Bedding slope is a typical heterogeneous slope consisting of different soil/rock layers and is likely to slide along the weakest interface.Conventional slope protection methods for bedding slopes,such as retaining wal...Bedding slope is a typical heterogeneous slope consisting of different soil/rock layers and is likely to slide along the weakest interface.Conventional slope protection methods for bedding slopes,such as retaining walls,stabilizing piles,and anchors,are time-consuming and labor-and energy-intensive.This study proposes an innovative polymer grout method to improve the bearing capacity and reduce the displacement of bedding slopes.A series of large-scale model tests were carried out to verify the effectiveness of polymer grout in protecting bedding slopes.Specifically,load-displacement relationships and failure patterns were analyzed for different testing slopes with various dosages of polymer.Results show the great potential of polymer grout in improving bearing capacity,reducing settlement,and protecting slopes from being crushed under shearing.The polymer-treated slopes remained structurally intact,while the untreated slope exhibited considerable damage when subjected to loads surpassing the bearing capacity.It is also found that polymer-cemented soils concentrate around the injection pipe,forming a fan-shaped sheet-like structure.This study proves the improvement of polymer grouting for bedding slope treatment and will contribute to the development of a fast method to protect bedding slopes from landslides.展开更多
High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress aro...High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress arouses the deformation of large integrated die-castings.Herein,the development of non-heat treatment Al alloys is becoming the hot topic.In addition,HPDC contains externally solidified crystals(ESCs),which are detrimental to the mechanical properties of castings.To achieve high strength and toughness of non-heat treatment die-casting Al-Si alloy,we used AlSi9Mn alloy as matrix with the introduction of Zr,Ti,Nb,and Ce.Their influences on ESCs and mechanical properties were systematically investigated through three-dimensional reconstruction and thermodynamic simulation.Our results reveal that the addition of Ti increased ESCs'size and porosity,while the introduction of Nb refined ESCs and decreased porosity.Meanwhile,large-sized Al_3(Zr,Ti)phases formed and degraded the mechanical properties.Subsequent introduction of Ce resulted in the poisoning effect and reduced mechanical properties.展开更多
Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temper...Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temperature and highpressure dissolution kinetic simulations were conducted.The results demonstrate that the intensity of burial dissolution is controlled by temperature and pressure,while tectonic-fluid activity influences the development pattern of burial dissolution,ultimately determining the direction of its differential modification.Extensive burial dissolution is likely to occur primarily at relatively shallow depths,significantly influencing reservoir formation,preservation,modification,and adjustment.The development of faults facilitates the maintenance of the intensity of burial dissolution.The maximum intensity of burial dissolution occurs at the tips and overlap zones of faults and intersections of multiple faults.The larger the scale of the faults,the more conducive it is to the development of burial dissolution.Burial dissolution fosters the formation of fault networks characterized by enhanced reservoir capacity and permeability.Burial dissolution controlled by episodic tectonic-fluid activity is a plausible explanation for forming the Tarim Basin's ultra-deep fault-controlled“stringbead-like”reservoirs.展开更多
Grouting has been the most effective approach to mitigate water inrush disasters in underground engineering due to its ability to plug groundwater and enhance rock strength.Nevertheless,there is a lack of potent numer...Grouting has been the most effective approach to mitigate water inrush disasters in underground engineering due to its ability to plug groundwater and enhance rock strength.Nevertheless,there is a lack of potent numerical tools for assessing the grouting effectiveness in water-rich fractured strata.In this study,the hydro-mechanical coupled discontinuous deformation analysis(HM-DDA)is inaugurally extended to simulate the grouting process in a water-rich discrete fracture network(DFN),including the slurry migration,fracture dilation,water plugging in a seepage field,and joint reinforcement after coagulation.To validate the capabilities of the developed method,several numerical examples are conducted incorporating the Newtonian fluid and Bingham slurry.The simulation results closely align with the analytical solutions.Additionally,a set of compression tests is conducted on the fresh and grouted rock specimens to verify the reinforcement method and calibrate the rational properties of reinforced joints.An engineering-scale model based on a real water inrush case of the Yonglian tunnel in a water-rich fractured zone has been established.The model demonstrates the effectiveness of grouting reinforcement in mitigating water inrush disaster.The results indicate that increased grouting pressure greatly affects the regulation of water outflow from the tunnel face and the prevention of rock detachment face after excavation.展开更多
The chloride penetration resistance of cement-based grout materials was improved by nano-silica emulsion.Specimens of mixtures containing different nano-silica particles or emulsions were exposed in sodium chloride so...The chloride penetration resistance of cement-based grout materials was improved by nano-silica emulsion.Specimens of mixtures containing different nano-silica particles or emulsions were exposed in sodium chloride solutions of specific concentrations with different test ages.Hardened properties of the mixes were assessed in terms of weight loss and compressive strength.X-ray diffraction(XRD)and scanning electron microscopy(SEM)of mixes were performed to analysis the phase evolution and microstructure.The results demonstrated that the introduction of nano-SiO_(2) emulsion significantly decreased the compressive strength loss and calcium hydroxide(CH)crystal content of hydration production,and then enhanced the resistance of cement-based grouting materials to chloride ion penetration.This improvement derives from the filling and pozzolanic effects of nano-SiO_(2) particles,which were incorporated via an emulsion and attributed to a well dispersion in grouting matrix.展开更多
Degradable metals,represented by magnesium and magnesium alloys,have attracted significant attention as fracture internal fixation and bone defect repairing materials due to their good biocompatibility,suitable elasti...Degradable metals,represented by magnesium and magnesium alloys,have attracted significant attention as fracture internal fixation and bone defect repairing materials due to their good biocompatibility,suitable elastic modulus and degradable properties.The Mg-3Zn-1Ca-0.5Sr(wt%)alloy is considered a competitor in the biomaterial field thanks to its unique composition of essential nutrients and excellent mechanical properties.However,the presence of coarse second-phase particles in the alloy accelerates its degradation rate and causes excessive gas formation during implantation,which restricts the alloy's potential for clinical device applications.In order to further optimize the properties of the alloy,extrusion combined with high-pressure torsion(HPT)was adopted for deformation processing.The results show that by optimizing the material processing means,the grain can be refined and broken,and the second-phase distribution can be improved,thus improving the microstructure,mechanical properties,and corrosion resistance of the alloy.After 15 cycles of HPT processing,the grains of the alloy are significantly refined to the nanometer scale,reaching approximately 98 nm.Additionally,the second-phase distribution is greatly improved,transforming the original streamlined structure into a more dispersed distribution.This change in microstructure leads to a significant strengthening effect on the alloy,with a noticeable increase in hardness from 60.3 HV in the as-extruded state to 98.5 HV.展开更多
