impact load direction)) were carried out. The influence of hole shape and location on the dynamic responses was analyzed to reveal the rocks' dynamic strengths and cracking characteristics. We used the ResNet18 (convolutional neural network-based) network to recognize crack types using high-speed photographs. Moreover, a prediction model for the stress-strain response of rocks with different openings was established using Deep Neural Network (DNN). The results show that the dynamic strengths of the granite with EL and ES holes are the highest and lowest, respectively. The strength-weakening coefficient decreases first and then increases with an increase of thickness-span ratio (h/L). The weakening of the granite with ES holes is the most obvious. The ResNet18 network can improve the analyzing efficiency of the cracking mechanism, and the trained model's recognition accuracy reaches 99%. Finally, the dynamic stress-strain prediction model can predict the complete stress-strain curve well, with an accuracy above 85%.
文摘Owing to the low p-type doping efficiency in the hole injection layers(HILs)of GaN-based ultra-violet(UV)vertical-cavity surface-emitting laser(VCSEL),effective hole injection in multi-quantum wells(MQW)is not achieved,significantly limiting the photoelectric performance of UV VCSELs.We developed a slope-shaped HIL and an EBL structure in AlGaN-based UV VCSELs.In this study,by improving hole in-jection efficiency,the hole concentration in the HIL is increased,and the hole barrier at the electron barrier layer(EBL)/HIL interface is decreased.This minimises the hindering effect of hole injection.A mathematic-al model of this structure was established using a commercial software,photonic integrated circuit simulator in three-dimension(PICS3D).We conducted simulations and theoretical analyses of the band structure and carrier concentration.Introducing polarisation doping through the Al composition gradient in the HIL en-hanced the hole concentration,thereby improving the hole injection efficiency.Furthermore,modifying the EBL eliminated the abrupt potential barrier for holes at the HIL/EBL interface,smoothing the valence band.This improved the stimulated radiative recombination rate in the MQW,increasing the laser power.There-fore,the sloped p-type layer can enhance the optoelectronic performance of UV VCSELs.
基金the state assignment on the topic“Interdisciplinary approaches to the creation and study of micro-/nanostructured systems”(No.125012200595-8)Conductivity measurements of the samples were performed in accordance with the state task for FRC PCP and MC RAS(No.124013000692-4).
文摘A series of solid solutions with high content of Tb_(2)O_(3)-(Tb_(x)Ti_(1−x))4O_(8−2x)(x=0.667-0.830)are synthesized in the Tb_(2)O_(3)-TiO_(2)system via co-precipitation and/or mechanical activation.This is followed by high-temperature annealing for 4-22 h.The X-ray diffrac-tion method showed that the fluorite structure was realized for(Tb_(x)Ti_(1−x))4O_(8−2x)(x=0.75-0.817).The solid solution Tb_(3.12)Ti_(0.88)O_(6.44)(64mol%Tb_(2)O_(3)(x=0.78))with a fluorite structure exhibited a maximum hole conductivity of~22 S/cm at 600℃.To separate the ionic component of the conductivity in the electronic conductor Tb_(3.12)Ti_(0.88)O_(6.44),its high entropy analogue,(La_(0.2)Gd_(0.2)Tm_(0.2)Lu_(0.2)Y_(0.2))_(3.12)Ti_(0.88)O_(6.44),was synthesized in which all rare-earth elements(REE)cations exhibited valency of+3.Consequently,the contribution of ionic(proton)conductivity(~7×10^(−6)S/cm at 600℃)was revealed with respect to the background of dominant hole conductivity.The proton conduct-ivity of high-entropy oxide(HEО)(La_(0.2)Gd_(0.2)Tm_(0.2)Lu_(0.2)Y_(0.2))_(3.12)Ti_(0.88)O_(6.44)was confirmed by the detection of the isotope effect,where the mobility of the heavier O-D ions was lower than that of the O-H hydroxyls,resulting in lower conductivity in D_(2)O vapors when com-pared to H_(2)O.
基金Project(52274086)supported by the National Natural Science Foundation of ChinaProject(2024KJH069)supported by the Shandong Provincial Youth Innovation and Technology Support Program,ChinaProject(tstp20221126)supported by the Project of Taishan Scholar in Shandong Province,China。
文摘Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway stability and relief effectiveness.In this study,a mechanical model for optimal matching between the large-diameter drilling hole and anchoring hole was established following the principle of synergistic control.The influence of large-diameter drilling hole diameter on the optimal spacing under the synergistic relief effect was investigated by integrating theoretical analysis,numerical simulation,and field practice.The results suggest that the hole spacing achieved a synergistic effect in a certain range when the optimal hole spacing increased linearly with the hole diameter.For instance,when the anchoring hole diameter was 20 mm,an increase in the aperture ratio from 5 to 10 brought about an increase in the optimal spacing from 0.25 m to 0.45 m.Additionally,the vertical stress between the large-diameter drilling hole and anchor hole increased nonlinearly under the condition of constant pore ratio but varying hole spacing.Both excessively small and excessively large hole spacings were detrimental to the pressure relief effect.In the engineering practice,optimizing the hole spacing from 0.55 m to 0.45 m in the 1208 working face contributed to reducing coal body drilling cuttings and the roadway moving quantity by 33%and 19.2%,respectively.This demonstrates that the pressure relief-support reinforcement synergistic effect should be fully considered in optimization design.
