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Effect of Substrate Micro-arc Oxidation Pretreatment on Microstructure and High-Temperature Oxidation Resistance of Si-Cr-Ti-Zr Coating on Ta12W Alloy
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作者 Yang Fan Chang Jianxiu +2 位作者 Wang Xin Li Hongzhan Yan Peng 《稀有金属材料与工程》 北大核心 2026年第1期92-104,共13页
To mitigate the impact of interdiffusion reactions between the silicide slurry and Ta12W alloy substrate during vacuum sintering process on the oxidation resistance of the silicide coating,a micro-arc oxidation pretre... To mitigate the impact of interdiffusion reactions between the silicide slurry and Ta12W alloy substrate during vacuum sintering process on the oxidation resistance of the silicide coating,a micro-arc oxidation pretreatment was employed to construct a Ta_(2)O_(5)ceramic layer on the Ta12W alloy surface.Subsequently,a slurry spraying-vacuum sintering method was used to prepare a Si-Cr-Ti-Zr coating on the pretreated substrate.Comparative studies were conducted on the microstructure,phase composition,and isothermal oxidation resistance(at 1600℃)of the as-prepared coatings with and without the micro-arc oxidation ceramic layer.The results show that the Ta_(2)O_(5)layer prepared at 400 V is more continuous and has smaller pores than that prepared at 350 V.After microarc oxidation pretreatment,the Si-Cr-Ti-Zr coating on Ta12W alloy consists of three distinct layers:an upper layer dominated by Ti_(5)Si_(3),Ta_(5)Si_(3),and ZrSi;a middle layer dominated by TaSi_(2);a coating/substrate interfacial reaction layer dominated by Ta_(5)Si_(3).Both the Si-Cr-Ti-Zr coatings with and without the Ta_(2)O_(5)ceramic layer do not fail after isothermal oxidation at 1600℃for 5 h.Notably,the addition of the Ta2O5 ceramic layer reduces the high-temperature oxidation rate of the coating. 展开更多
关键词 tantalum-tungsten alloy silicide coating micro-arc oxidation reaction formation mechanism high-temperature oxidation
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Impact of Burial Dissolution on the Development of Ultradeep Fault-controlled Carbonate Reservoirs:Insights from High-temperature and High-pressure Dissolution Kinetic Simulation 被引量:1
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作者 TAN Xiaolin ZENG Lianbo +6 位作者 SHE Min LI Hao MAO Zhe SONG Yichen YAO Yingtao WANG Junpeng LU Yuzhen 《Acta Geologica Sinica(English Edition)》 2025年第1期228-242,共15页
Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temper... Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temperature and highpressure dissolution kinetic simulations were conducted.The results demonstrate that the intensity of burial dissolution is controlled by temperature and pressure,while tectonic-fluid activity influences the development pattern of burial dissolution,ultimately determining the direction of its differential modification.Extensive burial dissolution is likely to occur primarily at relatively shallow depths,significantly influencing reservoir formation,preservation,modification,and adjustment.The development of faults facilitates the maintenance of the intensity of burial dissolution.The maximum intensity of burial dissolution occurs at the tips and overlap zones of faults and intersections of multiple faults.The larger the scale of the faults,the more conducive it is to the development of burial dissolution.Burial dissolution fosters the formation of fault networks characterized by enhanced reservoir capacity and permeability.Burial dissolution controlled by episodic tectonic-fluid activity is a plausible explanation for forming the Tarim Basin's ultra-deep fault-controlled“stringbead-like”reservoirs. 展开更多
关键词 burial dissolution tectonic-fluid ultra-deep carbonate reservoirs high-temperature and high-pressure dissolution kinetic simulation
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Recent advances in high-temperature oxidation behavior and underlying mechanisms of Mg-RE alloys:A comprehensive review
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作者 Yu Ma Yu Cao +4 位作者 Yulian Kuang Yajun Wang Yuhao Gong Bin Jiang Jonghyun Kim 《International Journal of Minerals,Metallurgy and Materials》 2026年第2期446-466,共21页