Appropriate determination of the mix ratios of cement grouts is of vital importance to the quality of rock grouting and the risk reduction of groundwater inflow.The behavior of grout,often highly temperature dependent...Appropriate determination of the mix ratios of cement grouts is of vital importance to the quality of rock grouting and the risk reduction of groundwater inflow.The behavior of grout,often highly temperature dependent,is likely to be affected by the elevated ground temperature in deep rock masses.This paper aims to experimentally gain insights into the effects of elevated ground temperatures on the properties of cement grout in fresh and hardened states in deep rock grouting.The results revealed that a temperature of 35°C is crucial for changes in the properties of thick cement grout with a water–cement ratio of less than 0.8.When the temperature is up to 35°C,there can be significant improvements in rheological parameters,acceleration of grout setting,and increase in the rheological time dependence of thick cement grout;however,there may also be a slight impact on the initial grout flowability and the nature of shear thinning.The high temperature may still improve the stability of fresh cement grout and also improve the porosity and creep deformation of hardened cement grout considerably.The proposed constitutive model that couples the Burgers model with a fractional derivativebased Abel dashpot in the series can be used to characterize the creep behavior of hardened cement grout appropriately.The paper provides a valuable reference for optimization of mixture design of cement grouts,thus enhancing deep rock grouting quality and improving safety.展开更多
Suction bucket jacket foundations exhibit considerable potential for implementation in deep-sea offshore wind power projects. To address water film formation resulting from negative pressure penetration during constru...Suction bucket jacket foundations exhibit considerable potential for implementation in deep-sea offshore wind power projects. To address water film formation resulting from negative pressure penetration during construction, certain suction bucket jacket foundation projects implement grouting techniques to ensure adequate bearing capacity. This study conducted a large-scale suction bucket foundation grouting model experiment to examine grout flow characteristics and specific phenomena under various grouting pipeline configurations. Comparative analyses of grouting efficiency and quality across different pipeline layouts identified critical influencing factors and their impact on grouting performance. The results demonstrate that the number of grout outlets should be maintained within an optimal range:insufficient outlets enhance the indentation effect and decrease fill efficiency, while excessive outlets necessitate precise spacing for effective distribution. Additionally, grout outlets should be uniformly arranged to reduce segregation and enhance overall grouting quality. This study's findings provide a scientific foundation for optimizing grouting design in suction bucket jacket foundations, with substantial implications for engineering applications.展开更多
Curtain grouting projects are characterized by their large scale and complexity,presenting significant challenges for real-time prediction of grout penetration using traditional methods.This study introduces an intell...Curtain grouting projects are characterized by their large scale and complexity,presenting significant challenges for real-time prediction of grout penetration using traditional methods.This study introduces an intelligent prediction method for grouting in fractured rock masses based on three core principles:integration of multi-source input features,fracture voxel modeling,and shortest path in sequential grouting.Three categories of data(geological structure data,grouting environmental data,and grouting operation data in the concept of a grouting geological model)are integrated and served as multi-source structured data in the intelligent prediction of grouting.A voxelization model quantifies the spatial characteristics of fractures,with voxel size optimized for capturing grouting paths.A shortest path algorithm based on a hierarchical solution is then developed to calculate grout penetration distances in the process of sequential grouting.A complete analysis framework is established,from the voxelization of the fracture network model to precise voxel classification,ultimately achieving an accurate prediction of grout penetration.The method demonstrates excellent performance on the test set,with validation against numerical methods in single-fracture and sequential grouting scenarios confirming its accuracy and prediction efficiency as hundreds of times faster than numerical methods.Application to the Dongzhuang hydraulic project’s grouting test area further validates its effectiveness in multi-hole grouting scenarios.展开更多
Grouting injection is a vital technique for addressing the challenges of high stress and significant deformation in the surrounding rock during deep mining operations,playing a crucial role in promoting green and low-...Grouting injection is a vital technique for addressing the challenges of high stress and significant deformation in the surrounding rock during deep mining operations,playing a crucial role in promoting green and low-carbon extraction methodologies.In this study,grouting reinforcement processes were examined by conducting grouting experiments on a fractured rock with varying negative pressures(0-100 kPa),followed by uniaxial compression testing of the grout-reinforced bodies.This investigation explored the diffusion patterns of grout under negative pressure and established a constitutive model of damage-bearing capacity for bodies reinforced by negative pressure grouting.It further studied the enhancement effect of negative pressure on the load-bearing capacity of the reinforced bodies and analyzed the instability mechanism of damage and failure in these bodies.The results indicated that the diffusion of grout under negative pressure is influenced by four types of forces,which alter the extent of grout diffusion within the fractured rock mass.Introducing a damage constitutive model that serially connects pore and framework elements characterizes the damage and failure behavior of groutreinforced bodies under different negative pressures.As the negative pressure increases,changes in porosity,water-to-cement ratio,and admixture quantity occur in the grout-reinforced specimens,with the strength mean curve showing a trend of first increasing and then decreasing,reaching a threshold at a negative pressure of 60 kPa.With increasing negative pressure,the negative pressure damage variable decreases and then increases,and the stronger the interfacial microelement connections caused by the negative pressure,the greater the bearing capacity,ultimately manifesting in different failure modes.展开更多
The ongoing operation of subway systems makes existing tunnels vulnerable to deformations and structural damage caused by adjacent foundation pit construction.Such deformations-manifesting as horizontal displacement,h...The ongoing operation of subway systems makes existing tunnels vulnerable to deformations and structural damage caused by adjacent foundation pit construction.Such deformations-manifesting as horizontal displacement,heightened lateral convergence,and internal force redistribution-may significantly compromise subway operational safety.Grouting remediation has become a widely adopted solution for tunnel deformation control and structural reinforcement.Developing optimized grouting materials is crucial for improving remediation effectiveness,ensuring structural integrity,and maintaining uninterrupted subway operations.This investigation explores the substitution of fine mortar aggregates with 0.1 mm discarded rubber particles at varying concentrations(0%,3%,6%,9%,12%,and 15%).Experimental parameters included three water-cement ratios(0.65,0.70,and 0.75)with constant 4%WPU content.Mechanical properties including compressive strength,flexural strength,and compression-to-bending ratio were evaluated across specified curing periods.Material characterization employed Fourier Transform Infrared Spectroscopy(FTIR)spectroscopy for molecular analysis and Scanning Electron Microscopy(SEM)for microstructural examination.Results indicate optimal toughness at 0.70 water-cement ratio with 6%rubber content,meeting mechanical pumping specifications while maintaining structural performance.展开更多
