It is well known that single-atom catalysts(SACs)have become a hot topic in the field of catalysis due to their advantages such as 100%metal atom utilization efficiency,high catalytic activity and selectivity compared...It is well known that single-atom catalysts(SACs)have become a hot topic in the field of catalysis due to their advantages such as 100%metal atom utilization efficiency,high catalytic activity and selectivity compared with conventional catalysts and nanocatalysts.However,the isolated metal atoms on SACs have thermodynamic instability and tend to agglomerate,which limit their catalytic performance.Therefore,it is of great significance to synthesize stable and high-loading single-atom catalysts(HLSACs).In this paper,we review the research progress of HLSACs from two aspects:design and application.Firstly,we comprehensively introduce the synthesis strategies of HLSACs,namely,top-down and bottom-up methods.Secondly,we overview the application status of HLSACs in three fields:electrocatalysis,thermal catalysis and photocatalysis.Finally,we summarize the development prospects and challenges of HLSACs.展开更多
Sulfur utilization improvement and control of dissolved lithium polysulfide(LiPS;Li_(2)S x,2<x≤8)are cru-cial aspects of the development of lithium-sulfur(Li-S)batteries,especially in high-loading sulfur elec-trode...Sulfur utilization improvement and control of dissolved lithium polysulfide(LiPS;Li_(2)S x,2<x≤8)are cru-cial aspects of the development of lithium-sulfur(Li-S)batteries,especially in high-loading sulfur elec-trodes and low electrolyte/sulfur(E/S)ratios.The sluggish reaction in the low E/S ratio induces poor LiPS solubility and unstable Li_(2)S electrodeposition,resulting in limited sulfur utilization,especially under high-loading sulfur electrode.In this study,we report on salt concentration effects that improve sulfur utilization with a high-loading cathode(6 mgs ulfurcm^(-2)),a high sulfur content(80 wt%)and a low E/S ratio(5 m L gs ulfur^(-1)).On the basis of the rapid LiPS dissolving in a low concentration electrolyte,we estab-lished that the quantity of Li_(2)S electrodeposition from a high Li+diffusion coefficient,referring to the reduction of LiPS precipitation,was significantly enhanced by a faster kinetic.These results demonstrate the importance of kinetic factors for the rate capability and cycle life stability of Li-S battery electrolytes through high Li_(2)S deposition under high-loading sulfur electrode.展开更多
Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loadin...Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loading Fe-SA catalysts by a simple procedure remains challenging.Herein,we report a high-loading(7.5 wt%)Fe-SA/NPC catalyst prepared by carbon-assisted pyrolysis of metal complexes.Both the nitrogen-doped porous carbon(NPC)support with high specific surface area and ο-phenylenediamine(o-PD)play key roles role in the preparation of high-loading Fe-SA/NPC catalysts.The results of X-ray photoelectron spectroscopy,high-angle annular dark-field scanning transmission electron microscopy,and X-ray absorption fine structure spectroscopy experiments show that the Fe atoms are anchored on the carbon carriers in a single-atom site configuration and coordinated with four of the doped nitrogen atoms of the carbon substrates(Fe-N_(4)).The activities of the Fe-SA/NPC catalysts in the oxygen reduction reaction increased with increasing iron loading.The optimized 250Fe-SA/NPC-800 catalyst exhibited an onset potential 0.97 V of and a half-wave potential of 0.85 V.Our study provides a simple approach for the large-scale synthesis of high-loading single-atom catalysts.展开更多
As the persistent concerns regarding sluggish reaction kinetics and insufficient conductivities of sulfur cathodes in all-solid-state Li-S batteries(ASSLSBs),numerous carbon additives and solid-state electrolytes(SSEs...As the persistent concerns regarding sluggish reaction kinetics and insufficient conductivities of sulfur cathodes in all-solid-state Li-S batteries(ASSLSBs),numerous carbon additives and solid-state electrolytes(SSEs)have been incorporated into the cathode to facilitate ion/electron pathways around sulfur.However,this has resulted in a reduced capacity and decomposition of SSEs.Therefore,it is worth exploring neotype sulfur hosts with electronic/ionic conductivity in the cathode.Herein,we present a hybrid cathode composed of few-layered S/MoS_(2)/C nanosheets(<5 layers)that exhibits high-loading and long-life performance without the need of additional carbon additives in advanced ASSLSBs.The multifunctional MoS_(2)/C host exposes the abundant surface for intimate contacting sites,in situ-formed LixMoS_(2)during discharging as mixed ion/electron conductive network improves the S/Li2S conversion,and contributes extra capacity for the part of active materials.With a high active material content(S+MoS_(2)/C)of 60 wt%in the S/MoS_(2)/C/Li_(6)PS_(5)Cl cathode composite(the carbon content is only~3.97 wt%),the S/MoS_(2)/C electrode delivers excellent electrochemical performance,with a high reversible discharge capacity of 980.3 mAh g^(-1)(588.2 mAh g^(-1)based on the whole cathode weight)after 100 cycles at 100 mA g^(-1).The stable cycling performance is observed over 3500 cycles with a Coulombic efficiency of 98.5%at 600 mA g^(-1),while a high areal capacity of 10.4 mAh cm^(-2)is achieved with active material loading of 12.8 mg cm^(-2).展开更多
