Separator modification is an effective approach to suppress dendrite growth to realize high-energy sodium metal batteries(SMBs)in practical applications,however,its success is mainly subject to surface modification.He...Separator modification is an effective approach to suppress dendrite growth to realize high-energy sodium metal batteries(SMBs)in practical applications,however,its success is mainly subject to surface modification.Herein,a separator with multifunctional layers composed of N-doped mesoporous hollow carbon spheres(HCS)as the inner layer and sodium fluoride(NaF)as the outer layer on commercial polypropylene separator(PP)is proposed(PP@HCS-NaF)to achieve stable cycling in SMB.At the molecular level,the inner HCS layer with a high content of pyrrolic-N induces the uniform Na^(+)flux as a potential Na^(+)redistributor for homogenous deposition,whereas its hollow mesoporous structure offers nanoporous buffers and ion channels to regulate Na^(+)ion distribution and uniform deposition.The outer layer(NaF)constructs the NaF-enriched robust solid electrolyte interphase layer,significantly lowering the Na^(+)ions diffusion barrier.Benefiting from these merits,higher electrochemical performances are achieved with multifunctional double-layered PP@HCS-NaF separators compared with single-layered separators(i.e.PP@HCS or PP@NaF)in SMBs.The Na‖Cu half-cell with PP@HCS-NaF offers stable cycling(280 cycles)with a high CE(99.6%),and Na‖Na symmetric cells demonstrate extended lifespans for over 6000 h at 1 mA cm^(-2)with a progressively stable overpotential of 9 mV.Remarkably,in Na‖NVP full-cells,the PP@HCS-NaF separator grants a stable capacity of~81 mA h g^(-1)after 3500 cycles at 1 C and an impressive rate capability performance(~70 mA h g^(-1)at 15 C).展开更多
The process through which a laminar flow undergoes transition to turbulence is of great fundamental and practical interest. Such a process is hugely complex as there are many diverse routes for a laminar flow to becom...The process through which a laminar flow undergoes transition to turbulence is of great fundamental and practical interest. Such a process is hugely complex as there are many diverse routes for a laminar flow to become turbulent flow. The transition process is usually initiated by flow instabilities—a primary instability stage followed by a secondary instability stage. This forms a rational framework for the early stage of a transition process and it is crucially important to understand the physics of instabilities leading to turbulence. This article reviews the results of studies on secondary instability of separated shear layers in separation bubbles and summaries the current status of our understanding in this area.展开更多
Global seismicity catalogs are sufficient for characterizing double seismic zones （DSZs） in subducting slab and facilitate to estimate layer separation without inconsistent uncertainties as local catalogs. Previous ...Global seismicity catalogs are sufficient for characterizing double seismic zones （DSZs） in subducting slab and facilitate to estimate layer separation without inconsistent uncertainties as local catalogs. Previous studies have shown the correlation between DSZs layer separation and plate age while correlation for those younger than -60 Ma is suspicious. The lacking of DSZs with layer separation less than 10 km further makes it difficult to precisely estimate such correlation. Thus, we incorporate eight DSZs data determined through local seismicity into globally-determined dataset and reexamine such correlation. The best fitting results show that both a linear model and a square root of plate age can mathematically fit the layer separation well. However, it is difficult to distinguish these two models when plate age is greater than -20 Ma since their difference is less than 2 km. However, if extrapolation is possible, both models should provide physical information that DSZs will not form if there is no subducting lithosphere. As a result, the DSZs cannot be produced until the oceanic lithospheric age becomes greater than 0.9 Ma in the square root model while the linear model gives a misleading result. As such the square root model demonstrates the relationship physically better than the linear one, it still needs further test in the future with more available data, nevertheless, our study might also provide evidence for the suggestion that the plate age is a primary control factor of the DSZs geometry as well as the subducting process which disregards any local tectonic stresses.展开更多
To address the early separation problem in the Menter Shear-Stress Transport(SST)turbulence model,a correction for the Turbulent Kinetic Energy(TKE)production term,P_(k),is introduced to account for the effect of the ...To address the early separation problem in the Menter Shear-Stress Transport(SST)turbulence model,a correction for the Turbulent Kinetic Energy(TKE)production term,P_(k),is introduced to account for the effect of the Adverse Pressure Gradient(APG).The correction is determined based on the distribution of Pkin the APG region before separation.When the friction coefficient C_(f) is decomposed,its direct dependence on Pkis clearly observed.However,with the introduction of Bradshaw’s assumption,Pkin the SST turbulence model is over-suppressed,resulting in a lower inner peak or no significant inner peak distribution at all.To address this problem,this paper proposes a Gaussian function,HGauss,which corrects the numerical values of P_(k) involved in the calculation of the Menter SST model by focusing on the inner peak region of P_(k).The modified SST model is then applied to four cases with APGs.The modification leads to an increase in the wall friction coefficient C_(f)in the APG region and causes a downstream shift in the separation location,improving the model’s consistency with high-accuracy data and experimental results.It is demonstrated that this correction can improve the early separation problem in the Menter SST turbulence model.展开更多
