In studying interactions between intense laser fields and atoms or molecules,the role of electron correlation effects on the dynamical response is an important and pressing issue to address.Utilizing Bohmian mechanics...In studying interactions between intense laser fields and atoms or molecules,the role of electron correlation effects on the dynamical response is an important and pressing issue to address.Utilizing Bohmian mechanics(BM),we have theoretically explored the two-electron correlation characteristics while generating high-order harmonics in xenon atoms subjected to intense laser fields.We initially employed Bohmian trajectories to reproduce the dynamics of the electrons and subsequently utilized time-frequency analysis spectra to ascertain the emission time windows for high-order harmonics.Within these time windows,we classified the nuclear region Bohmian trajectories and observed that intense high-order harmonics are solely generated when paired Bohmian particles(BPs)concurrently appear in the nuclear region and reside there for a duration within a re-collision time window.Furthermore,our analysis of characteristic trajectories producing high-order harmonics led us to propose a two-electron re-collision model to elucidate this phenomenon.The study demonstrates that intense high-order harmonics are only generated when both electrons are in the ground state within the re-collision time window.This work discusses the implications of correlation effects between two electrons and offers valuable insights for studying correlation in multi-electron high-order harmonic generation.展开更多
During Donald Trump’s first term,the“Trump Shock”brought world politics into an era of uncertainties and pulled the transatlantic alliance down to its lowest point in history.The Trump 2.0 tsunami brewed by the 202...During Donald Trump’s first term,the“Trump Shock”brought world politics into an era of uncertainties and pulled the transatlantic alliance down to its lowest point in history.The Trump 2.0 tsunami brewed by the 2024 presidential election of the United States has plunged the U.S.-Europe relations into more gloomy waters,ushering in a more complex and turbulent period of adjustment.展开更多
I am delighted to join my Thai and Chinese friends in celebrating the 50th anniversary of the establishment of diplomatic relations between our two great nations.It is the“Golden Jubilee”of Thailand-China friendship...I am delighted to join my Thai and Chinese friends in celebrating the 50th anniversary of the establishment of diplomatic relations between our two great nations.It is the“Golden Jubilee”of Thailand-China friendship.Half a century ago when Thailand’s then Prime Minister M.R.Kukrit Pramoj and China’s Premier Zhou Enlai signed a Joint Communique on the Establishment of Diplomatic Relations on July 1,1975,the foundation for a profound and mutually beneficial partnership was laid,fostering enduring friendship,cooperation,and understanding between our two nations.This bond has stood the test of time amidst the ever-changing international landscape and been further enhanced by both countries’commitment to advancing the Comprehensive Strategic Cooperative Partnership and building a Thailand-China community with a shared future for enhanced stability,prosperity,and sustainability through a forwardlooking and people-centered vision.展开更多
In recent years,with the rapid development of deep learning technology,relational triplet extraction techniques have also achieved groundbreaking progress.Traditional pipeline models have certain limitations due to er...In recent years,with the rapid development of deep learning technology,relational triplet extraction techniques have also achieved groundbreaking progress.Traditional pipeline models have certain limitations due to error propagation.To overcome the limitations of traditional pipeline models,recent research has focused on jointly modeling the two key subtasks-named entity recognition and relation extraction-within a unified framework.To support future research,this paper provides a comprehensive review of recently published studies in the field of relational triplet extraction.The review examines commonly used public datasets for relational triplet extraction techniques and systematically reviews current mainstream joint extraction methods,including joint decoding methods and parameter sharing methods,with joint decoding methods further divided into table filling,tagging,and sequence-to-sequence approaches.In addition,this paper also conducts small-scale replication experiments on models that have performed well in recent years for each method to verify the reproducibility of the code and to compare the performance of different models under uniform conditions.Each method has its own advantages in terms of model design,task handling,and application scenarios,but also faces challenges such as processing complex sentence structures,cross-sentence relation extraction,and adaptability in low-resource environments.Finally,this paper systematically summarizes each method and discusses the future development prospects of joint extraction of relational triples.展开更多
The year 2025 marks the 50th anniversary of diplomatic relations between China and the Philippines.Over the past half century,despite ups and downs,China-Philippines relations have maintained a steady momentum of deve...The year 2025 marks the 50th anniversary of diplomatic relations between China and the Philippines.Over the past half century,despite ups and downs,China-Philippines relations have maintained a steady momentum of development with continuous progress in political,economic,and cultural exchanges.Since the second half of 2023,the Philippines’freguent provocations in the South China Sea have negatively impacted bilateral relations.展开更多