The limited high-temperature oxidation resistance of Mg alloys is a key factor restricting their development and application.The addition of some rare earth elements(REs),owing to their unique physical and chemical pr... The limited high-temperature oxidation resistance of Mg alloys is a key factor restricting their development and application.The addition of some rare earth elements(REs),owing to their unique physical and chemical properties,can significantly enhance the oxidation resistance of Mg alloys.Based on our previous study,we conclude that REs such as Gd,Y,and Ce enhance the oxidation resistance of Mg-RE alloys.This article comprehensively reviews recent research progress on high-temperature oxidation behavior and the potential mechanism in Mg-RE alloys.Based on the thermodynamic and kinetic analyses,the evolution of the complex oxide system formed during the high-temperature oxidation of Mg-RE alloys is first summarized.The diffusion behavior and concentration control mechanisms of REs during the oxidation process and how these mechanisms affect the sustained growth of the oxide film and antioxidant properties were elucidated.Moreover,the different structures of the oxide films were classified,and their properties were discussed.Finally,this paper introduces the applications of commonly used REs in Mg alloys and frontier research on their oxidation mechanisms.Based on the above review,we propose that future research perspectives can be explored in terms of expanding the experimental temperature range for oxidation tests,optimizing the chemical composition by adding trace REs to study their synergistic mechanism,revealing the underlying oxidation mechanism through advanced in situ microscopic characterization methods,and investigating the mechanical properties of oxide films using diverse approaches. 展开更多
关键词 magnesium-rare earth element alloy high-temperature oxidation THERMODYNAMICS oxidation resistance oxide films
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High-temperature oxidation resistance of TiB_(2)coatings on molybdenum produced by molten salt electrophoretic deposition
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作者 Qian Kou Chuntao Ge +6 位作者 Yanlu Zhou Wenjuan Qi Junjie Xu Weiliang Jin Jun Zhang Hongmin Zhu Saijun Xiao 《International Journal of Minerals,Metallurgy and Materials》 2026年第1期282-291,共10页
TiB_(2)coatings can significantly enhance the high-temperature oxidation resistance of molybdenum,which would broaden the application range of molybdenum and alloys thereof.However,traditional methods for preparing Ti... TiB_(2)coatings can significantly enhance the high-temperature oxidation resistance of molybdenum,which would broaden the application range of molybdenum and alloys thereof.However,traditional methods for preparing TiB_(2)coatings have disadvantages such as high equipment costs,complicated processes,and highly toxic gas emissions.This paper proposes an environmentally friendly method,which requires inexpensive equipment and simple processing,for preparing TiB_(2)coating on molybdenum via electrophoretic deposition within Na3AlF6-based molten salts.The produced TiB_(2)layer had an approximate thickness of 60μm and exhibited high density,outstanding hardness(38.2 GPa)and robust adhesion strength(51 N).Additionally,high-temperature oxidation experiments revealed that,at900℃,the TiB_(2)coating provided effective protection to the molybdenum substrate against oxidation for 3 h.This result indicates that the TiB_(2)coating prepared on molybdenum using molten salt electrophoretic deposition possesses good high-temperature oxidation resistance. 展开更多
关键词 molten salt electrophoretic deposition MOLYBDENUM TiB_(2)coating high-temperature oxidation resistance
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3D printed high-temperature ceramic conformal array antenna:Design,analysis,manufacturing,and testing
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作者 Peng Li Ruibo Li +5 位作者 Zijiao Fan Jiujiu Han Guangda Ding Qunbiao Wang Wanye Xu Paolo Rocca 《Defence Technology(防务技术)》 2026年第1期340-353,共14页
In this study,the design,analysis,manufacturing,and testing of a 3D-printed conformal microstrip array antenna for high-temperature environments is presented.3D printing technology is used to fabricate a curved cerami... In this study,the design,analysis,manufacturing,and testing of a 3D-printed conformal microstrip array antenna for high-temperature environments is presented.3D printing technology is used to fabricate a curved ceramic substrate,and laser sintering and microdroplet spraying processes are used to add the conductive metal on the curved substrate.The problems of gain loss,bandwidth reduction,and frequency shift caused by high temperatures are addressed by using a proper antenna design,with parasitic patches,slots,and metal resonant cavities.The antenna prototype is characterized by the curved substrates and the conductive metals for the power dividers,the patch,and the ground plane;its performance is examined up to a temperature of 600℃in a muffle furnace and compared with the results from the numerical analysis.The results show that the antenna can effectively function at 600℃and even higher temperatures. 展开更多
关键词 Ceramic antenna Conformal array high-temperature environment 3D printing High gain and wide band