Given the limited exposure of active sites and the retarded separation of photogenerated charge carriers in those developed photocata-lysts,photocatalyticCO_(2)splitting into value-added chemicals has suffered from th...Given the limited exposure of active sites and the retarded separation of photogenerated charge carriers in those developed photocata-lysts,photocatalyticCO_(2)splitting into value-added chemicals has suffered from the poor activity and remained in great challenge for real application.Herein,hydrothermally synthesized BiOCl with layered structure(BOC-NSs)was exfoliated into thickness reduced nanosheets(BOCNSs-w)and even atomic layers(BOCNSs-i)via ultrasonication in water and isopro-panol,respectively.In comparison with the pristine BOCNSs,the exfoli-ated BiOCl,especially BOCNSs-i with atomically layered structure,exhibits much improved photocatalytic activity forCO_(2)overall splitting to produce CO andO_(2) at a stoichiometric ratio of 2:1,with CO evolution rate reaching 134.8µmolg^(-1)h^(-1) under simulated solar light(1.7 suns).By surpassing the photocatalytic performances of the state-of-the-artBi_(l)O_(m)X_(n)(X:Cl,Br,I)based photocatalysts,the CO evolution rate is further increased by 99 times,reaching 13.3 mmolg^(-1)h^(-1) under concentrated solar irradiation(34 suns).This excellent photocatalytic performance achieved over BOCNSs-i should be benefited from the shortened transfer distance and the increased built-in electric field intensity,which acceler-ates the migration of photogenerated charge carriers to surface.Moreover,with oxygen vacancies(VO)introduced into the atomic layers,BOCNSs-i is exposed with the electrons enriched Bi active sites that could transfer electrons to activateCO_(2)molecules for highly efficient and selective CO production,by lowering the energy barrier of rate-determining step(RDS),*OH+*CO_(2)-→HCO_(3)-.It is also realized that theH_(2)O vapor supplied during photocatalytic reaction would exchange oxygen atoms withCO_(2),which could alter the reaction path-ways and further reduce the energy barrier of RDS,contributing to the dramatically improved photocatalytic performance forCO_(2)overall splitting to CO andO_(2).展开更多
In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modific...In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modification with n-dodecyl mercaptan(DDT). This method provides a new strategy to fabricate superhydrophobic PU sponge with a water contact angle of 157° for absorbing oil with low cost and in large scale. It exhibits the strong absorption capacity and highly selective characteristic for various kinds of oils which can be recycled by simple squeezing. Besides, the as-prepared sponge can deal with the floating and underwater oils, indicating its application value in handling oil spills and domestic oily wastewater. The good self-cleaning ability shows the potential to clear the pollutants due to the ultralow adhesion to water. Especially, the most important point is that the superhydrophobic sponge can continuously and effectively separate the oil/water mixture against the condition of turbulent disturbance by using our designed device system, which exhibit its good superhydrophobicity, strong stability.Furthermore, the SS-PU still maintained stable absorption performance after 150 cycle tests without losing capacity obviously, showing excellent durability in long-term operation and significant potential as an efficient absorbent in large-scale dispose of oily water.展开更多
In this paper,we consider the solutions of 2-D incompressible magnetohydrodynamic(MHD)equations with homogenous Dirichlet boundary condition for velocity and with nonhomogenous Dirichlet boundary condition for magneti...In this paper,we consider the solutions of 2-D incompressible magnetohydrodynamic(MHD)equations with homogenous Dirichlet boundary condition for velocity and with nonhomogenous Dirichlet boundary condition for magnetic field.We obtain a condition of boundary layer separation by Taylor expansion of functions in the MHD equations and by structural bifurcation theory for divergence free flows with Dirichlet boundary conditions.Furthermore,the condition,determined by external forces,initial values and the value of magnetic field on the boundary,can predict when and where boundary layer separation for the magnetic fluid will occur.展开更多
Laminar boundary layer (BL), under adverse pressure gradient, can separate. The separated shear layer reattaches to form a laminar separation bubble. Such bubbles are usually observed on gas turbine blades, on low Rey...Laminar boundary layer (BL), under adverse pressure gradient, can separate. The separated shear layer reattaches to form a laminar separation bubble. Such bubbles are usually observed on gas turbine blades, on low Reynolds number wings and close to the leading edges of airfoils. Presence of bubbles has a weakening effect on the performance of a fluid device. The understanding of the prevailing mechanism of the separation bubble and ways to control it are essential for the efficient design of these devices. This is due to the significance of drag reduction in these various aerodynamic devices, such as gas turbines, re-entry space vehicles and airfoils. This study introduces a two-dimensional mathematical formulation of bubble formation after flow separation. The laminar BL equations with appropriate boundary conditions are dimensionalized using the Falkner-Skan transformation. Additionally, using the Keller-box method, the nonlinear system of partial differential equations (PDEs) is numerically solved. This study presents preliminary numerical results of bubble formation in low Mach numbers. These results reveal that after separation, a laminar bubble is formed in all studied cases, for Mach numbers, M = 0.2, 0.33 and 1.0. The flow after separation reverses close to the wall and finally reattaches downstream, in a new location. As the Mach number increases, this effect is more intense. After reattachment, the BL is again established in a lower energy level and the velocity field is substantially reduced, for all cases.展开更多
Electric double-layer field effect experiments were performed on ultrathin films of La0.325Pr0.3Ca0.375MnO3, which is noted for its micrometer-scale phase separation. A clear change of resistance up to 220% was observ...Electric double-layer field effect experiments were performed on ultrathin films of La0.325Pr0.3Ca0.375MnO3, which is noted for its micrometer-scale phase separation. A clear change of resistance up to 220% was observed and the characteristic metal-insulator transition temperature Tp was also shifted. The changes of both the resistance and Tp, suggest that the electric field induced not only tuning of the carrier density but also rebalancing of the phase separation states. The change of the charge-ordered insulating phase fraction was estimated to be temperature dependent, and a maximum of 16% was achieved in the phase separation regime. This tuning effect was partially irreversible, which might be due to an oxygen vacancy migration that is driven by the huge applied electric field.展开更多