This article investigates the anti-disturbance and stabilization problems for the nonlinear uncertain permanent magnet synchronous motor(PMSM)with stator voltage saturation and unknown load.A smooth switching mechanis...This article investigates the anti-disturbance and stabilization problems for the nonlinear uncertain permanent magnet synchronous motor(PMSM)with stator voltage saturation and unknown load.A smooth switching mechanism is presented to structure the adaptive integral terminal sliding mode control(SMC)strategy.The control design consists of compensation control and nominal control,which improves the rapidity and accuracy of trajectory tracking.The smooth saturation model based on the error function is applied to approximate the voltage saturation phenomenon.Additionally,to deal with the adverse effects of various unknown disturbances,including model parameter uncertainties and unknown external load disturbances,an improved disturbance observer(DO)is proposed.This observer effectively suppresses the fluctuations caused by fixed gain during the starting period of the system.Finally,the experimental results under different conditions show that the proposed strategy has good tracking and disturbance suppression performances.展开更多
Clarifying the gas ingestion mechanism in the turbine disc cavity of marine gas turbines is crucial for ensuring the normal operation of turbines.However, the ingestion is influenced by factors such as the rotational ...Clarifying the gas ingestion mechanism in the turbine disc cavity of marine gas turbines is crucial for ensuring the normal operation of turbines.However, the ingestion is influenced by factors such as the rotational pumping effect, mainstream pressure asymmetry, rotor–stator interaction,and unsteady flow structures, complicating the flow. To investigate the impact of rotor–stator interaction on ingestion, this paper decouples the model to include only the mainstream. This research employs experiments and numerical simulations to examine the effects of varying the flow coefficient through changes in rotational speed and mainstream flow rate. The main objective is to understand the influence of different rotor–stator interactions on the mainstream pressure field, accompanied by mechanistic explanations. The findings reveal inconsistent effects of the two methods for changing the flow coefficient on the mainstream pressure field. Particularly, the pressure distribution on the vane side primarily depends on the mainstream flow rate, while the pressure on the blade side is influenced by the mainstream flow rate and the attack angle represented by the flow coefficient. A larger angle of attack angle can increase pressure on the blade side, even surpassing the pressure on the vane side. Assessing the degree of mainstream pressure unevenness solely based on the pressure difference on the vane side is insufficient. This research provides a basis for subsequent studies on the influence of coupled real turbine rotor–stator interaction on gas ingestion.展开更多
High-density permanent magnet synchronous motors(PMSMs) are widely used in electric drive systems. However, they are susceptible to temperature influences under complex operating conditions, and prolonged operation at...High-density permanent magnet synchronous motors(PMSMs) are widely used in electric drive systems. However, they are susceptible to temperature influences under complex operating conditions, and prolonged operation at high temperatures can first damage the stator winding insulation, which in turn will damage the windings themselves and cause faults. Therefore, stator temperature monitoring is of crucial importance. This paper summarizes the existing temperature monitoring technologies for stator windings of permanent magnet motors, compares the advantages and disadvantages of various methods to help researchers understand this technology, and analyzes its opportunities and challenges, followed by an outlook.展开更多
The outlet flow fields of a low-speed repeating-stage compressor with bowed stator stages are measured with five-hole probe under the near stall condition when the rotor/stator axial gap varies. The performances of th...The outlet flow fields of a low-speed repeating-stage compressor with bowed stator stages are measured with five-hole probe under the near stall condition when the rotor/stator axial gap varies. The performances of the straight stator stages are investigated and compared to those of the bowed stator stages. The results show that using bowed stator stages could alleviate the flow separation at both upper and low corners of the suction surface and the endwalls, and decrease the losses along the flow passage as well as the outlet flow angle. As the rotor/stator axial gap decreases, although the diffusion capacity of the compressor increases obviously, the outlet flow field in the straight stator stages deteriorates quickly. By contrast, little changes occur in the bowed stator stages, indicating that as the rotor/stator axial gap decreases, improved performance is achieved in the bowed stator stages.展开更多