Grouting is a widely applied technique for reinforcing fractured zones in deep soft rock tunnels.By infiltrating rock fissures,slurry materials enhance structural integrity and improve the overall stability of the sur...Grouting is a widely applied technique for reinforcing fractured zones in deep soft rock tunnels.By infiltrating rock fissures,slurry materials enhance structural integrity and improve the overall stability of the surrounding rock.The performance of grouting is primarily governed by the flow behavior and diffusion extent of the slurry.This review considers recent advances in the theory and methodology of slurry flow and diffusion in fractured rock.It examines commonly used grout materials,including cement-based,chemical,and composite formulations,each offering distinct advantages for specific geological conditions.Themechanisms of reinforcement vary significantly across materials,requiring tailored application strategies.The rheological properties of grouting slurries,particularly cement-based types,have been widely modeled using classical constitutive approaches.However,the influence of time-and space-dependent viscosity evolution on slurry behavior remains underexplored.Experimental studies have provided valuable insights into slurry diffusion,yet further research is needed to capture real-time behavior under multi-scale and multi-physics coupling conditions.Similarly,current numerical simulations are largely limited to twoand three-dimensional models of single-fracture flow.These models often neglect the complexity of fracture networks and geological heterogeneity,highlighting a need for more realistic and integrated simulation frameworks.Future research should focus on:(1)fine-scale modeling of slurry hydration and mechanical reinforcement processes;(2)cross-scale analysis of slurry flow under coupled thermal,hydraulic,andmechanical fields;and(3)development of realtime,three-dimensional dynamic simulation tools to capture the full grouting process.These efforts will strengthen the theoretical foundation and practical effectiveness of grouting in complex underground environments.展开更多
With the global oil and gas industry increasingly targeting ultra-deep well development,the demand for wear resistance in polycrystalline diamond compact(PDC)bits is increasing.However,further improvement of the mecha...With the global oil and gas industry increasingly targeting ultra-deep well development,the demand for wear resistance in polycrystalline diamond compact(PDC)bits is increasing.However,further improvement of the mechanical properties of PDC incurs prohibitively elevated costs and stringent technological challenges.Here,we present a two-stage high-pressure infiltration(HPI)methodology involving cobalt removal pretreatment followed by lubricant infiltration.The successful infiltration of lubricants into diamond micropores has been systematically verified,and the effects of lubricant phase composition,infiltration pressure,and temperature on infiltration depth have been thoroughly investigated.Fractal dimension analysis characterizes the pore structure of cobalt-removed diamonds,revealing a strong correlation between the fractal dimension and friction coefficient reduction.Tribological testing confirms the formation of lubricating films at friction interfaces,achieving a 71.5%reduction in the coefficient of friction for lubricant-containing diamond materials.This straightforward strategy opens a gate to developing the next generation of self-lubricating diamond materials.展开更多
A rotary sealing device that automatically compensates for wear is designed to address the issues of easy wear and the short service life of the rotary sealing device with automatic wear compensation in mining machine...A rotary sealing device that automatically compensates for wear is designed to address the issues of easy wear and the short service life of the rotary sealing device with automatic wear compensation in mining machinery.After the end face of the guide sleeve wears out,it still tightly adheres to the sealing valve seat under the pressure difference,achieving automatic wear compensation.Based on fluid-solid coupling technology,the structural strength of the rotary sealing device was checked.The influence of factors on the sealing performance of rotary sealing devices was studied using the control variable method.The results show that as the pressure of water increases,the leakage rate of the sealing device decreases,and after 30 MPa,the leakage rate is almost 0 mL/h.The temperature of the rotating sealing device increases with the increase of rotation speed or pressure,and the temperature is more affected by the rotation speed factor.The frictional torque increases with increasing pressure and is independent of rotational speed.Comprehensive analysis shows that the wear resistance and reliability level of the sealing guide sleeve material is PVDF>PEEK>PE>PA.This study designs a high-pressure automatic compensation wear rotary sealing device and selects the optimal sealing material,providing technical support for the application of high-pressure water jet in mining machinery.展开更多
Perovskite oxynitrides AB(N,O)_(3), a crucial class in materials science, have attracted much attention. By precisely controlling A-and B-site ions and tuning the N/O ratio, new materials with exotic charge states and...Perovskite oxynitrides AB(N,O)_(3), a crucial class in materials science, have attracted much attention. By precisely controlling A-and B-site ions and tuning the N/O ratio, new materials with exotic charge states and intriguing electronic behaviors can be designed and synthesized. In this work, a novel oxynitride perovskite, CeNbO_(2)N, was prepared under high-temperature and high-pressure conditions. The compound crystallizes in an orthorhombic perovskite structure in Pnma symmetry with disordered N/O distribution. The x-ray absorption spectroscopy confirms the presence of a Nb^(4+) state with 4d^(1) electronic configuration in CeNbO_(2)N. As a result, the resistivity of CeNbO_(2)N is sharply reduced compared to its counterpart CeTa^(5+)ON_(2) and other Nb^(5+) compounds. No long-range spin order is found to occur with the temperature down to 2 K in CeNbO_(2)N, while a remarkable negative magnetoresistance effect shows up at lower temperatures, probably due to the magnetic scattering arising from short-range spin correlations.展开更多
Iron nitride(Fe_(x)N_y) is a promising candidate for the next generation of ferromagnetic materials. However, synthesizing high-quality bulk iron nitride with tuned structure and magnetic properties remains a challeng...Iron nitride(Fe_(x)N_y) is a promising candidate for the next generation of ferromagnetic materials. However, synthesizing high-quality bulk iron nitride with tuned structure and magnetic properties remains a challenge. Currently, experimental and theoretical results regarding the magnetic property of iron nitrides remain controversial. With the recent advancements in high-pressure technology, new synthetic pathways to iron nitrides have been proposed. High-pressure synthesis technology provides multidimensional possibilities for tuning the structure and magnetic properties of iron nitrides. This review summarizes recent progress in high-pressure synthesis of iron nitrides, especially the high-pressure solid-state metathesis reaction synthesis(HSM). We have summarized the reaction characteristics of HSM. The HSM reaction exhibits vector synthesis characteristics and promotes nitrogen disorder diffusion at high temperature. Due to this, the HSM reaction can achieve the synthesis of multinary iron-based metal nitrides and regulate the local magnetic moments. It serves as a powerful means for tuning the structure and magnetic properties of iron nitrides. Taking advantage of neutron diffraction in characterizing local magnetic moment and nitrogen disorder in iron nitrides, the relationship between iron local magnetic moment and nitrogen content has been elucidated. Moreover, the development of high-pressure in-situ imaging technology based on large-volume press allows the real-time observation of HSM reaction process. In this review, we also report our latest experiments on neutron diffraction and high-pressure in-situ image for the study of iron nitrides.展开更多