To control land surface subsidence caused the underground mineral exploitation and the catastrophic phenomena such as serious damage of buildings, waterbodies, cultivated lands, railways, bridges caused by land subsid...To control land surface subsidence caused the underground mineral exploitation and the catastrophic phenomena such as serious damage of buildings, waterbodies, cultivated lands, railways, bridges caused by land subsidence, bed separation grouting technology of overburden is put forward. To provide theoretical support for the technology, the characteristics and the mechanics mechanism of mining overburden from layer-split to formation of bed separation are studied. On the basis of elastic sheet board theory, calculation formula of rock sheet deflection is presented, and the mechanics criteria of the separation formation and the calculation formula of bed separation volume are set up. Finally, the applications and technics of bed separation grout technology of mining overburden to control land subsidence in china are introduced.展开更多
Wall pressure fluctuations generated by Turbulent Boundary Layers(TBL) provide a significant contribution in reducing the structural vibration and the aircraft cabin noise. However,it is difficult to evaluate these fl...Wall pressure fluctuations generated by Turbulent Boundary Layers(TBL) provide a significant contribution in reducing the structural vibration and the aircraft cabin noise. However,it is difficult to evaluate these fluctuations accurately through a wind tunnel test because of the pollution caused by the background noise generated by the jet or the valve of the wind tunnel. In this study, a new technology named Subsection Approaching Method(SAM) is proposed to separate the wall pressure fluctuations from the background noise induced by the jet or the valve for a transonic wind tunnel test. The SAM demonstrates good performance on separating the background noise from the total pressure compared to the other method in this study. The investigation considers the effects of the sound intensity and the decay factor on the sound-source separation. The results show that the SAM can derive wall pressure fluctuations effectively even when the level of background noise is considerably higher than the level of the wall pressure fluctuations caused by the TBL. In addition, the computational precision is also analyzed based on the broad band noise tested in the wind tunnel. Two methods to improve the precision of the computation with the SAM are also suggested: decreasing the loop gain and increasing the sensors for the signal analysis.展开更多
The purpose of this work is to improve the k-ω-γtransition model for separationinduced transition prediction.The fundamental cause of the excessively small separation bubble predicted by k-ω-γmodel is scrutinized ...The purpose of this work is to improve the k-ω-γtransition model for separationinduced transition prediction.The fundamental cause of the excessively small separation bubble predicted by k-ω-γmodel is scrutinized from the perspective of model construction.On the basis,three rectifications are conducted to improve the k-ω-γmodel for separation-induced transition.Firstly,a damping function is established via comparing the molecular diffusion timescale with the rapid pressure-strain timescale.The damping function is applied to prevent the effective length scale from incorrect distribution near the leading edge of the separation bubble.Secondly,the pressure gradient parameterλζ,is proposed as an indicator for local susceptibility to the separation instability.Additionally,λζ,-based separation intermittencyγsep is constructed to accelerate the substantial growth of turbulent kinetic energy after flow separation.The improved model appropriate for both low-and high-speed flow has been calibrated against a variety of diverse and challenging experiments,including the subsonic T3L plate,Aerospatial A airfoil,transonic NLR-7301 airfoil and deformed hypersonic inflatable aerodynamic decelerator aeroshell.The improved model is strictly based on local variables and Galilean invariance.Besides,the proposed improvement for k-ω-γmodel can be fairly convenient to incorporate into other existing intermittency-based transition models.展开更多
A transonic turbulent separation flow in a converging-diverging transonic diffuser was studied,when there existed a separation bubble on the top wall of the diffuser triggered by strong shock-wave-boundary-layer-inter...A transonic turbulent separation flow in a converging-diverging transonic diffuser was studied,when there existed a separation bubble on the top wall of the diffuser triggered by strong shock-wave-boundary-layer-interaction(SWBLI).To capture the essential behavior of this complex flow,the current study utilized an anisotropic turbulence model developed on the basis of a statistical partial average scheme.The first order moment of turbulent fluctuations,retained by a novel average scheme,and the turbulent length scale,can be determined from the momentum equations and mechanical energy equation of the fluctuation flow,respectively.The two physical quantities were readily used to construct the nonlinear anisotropic eddy viscosity tensor and to significantly improve the computational results.Comparisons between the computational results and experimental data were carried out for velocity profiles,pressure distribution,skin friction coefficient,Reynolds stress as well as streamline vectors distribution.Without using any empirical coefficients and wall functions,the numerical results were in good agreement with the available experimental data,further confirming that the nonlinear anisotropic eddy viscosity tensor is the decisive factor for the success of the computational results.展开更多
The developed process and theoretical achievement for the technology of controlling surface subsidence by grouting separated layer in overburden is summarized in this paper. The research progress of the technology is ...The developed process and theoretical achievement for the technology of controlling surface subsidence by grouting separated layer in overburden is summarized in this paper. The research progress of the technology is discussed synthetically on the basis of practice and research results obtained at coal mine of China in recent years. According to the development tendency of mining under buildings, water bodies and railroads and the properties of the technology, the future research direction is proposed.展开更多
An experimental study was conducted on turbulent separation behaviors induced by blunt fins with different sweep angles at Mach number 6.0.The Nano-particle based Planar Laser Scattering technique(NPLS)was applied to ...An experimental study was conducted on turbulent separation behaviors induced by blunt fins with different sweep angles at Mach number 6.0.The Nano-particle based Planar Laser Scattering technique(NPLS)was applied to visualize the flowfield,complemented by pressure tests.Sweep angles of the fins were 10°,20°,...,60°,with the same leading edge diameter of 10 mm.Fine structures of the interference flowfield induced by blunt fins have been obtained,including the shock systems and vortexes.It was found that the features and shapes of the detached shock depended on sweep angle.When sweep angle<50°,the detached shock appeared as the form of trailing shock,and the supersonic jet with its reflection could be observed.The detached shock would be curved for the 50°and 60°fins and became a transmitted shock.The Scale-Invariant Feature Transform(SIFT)was successfully applied to obtain the velocity field from NPLS images,and the extent of the separated region was found to decrease with increasing sweep angle.No separation appeared as sweep angle>30°.Two peak values were detected on the centerline pressure distribution.The first peak did not rely on sweep angle,while the second peak value decreased with increasing sweep angle.展开更多