If there were any doubts about the Trump administration’s inherent obsession with decoupling,polarization and jolting of global trade,they can be laid to rest.A series of statements and measures have been made by the...If there were any doubts about the Trump administration’s inherent obsession with decoupling,polarization and jolting of global trade,they can be laid to rest.A series of statements and measures have been made by the U.S.government on economic relations with China including administrative decision to hit Chinese goods with additional tariffs despite China.展开更多
We investigate theoretically the effects of chirped laser pulses on high-order harmonic generation(HHG)from solids.We find that the harmonic spectra display redshifts for the driving laser pulses with negative chirp a...We investigate theoretically the effects of chirped laser pulses on high-order harmonic generation(HHG)from solids.We find that the harmonic spectra display redshifts for the driving laser pulses with negative chirp and blueshifts for those with positive chirp,which is due to the change in the instantaneous frequency of the driving laser for different chirped pulses.The analysis of crystal-momentum-resolved(k-resolved)HHG reveals that the frequency shifts are equal for the harmonics generated by different crystal momentum channels.The frequency shifts in the cutoff region are larger than those in the plateau region.With the increase of the absolute value of the chirp parameters,the frequency shifts of HHG become more significant,leading to the shifts from odd-to even-order harmonics.We also demonstrate that the frequency shifts of harmonic spectra are related to the duration of the chirped laser field,but are insensitive to the laser intensity and dephasing time.展开更多
A new oxidative N-heterocyclic carbene(NHC)-catalyzed high-order[7+3]annulation reaction ofγ-indolyl phenols as 1,7-dinucleophiles andα,β-alkynals with the aid of Sc(OTf)_(3)is reported,enabling the highly regiosel...A new oxidative N-heterocyclic carbene(NHC)-catalyzed high-order[7+3]annulation reaction ofγ-indolyl phenols as 1,7-dinucleophiles andα,β-alkynals with the aid of Sc(OTf)_(3)is reported,enabling the highly regioselective access to unprecedented polyarene-fused ten-membered lactams bearing a bridged aryl-aryl-indole scaffold in moderate to good yields.This protocol demonstrates a broad substrate scope,good compatibility with substituents and complete regioselectivity,providing an organocatalytic modular synthetic strategy for creating medium-sized lactams.展开更多
The year 2025 marks the 75th anniversary of the establishment of diplomatic relations between China and Indonesia.Over the past 75 years,the bilateral relationship has made significant progress across various fields,l...The year 2025 marks the 75th anniversary of the establishment of diplomatic relations between China and Indonesia.Over the past 75 years,the bilateral relationship has made significant progress across various fields,laying a solid foundation for regional stability.China Report ASEAN interviewed Indonesian Ambassador to China Djauhari Oratmangun to reflect on the remarkable journey of Indonesia-China relations over the past 75 years.展开更多
Thermal expansion is crucial for various industrial processes and is increasingly the focus of research endeavors aimed at improving material performance.However,it is the continuous advancements in first-principles c...Thermal expansion is crucial for various industrial processes and is increasingly the focus of research endeavors aimed at improving material performance.However,it is the continuous advancements in first-principles calculations that have enabled researchers to understand the microscopic origins of thermal expansion.In this study,we propose a coefficient of thermal expansion(CTE)calculation scheme based on self-consistent phonon theory,incorporating the fourth-order anharmonicity.We selected four structures(Si,CaZrF_(6),SrTiO_(3),NaBr)to investigate high-order anharmonicity’s impact on their CTEs,based on bonding types.The results indicate that our method goes beyond the second-order quasi-harmonic approximation and the third-order perturbation theory,aligning closely with experimental data.Furthermore,we observed that an increase in the ionicity of the structures leads to a more pronounced influence of high-order anharmonicity on CTE,with this effect primarily manifesting in variations of the Grüneisen parameter.Our research provides a theoretical foundation for accurately predicting and regulating the thermal expansion behavior of materials.展开更多
An efficient and accurate scalar auxiliary variable(SAV)scheme for numerically solving nonlinear parabolic integro-differential equation(PIDE)is developed in this paper.The original equation is first transformed into ...An efficient and accurate scalar auxiliary variable(SAV)scheme for numerically solving nonlinear parabolic integro-differential equation(PIDE)is developed in this paper.The original equation is first transformed into an equivalent system,and the k-order backward differentiation formula(BDF k)and central difference formula are used to discretize the temporal and spatial derivatives,respectively.Different from the traditional discrete method that adopts full implicit or full explicit for the nonlinear integral terms,the proposed scheme is based on the SAV idea and can be treated semi-implicitly,taking into account both accuracy and effectiveness.Numerical results are presented to demonstrate the high-order convergence(up to fourth-order)of the developed schemes and it is computationally efficient in long-time computations.展开更多