The Suizhou meteorite is a heavily shock-met-amorphosed L6 chondrite which contains thin shock melt veins.So far,26 high-pressure phases have been identified from the meteorite.Among the high-pressure phases,ten of th...The Suizhou meteorite is a heavily shock-met-amorphosed L6 chondrite which contains thin shock melt veins.So far,26 high-pressure phases have been identified from the meteorite.Among the high-pressure phases,ten of them were approved as new minerals which include tuite,xieite,wangdaodeite,chenmingite,hemleyite,poirierite,asimowite,hiroseite,elgoresyite,and ohtaniite,by the Commission on New Minerals,Nomenclature and Classification of the International Mineralogical Association.Other high-pressure phases identified from the meteorite are ahrensite,akimotoite,bridgmanite,lingunite,magnesiowüstite,majorite,majorite-pyrope_(ss),maskelynite,riesite,ringwoodite,wadsleyite,and 5 other phases including phase A,vitrified phase B and phase C,phase D(Ca-rich majorite),and partly inverted ringwoodite.The occurrence and abundance of high-pressure phases makes this meteorite the one with the richest variety of high-pressure minerals to date.展开更多
The 304 austenitic stainless steel was processed by high-pressure torsion(HPT)at room temperature with 10,20,and 30 rotations under a pressure of 3 GPa and a rotation speed of 1 r/min.The phase transformation and micr...The 304 austenitic stainless steel was processed by high-pressure torsion(HPT)at room temperature with 10,20,and 30 rotations under a pressure of 3 GPa and a rotation speed of 1 r/min.The phase transformation and microstructural evolution of 304 stainless steel after HPT were investigated by X-ray diffraction(XRD)analysis,electron backscatter diffraction(EBSD)analysis,transmission electron microscopy(TEM),nanoindentation test and differential scanning calorimetry(DSC)analysis.The experimental results show that HPT causes elongated nanocrystalline grains of 25 nm width along the torsion direction.After 10 turns of HPT,the deformation-induced martensitic transformation is completed and the hardness increases from 3 GPa to 8.5 GPa at the edge of the disc.However,a local reverse phase transformation from martensite to austenite is observed in the peripheral regions of the sample after 30 turns of HPT,leading to a higher volume fraction of austenite,and the hardness of the sample also decreases accordingly.展开更多
The pore structure of rocks significantly influences the porosity and permeability of reservoirs and the migration ability of oil and gas,and being the key task on the development of volcanic gas reservoirs.Nine volca...The pore structure of rocks significantly influences the porosity and permeability of reservoirs and the migration ability of oil and gas,and being the key task on the development of volcanic gas reservoirs.Nine volcanic rock samples from the Yingcheng Formation and Huoshiling Formation in the Longfengshan area of the Changling Fault Depression in the Songliao Basin were selected for this study.The pore structures of the volcanic rocks in the study area were investigated using high-pressure mercury injection,X-ray diffraction combined with fractal theory.The relationships between the fractal dimension and physical properties characteristics,pore structure parameters,and mineral content were analyzed to provide guidance for the development of volcanic rock gas reservoirs.The results show that the reservoir can be divided into 3 types(I,II,and III)based on the shape of the capillary pressure curve,and the physical properties deteriorate successively.Different types of reservoirs exhibit different fractal characteristics.For typesⅠ,ⅡandⅢ,the average total fractal dimensions were 2.3418,2.6850,and 2.9203,respectively.The larger the fractal dimension,the stronger the heterogeneity of reservoir.A small number of macro-pores primarily contributed to permeability.The fractal dimension was negatively correlated with porosity and permeability.The fractal dimension of the rock was strongly correlated with quartz and feldspar contents,and the mineral composition and content are closely related to the pore evolution of the reservoir,which are the internal factors affecting the fractal dimension of volcanic rock.展开更多
Grouting represents a reliable method for strengthening fractured rock masses and preventing seawater infiltration in subsea tunnel engineering. However, grouting composites are continuously subjected to harsh marine ...Grouting represents a reliable method for strengthening fractured rock masses and preventing seawater infiltration in subsea tunnel engineering. However, grouting composites are continuously subjected to harsh marine environments,experiencing both chemical and physical effects from high-concentration erosive seawater ions, elevated water pressure, and complex flow fields. This multi-factor erosion deterioration diminishes the waterproofing capabilities of grouting composites and threatens the service life of subsea tunnel linings. To investigate the erosion deteriortion mechanism induced by sulfate, erosion weakening experiments were conducted using a seawater flow simulation device. The research examined the compressive strength and permeability coefficient of grouting composites under different erosion durations, water-cement ratios, and grouting pressures. In the later stages of the experiment, the strength of grouting composites in the static water erosion control group(SEG) and dynamic water erosion group(DEG) decreased by 31.2% and 18.8%, respectively, compared to the freshwater control group(FG). Futhermore, the permeability coefficient exhibited significant increases. Subsequent microscopic analyses of the eroded grouting composites were performed. This research elucidated the erosion-weakening mechanism of grouting composites subjected to sulfate-induced degradation in complex marine environments. The study emphasizes the critical role of erosion resistance and durability in design and implementation. From practical perspective, this work establishes a foundation for developing enhanced strategies to improve the long-term performance and integrity of grouting composites in subsea tunnel applications.展开更多
基金supported by the Fujian Science Foundation for Outstanding Youth(Grant No.2023J06039)the National Natural Science Foundation of China(Grant No.41977259 and No.U2005205)Fujian Province natural resources science and technology innovation project(Grant No.KY-090000-04-2022-019)。
文摘Bedding slope is a typical heterogeneous slope consisting of different soil/rock layers and is likely to slide along the weakest interface.Conventional slope protection methods for bedding slopes,such as retaining walls,stabilizing piles,and anchors,are time-consuming and labor-and energy-intensive.This study proposes an innovative polymer grout method to improve the bearing capacity and reduce the displacement of bedding slopes.A series of large-scale model tests were carried out to verify the effectiveness of polymer grout in protecting bedding slopes.Specifically,load-displacement relationships and failure patterns were analyzed for different testing slopes with various dosages of polymer.Results show the great potential of polymer grout in improving bearing capacity,reducing settlement,and protecting slopes from being crushed under shearing.The polymer-treated slopes remained structurally intact,while the untreated slope exhibited considerable damage when subjected to loads surpassing the bearing capacity.It is also found that polymer-cemented soils concentrate around the injection pipe,forming a fan-shaped sheet-like structure.This study proves the improvement of polymer grouting for bedding slope treatment and will contribute to the development of a fast method to protect bedding slopes from landslides.