Industrial thin-film composite(TFC)membranes achieve superior gas separation properties from high-performance selective layer materials,while the success of membrane technology relies on high-performance gutter layers...Industrial thin-film composite(TFC)membranes achieve superior gas separation properties from high-performance selective layer materials,while the success of membrane technology relies on high-performance gutter layers to achieve production scalability and low-cost manufacturing.However,the current literature predominantly focuses on the design of polymer architectures to obtain high permeability and selectivity,while the art of fabricating gutter layers is usually safeguarded by industrial manufacturers and appears lackluster to academic researchers.This is the first report aiming to provide a comprehensive and critical review of state-of-the-art gutter layer materials and their design and modification to enable TFC membranes with superior separation performance.We first elucidate the importance of the gutter layer on membrane performance through modeling and experimental results.Then various gutter layer materials used to obtain high-performance composite membranes are critically reviewed,and the strategies to improve their compatibility with the selective layer are highlighted,such as oxygen plasma treatment,polydopamine deposition,and surface grafting.Finally,we present the opportunities of the gutter layer design for practical applications.展开更多
Vibration energy harvesting is to transform the ambient mechanical energy to electricity. How to reduce the resonance frequency and improve the conversion efficiency is very important. In this paper, a layer-separated...Vibration energy harvesting is to transform the ambient mechanical energy to electricity. How to reduce the resonance frequency and improve the conversion efficiency is very important. In this paper, a layer-separated piezoelectric cantilever beam is proposed for the vibration energy harvester(VEH) for low-frequency and wide-bandwidth operation, which can transform the mechanical impact energy to electric energy. First,the electromechanical coupling equation is obtained by the Euler-Bernoulli beam theory.Based on the average method, the approximate analytical solution is derived and the voltage response is obtained. Furthermore, the physical prototype is fabricated, and the vibration experiment is conducted to validate the theoretical principle. The experimental results show that the maximum power of 0.445 μW of the layer-separated VEH is about3.11 times higher than that of the non-impact harvester when the excitation acceleration is 0.2 g. The operating frequency bandwidth can be widened by increasing the stiffness of the fundamental layer and decreasing the gap distance of the system. But the increasing of operating frequency bandwidth comes at the cost of reducing peak voltage. The theoretical simulation and the experimental results demonstrate good agreement which indicates that the proposed impact-driving VEH device has advantages for low-frequency and wide-bandwidth. The high performance provides great prospect to scavenge the vibration energy in environment.展开更多
The experimental investigation is conducted with LDV and hydrogen bubble technique in water flow. The shear layer thickness. the vorticity thickness. the maximulll value of turbulence intensities. the turbulent coher...The experimental investigation is conducted with LDV and hydrogen bubble technique in water flow. The shear layer thickness. the vorticity thickness. the maximulll value of turbulence intensities. the turbulent coherent structure. the variations of wall shear stress and the boundary layer shape factor are obtained. In the redevelopment region. the detailed analysis is first made for the streak structures in the near wall region and the turbulent boundary layer is formed at (x-xr) / h = 20.展开更多
Separated shear layer of blunt circular cylinder has been experimentally investigated for the Reynolds numbers (based on the diameter) ranging from 2.8 x 10(3) to 1.0 x 10(5), with emphasis on evolution of separated s...Separated shear layer of blunt circular cylinder has been experimentally investigated for the Reynolds numbers (based on the diameter) ranging from 2.8 x 10(3) to 1.0 x 10(5), with emphasis on evolution of separated shear layer, its structure and distribution of Reynolds shear stress and turbulence kinetic energy. The results demonstrate that laminar separated shear layer experiences 2 similar to 3 times vortex merging before it reattaches, and turbulence separated shear layer takes 5 similar to 6 times vortex merging. In addition, relationship between dimensionless initial frequencies of K-H instability and Reynolds numbers is identified, and reasons for the decay of turbulence kinetic energy and Reynolds shear stress in reattachment region are discussed.展开更多
Based on the research result on the strake-wing, when the size of a strakeis not large, there is a separation zone near the leading edge of the outwing of thestrake-wing at middle angles of attack. So the idea on sepa...Based on the research result on the strake-wing, when the size of a strakeis not large, there is a separation zone near the leading edge of the outwing of thestrake-wing at middle angles of attack. So the idea on separation control by rotating acone placed near the leading edge is presented. The cone surface consists of the part ofthe wing. The effect of rotating the cone on aerodynamic characteristics of thestrake-wing is investigated. The results show that a rotating surface could play an important role in controlling the flow separation for a 3-dimensional wing. For example,the relative increment in maximum lift coefficient attains 30%. The separation zone issuppressed to a certain extent.展开更多
基金supported by the National Natural Science Foundation of China(Grant Number 22350410379)Zhejiang Provincial Natural Science Foundation of China(LZ23B030003)+1 种基金the Fundamental Research Funds for the Central Universities(226-202400075)Ten Thousand Talent Program of Zhejiang Province.