This article is aimed to experimentally validate the beneficial effects of boundary layer suction on improving the aerodynamic performance of a compressor cascade with a large camber angle. The flow field of the casca...This article is aimed to experimentally validate the beneficial effects of boundary layer suction on improving the aerodynamic performance of a compressor cascade with a large camber angle. The flow field of the cascade is measured and the ink-trace flow visualization is also presented. The experimental results show that the boundary layer suction reduces losses near the area of rnidspan in the cascade most effectively for all suction cases under test. Losses of the endwall could remarkably decrease only when the suction is at the position where the boundary layer has separated but still not departed far away from the blade surface. It is evidenced that the higher suction flow rate and the suction position closer to the trailing edge result in greater reduction in losses and the maximum reduction in the total pressure loss accounts to 16.5% for all cases. The suction position plays a greater role in affecting the total pressure loss than the suction flow rate does.展开更多
The control platform of the induction motor （IM） with low costs is developed by using DSP MC56F8013 with a good performance/price rtaio. The control algorithm for the speed sensorless IM is studied based on the stat...The control platform of the induction motor （IM） with low costs is developed by using DSP MC56F8013 with a good performance/price rtaio. The control algorithm for the speed sensorless IM is studied based on the stator flux orientation （SFO）. The algorithm structure is simple to be implemented and cannot be influenced by motor parameters, The improved stator flux estimation is used to compensate errors caused by the low pass filter （LPF）. A new speed regulator is designed to ensure the system working with the maximal torque in the transient state. The system simulation and the prototype experiment are made. Results show that the con- trol system has good dynamic and static performance.展开更多
基金financially supported by Beijing Natural Science Foundation(No.2212018)Beijing Institute of Technology Research Fund Program for Young Scholars(No.2022CX01011)+3 种基金Ningbo 3315 Innovative Teams Program(No.2019A-14-C)the National Natural Science Foundation of China(No.12374390)the Member of Youth Innovation Promotion Association Foundation of CAS,China(No.2023310)the Key Scientific and Technological Special Project of Ningbo City No.(2023Z209)。
文摘It is well known that single-atom catalysts(SACs)have become a hot topic in the field of catalysis due to their advantages such as 100%metal atom utilization efficiency,high catalytic activity and selectivity compared with conventional catalysts and nanocatalysts.However,the isolated metal atoms on SACs have thermodynamic instability and tend to agglomerate,which limit their catalytic performance.Therefore,it is of great significance to synthesize stable and high-loading single-atom catalysts(HLSACs).In this paper,we review the research progress of HLSACs from two aspects:design and application.Firstly,we comprehensively introduce the synthesis strategies of HLSACs,namely,top-down and bottom-up methods.Secondly,we overview the application status of HLSACs in three fields:electrocatalysis,thermal catalysis and photocatalysis.Finally,we summarize the development prospects and challenges of HLSACs.
基金supported by a grant from the Korea Evaluation Institute of Industrial Technology(KEIT)funded by the Ministry of Trade,Industry and Energy(MOTIE)(No.20012341)。
文摘Sulfur utilization improvement and control of dissolved lithium polysulfide(LiPS;Li_(2)S x,2<x≤8)are cru-cial aspects of the development of lithium-sulfur(Li-S)batteries,especially in high-loading sulfur elec-trodes and low electrolyte/sulfur(E/S)ratios.The sluggish reaction in the low E/S ratio induces poor LiPS solubility and unstable Li_(2)S electrodeposition,resulting in limited sulfur utilization,especially under high-loading sulfur electrode.In this study,we report on salt concentration effects that improve sulfur utilization with a high-loading cathode(6 mgs ulfurcm^(-2)),a high sulfur content(80 wt%)and a low E/S ratio(5 m L gs ulfur^(-1)).On the basis of the rapid LiPS dissolving in a low concentration electrolyte,we estab-lished that the quantity of Li_(2)S electrodeposition from a high Li+diffusion coefficient,referring to the reduction of LiPS precipitation,was significantly enhanced by a faster kinetic.These results demonstrate the importance of kinetic factors for the rate capability and cycle life stability of Li-S battery electrolytes through high Li_(2)S deposition under high-loading sulfur electrode.