Green development is vital for bringing about high-quality development,which makes measuring and comparing provincial green development levels essential.This study calculates the comprehensive green development scores...Green development is vital for bringing about high-quality development,which makes measuring and comparing provincial green development levels essential.This study calculates the comprehensive green development scores using panel data from 30 Chinese provinces and autonomous regions(2013-2022)and a combined subjective-objective weighting method.It also innovatively establishes a grey relational degree matrix and a grey improvement sequence to analyze provincial similarities and identify benchmarks for improvement.The results indicate that ecological and environmental protection holds the highest weight among the primary indicators.Beijing,Shanghai,Tianjin,Zhejiang,and Jiangsu lead in green development,with Shanghai,Beijing,and Tianjin exhibiting distinct development trajectories,while Guizhou and Yunnan share a similar trend.Zhejiang and Shaanxi have prominent benchmarks for improvement,while some provinces dynamically adjust their targets.The results suggest that advanced regions should further refine their green development pathways to align with their specific contexts,while less-developed regions should adaptively learn from the appropriate benchmarks and periodically reassess their strategies.This study provides scientific guidance for regional green development planning,policymaking,and benchmarking,thus contributing to sustainable regional development.Furthermore,it lays a foundation for future research to expand into broader datasets,scales,influencing factors,and policy evaluations.展开更多
This year marks the 50th anniversary of the establishment of diplomatic relations between China and the EU.Over half a century,China and the EU have steadily enhanced political mutual trust,deepened mutually beneficia...This year marks the 50th anniversary of the establishment of diplomatic relations between China and the EU.Over half a century,China and the EU have steadily enhanced political mutual trust,deepened mutually beneficial cooperation,and firmly upheld multilateralism,bringing tangible benefits to both peoples and making a significant contribution to global peace and development.展开更多
We present a comprehensive study on the role of various excited states in high-order harmonic generation of hydrogen atoms driven by a long-wavelength(1500 nm)laser field.By numerically solving the time-dependent Schr...We present a comprehensive study on the role of various excited states in high-order harmonic generation of hydrogen atoms driven by a long-wavelength(1500 nm)laser field.By numerically solving the time-dependent Schrodinger equation(TDSE)and performing a time-frequency analysis,we investigate the influence of individual excited states on the harmonic spectrum.Our results reveal that the 2s excited state primarily contributes to the enhancement of high-energy harmonic yields by facilitating long electron trajectories,while the 2p excited state predominantly suppresses harmonic yields in the lower-energy region(20th-50th orders)by altering the contributions of electron trajectories.Our results highlight the critical role of the excited states in the HHG process,even at longer laser wavelengths.展开更多
This article attempts to distinguish public relations(PRs)from propaganda,within the context of information management.Speedy dissemination of information is an important feature of contemporary communication practice...This article attempts to distinguish public relations(PRs)from propaganda,within the context of information management.Speedy dissemination of information is an important feature of contemporary communication practice globally.In this era,the information content of communication is an important element requiring critical evaluation.This is so,because of the need to safeguard the information ecosystem,considering the thin line between public relations and propaganda.While both propaganda and public relations aim to shape perceptions,influence attitudes,and sway opinions,one key distinction lies in their ethical considerations.Public relations emphasize honesty,accuracy,accountability,and a commitment to the truth.In contrast,propaganda may involve manipulation,distortion,or even fabrication of information to advance a particular agenda,often at the expense of truth and transparency.Hinged on The Excellence Theory and the Two-Way Symmetrical Model,the paper focuses on the meeting points and differences between public relations and propaganda,with a view to safeguarding the integrity of the information ecosystem.The study adopted the survey research method,with interview as research instrument.The study discovered that while propaganda is not entirely a bad practice,it has a heavy tilt towards bias.It therefore recommends that deliberate steps be taken by relevant professional organisations and other stakeholders towards educating the citizens on ways of distinguishing between public relations and propaganda contents.展开更多