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Recent Advances in Hydrothermal Carbonization of Biomass:The Role of Process Parameters and the Applications of Hydrochar
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作者 Cheng Zhang Rui Zhang +5 位作者 Yu Shao Jiabin Wang Qianyue Yang Fang Xie Rongling Yang Hongzhen Luo 《Journal of Renewable Materials》 2026年第1期53-74,共22页
Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of... Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field. 展开更多
关键词 BIOMASS LIGNOCELLULOSE hydrothermal carbonization hydrochar application FERMENTATION
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High-Temperature Stable Dispersed Particle Gel for Enhanced Profile Control in Carbon Capture,Utilization,and Storage(CCUS)Applications 被引量:1
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作者 Lin Du Yao-Yu Xiao +2 位作者 Zhi-Chao Jiang Hongbo Zeng Huazhou Li 《Engineering》 2025年第5期128-140,共13页
CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voir... CO_(2)-responsive gels,which swell upon contact with CO_(2),are widely used for profile control to plug high-permeability gas flow channels in carbon capture,utilization,and storage(CCUS)applications in oil reser-voirs.However,the use of these gels in high-temperature CCUS applications is limited due to their rever-sible swelling behavior at elevated temperatures.In this study,a novel dispersed particle gel(DPG)suspension is developed for high-temperature profile control in CCUS applications.First,we synthesize a double-network hydrogel consisting of a crosslinked polyacrylamide(PAAm)network and a crosslinked sodium alginate(SA)network.The hydrogel is then sheared in water to form a pre-prepared DPG suspen-sion.To enhance its performance,the gel particles are modified by introducing potassium methylsilan-etriolate(PMS)upon CO_(2) exposure.Comparing the particle size distributions of the modified and pre-prepared DPG suspension reveals a significant swelling of gel particles,over twice their original size.Moreover,subjecting the new DPG suspension to a 100℃ environment for 24 h demonstrates that its gel particle sizes do not decrease,confirming irreversible swelling,which is a significant advantage over the traditional CO_(2)-responsive gels.Thermogravimetric analysis further indicates improved thermal sta-bility compared to the pre-prepared DPG particles.Core flooding experiments show that the new DPG suspension achieves a high plugging efficiency of 95.3%in plugging an ultra-high permeability sandpack,whereas the pre-prepared DPG suspension achieves only 82.8%.With its high swelling ratio,irreversible swelling at high temperatures,enhanced thermal stability,and superior plugging performance,the newly developed DPG suspension in this work presents a highly promising solution for profile control in high-temperature CCUS applications. 展开更多
关键词 carbon capture utilization and storage Profile control Dispersed particle gel Double-network hydrogel Irreversible swelling
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Effect of h-BN rods on high-temperature properties of alumina-carbon refractory
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作者 Ya-ge Li Shuai-bing Wu +8 位作者 Feng Liang Zhong Huang Tu Long Long Dong Jun-yi Lv Hong-juan Duan Biao Wen Yong Liu Hai-jun Zhang 《Journal of Iron and Steel Research International》 2025年第1期115-128,共14页
h-BN rods modified low-carbon alumina-carbon(Al_(2)O_(3)-C)refractories were prepared,and the effect of h-BN rod addition on the high-temperature properties was investigated and compared with commercial h-BN flake,car... h-BN rods modified low-carbon alumina-carbon(Al_(2)O_(3)-C)refractories were prepared,and the effect of h-BN rod addition on the high-temperature properties was investigated and compared with commercial h-BN flake,carbon black,and carbon nanotubes additives.The results demonstrated that Al_(2)O_(3)-C refractories containing h-BN rods exhibited optimal high-temperature service performances,including 25%higher hot modulus of rupture,21.3%higher thermal shock strength residual ratio,20.9%lower in oxidation and 44.3%less in slag corrosion,compared to the counterpart specimens without additives.Moreover,benefiting from the synergistic enhancement of the rod-like h-BN and in-situ generated SiC whiskers,the high-temperature service performances of h-BN rods containing specimens outperformed counterpart specimens containing commercial h-BN flake,carbon black,and carbon nanotubes,respectively. 展开更多
关键词 Al_(2)O_(3)-C refractory h-BN rod MICROSTRUCTURE high-temperature service performance
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Production of carbon anodes by high-temperature mould pressing 被引量:4
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作者 王耀武 彭建平 +1 位作者 狄跃忠 冯乃祥 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第10期3119-3124,共6页
Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition o... Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy (SEM), and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved. 展开更多
关键词 carbon anodes high temperature mould pressing aluminum electrolysis high bulk density
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Combing the Entropy Weight Method with Fuzzy Mathematics for Assessing the Quality and Post-Ripening Mechanism of High-Temperature Daqu during Storage 被引量:1
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作者 YANG Junlin YANG Shaojuan +8 位作者 WU Cheng YIN Yanshun YOU Xiaolong ZHAO Wenyu ZHU Anran WANG Jia HU Feng HU Jianfeng WANG Diqiang 《食品科学》 北大核心 2025年第9期48-62,共15页
This study investigated the physicochemical properties,enzyme activities,volatile flavor components,microbial communities,and sensory evaluation of high-temperature Daqu(HTD)during the maturation process,and a standar... This study investigated the physicochemical properties,enzyme activities,volatile flavor components,microbial communities,and sensory evaluation of high-temperature Daqu(HTD)during the maturation process,and a standard system was established for comprehensive quality evaluation of HTD.There were obvious changes in the physicochemical properties,enzyme activities,and volatile flavor components at different storage periods,which affected the sensory evaluation of HTD to a certain extent.The results of high-throughput sequencing revealed significant microbial diversity,and showed that the bacterial community changed significantly more than did the fungal community.During the storage process,the dominant bacterial genera were Kroppenstedtia and Thermoascus.The correlation between dominant microorganisms and quality indicators highlighted their role in HTD quality.Lactococcus,Candida,Pichia,Paecilomyces,and protease activity played a crucial role in the formation of isovaleraldehyde.Acidic protease activity had the greatest impact on the microbial community.Moisture promoted isobutyric acid generation.Furthermore,the comprehensive quality evaluation standard system was established by the entropy weight method combined with multi-factor fuzzy mathematics.Consequently,this study provides innovative insights for comprehensive quality evaluation of HTD during storage and establishes a groundwork for scientific and rational storage of HTD and quality control of sauce-flavor Baijiu. 展开更多
关键词 microbial community high-temperature Daqu comprehensive quality evaluation entropy weight method maturation process
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High-Temperature Oxidation Property and Corrosion and Wear Resistance of Laser Cladding Co-based Coatings on Pure Zr Surface 被引量:1
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作者 Xia Chaoqun Yang Bo +3 位作者 Liu Shuguang Zhang Bo Zhong Hua Li Qiang 《稀有金属材料与工程》 北大核心 2025年第6期1397-1409,共13页
Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,a... Co-based alloy coating was prepared on Zr alloy using laser melting and cladding technique to study the difference in the high-temperature oxidation behavior between pure metal Co coatings and Co-T800 alloy coatings,as well as the wear resistance of the coatings.Besides,the effect of changing the laser melting process on the coatings was also investigated.The oxidation mass gain at 800–1200℃and the high-temperature oxidation behavior during high-temperature treatment for 1 h of two coated Zr alloy samples were studied.Results show that the Co coating and the Co-T800 coating have better resistance against high-temperature oxidation.After oxidizing at 1000℃for 1 h,the thickness of the oxide layer of the uncoated sample was 241.0μm,whereas that of the sample with Co-based coating is only 11.8–35.5μm.The friction wear test shows that the depth of the abrasion mark of the coated sample is only 1/2 of that of the substrate,indicating that the hardness and wear resistance of the Zr substrate are greatly improved.The disadvantage of Co-based coatings is the inferior corrosion resistance in 3.5wt%NaCl solution. 展开更多
关键词 Zr metal laser cladding Co-based coating high-temperature oxidation resistance wear resistance
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Micro/nano multiscale reinforcing strategies toward extreme high-temperature applications:Take carbon/carbon composites and their coatings as the examples 被引量:18
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作者 Qiangang Fu Pei Zhang +6 位作者 Lei Zhuang Lei Zhou Jiaping Zhang Jie Wang Xianghui Hou Ralf Riedel Hejun Li 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第1期31-68,共38页