文摘Separator modification is an effective approach to suppress dendrite growth to realize high-energy sodium metal batteries(SMBs)in practical applications,however,its success is mainly subject to surface modification.Herein,a separator with multifunctional layers composed of N-doped mesoporous hollow carbon spheres(HCS)as the inner layer and sodium fluoride(NaF)as the outer layer on commercial polypropylene separator(PP)is proposed(PP@HCS-NaF)to achieve stable cycling in SMB.At the molecular level,the inner HCS layer with a high content of pyrrolic-N induces the uniform Na^(+)flux as a potential Na^(+)redistributor for homogenous deposition,whereas its hollow mesoporous structure offers nanoporous buffers and ion channels to regulate Na^(+)ion distribution and uniform deposition.The outer layer(NaF)constructs the NaF-enriched robust solid electrolyte interphase layer,significantly lowering the Na^(+)ions diffusion barrier.Benefiting from these merits,higher electrochemical performances are achieved with multifunctional double-layered PP@HCS-NaF separators compared with single-layered separators(i.e.PP@HCS or PP@NaF)in SMBs.The Na‖Cu half-cell with PP@HCS-NaF offers stable cycling(280 cycles)with a high CE(99.6%),and Na‖Na symmetric cells demonstrate extended lifespans for over 6000 h at 1 mA cm^(-2)with a progressively stable overpotential of 9 mV.Remarkably,in Na‖NVP full-cells,the PP@HCS-NaF separator grants a stable capacity of~81 mA h g^(-1)after 3500 cycles at 1 C and an impressive rate capability performance(~70 mA h g^(-1)at 15 C).
文摘The process through which a laminar flow undergoes transition to turbulence is of great fundamental and practical interest. Such a process is hugely complex as there are many diverse routes for a laminar flow to become turbulent flow. The transition process is usually initiated by flow instabilities—a primary instability stage followed by a secondary instability stage. This forms a rational framework for the early stage of a transition process and it is crucially important to understand the physics of instabilities leading to turbulence. This article reviews the results of studies on secondary instability of separated shear layers in separation bubbles and summaries the current status of our understanding in this area.
基金supported by the National Natural Science Foundation of China(grant Nos.40874047 and 40574047)
文摘Global seismicity catalogs are sufficient for characterizing double seismic zones （DSZs） in subducting slab and facilitate to estimate layer separation without inconsistent uncertainties as local catalogs. Previous studies have shown the correlation between DSZs layer separation and plate age while correlation for those younger than -60 Ma is suspicious. The lacking of DSZs with layer separation less than 10 km further makes it difficult to precisely estimate such correlation. Thus, we incorporate eight DSZs data determined through local seismicity into globally-determined dataset and reexamine such correlation. The best fitting results show that both a linear model and a square root of plate age can mathematically fit the layer separation well. However, it is difficult to distinguish these two models when plate age is greater than -20 Ma since their difference is less than 2 km. However, if extrapolation is possible, both models should provide physical information that DSZs will not form if there is no subducting lithosphere. As a result, the DSZs cannot be produced until the oceanic lithospheric age becomes greater than 0.9 Ma in the square root model while the linear model gives a misleading result. As such the square root model demonstrates the relationship physically better than the linear one, it still needs further test in the future with more available data, nevertheless, our study might also provide evidence for the suggestion that the plate age is a primary control factor of the DSZs geometry as well as the subducting process which disregards any local tectonic stresses.
基金supported by the National Natural Science Foundation of China(No.92252201)。
文摘To address the early separation problem in the Menter Shear-Stress Transport(SST)turbulence model,a correction for the Turbulent Kinetic Energy(TKE)production term,P_(k),is introduced to account for the effect of the Adverse Pressure Gradient(APG).The correction is determined based on the distribution of Pkin the APG region before separation.When the friction coefficient C_(f) is decomposed,its direct dependence on Pkis clearly observed.However,with the introduction of Bradshaw’s assumption,Pkin the SST turbulence model is over-suppressed,resulting in a lower inner peak or no significant inner peak distribution at all.To address this problem,this paper proposes a Gaussian function,HGauss,which corrects the numerical values of P_(k) involved in the calculation of the Menter SST model by focusing on the inner peak region of P_(k).The modified SST model is then applied to four cases with APGs.The modification leads to an increase in the wall friction coefficient C_(f)in the APG region and causes a downstream shift in the separation location,improving the model’s consistency with high-accuracy data and experimental results.It is demonstrated that this correction can improve the early separation problem in the Menter SST turbulence model.