We performed real-time and real-space numerical simulations of high-order harmonic generation in the threedimensional structured molecule methane(CH_(4)) using time-dependent density functional theory. By irradiating ...We performed real-time and real-space numerical simulations of high-order harmonic generation in the threedimensional structured molecule methane(CH_(4)) using time-dependent density functional theory. By irradiating the methane molecule with an elliptically polarized laser pulse polarized in the x–y plane, we observed significant even-order harmonic emission in the z-direction. By analyzing the electron dynamics in the electric field and the multi-orbital effects of the molecule, we revealed that electron recombination near specific atoms in methane is the primary source of highorder harmonic generation in the z-direction. Furthermore, we identified the dominant molecular orbitals responsible for the enhancement of harmonics in this direction and demonstrated the critical role played by multi-orbital effects in this process.展开更多
The high-speed development of space defense technology demands a high state estimation capacity for spacecraft tracking methods.However,reentry flight is accompanied by complex flight environments,which brings to the ...The high-speed development of space defense technology demands a high state estimation capacity for spacecraft tracking methods.However,reentry flight is accompanied by complex flight environments,which brings to the uncertain,complex,and strongly coupled non-Gaussian detection noise.As a result,there are several intractable considerations on the problem of state estimation tasks corrupted by complex non-Gaussian outliers for non-linear dynamics systems in practical application.To address these issues,a new iterated rational quadratic(RQ)kernel high-order unscented Kalman filtering(IRQHUKF)algorithm via capturing the statistics to break through the limitations of the Gaussian assumption is proposed.Firstly,the characteristic analysis of the RQ kernel is investigated in detail,which is the first attempt to carry out an exploration of the heavy-tailed characteristic and the ability on capturing highorder moments of the RQ kernel.Subsequently,the RQ kernel method is first introduced into the UKF algorithm as an error optimization criterion,termed the iterated RQ kernel-UKF(RQ-UKF)algorithm by derived analytically,which not only retains the high-order moments propagation process but also enhances the approximation capacity in the non-Gaussian noise problem for its ability in capturing highorder moments and heavy-tailed characteristics.Meanwhile,to tackle the limitations of the Gaussian distribution assumption in the linearization process of the non-linear systems,the high-order Sigma Points(SP)as a subsidiary role in propagating the state high-order statistics is devised by the moments matching method to improve the RQ-UKF.Finally,to further improve the flexibility of the IRQ-HUKF algorithm in practical application,an adaptive kernel parameter is derived analytically grounded in the Kullback-Leibler divergence(KLD)method and parametric sensitivity analysis of the RQ kernel.The simulation results demonstrate that the novel IRQ-HUKF algorithm is more robust and outperforms the existing advanced UKF with respect to the kernel method in reentry vehicle tracking scenarios under various noise environments.展开更多
Global challenges like epidemics,wars,and climate change expose humans to life-and-death threats daily,triggering death anxiety and subsequent death reflection,which involves deliberate cognitive processing of mortali...Global challenges like epidemics,wars,and climate change expose humans to life-and-death threats daily,triggering death anxiety and subsequent death reflection,which involves deliberate cognitive processing of mortality.While some studies have shown the positive impacts of death reflection,such as on well-being,the relationship between death reflection and existential well-being,closely related to life and death,remains unexplored.This study aimed to investigate the effects of death reflection on existential well-being and the mediating role of relational self-esteem.675 university students from Sichuan and Hubei,China,completed the death reflection scale,relational self-esteem scale,and the existential well-being subscale of the spiritual well-being scale.Results indicated that death reflection was positively correlated with both relational self-esteem and existential well-being,and relational self-esteem was positively related to existential well-being.Mediation analysis confirmed that relational self-esteem mediated the relationship between death reflection and existential well-being.This study not only enriches the research content on the positive effects of death reflection theoretically,but also holds significant practical value in guiding individuals who have experienced death or been exposed to death-related information in their psychological reconstruction and recovery.展开更多
Purpose:This paper presents a new semi-automatic methodology for identifying inter-actor relationships by discerning viewpoints in non-social,political textual corpora.Although previous research has successfully disce...Purpose:This paper presents a new semi-automatic methodology for identifying inter-actor relationships by discerning viewpoints in non-social,political textual corpora.Although previous research has successfully discerned viewpoints,biases,and affiliations based on textual features,the task of relationship analysis in the absence of interactional data remains unaddressed.Design/methodology/approach:We introduce a new paradigm for topic representation as a dynamic,continuous,multi-viewpoint spectrum based on the representation of viewpoints as vectors that capture common topical themes.As a proof of concept,we applied this paradigm to scrutinize the inter-state relationships reflected in the speeches of the UN General Assembly Debate Corpus(UNGDC).Findings:The proposed paradigm effectively identifies discursive trends in UNGDC.Our analysis reveals common attitudes towards the topic and their prominence among