Carbon fiber reinforced carbon composites(C/Cs),are the most promising high-temperature materials and could be widely applied in aerospace and nucleation fields,owing to their superior performances.However,C/Cs are ve... Carbon fiber reinforced carbon composites(C/Cs),are the most promising high-temperature materials and could be widely applied in aerospace and nucleation fields,owing to their superior performances.However,C/Cs are very susceptible to destructive oxidation and thus fail at elevated temperatures.Though matrix modification and coating technologies with Si-based and ultra-high temperature ceramics(UHTCs)are valid to enhance the oxidation/ablation resistance of C/Cs,it’s not sufficient to satisfy the increasing practical applications,due to the inherent brittleness of ceramics,mismatch issues between coatings and C/C substrates,and the fact that carbonaceous matrices are easily prone to high-temperature oxidation.To effectively solve the aforementioned problems,micro/nano multiscale reinforcing strategies have been developed for C/Cs and/or the coatings over the past two decades,to fabricate C/Cs with high strength and excellent high-temperature stability.This review is to systematically summarize the most recent major and important advancements in some micro/nano multiscale strategies,including nanoparticles,nanowires,carbon nanotubes/fibers,whiskers,graphene,ceramic fibers and hybrid micro/nano structures,for C/Cs and/or the coatings,to achieve high-temperature oxidation/ablation-resistant C/Cs.Finally,this review is concluded with an outlook of major unsolved problems,challenges to be met and future research advice for C/Cs with excellent comprehensive mechanical-thermal performance.It’s hoped that a better understanding of this review will be of high scientific and industrial interest,since it provides unusual and feasible new ideas to develop potential and practical C/Cs with improved high-temperature mechanical and oxidation/ablation-resistant properties. 展开更多
关键词 carbon/carbon composites Micro/nano multiscale reinforcing strategies Oxidation Ablation EROSION Hybrid structures
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Improvement of High-Temperature Mechanical Properties of Low-Carbon RAFM Steel by MX Precipitates 被引量:2
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作者 Jianguo Chen Yongchang Liu +3 位作者 Yantong xiao Yihuan Liu Chenxi Liu Huijun Li 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2018年第7期706-712,共7页
To investigate the influence of tantalum content on high-temperature mechanical properties of low-carbon reduced acti- vation ferritic/martensitic (RAFM) steels, RAFM steels containing different tantalum contents (... To investigate the influence of tantalum content on high-temperature mechanical properties of low-carbon reduced acti- vation ferritic/martensitic (RAFM) steels, RAFM steels containing different tantalum contents (0 and 0.073%) were fabricated, and the tensile tests at room temperature and high temperature were performed, as well as the creep tests were conducted at 550 ~C with the applied stress of 180 and 220 MPa. It was found that 0.073% tantalum addition results in the increase in amount of stable carbonitrides (MX), and the creep rupture time of the steel under 180 MPa is obviously increased. In addition, the increase in MX caused by tantalum addition also leads to the improvement of high-temperature tensile strength. The improvement of high-temperature mechanical properties of RAFM steels is primarily related to the evolution of precipitates. 展开更多
关键词 Low-carbon RAFM steels Tantalum addition PRECIPITATES high-temperature mechanical properties
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In Situ Partial-Cyclized Polymerized Acrylonitrile-Coated NCM811 Cathode for High-Temperature≥100℃ Stable Solid-State Lithium Metal Batteries 被引量:2
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作者 Jiayi Zheng Haolong Jiang +13 位作者 Xieyu Xu Jie Zhao Xia Ma Weiwei Sun Shuangke Liu Wei Xie Yufang Chen ShiZhao Xiong Hui Wang Kai Xie Yu Han Maoyi Yi Chunman Zheng Qingpeng Guo 《Nano-Micro Letters》 2025年第8期399-415,共17页
High-nickel ternary cathodes hold a great application prospect in solid-state lithium metal batteries to achieve high-energy density,but they still suffer from structural instability and detrimental side reactions wit... High-nickel ternary cathodes hold a great application prospect in solid-state lithium metal batteries to achieve high-energy density,but they still suffer from structural instability and detrimental side reactions with the solid-state electrolytes.To circumvent these issues,a continuous uniform layer polyacrylonitrile(PAN)was introduced on the surface of LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2) via in situ polymerization of acrylonitrile(AN).Furthermore,the partial-cyclized treatment of PAN(cPAN)coating layer presents high ionic and electron conductivity,which can accelerate interfacial Li+and electron diffusion simultaneously.And the thermodynamically