文摘Iron-based single-atom catalysts with nitrogen-doped carbon as support(Fe-SA/NPC)are considered effective alternatives to replace Pt-group metals for scalable application in fuel cells.However,synthesizing high-loading Fe-SA catalysts by a simple procedure remains challenging.Herein,we report a high-loading(7.5 wt%)Fe-SA/NPC catalyst prepared by carbon-assisted pyrolysis of metal complexes.Both the nitrogen-doped porous carbon(NPC)support with high specific surface area and ο-phenylenediamine(o-PD)play key roles role in the preparation of high-loading Fe-SA/NPC catalysts.The results of X-ray photoelectron spectroscopy,high-angle annular dark-field scanning transmission electron microscopy,and X-ray absorption fine structure spectroscopy experiments show that the Fe atoms are anchored on the carbon carriers in a single-atom site configuration and coordinated with four of the doped nitrogen atoms of the carbon substrates(Fe-N_(4)).The activities of the Fe-SA/NPC catalysts in the oxygen reduction reaction increased with increasing iron loading.The optimized 250Fe-SA/NPC-800 catalyst exhibited an onset potential 0.97 V of and a half-wave potential of 0.85 V.Our study provides a simple approach for the large-scale synthesis of high-loading single-atom catalysts.
基金the financial support from the National Natural Science Foundation of China(T2241003)the National Key Research and Development Program of China(2022YFB4003500)the Key R&D project of Hubei Province,China(2021AAA006)
文摘As the persistent concerns regarding sluggish reaction kinetics and insufficient conductivities of sulfur cathodes in all-solid-state Li-S batteries(ASSLSBs),numerous carbon additives and solid-state electrolytes(SSEs)have been incorporated into the cathode to facilitate ion/electron pathways around sulfur.However,this has resulted in a reduced capacity and decomposition of SSEs.Therefore,it is worth exploring neotype sulfur hosts with electronic/ionic conductivity in the cathode.Herein,we present a hybrid cathode composed of few-layered S/MoS_(2)/C nanosheets(<5 layers)that exhibits high-loading and long-life performance without the need of additional carbon additives in advanced ASSLSBs.The multifunctional MoS_(2)/C host exposes the abundant surface for intimate contacting sites,in situ-formed LixMoS_(2)during discharging as mixed ion/electron conductive network improves the S/Li2S conversion,and contributes extra capacity for the part of active materials.With a high active material content(S+MoS_(2)/C)of 60 wt%in the S/MoS_(2)/C/Li_(6)PS_(5)Cl cathode composite(the carbon content is only~3.97 wt%),the S/MoS_(2)/C electrode delivers excellent electrochemical performance,with a high reversible discharge capacity of 980.3 mAh g^(-1)(588.2 mAh g^(-1)based on the whole cathode weight)after 100 cycles at 100 mA g^(-1).The stable cycling performance is observed over 3500 cycles with a Coulombic efficiency of 98.5%at 600 mA g^(-1),while a high areal capacity of 10.4 mAh cm^(-2)is achieved with active material loading of 12.8 mg cm^(-2).
基金supported by the National Natural Science Foundation under Grant 62273189the Shandong Province Natural Science Foundation under Grant ZR2021MF005Systems Science Plus Joint Research Program of Qingdao University under Grant XT2024201 of China supporting this research work.
文摘This article investigates the anti-disturbance and stabilization problems for the nonlinear uncertain permanent magnet synchronous motor(PMSM)with stator voltage saturation and unknown load.A smooth switching mechanism is presented to structure the adaptive integral terminal sliding mode control(SMC)strategy.The control design consists of compensation control and nominal control,which improves the rapidity and accuracy of trajectory tracking.The smooth saturation model based on the error function is applied to approximate the voltage saturation phenomenon.Additionally,to deal with the adverse effects of various unknown disturbances,including model parameter uncertainties and unknown external load disturbances,an improved disturbance observer(DO)is proposed.This observer effectively suppresses the fluctuations caused by fixed gain during the starting period of the system.Finally,the experimental results under different conditions show that the proposed strategy has good tracking and disturbance suppression performances.