different groups of actors and facilitates the analysis of relationships between actors through a quantitative representation of viewpoint similarity.The method also successfully captured temporal shifts in viewpoints and overall discourse trends,correlating with major geopolitical events.Research limitations:One limitation of this study is the method’s sensitivity to data sparsity,which can skew viewpoint representations in cases of low topic involvement.Practical implications:The proposed paradigm can be utilized by scholars in political science and other domains as a tool for semi-automated unsupervised textual analysis of various non-social textual sources,enabling the discovery of latent relationships between actors and the modeling of viewpoints in complex topics.Originality/value:This study presents a novel framework for unsupervised semi-automatic textual analysis of relationships in non-social corpora through a new approach for the representation of viewpoints as thematic vectors.展开更多
基金Project supported by the Natural Science Foundation(General Project)of Jilin Province,China(Grant No.20230101283JC)。
文摘In studying interactions between intense laser fields and atoms or molecules,the role of electron correlation effects on the dynamical response is an important and pressing issue to address.Utilizing Bohmian mechanics(BM),we have theoretically explored the two-electron correlation characteristics while generating high-order harmonics in xenon atoms subjected to intense laser fields.We initially employed Bohmian trajectories to reproduce the dynamics of the electrons and subsequently utilized time-frequency analysis spectra to ascertain the emission time windows for high-order harmonics.Within these time windows,we classified the nuclear region Bohmian trajectories and observed that intense high-order harmonics are solely generated when paired Bohmian particles(BPs)concurrently appear in the nuclear region and reside there for a duration within a re-collision time window.Furthermore,our analysis of characteristic trajectories producing high-order harmonics led us to propose a two-electron re-collision model to elucidate this phenomenon.The study demonstrates that intense high-order harmonics are only generated when both electrons are in the ground state within the re-collision time window.This work discusses the implications of correlation effects between two electrons and offers valuable insights for studying correlation in multi-electron high-order harmonic generation.
文摘During Donald Trump’s first term,the“Trump Shock”brought world politics into an era of uncertainties and pulled the transatlantic alliance down to its lowest point in history.The Trump 2.0 tsunami brewed by the 2024 presidential election of the United States has plunged the U.S.-Europe relations into more gloomy waters,ushering in a more complex and turbulent period of adjustment.
文摘I am delighted to join my Thai and Chinese friends in celebrating the 50th anniversary of the establishment of diplomatic relations between our two great nations.It is the“Golden Jubilee”of Thailand-China friendship.Half a century ago when Thailand’s then Prime Minister M.R.Kukrit Pramoj and China’s Premier Zhou Enlai signed a Joint Communique on the Establishment of Diplomatic Relations on July 1,1975,the foundation for a profound and mutually beneficial partnership was laid,fostering enduring friendship,cooperation,and understanding between our two nations.This bond has stood the test of time amidst the ever-changing international landscape and been further enhanced by both countries’commitment to advancing the Comprehensive Strategic Cooperative Partnership and building a Thailand-China community with a shared future for enhanced stability,prosperity,and sustainability through a forwardlooking and people-centered vision.
基金funding from Key Areas Science and Technology Research Plan of Xinjiang Production And Construction Corps Financial Science and Technology Plan Project under Grant Agreement No.2023AB048 for the project:Research and Application Demonstration of Data-driven Elderly Care System.
文摘In recent years,with the rapid development of deep learning technology,relational triplet extraction techniques have also achieved groundbreaking progress.Traditional pipeline models have certain limitations due to error propagation.To overcome the limitations of traditional pipeline models,recent research has focused on jointly modeling the two key subtasks-named entity recognition and relation extraction-within a unified framework.To support future research,this paper provides a comprehensive review of recently published studies in the field of relational triplet extraction.The review examines commonly used public datasets for relational triplet extraction techniques and systematically reviews current mainstream joint extraction methods,including joint decoding methods and parameter sharing methods,with joint decoding methods further divided into table filling,tagging,and sequence-to-sequence approaches.In addition,this paper also conducts small-scale replication experiments on models that have performed well in recent years for each method to verify the reproducibility of the code and to compare the performance of different models under uniform conditions.Each method has its own advantages in terms of model design,task handling,and application scenarios,but also faces challenges such as processing complex sentence structures,cross-sentence relation extraction,and adaptability in low-resource environments.Finally,this paper systematically summarizes each method and discusses the future development prospects of joint extraction of relational triples.