stabilized cPAN coating layer cannot only effectively inhibit detrimental side reactions between cathode and solid-state electrolytes but also provide a homogeneous stress to simultaneously address the problems of bulk structural degradation,which contributes to the exceptional mechanical and electrochemical stabilities of the modified electrode.Besides,the coordination bond interaction between the cPAN and NCM811 can suppress the migration of Ni to elevate the stability of the crystal structure.Benefited from these,the In-cPAN-260@NCM811 shows excellent cycling performance with a retention of 86.8%after 300 cycles and superior rate capability.And endow the solid-state battery with thermal safety stability even at hightemperature extreme environment.This facile and scalable surface engineering represents significant progress in developing high-performance solid-state lithium metal batteries. 展开更多
关键词 Solid-state lithium metal battery Ni-rich cathode Interface engineering In situ partial-cyclized PAN high-temperature resistance
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Novel entropy-stabilized spinel materials and their potential application in high-temperature industry:[(Mg_(x)Zn_((1-x)/2)Cu_((1-x)/2))(Al_(0.9)Fe_(0.1))_(2)O_(4)](x=0.5,0.6,0.7,and 0.8) 被引量:1
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作者 Bo-Kang Li Lv-Ping Fu +2 位作者 Hua-Zhi Gu Ao Huang Shuang Yang 《Rare Metals》 2025年第8期5844-5858,共15页
High-temperature industries,as the primary consumers of energy,are greatly concerned with energy savings.Designing refractory linings with low thermal conductivity to reduce heat dissipation through high-temperature f... High-temperature industries,as the primary consumers of energy,are greatly concerned with energy savings.Designing refractory linings with low thermal conductivity to reduce heat dissipation through high-temperature furnace linings is a critical concern.In this study,a series of novel entropy-stabilized spinel materials are reported,and their potential applications in high-temperature industries are investigated.XRD and TEM results indicate that all materials possess a cubic spinel crystal structure with the■space group.Furthermore,these materials exhibit good phase stability at high temperatures.All entropy-stabilized spinel aggregates demonstrated high refractoriness(>1800℃)and a high load softening temperature(>1700℃).The impact of configurational entropy on the properties of entropy-stabilized spinel materials was also studied.As configurational entropy increased,the thermal conductivity of the entropy-stabilized spinel decreased,while slag corrosion resistance deteriorated.For the entropy-stabilized spinel with a configurational entropy value of 1.126R,it showed good high-temperature stability,reliable resistance to slag attack,and a low thermal conductivity of 2.776 W·m^(-1)·K^(-1)at 1000℃. 展开更多
关键词 Entropy-stabilized spinel Thermal conductivity high-temperature performance Configurational entropy
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In-situ high-temperature EBSD study of austenite reversion from martensite,bainite and pearlite in a high-strength steel 被引量:1
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作者 X.L.Wang X.Y.Wang +2 位作者 Z.P.Liu Z.J.Xie C.J.Shang 《Journal of Materials Science & Technology》 2025年第14期268-280,共13页
The austenite(γ)reversely transformed from lath martensite(LM),lath bainite(LB),granular bainite(GB)and pearlite+ferrite(P+F)in a high-strength steel was studied at high temperatures using in-situ electron backscatte... The austenite(γ)reversely transformed from lath martensite(LM),lath bainite(LB),granular bainite(GB)and pearlite+ferrite(P+F)in a high-strength steel was studied at high temperatures using in-situ electron backscatter diffraction(EBSD).The memory effect of initial γ significantly affects the nucleation of the reverted γ in LM and GB structures,while a weak influence on that of LB and P+F structures.This results in a significant difference in γ grain size after complete austenitization,with the first two obtaining larger γ grains while the latter two are relatively small.Crystallographic analysis revealed that the reverted γ with acicular morphology(γA),most of which maintained the same orientation with the prior γ,dominated the reaustenitization behavior of LM and GB structures through preferential nucleation within γ grains and coalesced growth modes.Although globular reverted γ(γ_(G))with random orientation or large deviation from the prior γ can nucleate at the grain boundaries or within the grains,it is difficult for it to grow and play a role in segmenting and refining the prior γ due to the inhibition of γ_(A) coalescing.For LB and P+F structures,the nucleation rate of intragranular γ_(G) increases with increasing temperature,and always shows a random orientation.These γ_(G) grains can coarsen simultaneously with the intergranular γ_(G),ultimately playing a role in jointly dividing and refining the finalγgrains.Research also found that the differences in the effects of four different microstructures on revertedγnucleation are closely related to the variant selection of the matrix structure,as well as the content and size of cementite(θ).High density of block boundaries induced by weakening of variant selection and many fineθformed in the lath are the key to promoting LB structure to obtain more intragranular γ_(G) formation,as well as the important role of the large-sized θ in P+F structure. 展开更多