基金financially supported by the National Natural Science Foundation of China(Nos.52175284 and 52474396)the National Key Research and Development Program of China(No.2022YFB3404201)。
文摘High pressure die casting(HPDC)AlSi10Mn Mg alloy castings are widely used in the automobile industry.Mg can optimize the mechanical properties of castings through heat treatment,while the release of thermal stress arouses the deformation of large integrated die-castings.Herein,the development of non-heat treatment Al alloys is becoming the hot topic.In addition,HPDC contains externally solidified crystals(ESCs),which are detrimental to the mechanical properties of castings.To achieve high strength and toughness of non-heat treatment die-casting Al-Si alloy,we used AlSi9Mn alloy as matrix with the introduction of Zr,Ti,Nb,and Ce.Their influences on ESCs and mechanical properties were systematically investigated through three-dimensional reconstruction and thermodynamic simulation.Our results reveal that the addition of Ti increased ESCs'size and porosity,while the introduction of Nb refined ESCs and decreased porosity.Meanwhile,large-sized Al_3(Zr,Ti)phases formed and degraded the mechanical properties.Subsequent introduction of Ce resulted in the poisoning effect and reduced mechanical properties.
基金supported by the National Natural Science Foundation of China(Grant No.U21B2062)supported by the Key Laboratory for Carbonate Reservoirs of China National Petroleum Corporation。
文摘Burial dissolution is a critical diagenetic process influencing ultra-deep carbonate reservoir development and preservation.Artificial carbonate samples with different internal structures were prepared,and high-temperature and highpressure dissolution kinetic simulations were conducted.The results demonstrate that the intensity of burial dissolution is controlled by temperature and pressure,while tectonic-fluid activity influences the development pattern of burial dissolution,ultimately determining the direction of its differential modification.Extensive burial dissolution is likely to occur primarily at relatively shallow depths,significantly influencing reservoir formation,preservation,modification,and adjustment.The development of faults facilitates the maintenance of the intensity of burial dissolution.The maximum intensity of burial dissolution occurs at the tips and overlap zones of faults and intersections of multiple faults.The larger the scale of the faults,the more conducive it is to the development of burial dissolution.Burial dissolution fosters the formation of fault networks characterized by enhanced reservoir capacity and permeability.Burial dissolution controlled by episodic tectonic-fluid activity is a plausible explanation for forming the Tarim Basin's ultra-deep fault-controlled“stringbead-like”reservoirs.
基金supported by the China Scholarship Council(CSC,Grant No.202108050072)JSPS KAKENHI(Grant No.JP19KK0121)。
文摘Grouting has been the most effective approach to mitigate water inrush disasters in underground engineering due to its ability to plug groundwater and enhance rock strength.Nevertheless,there is a lack of potent numerical tools for assessing the grouting effectiveness in water-rich fractured strata.In this study,the hydro-mechanical coupled discontinuous deformation analysis(HM-DDA)is inaugurally extended to simulate the grouting process in a water-rich discrete fracture network(DFN),including the slurry migration,fracture dilation,water plugging in a seepage field,and joint reinforcement after coagulation.To validate the capabilities of the developed method,several numerical examples are conducted incorporating the Newtonian fluid and Bingham slurry.The simulation results closely align with the analytical solutions.Additionally,a set of compression tests is conducted on the fresh and grouted rock specimens to verify the reinforcement method and calibrate the rational properties of reinforced joints.An engineering-scale model based on a real water inrush case of the Yonglian tunnel in a water-rich fractured zone has been established.The model demonstrates the effectiveness of grouting reinforcement in mitigating water inrush disaster.The results indicate that increased grouting pressure greatly affects the regulation of water outflow from the tunnel face and the prevention of rock detachment face after excavation.
基金Funded by a Science and Technology Project from the Ministry of Housing and Urban-Rural Development of the People’s Republic of China(No.2019-K-047)Yangzhou Government-Yangzhou University Cooperative Platform Project for Science and Technology Innovation(No.YZ2020262)。
文摘The chloride penetration resistance of cement-based grout materials was improved by nano-silica emulsion.Specimens of mixtures containing different nano-silica particles or emulsions were exposed in sodium chloride solutions of specific concentrations with different test ages.Hardened properties of the mixes were assessed in terms of weight loss and compressive strength.X-ray diffraction(XRD)and scanning electron microscopy(SEM)of mixes were performed to analysis the phase evolution and microstructure.The results demonstrated that the introduction of nano-SiO_(2) emulsion significantly decreased the compressive strength loss and calcium hydroxide(CH)crystal content of hydration production,and then enhanced the resistance of cement-based grouting materials to chloride ion penetration.This improvement derives from the filling and pozzolanic effects of nano-SiO_(2) particles,which were incorporated via an emulsion and attributed to a well dispersion in grouting matrix.
基金National Key Research and Development Program of China(2021YFB3701004)。
文摘Degradable metals,represented by magnesium and magnesium alloys,have attracted significant attention as fracture internal fixation and bone defect repairing materials due to their good biocompatibility,suitable elastic modulus and degradable properties.The Mg-3Zn-1Ca-0.5Sr(wt%)alloy is considered a competitor in the biomaterial field thanks to its unique composition of essential nutrients and excellent mechanical properties.However,the presence of coarse second-phase particles in the alloy accelerates its degradation rate and causes excessive gas formation during implantation,which restricts the alloy's potential for clinical device applications.In order to further optimize the properties of the alloy,extrusion combined with high-pressure torsion(HPT)was adopted for deformation processing.The results show that by optimizing the material processing means,the grain can be refined and broken,and the second-phase distribution can be improved,thus improving the microstructure,mechanical properties,and corrosion resistance of the alloy.After 15 cycles of HPT processing,the grains of the alloy are significantly refined to the nanometer scale,reaching approximately 98 nm.Additionally,the second-phase distribution is greatly improved,transforming the original streamlined structure into a more dispersed distribution.This change in microstructure leads to a significant strengthening effect on the alloy,with a noticeable increase in hardness from 60.3 HV in the as-extruded state to 98.5 HV.