文摘The year 2025 marks the 50th anniversary of diplomatic relations between China and the Philippines.Over the past half century,despite ups and downs,China-Philippines relations have maintained a steady momentum of development with continuous progress in political,economic,and cultural exchanges.Since the second half of 2023,the Philippines’freguent provocations in the South China Sea have negatively impacted bilateral relations.
文摘If there were any doubts about the Trump administration’s inherent obsession with decoupling,polarization and jolting of global trade,they can be laid to rest.A series of statements and measures have been made by the U.S.government on economic relations with China including administrative decision to hit Chinese goods with additional tariffs despite China.
基金Project supported by the Natural Science Foundation of Jilin Province of China(Grant No.20230101014JC)the National Natural Science Foundation of China(Grant No.12374265)。
文摘We investigate theoretically the effects of chirped laser pulses on high-order harmonic generation(HHG)from solids.We find that the harmonic spectra display redshifts for the driving laser pulses with negative chirp and blueshifts for those with positive chirp,which is due to the change in the instantaneous frequency of the driving laser for different chirped pulses.The analysis of crystal-momentum-resolved(k-resolved)HHG reveals that the frequency shifts are equal for the harmonics generated by different crystal momentum channels.The frequency shifts in the cutoff region are larger than those in the plateau region.With the increase of the absolute value of the chirp parameters,the frequency shifts of HHG become more significant,leading to the shifts from odd-to even-order harmonics.We also demonstrate that the frequency shifts of harmonic spectra are related to the duration of the chirped laser field,but are insensitive to the laser intensity and dephasing time.
基金National Natural Science Foundation of China(Nos.21971090 and 22271123)the NSF of Jiangsu Province(No.BK20230201)+1 种基金the Natural Science Foundation of Jiangsu Education Committee(No.22KJB150024)the Natural Science Foundation of Jiangsu Normal University(No.21XSRX010)。
文摘A new oxidative N-heterocyclic carbene(NHC)-catalyzed high-order[7+3]annulation reaction ofγ-indolyl phenols as 1,7-dinucleophiles andα,β-alkynals with the aid of Sc(OTf)_(3)is reported,enabling the highly regioselective access to unprecedented polyarene-fused ten-membered lactams bearing a bridged aryl-aryl-indole scaffold in moderate to good yields.This protocol demonstrates a broad substrate scope,good compatibility with substituents and complete regioselectivity,providing an organocatalytic modular synthetic strategy for creating medium-sized lactams.
文摘The year 2025 marks the 75th anniversary of the establishment of diplomatic relations between China and Indonesia.Over the past 75 years,the bilateral relationship has made significant progress across various fields,laying a solid foundation for regional stability.China Report ASEAN interviewed Indonesian Ambassador to China Djauhari Oratmangun to reflect on the remarkable journey of Indonesia-China relations over the past 75 years.
基金Project supported by the National Natural Science Foundation of China(Grant No.62125402).
文摘Thermal expansion is crucial for various industrial processes and is increasingly the focus of research endeavors aimed at improving material performance.However,it is the continuous advancements in first-principles calculations that have enabled researchers to understand the microscopic origins of thermal expansion.In this study,we propose a coefficient of thermal expansion(CTE)calculation scheme based on self-consistent phonon theory,incorporating the fourth-order anharmonicity.We selected four structures(Si,CaZrF_(6),SrTiO_(3),NaBr)to investigate high-order anharmonicity’s impact on their CTEs,based on bonding types.The results indicate that our method goes beyond the second-order quasi-harmonic approximation and the third-order perturbation theory,aligning closely with experimental data.Furthermore,we observed that an increase in the ionicity of the structures leads to a more pronounced influence of high-order anharmonicity on CTE,with this effect primarily manifesting in variations of the Grüneisen parameter.Our research provides a theoretical foundation for accurately predicting and regulating the thermal expansion behavior of materials.
基金Supported by the National Natural Science Foundation of China(Grant Nos.12001210 and 12261103)the Natural Science Foundation of Henan(Grant No.252300420308)the Yunnan Fundamental Research Projects(Grant No.202301AT070117).
文摘An efficient and accurate scalar auxiliary variable(SAV)scheme for numerically solving nonlinear parabolic integro-differential equation(PIDE)is developed in this paper.The original equation is first transformed into an equivalent system,and the k-order backward differentiation formula(BDF k)and central difference formula are used to discretize the temporal and spatial derivatives,respectively.Different from the traditional discrete method that adopts full implicit or full explicit for the nonlinear integral terms,the proposed scheme is based on the SAV idea and can be treated semi-implicitly,taking into account both accuracy and effectiveness.Numerical results are presented to demonstrate the high-order convergence(up to fourth-order)of the developed schemes and it is computationally efficient in long-time computations.