基金supported by the International Partnership Program of the Chinese Academy of Sciences (Grant No.025GJHZ2023106GC)。
文摘Primordial black holes(PBHs) offer a compelling candidate for dark matter. The production of PBHs through well-tested and accepted physical processes is highly worthy of investigation. This work highlights the role of turbulences in the very early universe in sustaining intense and persistent fluctuations in energy or mass density,which could provide a natural mechanism for PBH formation in the primordial universe. We analyze the mass range and abundance of PBHs produced in the magnetohydrodynamic turbulence induced by the electroweak phase transition. Remarkably, we find that the mass range of the produced PBHs falls within the most viable“asteroid mass” window from the present-day observations, and within natural parameter regions their abundance can be sufficiently large. These findings suggest that PBHs produced during magnetohydrodynamic turbulence in the very early universe may comprise a dominant part of dark matter.
基金supported by the National Natural Science Foundation of China(Nos.52001066,21805039,22375045,22373015 and 22271046)the Natural Science Foundation of Fujian Province(No.2023J01500)Young teacher training program of Fujian Normal University(No.SDPY2023013).
文摘Although lots of efforts have been devoted on new less hygroscopic dopants to address problems in hole transport materials(HTM),the long-time post-oxidation and the volatilization of 4-tert-butylpyridine(tBP)are still issues.A new doping mechanism for spiro-OMeTAD by disulfiram(TETD)is revealed in this work.Owing to its disulfide bond,TETD can be activated easily to produce reactive sulfur for the rapid oxidation of spiro-OMeTAD in the absence of oxygen with formation of[spiro-OMeTAD•]+[SC(S)N(C_(2)H_(5))_(2)]^(-).Thus,in this situation,the Li+ion has the opportunity to coordinate tBP and fix each other in HTM film.DFT calculations suggest that the resulting favorable energy(with a△E of−1.29 eV)must come from the mutual interactions among Li^(+),TFSI^(−),and tBP,which is different from the well-known doping process that tBP would not participate in the doping reaction.As a result,the introduction of a new radical into the HTM greatly reduce device performance fluctuations due to the environmental dependence and inhibit tBP volatilizing for enhanced long-term stability.
基金the National Natural Science Foundation of China(22209144)the Project of the Natural Science Foundation of Yunnan+4 种基金the Yunnan Revitalization Talent Support Program(202201AU070030 and 202201AT070114)the support from the National Natural Science Foundation of China(22065038)the High-Level Talents Introduction in Yunnan Province(C619300A010)the Fund for Excellent Young Scholars of Yunnan(202001AW070008)financial support from the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)under grant number RS-2024-00444389。
文摘2,2',7,7'-Tetrakis(N,N-di(4-methoxyphenyl)amino)-9,9'-spirobifluorene(Spiro)is an essential hole-transport material used in perovskite solar cells(PSCs).However,the redox reaction of Spiro and its impact at the interface with the metal electrode are not yet fully understood.In this study,we introduced a crystalline additive(CA)to regulate the redox process of Spiro and its interface with an Ag electrode.Our findings indicate that CA functions as a molecular scaffold,improving the crystallinity and stability of radicals in Spiro throughout the entire redox reaction.This enhancement increases the hole mobility of Spiro and strengthens the internal electric field,thereby improving hole extraction and transport efficiency at both interfaces.Moreover,the optimized redox reaction of Spiro reduces energy loss at the Ag electrode,significantly boosting the power conversion efficiency to 25.21%.Furthermore,CA mitigates the aggregation of lithium salt and enhances the stability of the device.Our findings contribute to a deeper understanding of hole-transport mechanisms of Spiro and emphasize the importance of reducing energy loss at the Spiro/Ag electrode interface in PSCs.
基金the Deanship of Research and Graduate Studies at King Khalid University for funding this work through Large Research Project under Grant No.RGP2/539/45。
文摘We assume exponential corrections to the entropy of 5D charged Ad S black hole solutions,which are derived within the framework of Einstein-Gauss-Bonnet gravity and nonlinear electrodynamics.Additionally,we consider two distinct versions of 5D charged Ad S black holes by setting the parameters q→0 and k→0(where q represents the charge,and k is the non-linear parameter).We investigate these black holes in the extended phase space,where the cosmological constant is interpreted as pressure,demonstrating the first law of black hole thermodynamics.The focus extends to understanding the thermal stability or instability,as well as identifying first and second-order phase transitions.This exploration is carried out through the analysis of various thermodynamic quantities,including heat capacity at constant pressure,Gibbs free energy(GFE),Helmholtz free energy(HFE),and the trace of the Hessian matrix.In order to visualize phase transitions,identify critical points,analyze stability and provide comprehensive analysis,we have made the contour plot of the mentioned thermodynamic quantities and observed that our results are very consistent.These investigations are conducted within the context of exponentially corrected entropies,providing valuable insights into the intricate thermodynamic behavior of these 5D charged Ad S black holes under different parameter limits.