基金The Fundamental Research Funds for the Central Universities,Grant/Award Number:YJ2021148National Natural Science Foundation of China,Grant/Award Number:52374132。
文摘Appropriate determination of the mix ratios of cement grouts is of vital importance to the quality of rock grouting and the risk reduction of groundwater inflow.The behavior of grout,often highly temperature dependent,is likely to be affected by the elevated ground temperature in deep rock masses.This paper aims to experimentally gain insights into the effects of elevated ground temperatures on the properties of cement grout in fresh and hardened states in deep rock grouting.The results revealed that a temperature of 35°C is crucial for changes in the properties of thick cement grout with a water–cement ratio of less than 0.8.When the temperature is up to 35°C,there can be significant improvements in rheological parameters,acceleration of grout setting,and increase in the rheological time dependence of thick cement grout;however,there may also be a slight impact on the initial grout flowability and the nature of shear thinning.The high temperature may still improve the stability of fresh cement grout and also improve the porosity and creep deformation of hardened cement grout considerably.The proposed constitutive model that couples the Burgers model with a fractional derivativebased Abel dashpot in the series can be used to characterize the creep behavior of hardened cement grout appropriately.The paper provides a valuable reference for optimization of mixture design of cement grouts,thus enhancing deep rock grouting quality and improving safety.
文摘Suction bucket jacket foundations exhibit considerable potential for implementation in deep-sea offshore wind power projects. To address water film formation resulting from negative pressure penetration during construction, certain suction bucket jacket foundation projects implement grouting techniques to ensure adequate bearing capacity. This study conducted a large-scale suction bucket foundation grouting model experiment to examine grout flow characteristics and specific phenomena under various grouting pipeline configurations. Comparative analyses of grouting efficiency and quality across different pipeline layouts identified critical influencing factors and their impact on grouting performance. The results demonstrate that the number of grout outlets should be maintained within an optimal range:insufficient outlets enhance the indentation effect and decrease fill efficiency, while excessive outlets necessitate precise spacing for effective distribution. Additionally, grout outlets should be uniformly arranged to reduce segregation and enhance overall grouting quality. This study's findings provide a scientific foundation for optimizing grouting design in suction bucket jacket foundations, with substantial implications for engineering applications.
基金supported by the National Natural Science Foundation of China(Grant No.U23A6018)Science and Technology Program of Hebei(Grant No.E2022202041,2022HBQZYCXY004,242Q9920Z)the project of“Key technologies of seepage control system for large-scale hydraulic projects”was also gratefully appreciated.
文摘Curtain grouting projects are characterized by their large scale and complexity,presenting significant challenges for real-time prediction of grout penetration using traditional methods.This study introduces an intelligent prediction method for grouting in fractured rock masses based on three core principles:integration of multi-source input features,fracture voxel modeling,and shortest path in sequential grouting.Three categories of data(geological structure data,grouting environmental data,and grouting operation data in the concept of a grouting geological model)are integrated and served as multi-source structured data in the intelligent prediction of grouting.A voxelization model quantifies the spatial characteristics of fractures,with voxel size optimized for capturing grouting paths.A shortest path algorithm based on a hierarchical solution is then developed to calculate grout penetration distances in the process of sequential grouting.A complete analysis framework is established,from the voxelization of the fracture network model to precise voxel classification,ultimately achieving an accurate prediction of grout penetration.The method demonstrates excellent performance on the test set,with validation against numerical methods in single-fracture and sequential grouting scenarios confirming its accuracy and prediction efficiency as hundreds of times faster than numerical methods.Application to the Dongzhuang hydraulic project’s grouting test area further validates its effectiveness in multi-hole grouting scenarios.
基金the funding support from the Natural Science Foundation of China(Grant No.52130402)the Anhui Province Graduate Education Quality Engineering Project(Grant No.2023cxcysj088)the China Scholarship Council Grants Program(Grant No.202308340082).
文摘Grouting injection is a vital technique for addressing the challenges of high stress and significant deformation in the surrounding rock during deep mining operations,playing a crucial role in promoting green and low-carbon extraction methodologies.In this study,grouting reinforcement processes were examined by conducting grouting experiments on a fractured rock with varying negative pressures(0-100 kPa),followed by uniaxial compression testing of the grout-reinforced bodies.This investigation explored the diffusion patterns of grout under negative pressure and established a constitutive model of damage-bearing capacity for bodies reinforced by negative pressure grouting.It further studied the enhancement effect of negative pressure on the load-bearing capacity of the reinforced bodies and analyzed the instability mechanism of damage and failure in these bodies.The results indicated that the diffusion of grout under negative pressure is influenced by four types of forces,which alter the extent of grout diffusion within the fractured rock mass.Introducing a damage constitutive model that serially connects pore and framework elements characterizes the damage and failure behavior of groutreinforced bodies under different negative pressures.As the negative pressure increases,changes in porosity,water-to-cement ratio,and admixture quantity occur in the grout-reinforced specimens,with the strength mean curve showing a trend of first increasing and then decreasing,reaching a threshold at a negative pressure of 60 kPa.With increasing negative pressure,the negative pressure damage variable decreases and then increases,and the stronger the interfacial microelement connections caused by the negative pressure,the greater the bearing capacity,ultimately manifesting in different failure modes.
基金supported by the National Natural Science Foundation of China,Grant Nos.42477185,41602308the Zhejiang Provincial Natural Science Foundation of China,Grant No.LY20E080005+2 种基金the Zhejiang Province University Students Science and Technology Innovation Program,Grant No.0201310P28the PostGraduate Course Construction Project of Zhejiang University of Science and Technology,Grant No.2021yjskj05the Zhejiang University of Science and Technology Graduate Research and Innovation Fund,Grant No.2023yjskc10.