文摘Green development is vital for bringing about high-quality development,which makes measuring and comparing provincial green development levels essential.This study calculates the comprehensive green development scores using panel data from 30 Chinese provinces and autonomous regions(2013-2022)and a combined subjective-objective weighting method.It also innovatively establishes a grey relational degree matrix and a grey improvement sequence to analyze provincial similarities and identify benchmarks for improvement.The results indicate that ecological and environmental protection holds the highest weight among the primary indicators.Beijing,Shanghai,Tianjin,Zhejiang,and Jiangsu lead in green development,with Shanghai,Beijing,and Tianjin exhibiting distinct development trajectories,while Guizhou and Yunnan share a similar trend.Zhejiang and Shaanxi have prominent benchmarks for improvement,while some provinces dynamically adjust their targets.The results suggest that advanced regions should further refine their green development pathways to align with their specific contexts,while less-developed regions should adaptively learn from the appropriate benchmarks and periodically reassess their strategies.This study provides scientific guidance for regional green development planning,policymaking,and benchmarking,thus contributing to sustainable regional development.Furthermore,it lays a foundation for future research to expand into broader datasets,scales,influencing factors,and policy evaluations.
文摘This year marks the 50th anniversary of the establishment of diplomatic relations between China and the EU.Over half a century,China and the EU have steadily enhanced political mutual trust,deepened mutually beneficial cooperation,and firmly upheld multilateralism,bringing tangible benefits to both peoples and making a significant contribution to global peace and development.
基金supported by the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi。
文摘We present a comprehensive study on the role of various excited states in high-order harmonic generation of hydrogen atoms driven by a long-wavelength(1500 nm)laser field.By numerically solving the time-dependent Schrodinger equation(TDSE)and performing a time-frequency analysis,we investigate the influence of individual excited states on the harmonic spectrum.Our results reveal that the 2s excited state primarily contributes to the enhancement of high-energy harmonic yields by facilitating long electron trajectories,while the 2p excited state predominantly suppresses harmonic yields in the lower-energy region(20th-50th orders)by altering the contributions of electron trajectories.Our results highlight the critical role of the excited states in the HHG process,even at longer laser wavelengths.
文摘This article attempts to distinguish public relations(PRs)from propaganda,within the context of information management.Speedy dissemination of information is an important feature of contemporary communication practice globally.In this era,the information content of communication is an important element requiring critical evaluation.This is so,because of the need to safeguard the information ecosystem,considering the thin line between public relations and propaganda.While both propaganda and public relations aim to shape perceptions,influence attitudes,and sway opinions,one key distinction lies in their ethical considerations.Public relations emphasize honesty,accuracy,accountability,and a commitment to the truth.In contrast,propaganda may involve manipulation,distortion,or even fabrication of information to advance a particular agenda,often at the expense of truth and transparency.Hinged on The Excellence Theory and the Two-Way Symmetrical Model,the paper focuses on the meeting points and differences between public relations and propaganda,with a view to safeguarding the integrity of the information ecosystem.The study adopted the survey research method,with interview as research instrument.The study discovered that while propaganda is not entirely a bad practice,it has a heavy tilt towards bias.It therefore recommends that deliberate steps be taken by relevant professional organisations and other stakeholders towards educating the citizens on ways of distinguishing between public relations and propaganda contents.
基金Project supported by the National Natural Science Foundation of China (Grant No. 12204214)the National Key Research and Development Program of China (Grant No. 2022YFE0134200)+1 种基金the Fundamental Research Funds for the Central Universities (Grant No. GK202207012), QCYRCXM-2022-241the Guangdong Basic and Applied Basic Research Foundation (Grant No. 2025A1515011117)。
文摘We performed real-time and real-space numerical simulations of high-order harmonic generation in the threedimensional structured molecule methane(CH_(4)) using time-dependent density functional theory. By irradiating the methane molecule with an elliptically polarized laser pulse polarized in the x–y plane, we observed significant even-order harmonic emission in the z-direction. By analyzing the electron dynamics in the electric field and the multi-orbital effects of the molecule, we revealed that electron recombination near specific atoms in methane is the primary source of highorder harmonic generation in the z-direction. Furthermore, we identified the dominant molecular orbitals responsible for the enhancement of harmonics in this direction and demonstrated the critical role played by multi-orbital effects in this process.