基金the National Natural Science Foundation Outstanding Youth Foundation (Grant No.52122603)the National Science and Technology Major Project (J2019-Ⅲ-0003–0046)。
文摘Clarifying the gas ingestion mechanism in the turbine disc cavity of marine gas turbines is crucial for ensuring the normal operation of turbines.However, the ingestion is influenced by factors such as the rotational pumping effect, mainstream pressure asymmetry, rotor–stator interaction,and unsteady flow structures, complicating the flow. To investigate the impact of rotor–stator interaction on ingestion, this paper decouples the model to include only the mainstream. This research employs experiments and numerical simulations to examine the effects of varying the flow coefficient through changes in rotational speed and mainstream flow rate. The main objective is to understand the influence of different rotor–stator interactions on the mainstream pressure field, accompanied by mechanistic explanations. The findings reveal inconsistent effects of the two methods for changing the flow coefficient on the mainstream pressure field. Particularly, the pressure distribution on the vane side primarily depends on the mainstream flow rate, while the pressure on the blade side is influenced by the mainstream flow rate and the attack angle represented by the flow coefficient. A larger angle of attack angle can increase pressure on the blade side, even surpassing the pressure on the vane side. Assessing the degree of mainstream pressure unevenness solely based on the pressure difference on the vane side is insufficient. This research provides a basis for subsequent studies on the influence of coupled real turbine rotor–stator interaction on gas ingestion.
基金supported by the National Key R&D Program of China (2021YFB2500600)。
文摘High-density permanent magnet synchronous motors(PMSMs) are widely used in electric drive systems. However, they are susceptible to temperature influences under complex operating conditions, and prolonged operation at high temperatures can first damage the stator winding insulation, which in turn will damage the windings themselves and cause faults. Therefore, stator temperature monitoring is of crucial importance. This paper summarizes the existing temperature monitoring technologies for stator windings of permanent magnet motors, compares the advantages and disadvantages of various methods to help researchers understand this technology, and analyzes its opportunities and challenges, followed by an outlook.
基金National Natural Science Foundation of China (50646021)Chinese Specialized Research Fund for the Doctoral Pro-gram of Higher Education (20060213007)
文摘The outlet flow fields of a low-speed repeating-stage compressor with bowed stator stages are measured with five-hole probe under the near stall condition when the rotor/stator axial gap varies. The performances of the straight stator stages are investigated and compared to those of the bowed stator stages. The results show that using bowed stator stages could alleviate the flow separation at both upper and low corners of the suction surface and the endwalls, and decrease the losses along the flow passage as well as the outlet flow angle. As the rotor/stator axial gap decreases, although the diffusion capacity of the compressor increases obviously, the outlet flow field in the straight stator stages deteriorates quickly. By contrast, little changes occur in the bowed stator stages, indicating that as the rotor/stator axial gap decreases, improved performance is achieved in the bowed stator stages.
基金National Basic Research Program of China (2007CB210100)National Natural Science Foundation of China (50876023)Chinese Specialized Research Fund for the Doctoral Program of Higher Education (20060213007)
文摘This article is aimed to experimentally validate the beneficial effects of boundary layer suction on improving the aerodynamic performance of a compressor cascade with a large camber angle. The flow field of the cascade is measured and the ink-trace flow visualization is also presented. The experimental results show that the boundary layer suction reduces losses near the area of rnidspan in the cascade most effectively for all suction cases under test. Losses of the endwall could remarkably decrease only when the suction is at the position where the boundary layer has separated but still not departed far away from the blade surface. It is evidenced that the higher suction flow rate and the suction position closer to the trailing edge result in greater reduction in losses and the maximum reduction in the total pressure loss accounts to 16.5% for all cases. The suction position plays a greater role in affecting the total pressure loss than the suction flow rate does.
文摘The control platform of the induction motor （IM） with low costs is developed by using DSP MC56F8013 with a good performance/price rtaio. The control algorithm for the speed sensorless IM is studied based on the stator flux orientation （SFO）. The algorithm structure is simple to be implemented and cannot be influenced by motor parameters, The improved stator flux estimation is used to compensate errors caused by the low pass filter （LPF）. A new speed regulator is designed to ensure the system working with the maximal torque in the transient state. The system simulation and the prototype experiment are made. Results show that the con- trol system has good dynamic and static performance.