文摘The ongoing operation of subway systems makes existing tunnels vulnerable to deformations and structural damage caused by adjacent foundation pit construction.Such deformations-manifesting as horizontal displacement,heightened lateral convergence,and internal force redistribution-may significantly compromise subway operational safety.Grouting remediation has become a widely adopted solution for tunnel deformation control and structural reinforcement.Developing optimized grouting materials is crucial for improving remediation effectiveness,ensuring structural integrity,and maintaining uninterrupted subway operations.This investigation explores the substitution of fine mortar aggregates with 0.1 mm discarded rubber particles at varying concentrations(0%,3%,6%,9%,12%,and 15%).Experimental parameters included three water-cement ratios(0.65,0.70,and 0.75)with constant 4%WPU content.Mechanical properties including compressive strength,flexural strength,and compression-to-bending ratio were evaluated across specified curing periods.Material characterization employed Fourier Transform Infrared Spectroscopy(FTIR)spectroscopy for molecular analysis and Scanning Electron Microscopy(SEM)for microstructural examination.Results indicate optimal toughness at 0.70 water-cement ratio with 6%rubber content,meeting mechanical pumping specifications while maintaining structural performance.
基金funded by the National Natural Science Foundation of China[U22A20234]Hubei Province key research and development project[2023BCB121]Wuhan innovation supporting projects[2023020201010079].
文摘Grouting is a widely applied technique for reinforcing fractured zones in deep soft rock tunnels.By infiltrating rock fissures,slurry materials enhance structural integrity and improve the overall stability of the surrounding rock.The performance of grouting is primarily governed by the flow behavior and diffusion extent of the slurry.This review considers recent advances in the theory and methodology of slurry flow and diffusion in fractured rock.It examines commonly used grout materials,including cement-based,chemical,and composite formulations,each offering distinct advantages for specific geological conditions.Themechanisms of reinforcement vary significantly across materials,requiring tailored application strategies.The rheological properties of grouting slurries,particularly cement-based types,have been widely modeled using classical constitutive approaches.However,the influence of time-and space-dependent viscosity evolution on slurry behavior remains underexplored.Experimental studies have provided valuable insights into slurry diffusion,yet further research is needed to capture real-time behavior under multi-scale and multi-physics coupling conditions.Similarly,current numerical simulations are largely limited to twoand three-dimensional models of single-fracture flow.These models often neglect the complexity of fracture networks and geological heterogeneity,highlighting a need for more realistic and integrated simulation frameworks.Future research should focus on:(1)fine-scale modeling of slurry hydration and mechanical reinforcement processes;(2)cross-scale analysis of slurry flow under coupled thermal,hydraulic,andmechanical fields;and(3)development of realtime,three-dimensional dynamic simulation tools to capture the full grouting process.These efforts will strengthen the theoretical foundation and practical effectiveness of grouting in complex underground environments.
基金supported by the National Natural Science Foundation of China(grant number:52203375 and 52073254)。
文摘With the global oil and gas industry increasingly targeting ultra-deep well development,the demand for wear resistance in polycrystalline diamond compact(PDC)bits is increasing.However,further improvement of the mechanical properties of PDC incurs prohibitively elevated costs and stringent technological challenges.Here,we present a two-stage high-pressure infiltration(HPI)methodology involving cobalt removal pretreatment followed by lubricant infiltration.The successful infiltration of lubricants into diamond micropores has been systematically verified,and the effects of lubricant phase composition,infiltration pressure,and temperature on infiltration depth have been thoroughly investigated.Fractal dimension analysis characterizes the pore structure of cobalt-removed diamonds,revealing a strong correlation between the fractal dimension and friction coefficient reduction.Tribological testing confirms the formation of lubricating films at friction interfaces,achieving a 71.5%reduction in the coefficient of friction for lubricant-containing diamond materials.This straightforward strategy opens a gate to developing the next generation of self-lubricating diamond materials.
基金Supported by Jiangsu Provincial Natural Science Foundation(Grant No.BK20231497)Jiangsu Provincial Post graduate Research&Practice Innovation Program(Grant No.KYCX25_2982)+3 种基金China University of Mining and Technology Graduate Innovation Program(Grant No.2025WLKXJ094)National Natural Science Foundation of China(Grant No.51975573)National Key R&D Program of China(Grant No.2022YFC2905600)Priority Academic Program Development of Jiangsu Higher Education Institute of China.
文摘A rotary sealing device that automatically compensates for wear is designed to address the issues of easy wear and the short service life of the rotary sealing device with automatic wear compensation in mining machinery.After the end face of the guide sleeve wears out,it still tightly adheres to the sealing valve seat under the pressure difference,achieving automatic wear compensation.Based on fluid-solid coupling technology,the structural strength of the rotary sealing device was checked.The influence of factors on the sealing performance of rotary sealing devices was studied using the control variable method.The results show that as the pressure of water increases,the leakage rate of the sealing device decreases,and after 30 MPa,the leakage rate is almost 0 mL/h.The temperature of the rotating sealing device increases with the increase of rotation speed or pressure,and the temperature is more affected by the rotation speed factor.The frictional torque increases with increasing pressure and is independent of rotational speed.Comprehensive analysis shows that the wear resistance and reliability level of the sealing guide sleeve material is PVDF>PEEK>PE>PA.This study designs a high-pressure automatic compensation wear rotary sealing device and selects the optimal sealing material,providing technical support for the application of high-pressure water jet in mining machinery.