关键词 In-situ characterization high-temperature EBSD Austenite reversion CEMENTITE Nucleation and growth Crystallography
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Properties evolutions during carbonization of carbon foam using lignin as sole precursor 被引量:1
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作者 Chen Liang Weiqiang Chen +4 位作者 Linghong Yin Xianli Wu Jie Xu Chunhua Du Wangda Qu 《Chinese Journal of Chemical Engineering》 2025年第2期33-43,共11页
Lignin has been proved to be a promising precursor for producing carbon foam.The thermal and chemistry properties of lignin during its thermal conversion make it quite unique comparing with other precursors,and the co... Lignin has been proved to be a promising precursor for producing carbon foam.The thermal and chemistry properties of lignin during its thermal conversion make it quite unique comparing with other precursors,and the conversion parameters can clearly affect the properties of the derived products.Therefore,this study systematically investigated the effects of key carbonization parameters on the properties of the resulting carbon foam materials.The findings demonstrate that the performance of the self-shaping lignin-derived carbon foam is simultaneously influenced by the factors that carbonization temperature,heating rate,and carbonization duration.Specifically,the carbonization temperature and carbonization duration have a significant impact on the mechanical performance,where higher temperatures and long carbonization time improve compressive strength and specific strength.Moreover,the data revealed that elevated temperatures,rapid heating rates,and shortened carbonization periods collectively promoted the development of higher porosities and larger pore diameters within the carbon foam structure.Conversely,lower carbonization temperatures,slower heating rates,and extended carbonization durations facilitated the formation of microporous in the carbon foam.This study provides a scientific foundation for optimizing the production of lignin-derived carbon foam with tailored properties and performance characteristics. 展开更多
关键词 Lignin based carbon foam BIOMASS carbonization Mechanical properties Morphology Pore structure
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Pre-Drilling Prediction Techniques on the High-Temperature High-Pressure Hydrocarbon Reservoirs Offshore Hainan Island,China 被引量:3
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作者 ZHANG Hanyu LIU Huaishan +6 位作者 WU Shiguo SUN Jin YANG Chaoqun XIE Yangbing CHEN Chuanxu GAO Jinwei WANG Jiliang 《Journal of Ocean University of China》 SCIE CAS CSCD 2018年第1期72-82,共11页
Decreasing the risks and geohazards associated with drilling engineering in high-temperature high-pressure(HTHP) geologic settings begins with the implementation of pre-drilling prediction techniques(PPTs). To improve... Decreasing the risks and geohazards associated with drilling engineering in high-temperature high-pressure(HTHP) geologic settings begins with the implementation of pre-drilling prediction techniques(PPTs). To improve the accuracy of geopressure prediction in HTHP hydrocarbon reservoirs offshore Hainan Island, we made a comprehensive summary of current PPTs to identify existing problems and challenges by analyzing the global distribution of HTHP hydrocarbon reservoirs, the research status of PPTs, and the geologic setting and its HTHP formation mechanism. Our research results indicate that the HTHP formation mechanism in the study area is caused by multiple factors, including rapid loading, diapir intrusions, hydrocarbon generation, and the thermal expansion of pore fluids. Due to this multi-factor interaction, a cloud of HTHP hydrocarbon reservoirs has developed in the Ying-Qiong Basin, but only traditional PPTs have been implemented, based on the assumption of conditions that do not conform to the actual geologic environment, e.g., Bellotti's law and Eaton's law. In this paper, we focus on these issues, identify some challenges and solutions, and call for further PPT research to address the drawbacks of previous works and meet the challenges associated with the deepwater technology gap. In this way, we hope to contribute to the improved accuracy of geopressure prediction prior to drilling and provide support for future HTHP drilling offshore Hainan Island. 展开更多