基金the financial support from the National Key R&D Program of China(2024YFF0506100)the National Natural Science Foundation of China(52225606 and 52488201).
文摘Given the limited exposure of active sites and the retarded separation of photogenerated charge carriers in those developed photocata-lysts,photocatalyticCO_(2)splitting into value-added chemicals has suffered from the poor activity and remained in great challenge for real application.Herein,hydrothermally synthesized BiOCl with layered structure(BOC-NSs)was exfoliated into thickness reduced nanosheets(BOCNSs-w)and even atomic layers(BOCNSs-i)via ultrasonication in water and isopro-panol,respectively.In comparison with the pristine BOCNSs,the exfoli-ated BiOCl,especially BOCNSs-i with atomically layered structure,exhibits much improved photocatalytic activity forCO_(2)overall splitting to produce CO andO_(2) at a stoichiometric ratio of 2:1,with CO evolution rate reaching 134.8µmolg^(-1)h^(-1) under simulated solar light(1.7 suns).By surpassing the photocatalytic performances of the state-of-the-artBi_(l)O_(m)X_(n)(X:Cl,Br,I)based photocatalysts,the CO evolution rate is further increased by 99 times,reaching 13.3 mmolg^(-1)h^(-1) under concentrated solar irradiation(34 suns).This excellent photocatalytic performance achieved over BOCNSs-i should be benefited from the shortened transfer distance and the increased built-in electric field intensity,which acceler-ates the migration of photogenerated charge carriers to surface.Moreover,with oxygen vacancies(VO)introduced into the atomic layers,BOCNSs-i is exposed with the electrons enriched Bi active sites that could transfer electrons to activateCO_(2)molecules for highly efficient and selective CO production,by lowering the energy barrier of rate-determining step(RDS),*OH+*CO_(2)-→HCO_(3)-.It is also realized that theH_(2)O vapor supplied during photocatalytic reaction would exchange oxygen atoms withCO_(2),which could alter the reaction path-ways and further reduce the energy barrier of RDS,contributing to the dramatically improved photocatalytic performance forCO_(2)overall splitting to CO andO_(2).
基金the financial support from National Key Research & Development Program of China (2017B0602702)。
文摘In this paper, the superhydrophobic polyurethane sponge(SS-PU) was facilely fabricated by etching with Jones reagent to bind the nanoparticles of Ni-Co double layered oxides(LDOs) on the surface, and following modification with n-dodecyl mercaptan(DDT). This method provides a new strategy to fabricate superhydrophobic PU sponge with a water contact angle of 157° for absorbing oil with low cost and in large scale. It exhibits the strong absorption capacity and highly selective characteristic for various kinds of oils which can be recycled by simple squeezing. Besides, the as-prepared sponge can deal with the floating and underwater oils, indicating its application value in handling oil spills and domestic oily wastewater. The good self-cleaning ability shows the potential to clear the pollutants due to the ultralow adhesion to water. Especially, the most important point is that the superhydrophobic sponge can continuously and effectively separate the oil/water mixture against the condition of turbulent disturbance by using our designed device system, which exhibit its good superhydrophobicity, strong stability.Furthermore, the SS-PU still maintained stable absorption performance after 150 cycle tests without losing capacity obviously, showing excellent durability in long-term operation and significant potential as an efficient absorbent in large-scale dispose of oily water.
基金Supported by the National Natural Science Foundation of China(Grant No.12171343)the Scientific Research Fund of the Science and Technology Department of Sichuan Province(Grant No.22CXTD0029)。
文摘In this paper,we consider the solutions of 2-D incompressible magnetohydrodynamic(MHD)equations with homogenous Dirichlet boundary condition for velocity and with nonhomogenous Dirichlet boundary condition for magnetic field.We obtain a condition of boundary layer separation by Taylor expansion of functions in the MHD equations and by structural bifurcation theory for divergence free flows with Dirichlet boundary conditions.Furthermore,the condition,determined by external forces,initial values and the value of magnetic field on the boundary,can predict when and where boundary layer separation for the magnetic fluid will occur.
文摘Laminar boundary layer (BL), under adverse pressure gradient, can separate. The separated shear layer reattaches to form a laminar separation bubble. Such bubbles are usually observed on gas turbine blades, on low Reynolds number wings and close to the leading edges of airfoils. Presence of bubbles has a weakening effect on the performance of a fluid device. The understanding of the prevailing mechanism of the separation bubble and ways to control it are essential for the efficient design of these devices. This is due to the significance of drag reduction in these various aerodynamic devices, such as gas turbines, re-entry space vehicles and airfoils. This study introduces a two-dimensional mathematical formulation of bubble formation after flow separation. The laminar BL equations with appropriate boundary conditions are dimensionalized using the Falkner-Skan transformation. Additionally, using the Keller-box method, the nonlinear system of partial differential equations (PDEs) is numerically solved. This study presents preliminary numerical results of bubble formation in low Mach numbers. These results reveal that after separation, a laminar bubble is formed in all studied cases, for Mach numbers, M = 0.2, 0.33 and 1.0. The flow after separation reverses close to the wall and finally reattaches downstream, in a new location. As the Mach number increases, this effect is more intense. After reattachment, the BL is again established in a lower energy level and the velocity field is substantially reduced, for all cases.