基金Project supported by the National Key R&D Program of China (Grant No. 2021YFA1400300)the National Natural Science Foundation of China (Grant Nos. 12425403, 12261131499, 12304268, 12304159, 11934017, and 11921004)+1 种基金the China Postdoctoral Science Foundation (Grant No. 2023M743741)The synchrotron x-ray diffraction experiments were performed at SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute (Grant Nos. 2023B1575, 2023B1976, 2024A1506, and 2024A1695)。
文摘Perovskite oxynitrides AB(N,O)_(3), a crucial class in materials science, have attracted much attention. By precisely controlling A-and B-site ions and tuning the N/O ratio, new materials with exotic charge states and intriguing electronic behaviors can be designed and synthesized. In this work, a novel oxynitride perovskite, CeNbO_(2)N, was prepared under high-temperature and high-pressure conditions. The compound crystallizes in an orthorhombic perovskite structure in Pnma symmetry with disordered N/O distribution. The x-ray absorption spectroscopy confirms the presence of a Nb^(4+) state with 4d^(1) electronic configuration in CeNbO_(2)N. As a result, the resistivity of CeNbO_(2)N is sharply reduced compared to its counterpart CeTa^(5+)ON_(2) and other Nb^(5+) compounds. No long-range spin order is found to occur with the temperature down to 2 K in CeNbO_(2)N, while a remarkable negative magnetoresistance effect shows up at lower temperatures, probably due to the magnetic scattering arising from short-range spin correlations.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 12374013 and U2030107)the Fundamental Research Funds for the Central University (Grant No. 2020SCUNL107)+1 种基金The high-pressure in-situ imaging experiments were conducted at BL12SW of SSRF (Proposal No. 2024-SSRF-PT-505499)The NPD experiments were supported by Chinese Academy of Engineering Physics。
文摘Iron nitride(Fe_(x)N_y) is a promising candidate for the next generation of ferromagnetic materials. However, synthesizing high-quality bulk iron nitride with tuned structure and magnetic properties remains a challenge. Currently, experimental and theoretical results regarding the magnetic property of iron nitrides remain controversial. With the recent advancements in high-pressure technology, new synthetic pathways to iron nitrides have been proposed. High-pressure synthesis technology provides multidimensional possibilities for tuning the structure and magnetic properties of iron nitrides. This review summarizes recent progress in high-pressure synthesis of iron nitrides, especially the high-pressure solid-state metathesis reaction synthesis(HSM). We have summarized the reaction characteristics of HSM. The HSM reaction exhibits vector synthesis characteristics and promotes nitrogen disorder diffusion at high temperature. Due to this, the HSM reaction can achieve the synthesis of multinary iron-based metal nitrides and regulate the local magnetic moments. It serves as a powerful means for tuning the structure and magnetic properties of iron nitrides. Taking advantage of neutron diffraction in characterizing local magnetic moment and nitrogen disorder in iron nitrides, the relationship between iron local magnetic moment and nitrogen content has been elucidated. Moreover, the development of high-pressure in-situ imaging technology based on large-volume press allows the real-time observation of HSM reaction process. In this review, we also report our latest experiments on neutron diffraction and high-pressure in-situ image for the study of iron nitrides.
基金Science and Technology Planning Project of Guangdong Province(2023B1212060048).
文摘The Suizhou meteorite is a heavily shock-met-amorphosed L6 chondrite which contains thin shock melt veins.So far,26 high-pressure phases have been identified from the meteorite.Among the high-pressure phases,ten of them were approved as new minerals which include tuite,xieite,wangdaodeite,chenmingite,hemleyite,poirierite,asimowite,hiroseite,elgoresyite,and ohtaniite,by the Commission on New Minerals,Nomenclature and Classification of the International Mineralogical Association.Other high-pressure phases identified from the meteorite are ahrensite,akimotoite,bridgmanite,lingunite,magnesiowüstite,majorite,majorite-pyrope_(ss),maskelynite,riesite,ringwoodite,wadsleyite,and 5 other phases including phase A,vitrified phase B and phase C,phase D(Ca-rich majorite),and partly inverted ringwoodite.The occurrence and abundance of high-pressure phases makes this meteorite the one with the richest variety of high-pressure minerals to date.
基金Funded by the National Natural Science Foundation of China(No.51905215)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.SJCX231233)。
文摘The 304 austenitic stainless steel was processed by high-pressure torsion(HPT)at room temperature with 10,20,and 30 rotations under a pressure of 3 GPa and a rotation speed of 1 r/min.The phase transformation and microstructural evolution of 304 stainless steel after HPT were investigated by X-ray diffraction(XRD)analysis,electron backscatter diffraction(EBSD)analysis,transmission electron microscopy(TEM),nanoindentation test and differential scanning calorimetry(DSC)analysis.The experimental results show that HPT causes elongated nanocrystalline grains of 25 nm width along the torsion direction.After 10 turns of HPT,the deformation-induced martensitic transformation is completed and the hardness increases from 3 GPa to 8.5 GPa at the edge of the disc.However,a local reverse phase transformation from martensite to austenite is observed in the peripheral regions of the sample after 30 turns of HPT,leading to a higher volume fraction of austenite,and the hardness of the sample also decreases accordingly.
基金Supported by Key Scientific and Technological Projects of Sinopec(No.P21104-2).
文摘The pore structure of rocks significantly influences the porosity and permeability of reservoirs and the migration ability of oil and gas,and being the key task on the development of volcanic gas reservoirs.Nine volcanic rock samples from the Yingcheng Formation and Huoshiling Formation in the Longfengshan area of the Changling Fault Depression in the Songliao Basin were selected for this study.The pore structures of the volcanic rocks in the study area were investigated using high-pressure mercury injection,X-ray diffraction combined with fractal theory.The relationships between the fractal dimension and physical properties characteristics,pore structure parameters,and mineral content were analyzed to provide guidance for the development of volcanic rock gas reservoirs.The results show that the reservoir can be divided into 3 types(I,II,and III)based on the shape of the capillary pressure curve,and the physical properties deteriorate successively.Different types of reservoirs exhibit different fractal characteristics.For typesⅠ,ⅡandⅢ,the average total fractal dimensions were 2.3418,2.6850,and 2.9203,respectively.The larger the fractal dimension,the stronger the heterogeneity of reservoir.A small number of macro-pores primarily contributed to permeability.The fractal dimension was negatively correlated with porosity and permeability.The fractal dimension of the rock was strongly correlated with quartz and feldspar contents,and the mineral composition and content are closely related to the pore evolution of the reservoir,which are the internal factors affecting the fractal dimension of volcanic rock.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 42477194 and 52279115)Fundamental Research Funds for the Central Universities (Grant No. 202441008)。
文摘Grouting represents a reliable method for strengthening fractured rock masses and preventing seawater infiltration in subsea tunnel engineering. However, grouting composites are continuously subjected to harsh marine environments,experiencing both chemical and physical effects from high-concentration erosive seawater ions, elevated water pressure, and complex flow fields. This multi-factor erosion deterioration diminishes the waterproofing capabilities of grouting composites and threatens the service life of subsea tunnel linings. To investigate the erosion deteriortion mechanism induced by sulfate, erosion weakening experiments were conducted using a seawater flow simulation device. The research examined the compressive strength and permeability coefficient of grouting composites under different erosion durations, water-cement ratios, and grouting pressures. In the later stages of the experiment, the strength of grouting composites in the static water erosion control group(SEG) and dynamic water erosion group(DEG) decreased by 31.2% and 18.8%, respectively, compared to the freshwater control group(FG). Futhermore, the permeability coefficient exhibited significant increases. Subsequent microscopic analyses of the eroded grouting composites were performed. This research elucidated the erosion-weakening mechanism of grouting composites subjected to sulfate-induced degradation in complex marine environments. The study emphasizes the critical role of erosion resistance and durability in design and implementation. From practical perspective, this work establishes a foundation for developing enhanced strategies to improve the long-term performance and integrity of grouting composites in subsea tunnel applications.