基金supported by the National Natural Science Foundation of China under Grant No.12072090.
文摘The high-speed development of space defense technology demands a high state estimation capacity for spacecraft tracking methods.However,reentry flight is accompanied by complex flight environments,which brings to the uncertain,complex,and strongly coupled non-Gaussian detection noise.As a result,there are several intractable considerations on the problem of state estimation tasks corrupted by complex non-Gaussian outliers for non-linear dynamics systems in practical application.To address these issues,a new iterated rational quadratic(RQ)kernel high-order unscented Kalman filtering(IRQHUKF)algorithm via capturing the statistics to break through the limitations of the Gaussian assumption is proposed.Firstly,the characteristic analysis of the RQ kernel is investigated in detail,which is the first attempt to carry out an exploration of the heavy-tailed characteristic and the ability on capturing highorder moments of the RQ kernel.Subsequently,the RQ kernel method is first introduced into the UKF algorithm as an error optimization criterion,termed the iterated RQ kernel-UKF(RQ-UKF)algorithm by derived analytically,which not only retains the high-order moments propagation process but also enhances the approximation capacity in the non-Gaussian noise problem for its ability in capturing highorder moments and heavy-tailed characteristics.Meanwhile,to tackle the limitations of the Gaussian distribution assumption in the linearization process of the non-linear systems,the high-order Sigma Points(SP)as a subsidiary role in propagating the state high-order statistics is devised by the moments matching method to improve the RQ-UKF.Finally,to further improve the flexibility of the IRQ-HUKF algorithm in practical application,an adaptive kernel parameter is derived analytically grounded in the Kullback-Leibler divergence(KLD)method and parametric sensitivity analysis of the RQ kernel.The simulation results demonstrate that the novel IRQ-HUKF algorithm is more robust and outperforms the existing advanced UKF with respect to the kernel method in reentry vehicle tracking scenarios under various noise environments.
文摘Global challenges like epidemics,wars,and climate change expose humans to life-and-death threats daily,triggering death anxiety and subsequent death reflection,which involves deliberate cognitive processing of mortality.While some studies have shown the positive impacts of death reflection,such as on well-being,the relationship between death reflection and existential well-being,closely related to life and death,remains unexplored.This study aimed to investigate the effects of death reflection on existential well-being and the mediating role of relational self-esteem.675 university students from Sichuan and Hubei,China,completed the death reflection scale,relational self-esteem scale,and the existential well-being subscale of the spiritual well-being scale.Results indicated that death reflection was positively correlated with both relational self-esteem and existential well-being,and relational self-esteem was positively related to existential well-being.Mediation analysis confirmed that relational self-esteem mediated the relationship between death reflection and existential well-being.This study not only enriches the research content on the positive effects of death reflection theoretically,but also holds significant practical value in guiding individuals who have experienced death or been exposed to death-related information in their psychological reconstruction and recovery.
基金part of the research project “What Are States Talking About?”(ISF Grant 2109/19),funded by the Israeli Science Foundation。
文摘Purpose:This paper presents a new semi-automatic methodology for identifying inter-actor relationships by discerning viewpoints in non-social,political textual corpora.Although previous research has successfully discerned viewpoints,biases,and affiliations based on textual features,the task of relationship analysis in the absence of interactional data remains unaddressed.Design/methodology/approach:We introduce a new paradigm for topic representation as a dynamic,continuous,multi-viewpoint spectrum based on the representation of viewpoints as vectors that capture common topical themes.As a proof of concept,we applied this paradigm to scrutinize the inter-state relationships reflected in the speeches of the UN General Assembly Debate Corpus(UNGDC).Findings:The proposed paradigm effectively identifies discursive trends in UNGDC.Our analysis reveals common attitudes towards the topic and their prominence among different groups of actors and facilitates the analysis of relationships between actors through a quantitative representation of viewpoint similarity.The method also successfully captured temporal shifts in viewpoints and overall discourse trends,correlating with major geopolitical events.Research limitations:One limitation of this study is the method’s sensitivity to data sparsity,which can skew viewpoint representations in cases of low topic involvement.Practical implications:The proposed paradigm can be utilized by scholars in political science and other domains as a tool for semi-automated unsupervised textual analysis of various non-social textual sources,enabling the discovery of latent relationships between actors and the modeling of viewpoints in complex topics.Originality/value:This study presents a novel framework for unsupervised semi-automatic textual analysis of relationships in non-social corpora through a new approach for the representation of viewpoints as thematic vectors.