基金supported by the National Basic Research Program of China(Grant Nos.2011CBA00106 and 2014CB921401)the National Natural Science Foundation of China(Grant Nos.11174342,9131208,and 11374344)
文摘Electric double-layer field effect experiments were performed on ultrathin films of La0.325Pr0.3Ca0.375MnO3, which is noted for its micrometer-scale phase separation. A clear change of resistance up to 220% was observed and the characteristic metal-insulator transition temperature Tp was also shifted. The changes of both the resistance and Tp, suggest that the electric field induced not only tuning of the carrier density but also rebalancing of the phase separation states. The change of the charge-ordered insulating phase fraction was estimated to be temperature dependent, and a maximum of 16% was achieved in the phase separation regime. This tuning effect was partially irreversible, which might be due to an oxygen vacancy migration that is driven by the huge applied electric field.
基金Foundation item:Key Project of Natural Seien6e Foundation of China(No:50434020 and NO:50274044)Key Project of Science Foundation of Shandong Province(No:Z20031:02)
文摘To control land surface subsidence caused the underground mineral exploitation and the catastrophic phenomena such as serious damage of buildings, waterbodies, cultivated lands, railways, bridges caused by land subsidence, bed separation grouting technology of overburden is put forward. To provide theoretical support for the technology, the characteristics and the mechanics mechanism of mining overburden from layer-split to formation of bed separation are studied. On the basis of elastic sheet board theory, calculation formula of rock sheet deflection is presented, and the mechanics criteria of the separation formation and the calculation formula of bed separation volume are set up. Finally, the applications and technics of bed separation grout technology of mining overburden to control land subsidence in china are introduced.
文摘Wall pressure fluctuations generated by Turbulent Boundary Layers(TBL) provide a significant contribution in reducing the structural vibration and the aircraft cabin noise. However,it is difficult to evaluate these fluctuations accurately through a wind tunnel test because of the pollution caused by the background noise generated by the jet or the valve of the wind tunnel. In this study, a new technology named Subsection Approaching Method(SAM) is proposed to separate the wall pressure fluctuations from the background noise induced by the jet or the valve for a transonic wind tunnel test. The SAM demonstrates good performance on separating the background noise from the total pressure compared to the other method in this study. The investigation considers the effects of the sound intensity and the decay factor on the sound-source separation. The results show that the SAM can derive wall pressure fluctuations effectively even when the level of background noise is considerably higher than the level of the wall pressure fluctuations caused by the TBL. In addition, the computational precision is also analyzed based on the broad band noise tested in the wind tunnel. Two methods to improve the precision of the computation with the SAM are also suggested: decreasing the loop gain and increasing the sensors for the signal analysis.
基金supported by the National Natural Science Foundation of China(Nos.11902367 and 12002355)the State Key Laboratory of Aerodynamics,China(No.SKLA20200202)+1 种基金the National Natural Science Foundation of Hunan Province,China(No.S2021JJQNJJ2716)upported in part by the High Performance Computing Center of Central South University。
文摘The purpose of this work is to improve the k-ω-γtransition model for separationinduced transition prediction.The fundamental cause of the excessively small separation bubble predicted by k-ω-γmodel is scrutinized from the perspective of model construction.On the basis,three rectifications are conducted to improve the k-ω-γmodel for separation-induced transition.Firstly,a damping function is established via comparing the molecular diffusion timescale with the rapid pressure-strain timescale.The damping function is applied to prevent the effective length scale from incorrect distribution near the leading edge of the separation bubble.Secondly,the pressure gradient parameterλζ,is proposed as an indicator for local susceptibility to the separation instability.Additionally,λζ,-based separation intermittencyγsep is constructed to accelerate the substantial growth of turbulent kinetic energy after flow separation.The improved model appropriate for both low-and high-speed flow has been calibrated against a variety of diverse and challenging experiments,including the subsonic T3L plate,Aerospatial A airfoil,transonic NLR-7301 airfoil and deformed hypersonic inflatable aerodynamic decelerator aeroshell.The improved model is strictly based on local variables and Galilean invariance.Besides,the proposed improvement for k-ω-γmodel can be fairly convenient to incorporate into other existing intermittency-based transition models.
基金Aerospace Power Foundation(6141B09050397)Foudamental Reasearch Foundation of North China University of Technology(110052971921/042).
文摘A transonic turbulent separation flow in a converging-diverging transonic diffuser was studied,when there existed a separation bubble on the top wall of the diffuser triggered by strong shock-wave-boundary-layer-interaction(SWBLI).To capture the essential behavior of this complex flow,the current study utilized an anisotropic turbulence model developed on the basis of a statistical partial average scheme.The first order moment of turbulent fluctuations,retained by a novel average scheme,and the turbulent length scale,can be determined from the momentum equations and mechanical energy equation of the fluctuation flow,respectively.The two physical quantities were readily used to construct the nonlinear anisotropic eddy viscosity tensor and to significantly improve the computational results.Comparisons between the computational results and experimental data were carried out for velocity profiles,pressure distribution,skin friction coefficient,Reynolds stress as well as streamline vectors distribution.Without using any empirical coefficients and wall functions,the numerical results were in good agreement with the available experimental data,further confirming that the nonlinear anisotropic eddy viscosity tensor is the decisive factor for the success of the computational results.
文摘The developed process and theoretical achievement for the technology of controlling surface subsidence by grouting separated layer in overburden is summarized in this paper. The research progress of the technology is discussed synthetically on the basis of practice and research results obtained at coal mine of China in recent years. According to the development tendency of mining under buildings, water bodies and railroads and the properties of the technology, the future research direction is proposed.