关键词 pre-drilling prediction techniques formation PORE pressure high-temperature high-pressure hydrocarbon RESERVOIRS HAINAN Island Ying-Qiong Basin
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Effect of side track height on aerodynamic characteristics of a high-speed high-temperature superconducting maglev train under crosswind 被引量:1
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作者 Yiming PAN Zongpeng LI +3 位作者 Xiaofei WANG Hongmin ZHAO Weihua ZHANG Zigang DENG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 2025年第10期983-996,共14页
Currently,the design of high-temperature superconducting(HTS)maglev trains adopts a U-shaped track operation mode,and the height of the side track significantly impacts the train’s aerodynamic characteristics.In this... Currently,the design of high-temperature superconducting(HTS)maglev trains adopts a U-shaped track operation mode,and the height of the side track significantly impacts the train’s aerodynamic characteristics.In this study,we used computational fluid dynamics(CFD)methods,based on the 3D Reynolds-averaged Navier-Stokes(RANS)method and shear stress transport(SST)k-ωturbulence model,to deeply investigate the effects of the presence or absence of a U-shaped track and different side track heights(800,880,and 960 mm)on the pressure distribution,velocity distribution,and flow field structure of HTS maglev trains at a speed of 400 km/h under crosswinds.The numerical methods were verified using a scaled ICE-2 model wind tunnel test.First,the aerodynamic characteristics of the train under different wind direction angles with and without side tracks were studied.We found that the aerodynamic performance of the train is the most adverse when the wind direction angle is 90°.The presence of a U-shaped track can effectively reduce the lateral force,lift,and yawing moment of the train.The aerodynamic performance of the first suspension bogie at the bottom,which is the worst,will also be effectively improved.Next,the aerodynamic effects of different side track heights on the HTS maglev train were studied.An increase in side track height will reduce the lift and lateral force of the train,while the increase in drag is relatively small.Under the premise of ensuring passengers can conveniently alight,we found that a U-shaped track with a side track height of 960 mm has the best aerodynamic performance.The research findings offer a valuable reference for the engineering application and design of the track structure of HTS maglev train systems. 展开更多
关键词 high-temperature superconducting(HTS) High-speed maglev train U-shaped track CROSSWIND Numerical simulation
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High-temperature effect on continuous glass fiber reinforced polypropylene multilayer composite and corrugated sandwich panels 被引量:1
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作者 Shuyan NIE Xin PAN +2 位作者 Liming CHEN Bing DU Jie WANG 《Chinese Journal of Aeronautics》 2025年第1期607-621,共15页
The high-temperature mechanical behaviors of Multi-Layer Composite Panels(MCP)and Corrugated Sandwich Panels(CSP)of Continuous Glass Fiber-Reinforced Polypropylene(CGFRPP)are critical for their application in aerospac... The high-temperature mechanical behaviors of Multi-Layer Composite Panels(MCP)and Corrugated Sandwich Panels(CSP)of Continuous Glass Fiber-Reinforced Polypropylene(CGFRPP)are critical for their application in aerospace fields,which have been rarely mentioned in previous studies.High-temperature quasi-static tensile and compression tests on CGFRPP MCP are conducted first.The results showed that the tensile and compression strength,stiffness,and tensile modulus of MCP decreased with increasing temperature.The Gibson model was found to be more suitable for predicting the high-temperature mechanical performance of MCP after comparing the calculated results of different theoretical models with experimental data.Secondly,hightemperature planar compression tests were conducted on the CGFRPP CSP,revealing that the main failure modes were corrugated core buckling and delamination between the face panel and core material,with delamination being intensified at higher temperatures.Therefore,we proposed a strength theoretical model that considers structural buckling failure and interface delamination failure,and introduced the influence factor to evaluate the effect of interface delamination on structural strength. 展开更多
关键词 high-temperature effect Fiber reinforced plastic Composite structure Sandwich structure Interface delamination Strength theory
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