基金supported by the National Natural Science Foundation of China(No.11902354)。
文摘An experimental study was conducted on turbulent separation behaviors induced by blunt fins with different sweep angles at Mach number 6.0.The Nano-particle based Planar Laser Scattering technique(NPLS)was applied to visualize the flowfield,complemented by pressure tests.Sweep angles of the fins were 10°,20°,...,60°,with the same leading edge diameter of 10 mm.Fine structures of the interference flowfield induced by blunt fins have been obtained,including the shock systems and vortexes.It was found that the features and shapes of the detached shock depended on sweep angle.When sweep angle<50°,the detached shock appeared as the form of trailing shock,and the supersonic jet with its reflection could be observed.The detached shock would be curved for the 50°and 60°fins and became a transmitted shock.The Scale-Invariant Feature Transform(SIFT)was successfully applied to obtain the velocity field from NPLS images,and the extent of the separated region was found to decrease with increasing sweep angle.No separation appeared as sweep angle>30°.Two peak values were detected on the centerline pressure distribution.The first peak did not rely on sweep angle,while the second peak value decreased with increasing sweep angle.
基金support from the U.S.Department of Energy National Energy Technology Laboratory(DE-FE0031736)the New York State Foundation for Science,Technology and Innovation(NYSTAR).
文摘Industrial thin-film composite(TFC)membranes achieve superior gas separation properties from high-performance selective layer materials,while the success of membrane technology relies on high-performance gutter layers to achieve production scalability and low-cost manufacturing.However,the current literature predominantly focuses on the design of polymer architectures to obtain high permeability and selectivity,while the art of fabricating gutter layers is usually safeguarded by industrial manufacturers and appears lackluster to academic researchers.This is the first report aiming to provide a comprehensive and critical review of state-of-the-art gutter layer materials and their design and modification to enable TFC membranes with superior separation performance.We first elucidate the importance of the gutter layer on membrane performance through modeling and experimental results.Then various gutter layer materials used to obtain high-performance composite membranes are critically reviewed,and the strategies to improve their compatibility with the selective layer are highlighted,such as oxygen plasma treatment,polydopamine deposition,and surface grafting.Finally,we present the opportunities of the gutter layer design for practical applications.
基金Project supported by the National Natural Science Foundation of China(Nos.11672008,11702188,and 1832002)
文摘Vibration energy harvesting is to transform the ambient mechanical energy to electricity. How to reduce the resonance frequency and improve the conversion efficiency is very important. In this paper, a layer-separated piezoelectric cantilever beam is proposed for the vibration energy harvester(VEH) for low-frequency and wide-bandwidth operation, which can transform the mechanical impact energy to electric energy. First,the electromechanical coupling equation is obtained by the Euler-Bernoulli beam theory.Based on the average method, the approximate analytical solution is derived and the voltage response is obtained. Furthermore, the physical prototype is fabricated, and the vibration experiment is conducted to validate the theoretical principle. The experimental results show that the maximum power of 0.445 μW of the layer-separated VEH is about3.11 times higher than that of the non-impact harvester when the excitation acceleration is 0.2 g. The operating frequency bandwidth can be widened by increasing the stiffness of the fundamental layer and decreasing the gap distance of the system. But the increasing of operating frequency bandwidth comes at the cost of reducing peak voltage. The theoretical simulation and the experimental results demonstrate good agreement which indicates that the proposed impact-driving VEH device has advantages for low-frequency and wide-bandwidth. The high performance provides great prospect to scavenge the vibration energy in environment.
文摘The experimental investigation is conducted with LDV and hydrogen bubble technique in water flow. The shear layer thickness. the vorticity thickness. the maximulll value of turbulence intensities. the turbulent coherent structure. the variations of wall shear stress and the boundary layer shape factor are obtained. In the redevelopment region. the detailed analysis is first made for the streak structures in the near wall region and the turbulent boundary layer is formed at (x-xr) / h = 20.
基金The proJect supported by the National Natural Science Foundation of Chinathe Key Laboratory for Hydrodynamics of NDCST
文摘Separated shear layer of blunt circular cylinder has been experimentally investigated for the Reynolds numbers (based on the diameter) ranging from 2.8 x 10(3) to 1.0 x 10(5), with emphasis on evolution of separated shear layer, its structure and distribution of Reynolds shear stress and turbulence kinetic energy. The results demonstrate that laminar separated shear layer experiences 2 similar to 3 times vortex merging before it reattaches, and turbulence separated shear layer takes 5 similar to 6 times vortex merging. In addition, relationship between dimensionless initial frequencies of K-H instability and Reynolds numbers is identified, and reasons for the decay of turbulence kinetic energy and Reynolds shear stress in reattachment region are discussed.
文摘Based on the research result on the strake-wing, when the size of a strakeis not large, there is a separation zone near the leading edge of the outwing of thestrake-wing at middle angles of attack. So the idea on separation control by rotating acone placed near the leading edge is presented. The cone surface consists of the part ofthe wing. The effect of rotating the cone on aerodynamic characteristics of thestrake-wing is investigated. The results show that a rotating surface could play an important role in controlling the flow separation for a 3-dimensional wing. For example,the relative increment in maximum lift coefficient attains 30%. The separation zone issuppressed to a certain extent.
